CN106240005B - Low-shrinkage plastic floor - Google Patents
Low-shrinkage plastic floor Download PDFInfo
- Publication number
- CN106240005B CN106240005B CN201610834520.1A CN201610834520A CN106240005B CN 106240005 B CN106240005 B CN 106240005B CN 201610834520 A CN201610834520 A CN 201610834520A CN 106240005 B CN106240005 B CN 106240005B
- Authority
- CN
- China
- Prior art keywords
- layer
- base layer
- parts
- wear
- deformation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 41
- 239000004033 plastic Substances 0.000 title claims abstract description 41
- 238000005187 foaming Methods 0.000 claims abstract description 14
- 239000002585 base Substances 0.000 claims description 55
- -1 acrylic ester Chemical class 0.000 claims description 33
- 239000011248 coating agent Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 26
- 239000002994 raw material Substances 0.000 claims description 19
- 229920002635 polyurethane Polymers 0.000 claims description 17
- 239000004814 polyurethane Substances 0.000 claims description 17
- 239000003085 diluting agent Substances 0.000 claims description 15
- 238000009408 flooring Methods 0.000 claims description 15
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 12
- 239000002262 Schiff base Substances 0.000 claims description 11
- 150000004753 Schiff bases Chemical class 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 11
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 8
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 8
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical group C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 7
- 230000001678 irradiating effect Effects 0.000 claims description 7
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 2
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract description 4
- 230000008602 contraction Effects 0.000 abstract description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 22
- 229920000915 polyvinyl chloride Polymers 0.000 description 22
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 10
- 239000006260 foam Substances 0.000 description 8
- 239000012046 mixed solvent Substances 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000005281 excited state Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000003504 photosensitizing agent Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- PQCLJXVUAWLNSV-UHFFFAOYSA-N 5-Methyl-2,3-hexanedione Chemical compound CC(C)CC(=O)C(C)=O PQCLJXVUAWLNSV-UHFFFAOYSA-N 0.000 description 1
- 102100035474 DNA polymerase kappa Human genes 0.000 description 1
- 101710108091 DNA polymerase kappa Proteins 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 241001077885 Gesta Species 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2471/00—Floor coverings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Floor Finish (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a low shrinkage plastic floor, which comprises a base layer, an elastic foaming layer, a printing film layer and a wear-resistant layer are sequentially arranged above the base layer, the base layer is provided with shading on one surface contacted with the ground, an anti-deformation layer with low shrinkage rate is arranged in the base layer, and the anti-deformation layer divides the base layer into an upper base layer and a lower base layer. According to the invention, the deformation prevention layer is arranged in the base layer, so that the thermal expansion and cold contraction performances of the whole plastic floor are reduced through the deformation prevention layer, the stability of the plastic floor is enhanced, the structure is simple, the construction is convenient, the local PVC floor can be simply replaced, the plastic floor is not easy to deform, and the service life is long.
Description
Technical Field
The invention relates to the field of floors, in particular to a low-shrinkage plastic floor.
Background
The plastic floor is a plastic bottom surface decorative material, and has various designs, light weight, wear resistance, good use function and low price. The plastic floor is classified according to the shape of the floor and can be divided into a block floor and a coiled material floor, wherein the block floor is convenient to transport and spread and is internally provided with a large amount of filler, and has the advantages of low price, smoke end burning resistance, pollution resistance, good wear resistance, easy replacement after damage and the like.
At present, the paving method of the block floor generally adopts adhesive to adhere the bottom plate to the bottom surface or connect the floors by non-setting adhesive, or the floors are connected and paved in a buckling manner. Before paving, complex bottom surface treatment such as self-leveling and waterproof treatment should be carried out. If the adhesive is used, the construction must be carried out by professional personnel, which is time-consuming and labor-consuming, and the phenomena of floor degumming, warping, cracking or arching can occur slightly carelessly, thus affecting the use and the beautiful appearance. Therefore, finding a plastic floor with simple structure, convenient laying and excellent performance is a common goal for industry personnel.
In the filed chinese patent 200910041835.0, the present inventors have proposed a block plastic flooring, which has a weight greater than that of other block plastic flooring by 7kg to 11kg per square meter, and has a ground-contacting surface provided with a ground pattern, so that sliding does not easily occur after laying. The appearance of the blocky plastic floor has profound influence on the laying process, and the blocky plastic floor can be laid on the relatively flat ground without using adhesives, and does not need professional technicians to carry out construction.
The inventors of the present invention filed a PCT application entitled "bulk plastic flooring" at 12/27 of 2010, having application number PCT/CN2010/080324, the PCT application is a further improvement proposal based on Chinese patent 200910041835.0, A PVC anti-slip film is pressed on one surface of the block plastic floor, which is contacted with the ground, and comprises 56% of polyvinyl chloride, 40% of plasticizer DINP, 2.5% of stabilizer and 1.5% of pigment by weight, wherein one surface of the PVC anti-slip film, which is contacted with the ground, is provided with anti-slip patterns. In this PCT application, the design of the slip-resistant film provides a more excellent slip-resistant effect to the bulk plastic flooring.
The PVC floor board is mainly made of PVC, the PVC floor board is greatly affected by temperature, and the repeated expansion and contraction easily cause the increase of gaps between the PVC floor boards, so that the PVC floor board cannot be recovered.
Disclosure of Invention
In view of the above, the invention discloses a low shrinkage plastic floor.
The aim of the invention is achieved by the following technical scheme:
the utility model provides a low shrinkage plastic floor, includes the basic unit, elastic foaming layer, stamp rete and wearing layer have been set gradually to the basic unit top, the one side of basic unit and ground contact is provided with the shading, be provided with the anti-deformation layer of low shrinkage in the basic unit, anti-deformation layer divide into basic unit and lower basic unit with the basic unit.
The deformation-preventing layer is arranged in the base layer, and tension is generated when the base layer expands with heat and contracts with cold through the deformation-preventing layer, so that the shrinkage deformation of the whole plastic floor is reduced, and the stability is enhanced.
Further, the upper surface of the deformation preventing layer is provided with a plurality of upper grooves, and the lower surface of the deformation preventing layer is provided with a plurality of lower grooves.
By arranging the upper groove and the lower groove on the upper surface and the lower surface of the deformation preventing layer, the bottom of the upper base layer can be fused into the upper groove during production, and the upper part of the lower base layer can be fused into the lower groove, so that the tension of the deformation preventing layer to the base layer is enhanced.
Further, the upper groove and the lower groove are respectively in a rectangular array and the projection areas are overlapped, and the upper groove is communicated with the lower groove.
The upper groove and the lower groove of the rectangular array can homogenize the tension of the deformation-preventing layer to the base layer and prevent the local tension from being excessively concentrated, the upper groove is communicated with the lower groove, the upper base layer and the lower base layer can be fused in the production of the plastic floor, so that the base layer and the deformation-preventing layer are better combined together.
Further, the upper grooves and the lower grooves are staggered and arranged in a rectangular array, the upper grooves are communicated with adjacent lower grooves, and the lower grooves are communicated with adjacent upper grooves.
The upper grooves are communicated with the adjacent lower grooves, and the lower grooves are communicated with the adjacent upper grooves, so that the fusion degree between the upper base layer and the lower base layer can be better enhanced, and the deformation-preventing layer can be better fused into the base layer.
Further, the thickness ratio of the base layer to the elastic foaming layer is 3:1.
The PVC floor mainly depends on the basic form of the basic unit determination, the hardness of the basic unit is higher than that of the elastic foaming layer, the elastic foaming layer is arranged to strengthen the buffering capacity of the PVC floor, meanwhile, due to the fact that the hardness of the wear-resisting layer is higher, the elastic foaming layer is arranged between the wear-resisting layer and the basic unit to strengthen the bonding strength of the wear-resisting layer, and the bending resistance of the PVC floor is enhanced. The thickness ratio of the base layer to the elastic foaming layer is 3:1, so that the shape, bending resistance and bonding strength of the wear-resistant layer of the PVC floor can be well ensured.
Furthermore, the wear-resisting layer is made of PVC, the thickness of the wear-resisting layer is 0.55mm-1mm, and the surface of the wear-resisting layer is also provided with a UV layer.
The service life of the PVC floor mainly depends on the thickness of the wear-resistant layer, the wear-resistant layer with the thickness of 0.55mm can be used for more than 5 years under normal conditions, the wear-resistant layer with the thickness of 1mm can be used for about 20 years under normal conditions, the service life of the base layer and the elastic foaming layer of the PVC floor per se, such as deterioration or elastic failure, and the cost for producing the PVC floor are considered, the wear-resistant layer with the thickness of 0.55-1 mm can meet good service requirements, the surface of the wear-resistant layer is subjected to UV treatment to strengthen the surface hardness of the wear-resistant layer, and the wear resistance of the PVC floor is enhanced.
Further, the UV layer comprises, by weight, 45-55 parts of aliphatic polyurethane acrylic ester, 5-9 parts of aromatic polyurethane acrylic ester, 5-8 parts of reactive diluent, 1-4 parts of photoinitiator, 50-60 parts of solvent and 0.5-0.9 part of auxiliary agent; the auxiliary agent comprises 10% of diethanolamine, 6% of isopropyl titanate, 2% of ferric sulfate, 20% of Schiff base and the balance of polydimethylsiloxane by weight.
Aromatic polyurethane acrylic ester: the aromatic polyurethane acrylic ester has urethane bond in the molecule, can form and hydrogen bond in the middle of the high molecular bond, and the oligomer has excellent wear resistance and flexibility, good resistance to chemicals, high and low temperature resistance, good impact resistance and good adhesive force to a substrate. The aromatic polyurethane acrylate used in the invention has higher mechanical strength, hardness and heat resistance, and low price is the first choice of UV coating. Aliphatic urethane acrylate: the paint is not easy to turn yellow, has light resistance, good weather resistance, low viscosity and good impact resistance. Photoinitiators are classified into cleavage type photoinitiators and hydrogen abstraction type photoinitiators, and are sometimes used with other auxiliary components such as photosensitizers and sensitizers, and function to initiate polymerization by allowing the molecule/photosensitizer to absorb light energy to migrate to an excited state during a broad curing process, and allowing the photoinitiator to transition from a ground state to an excited state after absorbing energy by energy transfer to the photoinitiator, resulting in a chemical change, resulting in an active intermediate. The solvent can be realized by any one of the prior art. Diethanolamine Chinese name 2,2' -dihydroxydiethylamine, diethanolamine; bis-hydroxyethyl amine; 2,2' -iminodiethanol: the English abbreviation DEA can be realized by the prior art. Isopropyl titanate (English name: titanium tetraisopropanolate) is called tetraisopropyl titanate and tetraisopropoxytitanium. The catalyst mainly used for transesterification and condensation reactions in organic synthesis can be realized by any commercial product. The ferric sulfate can be realized by any one of commercial products. Schiff base english name: schiff base is also called Schiff base and mainly refers to organic compounds containing imine or azomethine characteristic groups (-RC=N-) and is usually formed by condensing amine and active carbonyl, and the Schiff base can be realized by any one of the prior art. Polydimethylsiloxane (Polydimethylsiloxane), also known as dimethicone, is a hydrophobic type of silicone material. The polysiloxane has application in various fields of medicines, daily chemicals, foods, buildings and the like, the derivatives of the polysiloxane are hundreds, and the common polysiloxanes mainly comprise: polydimethylsiloxanes, cyclomethylsiloxanes, aminosilicones, polymethylphenylsiloxanes, polyether polysiloxane copolymers. Among them, cyclomethicone is one of the commonly used polysiloxanes. In the invention, any one of the prior art can be selected for implementation. Through verification of a designer, a proper amount of diethanolamine and isopropyl titanate can enable the UV layer to have recoatability and enable the recoated coating to have adhesiveness, when the UV layer of the floor is damaged, the floor is not required to be replaced, the UV layer can be directly recoated, and the service life of the floor can be effectively prolonged. In addition, the hardness of the UV layer can be effectively improved by the ferric sulfate and the Schiff base, so that the UV layer has higher wear resistance.
Further, the reactive diluent is tripropylene glycol diacrylate; the photoinitiator is 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-propanone, 2,4, 6-trimethylbenzoyl diphenyl phosphine oxide; the mixed solvent comprises ketone and alcohol ether, wherein the ketone is one or more of acetone, butanone, methyl-n-amyl ketone and methyl-isovaleryl ketone, and the alcohol ether is one or two of ethylene glycol methyl ether and ethylene glycol ethyl ether.
Preferably, the UV layer further comprises 0.5-1.5 parts of flatting agent and 0.8-1.8 parts of defoaming agent by weight.
The leveling agent and the defoaming agent can be realized by any one of the prior art.
Preferably, the UV layer is formed by uniformly mixing the raw materials, uniformly coating the raw materials on the wear-resistant layer by using a bar coater, and forming the UV layer at a speed of 110-180 mW/cm 2 And (3) irradiating the coating for 80-150 s to cure the coating to obtain the coating.
The invention has the beneficial effects that:
according to the invention, the deformation prevention layer is arranged in the base layer, so that the thermal expansion and cold contraction performances of the whole plastic floor are reduced through the deformation prevention layer, the stability of the plastic floor is enhanced, the structure is simple, the construction is convenient, the local PVC floor can be simply replaced, the plastic floor is not easy to deform, and the service life is long.
Drawings
Fig. 1 is a schematic structural view of the present invention.
Fig. 2 is a schematic view of the structure of the deformation preventing layer according to embodiment 2 of the present invention.
FIG. 3 is a schematic view showing the mechanism of the deformation preventing layer according to embodiment 3 of the present invention.
FIG. 4 is a schematic view of the mechanism of the deformation preventing layer according to embodiment 4 of the present invention.
Detailed Description
For the convenience of understanding by those skilled in the art, the present invention will be described in further detail with reference to the following examples:
example 1
This embodiment provides a low shrinkage plastic flooring, as shown in figure 1,
the anti-deformation foam plastic floor comprises a base layer, wherein an elastic foam layer 3, a printing film layer 4 and a wear-resistant layer 5 are sequentially arranged above the base layer, a ground contact surface of the base layer is provided with shading, an anti-deformation layer 2 with low shrinkage rate is arranged in the base layer, and the anti-deformation layer divides the base layer into an upper base layer 11 and a lower base layer 12.
The thickness ratio of the base layer to the elastic foaming 3 layers is 3:1.
The wear-resisting layer 5 is made of PVC, the thickness of the wear-resisting layer is 0.55mm-1mm, and the surface of the wear-resisting layer 5 is also provided with a UV layer 6.
Example 2
The present embodiment provides a low shrinkage plastic flooring, as shown in figures 1-2,
the anti-deformation foam plastic floor comprises a base layer, wherein an elastic foam layer 3, a printing film layer 4 and a wear-resistant layer 5 are sequentially arranged above the base layer, a ground contact surface of the base layer is provided with shading, an anti-deformation layer 2 with low shrinkage rate is arranged in the base layer, and the anti-deformation layer divides the base layer into an upper base layer 11 and a lower base layer 12.
The upper surface of the deformation preventing layer 2 is provided with a plurality of upper grooves 21, and the lower surface of the deformation preventing layer 2 is provided with a plurality of lower grooves 22.
The thickness ratio of the base layer to the elastic foaming 3 layers is 3:1.
The wear-resisting layer 5 is made of PVC, the thickness of the wear-resisting layer is 0.55mm-1mm, and the surface of the wear-resisting layer 5 is also provided with a UV layer 6.
Example 3
The present embodiment provides a low shrinkage plastic flooring, as shown in figures 1-2,
the anti-deformation foam plastic floor comprises a base layer, wherein an elastic foam layer 3, a printing film layer 4 and a wear-resistant layer 5 are sequentially arranged above the base layer, a ground contact surface of the base layer is provided with shading, an anti-deformation layer 2 with low shrinkage rate is arranged in the base layer, and the anti-deformation layer divides the base layer into an upper base layer 11 and a lower base layer 12.
The upper surface of the deformation preventing layer 2 is provided with a plurality of upper grooves 21, and the lower surface of the deformation preventing layer 2 is provided with a plurality of lower grooves 22.
The upper groove 21 and the lower groove 22 are respectively in rectangular arrays and the projection areas are coincident, and the upper groove 21 is communicated with the lower groove 22.
The thickness ratio of the base layer to the elastic foaming 3 layers is 3:1.
The wear-resisting layer 5 is made of PVC, the thickness of the wear-resisting layer is 0.55mm-1mm, and the surface of the wear-resisting layer 5 is also provided with a UV layer 6.
Example 4
The present embodiment provides a low shrinkage plastic flooring, as shown in figures 1-2,
the anti-deformation foam plastic floor comprises a base layer, wherein an elastic foam layer 3, a printing film layer 4 and a wear-resistant layer 5 are sequentially arranged above the base layer, a ground contact surface of the base layer is provided with shading, an anti-deformation layer 2 with low shrinkage rate is arranged in the base layer, and the anti-deformation layer divides the base layer into an upper base layer 11 and a lower base layer 12.
The upper surface of the deformation preventing layer 2 is provided with a plurality of upper grooves 21, and the lower surface of the deformation preventing layer 2 is provided with a plurality of lower grooves 22.
The upper grooves 21 and the lower grooves 22 are staggered and are in a rectangular array, the upper grooves 21 are communicated with the adjacent lower grooves 22, and the lower grooves 22 are communicated with the adjacent upper grooves 21.
The thickness ratio of the base layer to the elastic foaming 3 layers is 3:1.
The wear-resisting layer 5 is made of PVC, the thickness of the wear-resisting layer is 0.55mm-1mm, and the surface of the wear-resisting layer 5 is also provided with a UV layer 6.
Example 5
The present embodiment provides a low shrinkage plastic flooring, which has the same structure as that of embodiment 1. In particular, the UV layer in this embodiment comprises, by weight, 50 parts of aliphatic urethane acrylate (gesta 306), 7 parts of aromatic urethane acrylate (eubiex EB 205), 6 parts of reactive diluent (eubiex EB 1110), 2 parts of photoinitiator (steam refinement 184), 54 parts of solvent, and 0.8 part of auxiliary agent; the auxiliary agent comprises 10% of diethanolamine, 6% of isopropyl titanate, 2% of ferric sulfate, 20% of Schiff base and the balance of polydimethylsiloxane by weight.
The mixed solvent comprises acetone and ethylene glycol methyl ether, and the acetone and the ethylene glycol methyl ether are mixed according to the mass ratio of 1:1.
Further, the UV layer also comprises 0.9 part of flatting agent (Bayer BYK-3500) and 1.5 parts of defoaming agent (pretty 2700) by weight.
Preferably, the UV layer is formed by uniformly mixing the raw materials, uniformly coating the raw materials on the wear-resistant layer by using a bar coater at a speed of 140mW/cm 2 And (3) irradiating for 100s to cure the coating to obtain the coating.
Example 6
The present embodiment provides a low shrinkage plastic flooring, which has the same structure as that of embodiment 1. Particularly, the raw materials of the UV layer in the embodiment comprise 55 parts of aliphatic polyurethane acrylic ester, 5 parts of aromatic polyurethane acrylic ester, 8 parts of reactive diluent, 1 part of photoinitiator, 60 parts of solvent and 0.5 part of auxiliary agent by weight; the auxiliary agent comprises 10% of diethanolamine, 6% of isopropyl titanate, 2% of ferric sulfate, 20% of Schiff base and the balance of polydimethylsiloxane by weight.
Further, the reactive diluent is tripropylene glycol diacrylate (PPGTA of basf is selected in the embodiment); the photoinitiator is 16992 of the America Dow; the mixed solvent is prepared by mixing butanone and ethylene glycol diethyl ether according to the mass ratio of 1:2.
Further, the UV layer comprises 1.5 parts of flatting agent and 0.8 parts of defoaming agent by weight.
Preferably, the UV layer is formed by uniformly mixing the raw materials, uniformly coating the raw materials on the wear-resistant layer by using a bar coater, and forming the UV layer at 180mW/cm 2 And (3) irradiating for 80s to cure the coating to obtain the coating.
Example 7
The present embodiment provides a low shrinkage plastic flooring, which has the same structure as that of embodiment 1. In particular, the raw materials of the UV layer in the embodiment comprise 45 parts of aliphatic polyurethane acrylic ester, 9 parts of aromatic polyurethane acrylic ester, 5 parts of reactive diluent, 4 parts of photoinitiator, 50 parts of solvent and 0.9 part of auxiliary agent by weight; the auxiliary agent comprises 10% of diethanolamine, 6% of isopropyl titanate, 2% of ferric sulfate, 20% of Schiff base and the balance of polydimethylsiloxane by weight.
Further, the reactive diluent is tripropylene glycol diacrylate
Comparative example 8
The present embodiment provides a low shrinkage plastic flooring, which has the same structure as that of embodiment 1. Particularly, the raw materials of the UV layer in the embodiment comprise 55 parts of aliphatic polyurethane acrylic ester, 5 parts of aromatic polyurethane acrylic ester, 8 parts of reactive diluent, 1 part of photoinitiator, 60 parts of solvent and 0.5 part of auxiliary agent by weight; the auxiliary agent comprises 10% of triethanolamine, 6% of isopropyl titanate, 2% of ferrous sulfate, 20% of Schiff base and the balance of polydimethylsiloxane by weight.
Further, the reactive diluent is tripropylene glycol diacrylate (PPGTA of basf is selected in the embodiment); the photoinitiator is 16992 of the America Dow; the mixed solvent is prepared by mixing butanone and ethylene glycol diethyl ether according to the mass ratio of 1:2.
Further, the UV layer comprises 1.5 parts of flatting agent and 0.8 parts of defoaming agent by weight.
Preferably, the UV layer is formed by uniformly mixing the raw materials, uniformly coating the raw materials on the wear-resistant layer by using a bar coater, and forming the UV layer at 180mW/cm 2 And (3) irradiating for 80s to cure the coating to obtain the coating.
Example 9
The present embodiment provides a low shrinkage plastic flooring, which has the same structure as that of embodiment 1. Particularly, the raw materials of the UV layer in the embodiment comprise 55 parts of aliphatic polyurethane acrylic ester, 5 parts of aromatic polyurethane acrylic ester, 8 parts of reactive diluent, 1 part of photoinitiator, 60 parts of solvent and 0.5 part of auxiliary agent by weight; the auxiliary agent contains 10% by weight of diethanolamine, 2% of ferric sulfate and the balance of polydimethylsiloxane.
Further, the reactive diluent is tripropylene glycol diacrylate (PPGTA of basf is selected in the embodiment); the photoinitiator is 16992 of the America Dow; the mixed solvent is prepared by mixing butanone and ethylene glycol diethyl ether according to the mass ratio of 1:2.
Further, the UV layer comprises 1.5 parts of flatting agent and 0.8 parts of defoaming agent by weight.
Preferably, the UV layer is formed by uniformly mixing the raw materials, uniformly coating the raw materials on the wear-resistant layer by using a bar coater, and forming the UV layer at 180mW/cm 2 And (3) irradiating for 80s to cure the coating to obtain the coating.
Example 10
The present embodiment provides a low shrinkage plastic flooring, which has the same structure as that of embodiment 1. In particular, the raw materials of the UV layer in the embodiment comprise 55 parts of aliphatic polyurethane acrylate, 5 parts of aromatic polyurethane acrylate, 8 parts of reactive diluent, 1 part of photoinitiator and 60 parts of solvent by weight.
Further, the reactive diluent is tripropylene glycol diacrylate (PPGTA of basf is selected in the embodiment); the photoinitiator is 16992 of the America Dow; the mixed solvent is prepared by mixing butanone and ethylene glycol diethyl ether according to the mass ratio of 1:2.
Further, the UV layer comprises 1.5 parts of flatting agent and 0.8 parts of defoaming agent by weight.
Preferably, the UV layer is formed by uniformly mixing the raw materials, uniformly coating the raw materials on the wear-resistant layer by using a bar coater, and forming the UV layer at 180mW/cm 2 And (3) irradiating for 80s to cure the coating to obtain the coating.
And (3) re-coating the surface of the UV layer to obtain a re-coated layer, and testing the performance of the re-coated layer. The results are shown in the following table.
The foregoing is a description of specific embodiments of the invention, which are described in greater detail and are not to be construed as limiting the scope of the invention. It should be noted that modifications and improvements can be made by those skilled in the art without departing from the spirit of the invention, and that these obvious alternatives fall within the scope of the invention.
Claims (2)
1. A low shrinkage plastic floor, characterized in that: the anti-deformation floor comprises a base layer, wherein an elastic foaming layer, a printing film layer and a wear-resistant layer are sequentially arranged above the base layer, the surface of the base layer, which is in contact with the ground, is provided with a shading layer with low shrinkage rate, and the base layer is divided into an upper base layer and a lower base layer by the anti-deformation layer;
the upper surface of the deformation preventing layer is provided with a plurality of upper grooves, and the lower surface of the deformation preventing layer is provided with a plurality of lower grooves;
the upper groove and the lower groove are respectively in a rectangular array and the projection areas are coincident, and the upper groove is communicated with the lower groove; or the upper grooves and the lower grooves are staggered and are in a rectangular array, the upper grooves are communicated with the adjacent lower grooves, and the lower grooves are communicated with the adjacent upper grooves;
the thickness ratio of the base layer to the elastic foaming layer is 3:1;
the wear-resistant layer is made of PVC, the thickness of the wear-resistant layer is 0.55mm-1mm, and the surface of the wear-resistant layer is also provided with a UV layer;
the UV layer comprises, by weight, 45-55 parts of aliphatic polyurethane acrylic ester, 5-9 parts of aromatic polyurethane acrylic ester, 5-8 parts of reactive diluent, 1-4 parts of photoinitiator, 50-60 parts of solvent and 0.5-0.9 part of auxiliary agent; the auxiliary agent comprises 10% of diethanolamine, 6% of isopropyl titanate, 2% of ferric sulfate, 20% of Schiff base and the balance of polydimethylsiloxane by weight;
the reactive diluent is tripropylene glycol diacrylate; the photoinitiator is 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2 methyl-1 phenyl-1 acetone or 2,4, 6-trimethyl benzoyl diphenyl phosphine oxide; the solvent comprises ketone and alcohol ether, wherein the ketone is one or more of acetone, butanone, methyl-n-amyl ketone and methyl-isoprene ketone, and the alcohol ether is one or two of ethylene glycol methyl ether and ethylene glycol ethyl ether;
the UV layer also comprises 0.5-1.5 parts by weight of flatting agent and 0.8-1.8 parts by weight of defoaming agent.
2. The low shrinkage plastic flooring of claim 1, wherein the UV layer is formed by uniformly mixing the raw materials, uniformly coating the raw materials on the abrasion-resistant layer by using a bar coater at a ratio of 110-180 mW/cm 2 And (3) irradiating the coating for 80-150 s to cure the coating to obtain the coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834520.1A CN106240005B (en) | 2016-09-20 | 2016-09-20 | Low-shrinkage plastic floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834520.1A CN106240005B (en) | 2016-09-20 | 2016-09-20 | Low-shrinkage plastic floor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106240005A CN106240005A (en) | 2016-12-21 |
| CN106240005B true CN106240005B (en) | 2023-12-29 |
Family
ID=57599926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610834520.1A Active CN106240005B (en) | 2016-09-20 | 2016-09-20 | Low-shrinkage plastic floor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106240005B (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR200260825Y1 (en) * | 2001-10-16 | 2002-01-17 | 주식회사 금강고려화학 | Heat-resisting film laminated PVC floors with reduced curling |
| CN201593361U (en) * | 2009-12-31 | 2010-09-29 | 春天集团有限公司 | Wood door with deformation preventive balancing structure |
| CN201614723U (en) * | 2010-03-24 | 2010-10-27 | 北京恩宇新型材料有限公司 | Sports floor board |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN202265992U (en) * | 2011-10-25 | 2012-06-06 | 泰州市华丽塑料有限公司 | Composite plastic floor |
| CN202936986U (en) * | 2012-11-29 | 2013-05-15 | 范云蛟 | Deformation prevention solid wood floor |
| CN103758328A (en) * | 2013-12-13 | 2014-04-30 | 浙江晶通塑胶有限公司 | Plastic-wood floor and production method thereof |
| CN104989067A (en) * | 2015-07-20 | 2015-10-21 | 江苏锐升新材料有限公司 | Tough and flexible PVC composite floor with UV protective layer structure |
| CN206085814U (en) * | 2016-09-20 | 2017-04-12 | 惠州市耐宝塑胶制品有限公司 | Low -shrinkage rate plastic floor |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI605943B (en) * | 2015-03-11 | 2017-11-21 | Non-PVC floor tiles |
-
2016
- 2016-09-20 CN CN201610834520.1A patent/CN106240005B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR200260825Y1 (en) * | 2001-10-16 | 2002-01-17 | 주식회사 금강고려화학 | Heat-resisting film laminated PVC floors with reduced curling |
| CN201593361U (en) * | 2009-12-31 | 2010-09-29 | 春天集团有限公司 | Wood door with deformation preventive balancing structure |
| CN201614723U (en) * | 2010-03-24 | 2010-10-27 | 北京恩宇新型材料有限公司 | Sports floor board |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN202265992U (en) * | 2011-10-25 | 2012-06-06 | 泰州市华丽塑料有限公司 | Composite plastic floor |
| CN202936986U (en) * | 2012-11-29 | 2013-05-15 | 范云蛟 | Deformation prevention solid wood floor |
| CN103758328A (en) * | 2013-12-13 | 2014-04-30 | 浙江晶通塑胶有限公司 | Plastic-wood floor and production method thereof |
| CN104989067A (en) * | 2015-07-20 | 2015-10-21 | 江苏锐升新材料有限公司 | Tough and flexible PVC composite floor with UV protective layer structure |
| CN206085814U (en) * | 2016-09-20 | 2017-04-12 | 惠州市耐宝塑胶制品有限公司 | Low -shrinkage rate plastic floor |
Non-Patent Citations (1)
| Title |
|---|
| 章迎尔主编.《建筑装饰丛书之三 建筑装饰材料》.同济大学出版社,2009,238. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106240005A (en) | 2016-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102741221B (en) | Amino (methyl) acrylate of radiation-hardenable | |
| CN102924993B (en) | Acrylate group modified polysiloxanes purposes and composition thereof | |
| CN101084251B (en) | Radiation-hardenable compounds | |
| CN101787229B (en) | Spraying type ultraviolet cured woodware varnish | |
| EP3277760B1 (en) | Scratch resistant coating | |
| KR101417247B1 (en) | In-mold transcription film including elastic texture and method for manufacturing the same | |
| CN109719892A (en) | The manufacturing method of mould internal shaping transfer film, its manufacturing method and mould internal shaping body | |
| JP6384485B2 (en) | Inkjet ink composition for three-dimensional modeling and method for producing three-dimensional modeling | |
| TW201827443A (en) | Fluorine-containing acrylic compound, method for producing the same, and curable composition and article wherein the article has a water-repellent and oil-repellent surface for antifouling | |
| CN102753344A (en) | Hard coating forming method | |
| KR101106565B1 (en) | Composition of one component type dual curing clear coat for car using acrylic modified acrylate and Dual curing system using the same | |
| KR20140045916A (en) | Active-energy-curable resin compositon and coating agent | |
| US9527956B2 (en) | Modified phosphorus-containing unsaturated polyester | |
| KR20160127005A (en) | Surface-modifying agent and article using same | |
| JP6937300B2 (en) | Manufacturing method of resin composition for model material and stereolithography | |
| TW200604238A (en) | Curable resin composition, overcoats, and process for formation thereof | |
| AU2014274547B2 (en) | Hybrid flooring product | |
| CN108948975A (en) | A kind of preparation method and applications of the dual cure metal coating with anti-pollution function | |
| CN107407096A (en) | Construction method is close on contactless ground closing-type Assembly floor and floor | |
| US20180327606A1 (en) | Surface covering having an improved wear layer | |
| CN106240005B (en) | Low-shrinkage plastic floor | |
| JP7068270B2 (en) | Manufacturing method of model material ink set, support material composition, ink set, three-dimensional model and three-dimensional model | |
| KR102060079B1 (en) | Dual curing type hard coating composition and decoration sheet using the same and method of manufacturing the decoration sheet | |
| CN106750318A (en) | A kind of amino-contained silicone acrylates and its preparation method and application | |
| JP2017165804A (en) | Resin composition for model material, and method for manufacturing stereolithographic article |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180820 Address after: 517000 Longling three industrial road, Longping Road, Heyuan, Guangdong. Applicant after: HEYUAN CITY NEBO NEW BUILDING MATERIALS Co.,Ltd. Address before: 516000 Shek Hu tou Industrial Park, Jilong Town, Huidong County, Huizhou, Guangdong, China Applicant before: HUIZHOU NAIBAO PLASTIC PRODUCTS Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20230830 Address after: No. 71, Changgangqi Group, Taiyangsheng Village, Yuancheng District, Heyuan City, Guangdong Province, 517000 Applicant after: Lan Xiaobing Address before: 517000 Longling three industrial road, Longping Road, Heyuan, Guangdong. Applicant before: HEYUAN CITY NEBO NEW BUILDING MATERIALS Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |