CN106232794A - Comprise the Fabrid care composition of polyurethane, polyureas and/or polyurethaneurea polymer - Google Patents

Comprise the Fabrid care composition of polyurethane, polyureas and/or polyurethaneurea polymer Download PDF

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Publication number
CN106232794A
CN106232794A CN201580022334.1A CN201580022334A CN106232794A CN 106232794 A CN106232794 A CN 106232794A CN 201580022334 A CN201580022334 A CN 201580022334A CN 106232794 A CN106232794 A CN 106232794A
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group
alkyl
care composition
independently selected
mixture
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CN106232794B (en
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R·K·帕纳戴克
B·W·克鲁森纳
J·A·曼克浩斯
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Procter and Gamble Ltd
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Procter and Gamble Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

It relates to comprise stickiness to keep compositions and the system of polymer, and the method prepared and use them.Also disclosing the method using such composition, described method includes making fabric contact with Fabrid care composition.

Description

Comprise the Fabrid care composition of polyurethane, polyureas and/or polyurethaneurea polymer
Technical field
It relates to comprise stickiness to keep compositions and the system of polymer, and prepare and use their side Method.
Background technology
When wearing fabric such as clothes, this kind fabric may lose their shape because of the stress and strain in garment fabric Shape, described stress and strain occurs because of the motion of such as wearer every day.Therefore, " stickiness " of clothes is lost, and clothing The outward appearance of clothes and comfort level are lost.In order to alleviate this problem, fiber such as spandex (elastic fiber) is incorporated in some clothes, And/or clothes weave can be changed.Regrettably, this type of solution generally increases the cost of clothes, and must use producing When the fabric of this type of clothes, complete in textile mills.Therefore, if this type of solution is implemented the most from the outset, then cannot Solve this type of " stickiness " problem subsequently.
Therefor it is required that can be in the scheme of solution " stickiness " problem of any time enforcement during fabric life. Applicant provides this type of solution in this article.
Summary of the invention
It relates to comprise stickiness to keep compositions and the system of polymer, and prepare and use their side Method.Also disclosing the method using such composition, described method includes making fabric contact with described Fabrid care composition.
Detailed description of the invention
As used herein, when in claim, article " " and " a kind of " are understood to mean and are wanted by right Ask book protection or one or more materials described.
As used herein, " comprising " refers to can be in conjunction with the various components in preparing for disclosure compositions.Therefore, term " substantially by ... composition " and " Consists of " are included in during term " comprises ".
As used herein, " Fabrid care composition " includes the compositions for hand-washing, machine-washing, compositions of additives, fits For soaking and/or compositions, rinse added compositions, spray and the ironing aids of the dirty fabric of pretreatment.Fabric nursing group Compound can take the following form, and such as liquid and granule laundry detergent compositions, fabric conditioner, other washing, rinsing, dehydrator add Add product such as sheet material and spray, capsule encapsulating and/or dosage composition, ironing aids, fabric spray on dry fabric Agent or for comprising the compositions of two or more common separation phases of distribution.The Fabrid care composition of liquid form is general It is present in aqueous carrier, and typically there are about 1 to about 2000 centipoise (1-2000mPa*s), or about 200 to about 800 centipoises (200-800mPa*s) viscosity.Viscosity can be measured by this area conventional method easy to know.Described term also includes water content Low or concentrated type preparation, as comprised less than about 50%, or less than about 30%, or those of less than about 20% water or other carrier.
As used herein, term " substituted " refers to chemical acceptable part such as hydroxyl, amine, aryl, alkoxyl, carboxylic Perester radical, phosphate-based or sulfate group replacement H.
As used herein, term " includes ", " comprising " and " containing " is intended to nonrestrictive.
Except as otherwise noted, all components or composition levels are all for the active part of this component or compositions, And do not include the impurity being likely to be present in the commercial source of these components or compositions, such as residual solvent or by-product.
Should be appreciated that each greatest measure limit provided in this manual includes each lower numerical limitation, as This type of lower numerical limitation is expressly written herein in this article.The each minimum value limit be given in this manual will include Each higher numerical limitation, as this type of higher numerical limitation is expressly written herein in this article.Be given in this manual Each numerical range will include falling each narrower numerical range in this type of wider numerical range, such as this type of narrower numerical value model It is trapped among and is expressly written herein herein.
The form of compositions.Described compositions can be any liquid form, such as liquid or gel form, or they appoint What combination.Described compositions can be any unit dosage forms, such as pouch.But, the compositions of the most highly preferred gel form.
Finished product laundry detergent composition, fabric treatment composition and/or fabric that described compositions can be complete strengthen Agent.In one aspect, described compositions more than can be incorporated into the laundry detergent composition group in laundry detergent composition Point, it is complete finished product laundry detergent composition.In one aspect, during the inventive method, also can make rinse-added Compositions of additives (such as fabric conditioner or reinforcing agent) or main laundry additive composition (such as bleaching additive) and institute Stating liquid laundry detergent composition to be applied in combination, this is in scope.In one aspect, in the inventive method phase Between, it is applied in combination with described laundry detergent composition without bleaching compositions of additives.
In one aspect, disclosing Fabrid care composition, described compositions comprises:
A) based on total Fabrid care composition weight meter about 0.01% to about 30%, preferably about 0.01% to about 20%, The most about 0.1% to about 10%, the organic siloxane polymer of the most about 0.5% to about 5%, described organic silica Alkane polymer has with following formula I, Formula II or formula III:
Described Formulas I comprises totally 1 to about 200 Q, and described Formula II comprises 2 to about 200 Q,
Each Q in Formulas I and II is independently selected from following formula IV, Formula V and Formula IV:
Wherein for each of Formulas I to VI:
(i) each X independently selected fromAnd combinations thereof；
(ii) each L is divalent alkyl linking group, the most each L independently selected from-(CH2)s-；Most preferably L is-(CH2)s-；
(iii) at least one, preferably at least two, more preferably at least three R-portion be-OR2, and all other R-portion is independently selected from H, C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted Aromatic yl group, C7-C20Kiki fang alkyl group and combinations thereof, in one aspect, 1 to 6, preferably 2 to 6, more preferably 2 to 4 R-portion are-OR2, and described R-portion and end Si covalent bond；
(iv) each R1Independently selected from H, C1-C20Alkyl group, C6-C10Aromatic yl group, C1-C4Substituted alkyl group, And C6-C10Group of naphthene base；Preferably, each R1Independently selected from H and C1-C4Alkyl group；It is highly preferred that each R1For H；
(v) each R2Independently selected from H, C1-C4Alkyl group ,-C (O) R6, the most each R6Independently selected from C1-C20Alkane Base group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted aromatic yl group and C7-C20Alkylaryl Group；
(vi) each R3Independently selected from comprise 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, more preferably 6 to The aromatic group of 14 carbon atoms, comprises 2 to 30 carbon atoms, preferably 2 to 20 carbon atoms, more preferably 2 to 14 carbon The aliphatic group of atom, and comprise 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, more preferably 6 to 14 carbon atoms Alicyclic group；And
(vii) each R4Independently selected from H, C1-C20Alkyl group, C6-C10Aromatic yl group, C1-C4Substituted alkyl base Group and C6-C10Group of naphthene base；Preferably, each R4Independently selected from H and C1-C4Alkyl group；It is highly preferred that each R4For H；
(viii) each R5Independently selected from H, C1-C4Alkyl group, C1-C4Substituted alkyl group, C6-C10Aryl base Group and C6-C10Substituted aromatic yl group；Preferably, each R5Independently selected from H and C1-C2Alkyl group；
(ix) each W inserts described C independently selected from optionally comprising at least one1-C200The heteroatomic C of chain1-C200 Alkylidene group, or optionally comprise the described C of at least one insertion1-C200The hetero atom of chain and/or optionally comprise at least one The heteroatomic substituted C of the described substituent group of individual insertion1-C200Alkylidene group；Preferably, each W is independently selected from optionally Comprise at least one and insert described C1-C100The heteroatomic C of chain1-C100Alkylidene group, or it is slotting optionally to comprise at least one Enter described C1-C100The hetero atom of chain and/or optionally at least one inserts the heteroatomic substituted C of described substituent group1-C100Sub- Alkyl group；Preferably, described C1-C100Chain is inserted by least one hetero atom；It is highly preferred that each W is independently selected from optionally Ground comprises at least one and inserts described C1-C10The hetero atom of chain and/or optionally at least one inserts the hetero atom of described substituent group Substituted C1-C10Alkylidene group；Preferably, each W independently selected from Wherein forR5With y as the most previously described
X () p is about 2 to about 2000, preferably about 2 to about 1000, the most about 10 to about 400, the most about 20 To the integer of about 200；
(xi) s is about 2 to about 83, preferably about 2 to about 10, the integer of the most about 2 to about 4；
(xii) y is about 1 to about 50, preferably about 1 to about 20, the integer of the most about 1 to about 10；
(xiii) n is about 0 to about 50, preferably about 1 to about 50, the most about 1 to about 20, and the most about 1 to about The integer of 10；
(xiv) k is selected from 0 to about 100, preferably about 1 to about 50, the integer of the most about 5 to about 20；With
B) optional have formula Si (R7)m(OR8)jMaterial, wherein said index j is 1 to 4, and described exponent m= 4-j, and each R7Independently selected from C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20 Substituted aromatic yl group and C7-C20Kiki fang alkyl group, it is preferable that R7Comprise double bond, and each R8Independently selected from H, C1- C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted aromatic yl group, C7-C20Alkyl virtue Base group and-C (O) R9, the most each R9Independently selected from C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Virtue Base group, C6-C20Substituted aromatic yl group and C7-C20Kiki fang alkyl group；
C) optionally, dicyandiamide solution
D) optionally, carrier；With
E) optional surfactant based on total Fabrid care composition weight meter about 0.1% to about 95%.
In one aspect, disclosing Fabrid care composition, described compositions comprises:
A. based on total Fabrid care composition weight meter about 0.01% to about 30%, preferably about 0.01% to about 20%, The most about 0.1% to about 10%, the organic siloxane polymer of the most about 0.5% to about 5%, described organic silica Alkane polymer comprises at least one repetitive with formula (I):
Wherein
(i) each X independently selected fromAnd combinations thereof；
(ii) each L is divalent alkyl linking group, or independently selected from-(CH2)s-；And combinations thereof；
(iii) at least one, the R-portion of preferably at least two, more preferably at least three Formulas I be-OR2, and institute There is other R-portion independently selected from H, C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20 Substituted aromatic yl group, C7-C20Kiki fang alkyl group and combinations thereof, in one aspect, 1 to 6, preferably 2 to 6, more Preferably 2 to 4 R-portion are-OR2, and described R-portion and end Si covalent bond；
(iv) each R1Independently selected from H, C1-C20Alkyl group, C6-C10Aromatic yl group, C1-C4Substituted alkyl group, And C6-C10Group of naphthene base；Preferably, each R1Independently selected from H and C1-C4Alkyl group；It is highly preferred that each R1For H；
(v) each R2Independently selected from H, C1-C4Alkyl group ,-C (O) R6, the most each R6Independently selected from C1-C20Alkane Base group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted aromatic yl group and C7-C20Alkylaryl Group；
(vi) each R3Independently selected from comprise 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, more preferably 6 to The aromatic group of 14 carbon atoms, comprises 2 to 30 carbon atoms, preferably 2 to 20 carbon atoms, more preferably 2 to 14 carbon The aliphatic group of atom, and comprise 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, more preferably 6 to 14 carbon atoms Alicyclic group；And
(vii) each R4Independently selected from H, C1-C20Alkyl group, C6-C10Aromatic yl group, C1-C4Substituted alkyl base Group and C6-C10Group of naphthene base；Preferably, each R4Independently selected from H and C1-C4Alkyl group；It is highly preferred that each R4For H；
(viii) each R5Independently selected from H, C1-C4Alkyl group, C1-C4Substituted alkyl group, C6-C10Aryl base Group and C6-C10Substituted aromatic yl group；Preferably, each R5Independently selected from H and C1-C2Alkyl group；
(ix) each W inserts described C independently selected from optionally comprising at least one1-C200The heteroatomic C of chain1-C200 Alkylidene group；Preferably, each W inserts described C independently selected from optionally comprising at least one1-C100Chain heteroatomic C1-C100Alkylidene group, it is preferable that described C1-C100Chain is inserted by least one hetero atom；It is highly preferred that each W is independently Described C is inserted selected from optionally comprising at least one1-C10The heteroatomic substituted C of chain1-C10Alkylidene group；
X () p is about 2 to about 2000, preferably about 2 to about 1000, the most about 10 to about 400, the most about 20 To the integer of about 200；
(xi) s is about 2 to about 83, preferably about 2 to about 10, the integer of the most about 2 to about 4；
(xii) y is about 1 to about 50, preferably about 1 to about 20, the integer of the most about 1 to about 10；
(xiii) n is about 0 to about 50, preferably about 1 to about 50, the most about 1 to about 20, and the most about 1 to about The integer of 10；
(xiv) k is selected from 0 to about 100, preferably about 1 to about 50, the integer of the most about 5 to about 20；With
The most optional has formula Si (R7)m(OR8)jMaterial, wherein said index j is 1 to 4, and described exponent m= 4-j, and each R7Independently selected from C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20 Substituted aromatic yl group and C7-C20Kiki fang alkyl group, it is preferable that R7Comprise double bond, and each R8Independently selected from H, C1- C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted aromatic yl group, C7-C20Alkyl virtue Base group and-C (O) R9, the most each R9Independently selected from C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Virtue Base group, C6-C20Substituted aromatic yl group and C7-C20Kiki fang alkyl group；
The most optional dicyandiamide solution
The most optional carrier；With
E. optional surfactant based on total Fabrid care composition weight meter about 0.1% to about 95%.
At an aspect of described Fabrid care composition, described organic siloxane polymer comprises with total organosiloxane Polymer weight meter about 5% to about 100%, preferably about 20% to about 100%, or the most about 50% to about 100% There is the described repetitive of formula (I).
At an aspect of described Fabrid care composition, 1 to 20, preferably 1 to 10, the R of more preferably 2 to 6 Formulas I Part is-OR2。
At an aspect of described Fabrid care composition, described dicyandiamide solution is about-0.180 to about selected from ClogP The solvent of 3.764, it is preferable that described solvent selected from water, glycerol, polyglycereol, ethylene glycol, diethylene glycol, Polyethylene Glycol, propylene glycol, Dipropylene glycol, polypropylene glycol, butanediol, monoethanolamine, diethanolamine and triethanolamine, methyl diethanolamine, diglycol monotertiary first Ether, an acetin and diacetine, methanol and their mixture.
At an aspect of described Fabrid care composition, described solvent selected from ethanol, acetic acid, 1-propanol, n-butyl alcohol, 2- Propanol, acetonitrile, the tert-butyl alcohol, dimethylformamide, acetone, 1,2-dichloroethanes, dichloromethane, chloroform, ethyl acetate, tetrahydrochysene furan Mutter, dioxane, methyl tertiary butyl ether(MTBE), ether, benzene, toluene, butyl cellosolve, butyl carbitol, hexanediol, water, sweet Oil, polyglycereol, ethylene glycol, diethylene glycol, Polyethylene Glycol, propylene glycol, dipropylene glycol, polypropylene glycol, butanediol, monoethanolamine, two Ethanolamine and triethanolamine, methyl diethanolamine, diethylene glycol monomethyl ether, an acetin and diacetine, methanol, with And their mixture.
At an aspect of described Fabrid care composition, described Fabrid care composition comprises the weight by described compositions The quaternary ammonium compound being suitable to softening fabrics of gauge 1% to 49%, and the spice of 0.1% to 3%.
At an aspect of described Fabrid care composition, described carrier is selected from polymer, wax, salt and theirs is mixed Compound, it is preferable that described polymer is selected from polysaccharide, Polyethylene Glycol and their mixture, and described salt is selected from detergent Builder.
At an aspect of described Fabrid care composition, described surfactant is selected from:
A. anion surfactant, it is preferable that described anion surfactant is selected from alkylbenzenesulfonate, alkyl sulfide Hydrochlorate and alkyl aryl sulfate, alkyl carboxylate and alkylaryl carboxylic acids's salt, alkyl ethoxy sulfate, alkyl glycerol base sulphur Hydrochlorate, ammonium lauryl sulfate, sodium lauryl sulfate, sodium laureth sulfate, linear alkylbenzene sulfonate (LAS) and it Mixture；
B. cationic surfactant, the most described cationic surfactant is selected from alkyl trimethyl ammonium salt, spermaceti Base trimethylammonium bromide, CTAB, cetyl pyridinium chloride, quaternary surfactant, ester quaternary ammonium compound, And their mixture；
C. amphoteric surfactant, the most described amphoteric surfactant is selected from cocoamidopropyl, the moon Osmanthus amido propyl betaine, oleoyl amidopropyl betaine, Oleum Ricini amido propyl betaine, cetyl betaine and Dimerization Asia oleoyl amidopropyl betaine, sulfobetaines, hydroxyl sulfo betaine and thetine (sultaines), oxygen Change amine and their mixture；
D. nonionic surfactant, the most described nonionic surfactant is selected from polyoxyalkylene glycol alkyl Ether, alkyl ethoxylate, glucoside alkyl ether, polyoxyalkylene glycol octyl phenol ether, polyoxyalkylene glycol alkylbenzene 2, 2-Oxydiphenol and their mixture；
E. their mixture.
At an aspect of described Fabrid care composition, there is formula Si (R7)mO(R8)jDescribed material selected from single alcoxyl Base silane, monovinylphenyl silane, dialkoxy silicane, diacetoxy silane, trialkoxy silane, triacetoxyl group silicon Alkane, tetraalkoxysilane, four acetoxylsilanes and their mixture.
An aspect at described Fabrid care composition:
The most described monoalkoxysilane is selected from methoxytrimethylsilane, ethoxytrimethylsilane, (3-aminopropyl) Ethyoxyl dimethylsilane, (3-aminopropyl) methoxyl group dimethylsilane, 2-(trimethylsiloxy)-1-amino second Alkane and their mixture；
The most described monovinylphenyl silane is acetoxytrimethylsilane；
The most described dialkoxy silicane is selected from dimethoxydimethylsilane, 2-amino-ethyl-3-amino propyl methyl two Methoxy silane, dimethyldiethoxysilane, (3-aminopropyl) methyldiethoxysilane, 3-amino propyl methyl diformazan TMOS and their mixture；
The most described diacetoxy silane is diacetoxy dimethylsilane；
The most described trialkoxy silane is selected from (3-aminopropyl) triethoxysilane, (3-aminopropyl) trimethoxy silicon Alkane, 3-(N-amino-ethyl) TSL 8330, MTMS, MTES, (amino Methyl) trimethoxy silane and (diethylamino) MTES and their mixture；
The most described triacetoxysilane selected from triacetoxyl group methyl-monosilane, triacetoxyl group ethylsilane and it Mixture；And
The most described tetraalkoxysilane is selected from tetramethoxy-silicane, tetraethoxysilane and their mixture.
At an aspect of described Fabrid care composition, described Fabrid care composition comprises based on total fabric nursing group The polymer weight material comprising aldehyde and/or ketone groups less than 2%.
At an aspect of described Fabrid care composition, described surfactant is selected from straight or branched alkyl benzene sulphonate Salt, alkyl sulfate, alkyl ethoxy sulfate, alkyl ethoxylate, alkyl glycerol sulfonate, quaternary ammonium surfactant Agent, ester quaternary ammonium compound and their mixture.
At an aspect of described Fabrid care composition, described Fabrid care composition comprises auxiliary agent, and described auxiliary agent selects From delivery enhancer, fluorescent whitening agent, enzyme, rheology modifier, builder and their mixture.
At an aspect of described Fabrid care composition, described Fabrid care composition comprises delivery enhancer.
At an aspect of described Fabrid care composition, described delivery enhancer comprises clean cationic charge density and is about The cationic polymer of 0.05meq/g to about 23meq/g.
At an aspect of described Fabrid care composition, described delivery enhancer is that clean cationic charge density is about The cationic polymer of 0.05meq/g to about 23meq/g.
At an aspect of described Fabrid care composition, described Fabrid care composition comprises 0.01 weight % to about The stabilizer of 0.3 weight %.
At an aspect of described Fabrid care composition, described stabilizer includes the hydroxyl stabilizer of crystallization.
At an aspect of described Fabrid care composition, described stabilizer is the hydroxyl stabilizer of crystallization.
At an aspect of described Fabrid care composition, described Fabrid care composition is rinse added compositions shape Formula.
At an aspect of described Fabrid care composition, described Fabrid care composition is laundry detergent compositions.
At an aspect of described Fabrid care composition, described Fabrid care composition has at least 1.1, preferably about 1.1 to about 2.2, the index of recovery (I of preferably about 1.2 to about 1.8R)。
The position that method & is processed
In one aspect, disclosing the method providing beneficial effect to fabric, described method includes making described fabric and knitting Thing care composition contact, described Fabrid care composition selected from Fabrid care composition disclosed herein and they Mixture.
At an aspect of described method, described fabric is the form of finished garment, and by described clothes transmission or After being sold to consumer, described clothes is made to contact with described Fabrid care composition.
In one aspect, disclosing position, described position comprises organic siloxane polymer concentrated product, described organosilicon Oxygen alkane polymer comprises at least one repetitive with upper formula (I).Preferably, described position comprises about 20 microgram polymerizations Thing/gram position is to about 0.1 gram of polymer/gram position, it is highly preferred that described position comprises about 100 microgram polymer/gram position extremely About 3,000 microgram polymer/gram position, it is preferable that described position is fabric and/or clothes.
Auxiliary component
Detersive surfactant.Described detersive surfactant generally comprises anionic detersive surfactant and nonionic Surfactant, the most preferably, anionic detersive surfactant is more than with the weight ratio of non-ionic detersive surfactant 1:1, preferably more than 1.5:1, or even greater than 2:1, or even greater than 2.5:1, or more than 3:1.
Described compositions preferably comprises detersive surfactant, preferably comprises 10 weight % to 40 weight %, preferably Ground 12 weight %, or 15 weight %, or the detersive surfactant of even 18 weight %.Preferably, described surfactant bag Include alkylbenzenesulfonate and one or more decontamination cosurfactants.Described surfactant preferably comprises C10-C13Alkane Base benzene sulfonate and one or more cosurfactants.Described cosurfactant is preferably chosen from C12-C18Alkyl second Epoxide alcohol, it is therefore preferred to have the average degree of ethoxylation of 1 to 7；C12-C18Alkyl ethoxylated sulfate, it is therefore preferred to have 1 To the average degree of ethoxylation of 5；And their mixture.But, other surfactant system is applicable to the present invention.
Suitable detersive surfactant includes anionic detersive surfactant, non-ionic detersive surfactant, sun Ion detersive surfactant, zwitterionic detersive surfactants, amphoteric detersive surfactants and their mixing Thing.
Suitable anionic detersive surfactant includes: alkyl sulfate；Alkylsulfonate；Alkylphosphonic；Alkyl Phosphonate；Alkyl carboxylate；And their mixture.Described anion surfactant is selected from: C10-C18Benzene sulfonamide Hydrochlorate (LAS), preferably C10-C13Alkylbenzenesulfonate；C10-C20The primary alkyl sulphates (AS) of side chain, straight chain and random chain, It is generally of following formula:
CH3(CH2)xCH2-OSO3 -M+
Wherein, M is for hydrogen or provides electroneutral cation, and preferred cation is sodium and ammonium cation, and wherein x is at least 7, the integer of preferably at least 9；C10-C18Secondary (2,3) alkyl sulfate, it is generally of following formula:
Wherein, M is for hydrogen or provides electroneutral cation, and preferred cation includes sodium and ammonium cation, wherein x be to Few 7, the integer of preferably at least 9, y is at least 8, the integer of preferably at least 9；C10-C18Alkyl alkoxy carboxylates；Middle chain Branched alkyl sulfate；Modified alkylbenzenesulfonate (MLAS)；Methyl ester sulfonate (MES)；Alpha-alkene sulfonate (AOS), And their mixture.
Preferably anionic detersive surfactant includes: alkyl benzene sulphonate straight or branched, substituted or unsubstituted Salt detersive surfactant, preferably straight chain C8-C18Alkyl sulphate detersive surfactant；Straight or branched, replacement Or unsubstituted alkyl sulfate detersive surfactant；Alkyl sulfate straight or branched, substituted or unsubstituted goes Dirty surfactant, including straight chain C8-C18Alkyl sulphate detersive surfactant, C1-C3Alkyl-branched C8-C18Alkyl sulfide Hydrochlorate detersive surfactant, straight or branched alkoxylate C8-C18Alkyl sulphate detersive surfactant and they Mixture；Alkylsulfonate detersive surfactant straight or branched, substituted or unsubstituted；And their mixture.
Preferably alkoxylated alkyl sulphate detersive surfactant is straight or branched, substituted or unsubstituted C8-18Alkyl alkoxylated suifate detersive surfactant, it has 1 to 30, the average degree of alkoxylation of preferably 1 to 10. Preferably, described alkoxylated alkyl sulphate detersive surfactant is C straight or branched, substituted or unsubstituted8-18 Alkyl ethoxylated sulfate, it has the average degree of ethoxylation of 1 to 10.Most preferably, described alkoxylated alkyl sulphuric acid Salt detersive surfactant is the unsubstituted C of straight chain8-18Alkyl ethoxylated sulfate, it has the average ethoxylation of 3 to 7 Degree.
Preferably anionic detersive surfactant is selected from: C straight or branched, substituted or unsubstituted12-18Alkyl sulfide Hydrochlorate；C straight or branched, substituted or unsubstituted10-13Alkylbenzenesulfonate, preferably straight chain C10-13Alkylbenzenesulfonate；With And their mixture.Highly preferred straight chain C10-13Alkylbenzenesulfonate.Highly preferred obtainable straight chain C10-13Benzene sulfonamide Hydrochlorate, the straight chain C preferably obtained by the commercially available linear alkylbenzene (LAB) (LAB) of sulfonation10-13Alkylbenzenesulfonate；Suitably LAB include rudimentary 2-phenyl LAB as by Sasol with trade nameThose provided, or by Petresa with commodity NameThere is provided those, other suitable LAB includes senior 2-phenyl LAB, as by Sasol with trade nameThose provided.Suitable anionic detersive surfactant is the alkylbenzene obtained by DETAL catalysis process Sulfonate, although other route of synthesis such as HF is also suitable.
Another kind of suitable anionic detersive surfactant is alkyl ethoxy carboxylate.Described anionic detersive surface Activating agent generally exists with their salt form, generally with suitable cationic complex.Suitable counter ion counterionsl gegenions include Na+And K+、 Substituted ammonium such as C1-C6Alkanol ammonium, preferably monoethanolamine (MEA), triethanolamine (TEA), diethanolamine (DEA) and they Any mixture.
It is preferable, however, that at least 20 weight %, or at least 30 weight %, or at least 40 weight %, or at least 50 weight %, or At least 60 weight %, or at least 70 weight %, or at least 80 weight %, or even or the anionic detersive table of at least 90 weight % Face activating agent is neutralized by sodium cation.
Anionic detersive surfactant the most preferably has the hydrophilic index (HI of 8.0 to 9.1C), or anionic detersive Surfactant can the most preferably have lower hydrophilic index (HIC), such as 6.0 to 8.0, or 7.0 in the range of less than 8.0 One.Hydrophilic index (HIC) be described in more detail in WO00/27958.
Suitable cationic detersive surfactants includes: alkyl pyridinium compounds；Alkyl quaternary ammonium compound；Alkyl quaternary Ammonium compounds；Alkyl ternary sulfonium compound；And their mixture.Cationic detersive surfactants is selected from: alkane Epoxide compound quaternary ammonium (AQA) surfactant；Dimethyl hydroxy ethyl quaternary ammonium；Polyamine cationic surfactant；Cationic ester table Face activating agent；Amino surfactants, specially cocoamidopropyl dimethyl amine；And their mixture.Preferably sun from Sub-detersive surfactant is the quaternary ammonium compound with below general formula:
(R)(R1)(R2)(R3)N+X-
Wherein R is C straight or branched, substituted or unsubstituted6-18Alkyl or alkenyl part, R1And R2Independently selected from Methyl or aminoethyl moiety, R3For hydroxyl, methylol or hydroxyethyl moieties, X is for providing electroneutral anion, preferred anion Including halogen ion (such as chloride ion)；Sulfate radical and sulfonate radical.Preferably cationic detersive surfactants is-a C6-18Alkyl one Hydroxyethyl dimethyl aliquat.Highly preferred cationic detersive surfactants is-a C8-10Alkyl one ethoxy two Methyl chloride quaternary ,-a C10-12Alkyl one hydroxyethyl dimethyl aliquat and-a C10Alkyl one hydroxyethyl dimethyl Aliquat.
Suitable non-ionic detersive surfactant is selected from: C8-C18Alkyl ethoxylate, as derived from ShellNonionic surfactant；C6-C12Alkyl phenolic alkoxy thing, wherein said alkoxylate unit is ethylene Epoxide unit, propyleneoxy units or their mixture；C12-C18Alcohol and C6-C12Alkyl phenol and ethylene oxide/propylene oxide The condensation substance of block polymer, as derived from BASFC14-C22The alcohol BA of mid-chain branched；C14-C22Mid-chain branched Alkyl alkoxylates BAEx, wherein x=1 to 30；Alkyl polysaccharide, specially alkyl polyglycoside；Polyhydroxy fatty acid amide；Ether seals Poly-(alkoxylate) alcohol surfactant of end；And their mixture.
Described non-ionic detersive surfactant can be alkyl polyglucoside and/or alkyl alkoxylated alcohol.Described non-from Sub-detersive surfactant is preferably C straight or branched, substituted or unsubstituted8-18Alkyl ethoxylated alcohol, its have 1 to 10, the average degree of ethoxylation of more preferably 3 to 7.
Suitable amphion and/or amphoteric detersive surfactants include alkanolamine sulfobetaines.
Described compositions preferably comprises branched anionic detersive surfactant and/or branched Nonionic detersive Surfactant.Described branched anionic detersive surfactant and/or branched non-ionic detersive surfactant are preferred Derived from natural source, it is preferable that wherein said natural source includes biologically-derived isoprenoid, most preferably farnesene.
Surface activity strengthens polymer.Described compositions can comprise surface activity and promote polymer.Preferably polymer is Amphiphilic alkoxylate grease cleaning polymer and/or random graft copolymer.These polymer are described in more detail below.
Amphipathic alkoxylate grease cleaning polymer.Amphiphilic alkoxylate grease cleaning polymer refer to any have flat The hydrophilic of weighing apparatus and the polymer of hydrophobic alkoxylate, this makes them remove fat particles from fabric and surface.This The specific embodiments of bright amphipathic alkoxylate grease cleaning polymer includes cored structure and multiple is connected to this cored structure Alkoxylate groups.
Described cored structure can include polyalkyleneimine structure, its with intensive form comprise formula (I), (II), (III) and (IV) repetitive:
The most in each case, # represents two neighbouring repetitions at nitrogen-atoms and formula (I), (II), (III) or (IV) / 2nd of key between the free bound site of the group A1 of unit；In each case, * represents and is connected to alcoxylates / 2nd of the key of group；And A1Independently selected from straight or branched C2-C6-alkylidene；Wherein said polyalkyleneimine Structure is repeated by 1 formula (I) repetitive, x formula (II) repetitive, y formula (III) repetitive and y+1 formula (IV) Unit forms, and the most in each case, x and y has the value in the range of 0 to about 150；Wherein polyalkyleneimine cored structure Average weight-average molecular weight Mw is about the value in the range of 60 to about 10,000g/mol.
Alternatively, described cored structure can comprise at least one selected from formula (I.a) and/or (I.b) N-(hydroxyl alkane Base) the polyalkanolamines structure of condensation product of compound of amine,
Wherein A is independently selected from C1-C6-alkylidene；R1、R1*、R2、R2*、R3、R3*、R4、R4*、R5And R5* independently selected from Hydrogen, alkyl, cycloalkyl or aryl, rear three groups mentioned can optionally be replaced；And R6Selected from hydrogen, alkyl, cycloalkanes Base or aryl, wherein said rear three groups mentioned can optionally be replaced.
It is connected to multiple polyoxyalkylene group alkylene oxide units independently selected from formula (V) of described cored structure,
The most in each case, * represent be connected to formula (I), (II) or (IV) repetitive nitrogen-atoms key two / mono-；In each case, A2Independently selected from 1,2-propylidene, 1,2-butylidene and 1,2-isobutylidene；A3Sub-for 1,2- Propyl group；In each case, R is independently selected from hydrogen and C1-C4-alkyl；M has the meansigma methods in the range of 0 to about 2；N has about Meansigma methods in the range of 20 to about 50；And p has the meansigma methods in the range of about 10 to about 50.
The specific embodiments of amphipathic alkoxylate grease cleaning polymer is selected from having interior poly-ethylene oxide block With the alkoxylated polyalkyleneimine of outer propyleneoxides, ethoxylation degree and propoxylation degree not over or be less than Concrete limit value.The specific embodiments of the alkoxylated polyalkyleneimine according to the present invention has the minimum of about 0.6 and gathers The ratio (n/p) of ethylene block and polyproplyene block and about 1.5 (x+2y+1)1/2Maximum rate.It has been found that n/p ratio is about 0.8 to about 1.2 (x+2y+1)1/2Alkoxylated polyalkyleneimine there is particularly useful characteristic.
Alkoxylated polyalkyleneimine according to the present invention has main chain, and described main chain is by primary amine, secondary amine and tertiary amine nitrogen Atom forms, and it is interconnected by alkylidene group A and is random arrangement.Primary amino moieties, it is that polyalkylene is sub- The main chain of amine main chain and the starting point of side chain or destination node and its remaining hydrogen atom are replaced by alkylene oxide units subsequently, Such part is known respectively as formula (I) or the repetitive of (IV).Secondary amino moiety, its remaining hydrogen atom is subsequently by alkylene Epoxide unit replaces, and is referred to as the repetitive of formula (II).Tertiary amino part, it makes main chain and side chain bifurcated, is referred to as formula (III) repetitive.
Owing to can be cyclized in the formation of polyalkyleneimine main chain, there is likely to be a small amount of ring-type in main chain Amino part.Certainly, comprise this type of polyalkyleneimine of cyclic amino part with by non-annularity primary amino radical and parahelium base portion The mode alkoxylate that those being grouped into are identical.
By nitrogen-atoms and group A1The polyalkyleneimine main chain of composition has about 60 to about 10,000g/mol, preferably from about 100 to about 8,000g/mol, and more preferably from about 500 to about 6, the average molecular weight Mw of 000g/mol.
(x+2y+1) and corresponding to being present in the alkyleneimine units in a single polyalkyleneimine main chain Sum, thus directly the most relevant to the molecular weight of described polyalkyleneimine main chain.But, the value be given in this manual relates to And the average of all polyalkyleneimines present in described mixture.(x+2y+2) and corresponding to being present in one individually Polyalkyleneimine main chain in the sum of amino.
Connect the group A of amino nitrogen atom1Can be identical or different, the C of straight or branched2-C6-alkylidene group, As 1,2-ethylidene, 1,2-propylidene, 1,2-butylidene, 1,2-Asia isobutene., 1,2-pentylidene, 1,2-hexylidene or six are sub- Methyl.Preferably branched alkylidene is 1,2-propylidene.Preferably straight-chain alkyl-sub-is ethylidene and hexa-methylene.Preferred Alkylidene is 1,2-ethylidene.
In polyalkyleneimine main chain, the hydrogen atom of primary amine groups and secondary amine is replaced by the alkylene oxide units of formula (V).
In the formula, described variable preferably has a kind of implication forth below:
In each case, A2Selected from 1,2-propylidene, 1,2-butylidene and 1,2-isobutylidene；Preferably, A2For 1,2- Propylidene.A3For 1,2-propylidene；In each case, R is selected from hydrogen and C1-C4-alkyl, such as methyl, ethyl, n-pro-pyl, isopropyl Base, normal-butyl, isobutyl group and the tert-butyl group；R is preferably hydrogen.In all cases, exponent m has the value of 0 to about 2；M is preferably 0 Or about 1；More preferably m is 0.Index n has in the range of about 20 to about 50, preferably in the range of about 22 to about 40, and more The preferably meansigma methods in the range of about 24 to about 30.Index p has in the range of about 10 to about 50, preferably at about 11 to about 40 models In enclosing, and more preferably meansigma methods in the range of about 12 to about 30.
Formula (V) alkylene oxide units is preferably the alcoxylates block of nonrandom sequences.First nonrandom sequences refers to Add [-A2-O-]m(i.e. closest to the key of nitrogen-atoms of formula (I), (II) or (III) repetitive), secondly adds [-CH2- CH2-O-]n, again add [-A3-O-]p.The offer of this target has internal layer poly-ethylene oxide block and outer layer poly(propylene oxide) is embedding The alkoxylated polyalkyleneimine of section.
The essential part of formula (V) these alkylene oxide units is by ethyleneoxy unit-[CH2-CH2-O)]n-and sub-propoxyl group Unit-[CH2-CH2(CH3)-O]p-formed.Alkylene oxide units also can have small part Asia propoxyl group or Aden's epoxide extraly Unit-[A2-O]m-, the polyalkyleneimine main chain that i.e. hydrogen atom is saturated originally can be with a small amount of, i.e. for NH contained by every mole Part is at most about 2 moles, the most about 0.5 to about 1.5 mole, the expoxy propane of the most about 0.8 to about 1.2 mole or ring Oxygen butane reacts, i.e. initial alkoxylate.
If necessary, this initial modification of described polyalkyleneimine main chain can make to react in alkoxy process The viscosity of mixture reduces.But, described modification does not generally interfere with the Performance Characteristics of alkoxylated polyalkyleneimine, therefore Do not constitute and preferably measure.
The grease cleaning polymer of described amphiphilic alkoxylate is by weight of the composition with about 0.05% to 10% In the range of content be present in decontamination and the Cleasing compositions of the present invention.The embodiment of described compositions can be wrapped by weight Containing about 0.1% to about 5%.More specifically, described embodiment can include about the grease cleaning polymer of 0.25 to about 2.5%.
Random graft copolymer.Suitable random graft copolymer generally comprises: (i) hydrophilic backbone, described main chain bag Containing selected from following monomer: undersaturated C1-C6Carboxylic acid, ether, alcohol, aldehyde, ketone, ester, sugar unit, oxyalkyl units, maleic anhydride, Saturated polyol and their mixture such as glycerol；(ii) one or more hydrophobic side chains, described side chain is selected from: C4-C25Alkyl group, polypropylene, polybutene, saturated C1-C6The C of monocarboxylic vinyl esters, acrylic or methacrylic acid1- C6Arrcostab and their mixture.
Described polymer preferably has a formula:
Wherein X, Y and Z are blocking units, independently selected from H or C1-6Alkyl；Each R1Independently selected from methyl and ethyl； Each R2Independently selected from H and methyl；Each R3Independently be C1-4Alkyl；And each R4Independently selected from ketopyrrolidine and benzene Base group.The weight average molecular weight of described poly(ethylene oxide) main chain is typically about 1,000g/mol to about 18,000g/mol, or about 3, 000g/mol to about 13,500g/mol, or about 4,000g/mol to about 9,000g/mol.Select the value of m, n, o, p and q, so that Described side base content is calculated as at least 50%, or about 50% to about 98%, or about 55% to about 95% by the weight of described polymer, Or about 60% to about 90%.Can be used for polymer herein and be generally of about 1,000 to about 100,000g/mol, or preferably from about 2, 500g/mol to about 45,000g/mol, or about 7,500g/mol to about 33,800g/mol, or about 10,000g/mol to about 22, The weight average molecular weight of 500g/mol.
Other polymer.In addition to surface activity strengthens polymer, described compositions preferably comprises polymer.Suitable Other suitable polymer includes detergency polymer, antiredeposition polymer, carboxylate polymer and/or deposition aid polymerization Thing.Other suitable polymer includes that dye transfer inhibitor such as polyvinyl pyrrolidone polymers, many amine n-oxides are polymerized Thing, NVP and the copolymer of N-vinylimidazole polymers.
Detergency polymer.Suitable detergency polymer include random or block configuration comprise at least one selected from Under the polymer of monomeric unit: sugar, dicarboxylic acids, polyhydric alcohol and combinations thereof.Other suitable detergency polymer Including polymer based on PETP and copolymer thereof, the preferably random or p-phthalic acid second two of block configuration Ester and the copolymer of poly(ethylene oxide).
Antiredeposition polymer.Described compositions can comprise antiredeposition polymer, and preferably 0.1 weight % is to 10 weight % Antiredeposition polymer.Suitable antiredeposition polymer includes carboxylate polymer, as comprised at least one selected from following The polymer of monomer: acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, equisetic acid, mesaconic acid, citraconic acid, Methylene malonic acid and their any mixture.Suitable carboxylate polymer includes.
Other suitable antiredeposition polymer includes Polyethylene Glycol, preferably has 500 to 100, dividing in the range of 000Da Son amount.
Carboxylate polymer.Described compositions preferably comprises the most about 0 weight % to 5 weights The polymeric carboxylates of amount %.Described polymeric carboxylates can free calcium ions in sequestration wash liquid.Described carboxylate gathers Compound also acts as dirt dispersant, and can provide the particulate stain removal cleaning beneficial effect of improvement.
Described compositions preferably comprises polycarboxylate.Preferably polycarboxylate includes: weight average molecular weight is preferably 1, The polyacrylate of 000Da to 20,000Da；Maleic acid and acrylic acid copolymer, preferably maleic acid monomer and acrylic monomers Mol ratio be 1:1 to 1:10, and weight average molecular weight is 10, the copolymer of 000Da to 200,000Da, or preferably maleic acid Monomer is 0.3:1 to 3:1 with the mol ratio of acrylic monomers, and weight average molecular weight is 1, the copolymerization of 000Da to 50,000Da Thing.
Deposition aid.Described compositions can comprise deposition aid.Suitable deposition aid is polysaccharide, and preferred cellulose is polymerized Thing.Other suitable deposition aid includes the random or diallyl dimethyl ammonium halide (DADMAC) of block configuration, and DADMAC and vinyl pyrrolidone, acrylamide, imidazoles, the copolymer of imidazolinium halides, and their mixture.Its Its suitable deposition aid include cation guar gum, cationic cellulose such as cationic hydroxyethyl cellulose, cationic starch, PAMC and their mixture.
Non-polymeric dye transfer inhibitor.It is used as non-polymeric dye transfer inhibitor thing, such as phthalein cyanogen manganese, peroxide Compound enzyme and their mixture.
Chelating agen.Chelating agen can be but be not limited to following these: ethylenediaminetetraacetic acid (EDTA)；Diethylenetriamines five is sub- Methylphosphonic acid (DTPMP)；Hydroxyethane diphosphonic acid (HEDP)；Ethylenediamine N, N'-disuccinic acid (EDDS)；Methylglycine diethyl Acid (MGDA)；Diethylene-triamine pentaacetic acid (DTPA)；Trimethylen-edinitrilo-tetraacetic acid (PDTA)；2 hydroxy pyrimidine-N-oxide (HPNO)；Or MDGA (MGDA)；Glutamic acid N, N-oxalic acid (N, N-bis-carboxymethyl glutamic acid tetrasodium salt (GLDA))；Nitrilotriacetic acid(NTA) (NTA)；Benzenedisulfonic acid between 4,5-dihydroxy；Citric acid；And their any salt.
The content of described chelating agen 0.1 weight % the most by weight of the composition is to 10 weight %.Described chela Mixture can be the solid particulate form being suspended in described fluid composition.
Dope dye.Described compositions can comprise fabric hueing agent (sometimes referred to as opacifier, blueing agent or brightening agent). Toner generally provides blue or violet hue to fabric.Toner can be used singly or in combination, specific to produce Toning tone and/or to different fabric type tonings.This can be such as by mixing redness and aeruginous dyestuff to produce indigo plant Color or violet hue provide.Toner is selected from the dyestuff of any known chemical classes, includes but not limited to acridine, Anthraquinones (including polycyclic quinone), azine, azo (such as, monoazo, bisazo, trisazo-, four azos, polyazo), include pre-metal Change azo, benzo two furan and benzodifuranone, carotenoid, coumarin, Hua Jing, diaza half flower cyanines, diphenyl-methane, First, half flower cyanines, indigoid type, methane, naphthols acid imide, naphthols quinone, nitro and nitroso-group, piperazine, phthalocyanine, pyrazoles, hexichol Ethylene, styryl, triarylmethane, tritan., xanthene and their mixture.
Suitable fabric hueing agent includes dyestuff, dye clay conjugates and organic pigment and inorganic pigment.Suitably Dyestuff include small molecule dyes and polymeric dye.Suitable small molecule dyes includes selected from belonging to Colour Index (C.I.) point Class direct, alkaline, active or the activity of hydrolysis, solvent or disperse dyes (be such as classified as indigo plant, purple, red, green or black) And the small molecule dyes of desired tone is provided either individually or in combination.On the other hand, suitable small molecule dyes bag Include the little molecule of lower column number selected from Colour Index (Society of Dyers and Colourists, Bradford, UK) Dyestuff: directly purple dye such as 9,35,48,51,66 and 99, sun blue dyestuff such as 1,71,80 and 279, acid red dye such as 17, 73,52,88 and 150, acid violet dyestuff such as 15,17,24,43,49 and 50, acid blue dye such as 15,17,25,29,40,45, 75,80,83,90 and 113, acid black dye such as 1, basic purple dye such as 1,3,4,10 and 35, basic dye such as 3,16,22, 47,66,75 and 159, dispersion or solvent dye, and their mixture.In yet another aspect, suitable small molecule dyes bag Include the small molecule dyes selected from following color index: acid violet 17, sun blue 71, the most purple 51, sun blue 1, Xylene Red 88, azogeramine 50, acid blue 29, Acid blue 113 or their mixture.
Suitable polymeric dye includes selected from following polymeric dye: comprises and covalently bound (is sometimes referred to as puting together ) polymer (dye-polymer conjugate) of chromogen (such as has the poly-of the chromogen that is copolymerized in this main polymer chain Compound) and their mixture.
On the other hand, suitable polymeric dye is selected from: with trade name(Milliken, Spartanburg, South Carolina, USA) sell fabric-entity coloring agent, formed by least one reactive dye Dye-polymer conjugate and selected from comprising the polymer of the polymer with lower part, described part selected from hydroxylic moiety, Primary amine moiety, secondary amine moieties, thiol moiety and their mixture.On the other hand, suitable polymeric dye includes choosing Polymeric dye from following:Purple CT, with reactive blue, reactive violet or the carboxymethyl of active red dye covalent bonding Cellulose (CMC), if the CMC puted together with C.I. active blue 19 is (by Megazyme (Wicklow, Ireland) with ProductName AZO- CM-CELLULOSE, product code S-ACMC sell), the triphenyl of alkoxylate-methane polymeric colorant, alkoxylate Thiophene polymeric colorant, and their mixture.
Preferably dope dye includes brightening agent.The toner being preferred in the present invention can be these lists of references following Disclosed in preferred coloring agent, including in the table 5 of WO2011/011799 embodiment 1-42 those.Other preferred dyestuff It is disclosed in US 8138222.Other preferred dyestuff is disclosed in WO2009/069077.
Suitable dye clay conjugates includes selected from following dye clay conjugates: at least one cation/alkalescence Dyestuff and smectic clays and their mixture.On the other hand, suitable dye clay conjugates includes selected from following Dye clay conjugates: a kind of cation/basic stain, it is selected from: C.I. basic yellow 1 to 108, C.I. Basic Orange 1 to 69, C.I. alkali red 1:1 to 118, C.I. alkaline purple 1 to 51, C.I. alkali blue 1 to 164, C.I. Viride Nitens 1 to 14, C.I. bismarck brown 1 To 23, CI basic black 1 to 11 and clay, described clay is selected from: montmorillonitic clay, HECTABRITE DP, saponite clay, with And their mixture.On the other hand, suitable dye clay conjugates includes selected from following dye clay conjugates: cover De-stone alkali blue B7C.I.42595 conjugate, montmorillonite alkali blue B9C.I.52015 conjugate, montmorillonite alkalescence is purple V3C.I.42555 conjugate, montmorillonite Viride Nitens G1C.I.42040 conjugate, the montmorillonite red R1C.I.45160 of alkalescence puts together Thing, montmorillonite C.I. basic black 2 conjugate, Strese Hofmann's hectorite. alkali blue B7C.I.42595 conjugate, Strese Hofmann's hectorite. alkali blue B9C.I.52015 conjugate, Strese Hofmann's hectorite. alkalescence purple V3C.I.42555 conjugate, Strese Hofmann's hectorite. Viride Nitens G1C.I.42040 sews Compound, the Strese Hofmann's hectorite. red R1C.I.45160 conjugate of alkalescence, Strese Hofmann's hectorite. C.I. basic black 2 conjugate, soap alkali blue B7C.I.42595 conjugate, soap alkali blue B9C.I.52015 conjugate, soap alkalescence purple V3C.I.42555 conjugate, soap alkalescence Green G1C.I.42040 conjugate, the soap red R1C.I.45160 conjugate of alkalescence, soap C.I. basic black 2 conjugate, and they Mixture.
Suitable pigment includes selected from following pigment: flavanthrone, blue anthrone, comprise 1 to 4 chlorine atom chlorination blue Anthrone, pyranthrone, dichloro pyranthrone, single bromine dichloro pyranthrone, Dibromo-dichloro pyranthrone, tetrabromo pyranthrone, perylene-3,4, 9,10-tetracarboxylic acid diimides, wherein said imide group can be unsubstituted or by C1 to C3 alkyl or phenyl or Heterocyclic radical replaces, and wherein phenyl and heterocyclic radical can be further with not providing the substituent group of dissolubility in water, pyrazolopyrimidine carboxylic Acid amide, violanthrone, isoviolanthrone, dioxazine pigment, each molecule can comprise the C.I. Pigment Blue 15 of most 2 chlorine atoms, many chlorine copper phthalein Cyanines or each molecule comprise many bromines C.I. Pigment Blue 15 and their mixture of most 14 bromine atoms.
On the other hand, suitable pigment includes selected from following pigment: ultramarine blue (C.I. alizarol saphirol 29), ultramarine violet (C.I. pigment violet 1 5) and their mixture.
Above-mentioned fabrics toner (any mixture of fabric hueing agent can be used) can be applied in combination.
Enzyme.Described compositions preferably comprises enzyme.Preferably, described compositions comprises the enzyme of high level.Most preferably, Described compositions comprises the organized enzyme of at least 0.01 weight %.Described compositions preferably comprises the work of at least 0.03 weight % Property enzyme.
Described compositions preferably comprises at least one ternary enzyme system, described enzyme system selected from protease, amylase, Lipase and/or cellulase.
Lipase.Suitable lipase includes those of bacterial origin or originated from fungus.Including through chemical modification or egg The mutant of white through engineering approaches.The example of available lipase includes the lipase example from Humicola (synonym thermophilic fungal genus) As from thin continuous shape humicola lanuginosa (Thermomyces lanuginosus) or the lipase from Humicola insolens, Rhodopseudomonas lipase Such as from Pseudomonas alcaligenes or pseudomonas pseudoalcaligenes, Pseudomonas cepacia, pseudomonas-stutzeri, pseudomonas fluorescens, Pseudomonas strain SD 705, the lipase of Wisconsin pseudomonas, bacillus lipase, such as from hay bud The lipase of spore bacillus, bacstearothermophilus or Bacillus pumilus.
Lipase can be " the first circulation lipase ".In one aspect, described lipase is the first washing lipase, preferably For carrying out the wild type lipase variant of the thermophilic hyphomycete of thin cotton like of self-contained T231R and N233R sudden change.Wild-type sequence is Swissprot accession number is the 269 of Swiss-Prot O59952 (deriving from the thermophilic hyphomycete of thin cotton like (Humicola lanuginosa genus)) Individual aminoacid (aminoacid 23-291).Preferably lipase will include with trade nameWithThose sold by Novozymes (Bagsvaerd, Denmark).
Described compositions preferably comprises and has 90% homogeneity and at T231 and/or N233 with wild-type amino acid Place, comprises MIAOMAO thermophilic hyphomycete lipase Variant (this of one or more substituent group at preferably T231R and/or N233R Literary composition: " the first washing lipase ").
Protease.Suitable protease includes metalloproteases and/or serine protease, including neutrality or alkaline micro-life Thing serine protease, such as subtilisin (EC3.4.21.62).Be suitable for protease include animal sources, plant source or Those of microbial source.In one aspect, this type of suitable protease can be microbial source.Suitable protease includes through chemistry Modification or the mutant of the above-mentioned adequate proteins enzyme through genetic modification.In one aspect, suitable protease can be serine egg White enzyme, such as alkaline microbial protease or/and trypsin type protease.The example bag of suitable neutrality or alkaline protease Include:
A () subtilisin (EC 3.4.21.62), including deriving from those of bacillus cereus, such as slow spore bar Bacterium, Alkaliphilic bacillus, bacillus subtilis, bacillus amyloliquefaciens, Bacillus pumilus and bacillus gibsonii.
B () trypsin type or chymase type protease, if trypsin is for example originating from pig or the Trypsin of cattle Enzyme), including the Fusarium protease and the chymase that derive from Cellulomonas.
C () metalloproteases, including deriving from those of bacillus amyloliquefaciens.
Preferably protease includes those deriving from bacillus gibsonii or bacillus lentus.
The commercially available protease being suitable for includes with trade name LiquanaseSavinaseWithBy Novozymes A/S (Denmark) sell those, with trade name PurafectPurafect And PurafectThose sold by Genencor International, with trade nameWithThose sold by Solvay Enzymes, deriving from those of Henkel/Kemira is that BLAP (has following prominent Become S99D+S101R+S103A+V104I+G159S, hereinafter referred to as BLAP), BLAP R (there is S3T+V4I+V199M+V205I+ The BLAP of L217D), BLAP X (there is the BLAP of S3T+V4I+V205I) and BLAP F49 (there is S3T+V4I+A194P+ The BLAP of V199M+V205I+L217D)-all derive from Henkel/Kemira；(there is sudden change A230V+ with the KAP deriving from Kao The Alkaliphilic bacillus subtilisin of S256G+S259N).
Described compositions preferably comprises the subtilisin selected from BLAP, BLAP R, BLAP X or BLAP F49.
Cellulase.The cellulase being suitable for includes those of bacterial origin or fungal source.Including through chemical modification or egg The mutant of white through engineering approaches.Suitable cellulase include from bacillus, Rhodopseudomonas, Humicola, Fusarium, The cellulase that grass Rhizopus, branch acremonium belong to, such as by Humicola insolens, thermophilic ruin that a bacterium and Fusarium oxysporum produce true Fungin enzyme.
In one aspect, described cellulase can include showing β-Isosorbide-5-Nitrae-endoglucanase activity (E.C.3.2.1.4) the endoglucanase being derived from microorganism.Suitable endoglucanase is with trade name (Novozymes A/S, Bagsvaerd, Denmark) sells.Other suitable endoglucanase is the variant of XYG1006 enzyme (Novozymes).Suitable endoglucanase is with trade name(Novozymes A/S, Bagsvaerd, Denmark) sell.
Preferably, described compositions comprises the cleaning belonging to glycosyl hydrolase family 45 (molecular weight is 17kDa to 30kDa) Cellulase, such as with trade nameNCD, DCC and DCL (AB Enzymes, Darmstadt, Germany) sell Endoglucanase.
Amylase.Described compositions preferably comprises the AA560 α-amylase tool endogenous with bacillus DSM 12649 There is the amylase more than 60% homogeneity, the variant of preferably endogenous with bacillus DSM 12649 AA560 α-amylase, It has:
A () is in the sudden change of one or more lower column positions: 9,26,149,182,186,202,257,295,299,323, 339 and 345；And
118,183 b () optionally has one or more at lower column position, preferably all of replacement and/or disappearance:, 184,195,320 and 458, if it does, preferably comprise R118K, D183*, G184*, N195F, R320K and/or R458K.
Suitable commercially available amylase includesPlus、Natalase、Ultra、SZ (all derive from Novozymes, Bagsvaerd, Denmark), andAA or Ultraphlow (Genencor, Palo Alto, USA).
Choline dehydrogenase.Described compositions preferably comprises Choline dehydrogenase, such as the interior 59.1kDa coming from nicotianae Choline dehydrogenase.
Other enzyme.Other suitable enzyme is peroxidase/oxidase, and it includes being derived from that of plant, antibacterial or fungus A bit.Including through chemical modification or proteins engineered mutant.The example of available peroxidase includes from Coprinus Peroxidase such as Coprinus cinereus, and variant.
Commercially available peroxidase includes(Novozymes A/S)。
Other preferred enzyme includes: with trade nameThe pectate lyase sold；With With trade nameSell mannase (all deriving from Novozymes A/S, Bagsvaerd, Denmark) and(Genencor International Inc., Palo Alto, California)；At；Phospholipase；With And their mixture.
Homogeneity.Relation between two kinds of aminoacid sequences is described by parameter " homogeneity ".For purposes of the present invention, two The comparison of individual aminoacid sequence is passed through to use from EMBOSS software kit (http://emboss.org), version 2 .8.0's Needle program is determined.Needle program performs Needleman, S.B. and Wunsch, and C.D. is in (1970) Overall comparison algorithm described in J.Mol.Biol.48,443-453.The substitution matrix used is BLOSUM62, and room is open to be penalized Being divided into 10, gap extension penalties is 0.5.
Enzyme stabilizers.Described compositions can comprise enzyme stabilizers.Suitable enzyme stabilizers include polyhydric alcohol such as propylene glycol or Glycerol, sugar or sugar alcohol, lactic acid, reversible protease inhibitors, boric acid or boronic acid derivatives such as aromatic borate or phenylboric acid Derivant such as 4-formyl phenylboronic acid.Described compositions preferably comprises nil-boron enzyme stabilizer, is preferably selected from polyhydric alcohol such as third Glycol or glycerol, sugar or sugar alcohol.Described compositions is even preferably substantially free from boron.It is substantially free of and typically refers to: " do not comprise Intentionally add ".Not boracic also generally include not boracic originate such as Borax.
Calcium and magnesium cation.Described compositions preferably comprises calcium and/or the magnesium sun of at least 0.2 weight % to 5 weight % Ion.
Visual signal composition.Suitable visual signal composition includes any reflection and/or refractive material, preferably Muscovitum.
Defoamer.Composition of detergent comprises the defoamer of about 0.001 weight % to about 4.0 weight % herein, described in disappear Infusion is selected from organosilicon defoaming compounds；Silicone oil defoaming compounds and hydrophobic granule；And their mixture.An enforcement In scheme, confectionery composition comprises about 0.01 weight % to about 2.0 weight %, or 0.05 weight % having to about 1.0 weight % Machine silicon defoaming agent (does not include any carrier by the percentage ratio of active substance gauge).
In one embodiment, described defoamer is selected from: have the organically-modified of aryl or alkylaryl substituent group Organosilicon polymer and organic siliconresin and the combination of improved silica；M/Q resin；And their mixture.
Fatty acid.Described compositions comprises 0 weight % to 10 weight %, preferably 0 weight % to 5 weight %, preferably 0.1 weight Amount % to 5 weight %, preferably 0.5 weight % to the saturated of 3 weight % or unsaturated fatty acid is the most saturated or undersaturated C12-C24Fatty acid；Highly preferred saturated C12-C18Fatty acid.
Structural agent/thickening agent.Structuring liquid can be internal structured, so that described structure is by main component (such as surfactant materials) is formed, and/or can be by using secondary component (such as polymer, clay and/or silicate Material) three dimensional matrix structure and external structurant are provided.
Described compositions can comprise structural agent, and preferably 0.01 weight % to 5 weight %, 0.1 weight % is to 2.0 weight % Structural agent.Described structural agent be generally selected from diglyceride and triglyceride, glycol distearate, microcrystalline Cellulose, based on The material of cellulose, microfibrous cellulose, biopolymer, xanthan gum, gellan gum and their mixture.Suitable knot Structure agent includes castor oil hydrogenated and unethoxylated derivant thereof.Described compositions is preferably substantially free of lipase, substantially Upper without typically referring to: " do not comprise and intentionally add ".When described compositions comprises castor oil hydrogenated and unethoxylated spreads out Biochron, this is especially preferred.
Diglycol stearate also is used as visual signal composition.
Solvent.Described compositions preferably comprises solvent.Preferably solvent includes alcohol and/or glycol, preferably methanol, ethanol And/or propylene glycol.For improving enzyme stability, described compositions does not comprises or the methanol that comprises trace and ethanol, but bag Containing larger amount of propylene glycol.Described compositions preferably comprises propylene glycol.
Suitable solvent includes C4-C14Ether and diether, glycols, alkoxylated diols class, C6-C16Glycol ethers, alkoxyl Change branched-chain alcoho fragrant and mellow, fragrant and mellow, aliphatic, alkoxylated aliphatic branched-chain alcoho, alkoxylate straight chain C1-C5Alcohol, straight chain C1-C5Alcohol, amine, C8-C14Alkyl and cycloalkyl hydrocarbon and halogenated hydrocarbons and their mixture.
Preferably solvent selected from methoxyl group octadecanol, 2-(2-ethoxy ethoxy) ethanol, benzylalcohol, 2-ethyl butanol and/ Or 2-methyl butanol, 1-methyl-prop ethoxy-ethanol and/or 2-methylbutoxy group ethanol, straight chain C1-C5Alcohol (as methanol, ethanol, third Alcohol, butyl diglycol ether (BDGE), fourth 2,2'-ethylenedioxybis(ethanol). ether, tertiary pentyl alcohol, glycerol, isopropanol) and their mixture.Can Especially preferred solvent for herein be butoxy propoxy propanol, butyldiglycol ether, benzylalcohol, butoxypropanol, the third two Alcohol, glycerol, ethanol, methanol, isopropanol, and their mixture.Other suitable solvent include propylene glycol and diethylene glycol with And their mixture.
Electrolysis strength.The deionized water solution of compositions described in 1g/L electrolysis strength at a temperature of 25 DEG C is (with mScm-1For Unit) preferably smaller than 200mScm-1, more preferably less than 150mScm-1, even more preferably less than 100mScm-1, and be even less than 75mScm-1, or even less than 50mScm-1.Described electrolysis strength can be measured by any suitable device such as conductivity meter.
Buffer agent.Described compositions generally comprises buffer agent.Preferably buffer agent includes monoethanolamine (MEA) and three ethanol Amine (TEA).Can use Borax as buffer agent, but described compositions is preferably substantially free from Borax, is substantially free of generally Refer to be not incorporated in described compositions by the Borax intentionally added.
Alkanolammonium cations.Described compositions preferably comprises alkanolammonium cations, preferably monoethanolamine (MEA) And/or triethanolamine (TEA).
Hydrotropic agent.Described compositions can comprise hydrotropic agent.Preferably hydrotropic agent is MPG.
Encapsulation object
Described compositions can comprise encapsulation object.In one aspect, encapsulation object comprises core, has inner surface and outer surface Shell, described shell encapsulates described core.
At an aspect of described encapsulation object, described core can comprise following material, and described material is selected from spice；Brightening agent； Dyestuff；Anthelmintic；Silicone；Wax；Flavoring agent；Vitamin；Fabric softener；Skin protectant, in one aspect, paraffin；Enzyme；Antibacterial Agent；Bleach；Sensory agent；And their mixture；Described shell can comprise material, described material choosing freely following composition Group: polyethylene；Polyamide；Polyvinyl alcohol, optionally comprises other comonomer；Polystyrene；Polyisoprene；Poly-carbonic acid Ester；Polyester；Polyacrylate；Aminoplast, the most described aminoplast can comprise polyureas, polyurethane and/or poly-ammonia Ester urea, the most described polyureas can comprise anaflex and/or melamino-formaldehyde；Polyolefin；Polysaccharide, in one aspect Described polysaccharide can comprise sodium alginate and/or chitosan；Gelatin；Lac；Epoxy resin；Polyvinyl；Water-insoluble Inorganic matter；Silicone；And their mixture.
At an aspect of described encapsulation object, described core can comprise spice.
At an aspect of described encapsulation object, described shell can comprise the tripolycyanamide of melamino-formaldehyde and/or crosslinking Formaldehyde.
In one aspect, disclosing the suitable encapsulation object that can comprise core material and shell, described shell at least partly surrounds Described core material.The described encapsulation object of at least 75%, 85% or even 90% can have about 0.2MPa to about 10MPa, about 0.4MPa is to about 5MPa, about 0.6MPa to about 3.5MPa, or the most about 0.7MPa is to the rupture strength of about 3MPa；About 0% to About 30%, about 0% to about 20%, or the beneficial agent leakage, regarded of the most about 0% to about 5%.
In one aspect, the described encapsulation object of at least 75%, 85% or even 90% can have about 1 micron micro-to about 80 Rice, about 5 microns to 60 microns, about 10 microns to about 50 microns, or the granularity of the most about 15 microns to about 40 microns.
In one aspect, the described encapsulation object of at least 75%, 85% or even 90% can have about 30nm to about 250nm, About 80nm to about 180nm, or the granule wall thickness of the most about 100nm to about 160nm.
In one aspect, the core material of described encapsulation object can include selected from following material: perfume base and/or optional Material, described material is selected from vegetable oil, including vegetable oil that is pure and/or that mix, including Oleum Ricini, Oleum Cocois, Oleum Gossypii semen, Portugal Grape seed oil, Semen Brassicae campestris, soybean oil, Semen Maydis oil, Petiolus Trachycarpi oil, Semen Lini oil, safflower oil, olive oil, Oleum Arachidis hypogaeae semen, Oleum Cocois, Petiolus Trachycarpi Core oil, Oleum Ricini, Fructus Citri Limoniae oil and their mixture；The ester of vegetable oil, esters, including dibutyl adipate, O-phthalic Dibutyl phthalate, butyl benzyl adipate ester, octyl adipate ester, tricresyl phosphate, trioctyl phosphate and they Mixture；Straight or branched hydro carbons, including those straight or branched hydro carbons of the boiling point with greater than about 80 DEG C；Partially hydrogenated Terphenyl, dialkyl phthalate, alkyl biphenyl (including single isopropyl biphenyl), alkylnaphthalene (including dipropyl naphthalene), stone Olein (including kerosene), mineral oil and their mixture；Aromatic solvent, including benzene, toluene and their mixing Thing；Silicone oil；And their mixture.
In one aspect, the sheathing material of described encapsulation object can include that suitable resin, described resin include aldehyde and amine Product, suitable aldehyde includes formaldehyde.Suitable amine includes tripolycyanamide, urea, benzoguanamine, glycoluril and their mixing Thing.Suitable tripolycyanamide include melamine methylol, the melamine methylol that methylates, imino group tripolycyanamide and Their mixture.Suitable urea includes dimethylol urea, the dimethylol urea that methylates, urea-resorcinol and theirs is mixed Compound.
In one aspect, the formaldehyde scavenger being suitable for can be used together with described encapsulation object, such as, adds capsule suspension liquid In and/or join in this type of consumer goods before, during or after described encapsulation object is added in consumer goods.
Suitable capsule is purchased from Appleton Papers Inc. (Appleton, Wisconsin, USA).
Additionally, the material for preparing above-mentioned encapsulation object be purchased from Solutia Inc. (St Louis, Missouri, U.S.A.), Cytec Industries (West Paterson, New Jersey, U.S.A.), sigma-Aldrich (St.Louis, Missouri, U.S.A.), CP Kelco Corp. (San Diego, California, USA)；BASF AG (Ludwigshafen, Germany)；Rhodia Corp. (Cranbury, New Jersey, USA)；Hercules Corp. (Wilmington, Delaware, USA)；Agrium Inc. (Calgary, Alberta, Canada), ISP (New Jersey, U.S.A.), Akzo Nobel (Chicago, IL, USA)；Stroever Shellac Bremen (Bremen, Germany)； Dow Chemical Company (Midland, MI, USA)；Bayer AG (Leverkusen, Germany)；Sigma- Aldrich Corp. (St.Louis, Missouri, USA).
Spice-in one aspect, described compositions comprises spice, and described spice comprises one or more selected from following perfume (or spice) Material raw material: the double-2-propanol of 1,1'-epoxide；Isosorbide-5-Nitrae-cyclohexane cyclohexanedimethanodibasic, diethylester；((ethoxymethyl) epoxide) cyclododecane；1,3- Nonanediol, monoacetate；(3-methylbutoxy group) acetic acid, 2-propylene；Beta-methyl cyclododecane ethanol；2-methyl-3-[(l, 7,7-trimethyl bicyclo-[2.2.1] hept-2-yl) oxo]-l-propanol；OMEGA-pentadecalactone；Acetic acid Alpha-Methyl-benzyl alcohol Ester；Trans-3-ethyoxyl-1,1,5-trimethyl-cyclohexane；Acetic acid 4-(1,1-dimethyl ethyl) hexamethylene alcohol ester；Ten dihydro-3a, 6,6,9a-tetramethyl naphtho-[2,1-b] furan；Beta-methyl benzenpropanal；Beta-methyl-3-(1-Methylethyl) benzenpropanal；4-phenyl- 2-butanone；2-Methyl Butyric Acid, ethyl ester；Benzaldehyde；2-Methyl Butyric Acid, 1-Methylethyl ester；Dihydro-5-amyl group-2 (3H) furan Ketone；(2E)-1-(2,6,6-trimethyl-2-cyclohexene-1-base)-2-butylene-1-ketone；Lauric aldehyde；The hendecanal；Capraldehyde；2-(phenyl Methylene) octanal；2-[[3-[4-(1,1-dimethyl ethyl) phenyl]-2-methyl propylene] amino] benzoic acid, methyl ester；1- (2,6,6-trimethyl-3-cyclohexene-1-base)-2-butylene-1-ketone；2-amyl group Ketocyclopentane；3-oxo-2-pentyl-cyclopentane second Acid, methyl ester；3-methoxy-4-hydroxybenzaldehyde；Vanirom；Alismone；1-(4-methylbenzene Base) ethyl ketone；(3E)-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-3-butene-2-one；(3E)-4-(2,6,6-trimethyl- 2-cyclohexene-1-base)-3-butene-2-one；Phenethanol；2H-1-chromen-2-one；4-methoxybenzaldehyde；10-hendecene Aldehyde；Propanoic acid, benzene methyl；Beta-methyl fenipentol；1,1-diethoxy-3,7-dimethyl-2,6-octadiene；(2E)-1-(2,6,6- Trimethyl-1-cyclohexene-1-base)-2-butylene-1-ketone；Acetic acid, benzene methyl；Hexamethylene propanoic acid, 2-acrylic ester；Caproic acid, 2-third Alkenyl esters；1,2-dimethoxy-4 '-(2-acrylic) benzene；1,5-dimethyl-bicyclo-[3.2.1] octyl-8-ketoxime；4-(4-hydroxyl- 4-methyl amyl)-3-cyclohexene-1-formaldehyde；3-butene-2-ol；2-[[[2,4 (or 3,5)-dimethyl-3-cyclohexenyl group-1- Base] methylene] amino] benzoic acid, methyl ester；8-ring 16-1-ketone；Methyl ionone；2,6-dimethyl-7-octen-2-ol；2- Methoxyl group-4-(2-acrylic) phenol；(2E)-3,7-dimethyl-2,6-octadiene-1-alcohol；2-hydroxy-benzoic acid, (3Z)-3- Hexenyl ester；2-tridecylene nitrile；4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methyl-3-butene-2-one；Tetrahydrochysene-4- Methyl-2-(2-methyl-1-propylene base)-2H-pyrans；Acetic acid, (2-methylbutoxy group)-, 2-acrylic ester；Benzoic acid, 2-hydroxyl Base-, 3-methyl butyl ester；2-butylene-1-ketone, 1-(2,6,6-trimethyl-1-cyclohexene-1-base)-, (Z)-；Cyclopentane carboxylic acid, 2-hexyl-3-oxo-, methyl ester；Benzenpropanal, 4-ethyl-α, alpha-alpha-dimethyl-；3-cyclohexene-1-formaldehyde, 3-(4-hydroxyl-4-first Base amyl group)；Ethyl ketone, 1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a, 7-methanol azulene-5-base)-, [3R-(3α,3aβ,7β,8aα)]-；The hendecanal, 2-methyl-2H-pyran-2-one, 6-butyl tetrahydrochysene；Benzenpropanal, 4-(1,1-bis- Methylethyl)-Alpha-Methyl；2 (3H)-furanones, 5-heptyl dihydro-；Benzoic acid, 2-[(7-hydroxyl-3,7-dimethyl is octylene) Amino]-, methyl；Benzoic acid, 2-hydroxyl-, benzene methyl；Naphthalene, 2-methoxyl group-；2-cyclopentene-1-one, 2-hexyl-；2 (3H)-furans Mutter ketone, 5-hexyl dihydro；Oxirane formic acid, 3-methyl-3-phenyl-, ethyl ester；2-oxabicyclo [2.2.2] octane, 1,3, 3-trimethyl-；Fenipentol, γ-methyl-；3-capryl alcohol, 3,7-dimethyl-；3,7-dimethyl-2,6-octadiene nitrile；3,7-diformazan Base-6-octen-1-ol；Terpinyl acetate；2-methyl-6-methylene-7-octen-2-ol, dihydro derivative；Propanoic acid 3a, 4, 5,6,7,7a-hexahydro-4,7-methanol-1H-indenes-6-phenolic ester；Acetic acid 3-M2BOL ester；Acetic acid (Z)-3-hexene- 1-alcohol ester；2-ethyl-4-(2,2,3-trimethyl-3-cyclopentenes-1-base)-2-butylene-1-alcohol；4-(octahydro-4,7-methanol-5H- Indenes-5-subunit)-butyraldehyde；3-2,4-Dimethyl-cyclohex alkene-1-formaldehyde；1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-four Methyl-2-naphthyl)-ethyl ketone；2-hydroxy-benzoic acid, methyl ester；2-hydroxy-benzoic acid, own ester；2-phenoxy-ethanol；2-hydroxyl- Benzoic acid, pentyl ester；2,3-heptadione；2-hexen-1-ol；6-octen-2-ol, 2,6-dimethyl；Damascone (α, β, γ or δ or Their mixture), 4,7-methanol-1H-indenes-6-phenol, 3a, 4,5,6,7,7a-hexahydros-, acetas；9-undecylene aldehyde；8-ten One olefine aldehydr；Isocyclocitral；Ethyl ketone, 1-(1,2,3,5,6,7,8,8a-octahydro-2,3,8,8-tetramethyl-2-naphthyls)-；3-ring Hexene-1-formaldehyde, 3,5-dimethyl-；3-cyclohexene-1-formaldehyde, 2,4-dimethyl-；1,6-octadiene-3-alcohol, 3,7-diformazans Base-；1,6-octadiene-3-alcohol, 3,7-dimethyl-, acetas；Lilestralis (p-t-Bucinal) and Ketocyclopentane, 2-[2-(4-first Base-3-cyclohexene-1-base) propyl group]-and 1-methyl-4-(1-methyl ethylene) cyclohexene and their mixture.
In one aspect, described compositions can comprise the perfume particle of encapsulating, and it comprises water soluble hydroxy compound or three Melamine-formaldehyde or the polyvinyl alcohol of modification.In one aspect, described encapsulation object comprises (a) and has one or more water solublity hydroxyls At least part of water miscible solid matrix of based compound, preferred starch；(b) perfumery oil encapsulated by solid matrix.
In yet another aspect, described spice can be with polyamine (preferably polyethylene imines) its pre-mated, in order to form Schiff's base.
The compositions of the water-solubility membrane present invention also can be encapsulated in water-solubility membrane.Preferably membrane material is preferably polymerization Thing material.As it is known in the art, described membrane material can be by such as pouring into a mould polymeric material, be blow molded, extrude or be blow molded Extrude and obtain.
The compositions of health and the stench present invention also can comprise zinc ricinate, thymol, quaternary ammonium salt (as ), polymine is (as derived from BASF) and Zn complex, silver and silver compound (be especially intended to slowly release Put Ag+Or those of nanometer silver dispersion) in one or more.
Compositions described in probiotic bacteria can comprise probiotic bacteria.
Fabric softener: alternatively, described compositions can be fabric-softening/reagent treatment that rinsing is added.
1. preferred fabric-softening reactive compound
The fabric-softening active substance of the first preferred type comprises following formula: compound as main active substances
{R4-m-N+-[(CH2)n-Y-R1]m}X- (1)
The most each R substituent is hydrogen, short chain C1-C6, preferred C1-C3Alkyl or hydroxyalkyl group such as methyl, ethyl, third Base, ethoxy etc., poly-(C2-3Alkoxyl), preferred polyethoxy, benzyl, or their mixture；Each m is 2 or 3；Each n It is 1 to about 4, preferably 2；Each Y is-O-(O) C-,-C (O)-O-,-NR-C (O)-or-C (O)-NR-；Each R1In carbon total With for C12-C22, preferably C14-C20, when Y be-O-(O) C-or-NR-C (O)-time, carbon summation adds one, each R1For alkyl or replacement Hydrocarbyl group, and X-Can be the compatible anion of any softening agent, preferably chloride ion, bromide ion, methylsulfate, ethyl ester Sulfate radical, sulfate radical and nitrate anion, more preferably chloride ion or methylsulfate；
The preferred fabric of the second type softens active substance and has a formula:
[R3N+CH2CH(YR1)(CH2YR1)]X-
The most each Y, R, R1And X-There is implication same as above.This compounds includes having those of the formula:
[CH3]3N(+)[CH2CH(CH2O(O)CR1)O(O)CR1]C1(-) (2)
The most each R is methyl or ethyl group, and preferably, each R1At C15To C19In the range of.As used herein , when being appointed as diester, it can include the monoesters existed.
Preferably the example of DEQA (2) is " propyl group " with formula 1,2-bis-(acyloxy)-3-thmethylpropyl ammonium chloride Ester quaternary ammonium fabric softener active.
The preferred fabric-softening active substance of the third type has a formula:
[R4-m-N+-R1 m]X- (3)
The most each R, R1And X-There is implication same as above.
The preferred fabric-softening active substance of the 4th type has a formula:
The most each R, R1And A-There is implication given above；Each R2For C1-6Alkylidene group, preferably ethylidene base Group；And G is oxygen atom or-NR-group；
The preferred fabric-softening active substance of the 5th type has a formula:
Wherein R1、R2With G as defined above.
The preferred fabric-softening active substance of the 6th type is fatty acid and two alkylenes that such as molecular proportion is about 2:1 The condensation reaction products of base triamine, described product comprises the compound of following formula:
R1-C(O)-NH-R2-NH-R3-NH-C(O)-R1 (6)
Wherein R1、R2As defined above, and each R3For C1-6Alkylidene group, preferably ethylene group, and wherein Can be the most quaternized by product by addition alkylating agent such as dimethyl sulfate.
The preferred fabric-softening active substance of the 7th type has a formula:
[R1-C(O)-NR-R2-N(R)2-R3-NR-C(O)-R1]+A- (7)
Wherein R, R1、R2、R3And A-As defined above；
The preferred fabric-softening active substance of the 8th type is fatty acid and the hydroxyalkyl alkylene that molecular proportion is about 2:1 The product of base diamidogen, described product comprises the compound of following formula:
R1-C(O)-NH-R2-N(R3OH)-C(O)-R1 (8)
Wherein R1、R2And R3As defined above；
The preferred fabric-softening active substance of the 9th type has a formula:
Wherein R, R1、R2And A-As defined above.
The non-limiting example of compound (1) is double (steroyl oxyethyl)-N, the N-alkyl dimethyl ammonium chloride of N, N-, N, N-couple (Adeps Bovis seu Bubali acyloxyethyl)-N, N-alkyl dimethyl ammonium chloride, double (steroyl oxyethyl)-N-(2-the hydroxyethyl)-N-methyl first of N, N- Ester ammonium sulfate.
The non-limiting example of compound (2) is 1,2-bis-(stearoyl-oxy)-3-thmethylpropyl ammonium chloride.
The non-limiting example of compound (3) is two alkylidene dimethyl ammoniums, as two canola oil base alkyl dimethyl ammonium chlorides, Two (firmly) tallow dimethyl ammonium chloride, two canola oil base dimethyl ammonium methyl sulfate.Can be used in the present invention commercially available obtains The example of the two alkylidene dimethyl ammoniums obtained is with trade name472 two oil deriving from Witco Corporation Base alkyl dimethyl ammonium chloride and derive from the two hard tallow dimethyl ammonium chloride of Akzo Nobel with trade name Arquad 2HT75.
The non-limiting example of compound (4) is with trade nameCommercially available from Witco Corporation 1-methyl isophthalic acid-stearoyl amino-ethyl-2-stearoyl imidazoline methosulfate, wherein R1For acyclic aliphatic C15-C17Alkyl Group, R2For ethylene group, G is NH group, R5For methyl group, and A-For methylsulfate anion.
The non-limiting example of compound (5) is 1-Adeps Bovis seu Bubali acylamino-ethyl-2-Adeps Bovis seu Bubali acyl imidazoline, wherein R1For acyclic Aliphatic series C15-C17Hydrocarbyl group, R2For ethylene group, and G is NH group.
The non-limiting example of compound (6) is that the reaction of fatty acid and diethylenetriamines that molecular proportion is about 2:1 is produced Thing, described mixture of reaction products comprises the N with following formula, N "-dialkyl group diethylenetriamines:
R1-C(O)-NH-CH2CH2-NH-CH2CH2-NH-C(O)-R1
Wherein R1-C (O) is that the commercially available fatty acid of plant or animal origin is (as purchased from Henkel Corporation's223LL or7021) alkyl group, and R2And R3For divalent ethylene Group.
The non-limiting example of compound (7) is to have the softening agents based on two fat amidoamines of following formula:
[R1-C(O)-NH-CH2CH2-N(CH3)(CH2CH2OH)-CH2CH2-NH-C(O)-R1]+CH3SO4 -
Wherein R1-C (O) is to be alkyl group, such as with trade name222LT is from Witco Corporation is commercially available.
The example of compound (8) is that the reaction of fatty acid and N-2-ethoxy ethylene diamine that molecular proportion is about 2:1 is produced Thing, described mixture of reaction products comprises the compound of following formula:
R1-C(O)-NH-CH2CH2-N(CH2CH2OH)-C(O)-R1
Wherein R1-C (O) is that the commercially available fatty acid of plant or animal origin is (as purchased from Henkel Corporation's223LL or7021) alkyl group.
The example of compound (9) is to have the diquaternary ammonium compound of following formula:
Wherein R1Derived from fatty acid, and described compound is purchased from Witco Company.
Should be appreciated that the combination of above-disclosed softener active is applicable to the present invention.
Anion A
In this paper cation is containing nitrogen salt, anion A-It it is any anion compatible with softening agent, it is provided that electric neutrality.? Commonly, being used for providing electroneutral anion to come from strong acid in these salt, especially halogen ion, such as chloride ion, bromine Ion or iodide ion.But, other anion can be used, as methyl-sulfuric acid root, etherosulfuric acid root, acetate, formate, sulfate radical, Carbonate etc..Chloride ion and methyl-sulfuric acid root are in this article preferably as anion A.Anion can also but the most preferably with double Electric charge, in this case, A-Represent half group.
Organosilicon can use additional organosilicon.Suitably organosilicon comprises Si-O part, and is selected from (a) non-official Siloxane polymer, (b) functional silicone polymer, and combinations thereof can be changed.The molecular weight of described organosilicon is usual Can be illustrated by the viscosity with reference to described material.In one aspect, organosilicon can have about 10 centistokes to about 2 at 25 DEG C, The viscosity of 000,000 centistoke.On the other hand, suitable organosilicon can have about 10 centistokes to about 800,000 lis at 25 DEG C The viscosity of stoke.
Suitably organosilicon can be straight chain, side chain or crosslinking.In one aspect, described organosilicon can comprise organosilicon tree Fat.Organic siliconresin is highly cross-linked polymeric siloxane systems.Crosslinking is during preparing organic siliconresin, by by three The silane of sense and four senses and simple function or dual functional silane or both combine and introduce.As used herein, name SiO " n "/2 represent the ratio of oxygen and silicon atom.Such as, SiO1/2Represent that an oxygen is shared between two Si atoms.Equally, SiO2/2 Represent that two oxygen atoms are shared between two silicon atoms, and SiO3/2Represent that three oxygen atoms are shared between two silicon atoms.
Specifically, organosilicon material and organic siliconresin can be referred to as " MDTQ " according to known to persons of ordinary skill in the art Name shorthand nomenclature system and be identified easily.Under this system, according to the various siloxanes constituting organosilicon existed Monomeric unit describes organosilicon.In short, symbol M represents monofunctional unit (CH3)3SiO0.5；D represents difunctional unit (CH3)2SiO；T represents trifunctional units (CH3)SiO1.5；And Q represents season-or four-functional unit SiO2.Unit symbol upper Mark (such as M', D', T' and Q') represents the substituent group in addition to methyl, and specifically must define when occurring every time.
The organosilicon of other modification or Organosiliconcopolymere can also be used for herein.These example includes based on organosilicon Quaternary ammonium compound (Kennan quaternary salt)；End season type siloxanes；Organosilicon amino polyalkylene oxide block copolymer；Hydrophilic Property organic silicon emulsion；With the polymer being made up of one or more crosslinking rake or comb shape Organosiliconcopolymere segment.
In one aspect, described organosilicon can include the nonfunctionalized siloxane polymer with following formula (XXIV), and Poly-alkyl and/or phenyl silicone fluid, resin and/or natural gum can be included.
[R1R2R3SiO1/2]n[R4R4SiO2/2]m[R4SiO3/2]j
Formula (XXIV)
Wherein:
i)R1、R2、R3And R4H ,-OH, C can be each independently selected from1-C20Alkyl, C1-C20Substituted alkyl, C6-C20Virtue Base, C6-C20Substituted aryl, alkylaryl and/or C1-C20Alkoxy portion；
Ii) n can be about 2 to about 10, or about 2 to about 6, or the integer of 2 so that n=j+2；
Iii) m can be about 5 to about 8,000, about 7 to about 8,000, or the integer of about 15 to about 4,000；
Iv) j can be 0 to about 10, or 0 to about 4, or the integer of 0；
In one aspect, R2、R3And R4Methyl, ethyl, propyl group, C can be included4-C20Alkyl and/or C6-C20Aryl moiety. In one aspect, R2、R3And R4Methyl can be respectively.Close each R of the organosilicon end of the chain1Part can comprise selected from following portion Point: hydrogen, methyl, methoxyl group, ethyoxyl, hydroxyl, propoxyl group and/or aryloxy group.
In an aspect, described organosilicon can be dimethione, polydimethylsiloxane, polydimethylsiloxane Alcohol, Dimethicone Crosspolymer, phenyltrimethicone, poly-alkyl dimethicone, polyoxyethylene lauryl base two Methylsiloxane, poly-stearyl dimethicone and polyphenylene dimethyl siloxane.Example includes with trade name DC 200Fluid, DC 1664, DC 349, DC 346G are purchased from DowThose of Corporation (Midland, MI), And with trade name SF1202, SF1204, SF96 andPurchased from Momentive Silicones (Waterford, NY) those.
In one aspect, described organosilicon can include cyclic organic.Described cyclic organic can include by formula [(CH3)2SiO]nThe cyclomethicone represented, wherein n is that scope is about 3 to about 7, or the integer of about 5 to about 6.
In an aspect, described organosilicon can include functional silicone polymer.Functional silicone polymer can Comprise one or more functional moieties, described functional moieties selected from amino, acylamino-, alkoxyl, hydroxyl, polyethers, carboxyl, Hydrion, sulfydryl, sulfate radical, phosphate radical and/or quaternary ammonium group.These parts can be directly connected to by divalent alkylene groups On siloxane main chain (i.e. " side base "), it can be maybe a part for main chain.Suitable functional silicone polymer includes being selected from Following material: amido organosilicon, acylamino-organosilicon, organic silicon polyether, organosilicon-urethane polymer, season ABn have Machine silicon, amino ABn organosilicon and combinations thereof.
In one aspect, functional silicone polymer can include organic silicon polyether, and it is also known as " polydimethylsiloxane Polyol ".In general, organic silicon polyether comprises polydimethylsiloxanebackbone backbone and one or more polyoxyalkylenes Chain.Described polyoxyalkyl base section can be incorporated in described polymer as side chain or as end-blocks.Commercially available Exemplary silicone polyethers include being purchased from DowThe DC 190 of Corporation, DC 193, FF400, and Various purchased from Momentive SiliconesSurfactant.
In another aspect, described functional silicone polymer can include amido organosilicon.On the other hand, amino has Machine silicon can have a structure of formula (XXV):
[R1R2R3SiO1/2]n[(R4Si(X-Z)O2/2]k[R4R4SiO2/2]m[R4SiO3/2]j
Formula (XXV)
Wherein
i.R1、R2、R3And R4H, OH, C can be each independently selected from1-C20Alkyl, C1-C20Substituted alkyl, C6-C20Virtue Base, C6-C20Substituted aryl, alkylaryl and/or C1-C20Alkoxyl；
The most each X can be independently selected from the divalent alkylene groups-(CH comprising 2-12 carbon atom2) s-, wherein s can It is about the integer of 2 to about 10；–CH2–CH(OH)-CH2–；And/or
The most each Z can be independently selected from N (R5)2；The most each R5Can be only On the spot selected from H, C1-C20Alkyl；And A-It can be compatible anion.In one aspect, A-It can be halogen ion；
Iv.k can be about 3 to about 20, about 5 to about 18, or the integer of the most about 5 to about 10；
V.m can be about 100 to about 2,000, or the integer of about 150 to about 1,000；
Vi.n can be about 2 to about 10, or about 2 to about 6, or the integer of 2 so that n=j+2；And
Vii.j can be 0 to about 10, or 0 to about 4, or the integer of 0；
In one aspect, R1OH can be included.In this aspect, described organosilicon is acylamino-polymethyl siloxane.Commercially available The exemplary amido organosilicon obtained includes DC 8822,2-8177 and DC-purchased from Dow Corning Corporation 949, and the KF-873 purchased from Shin-Etsu Silicones (Akron, OH).
In one aspect, described organosilicon is selected from having the random of following formula or block organosilicon polymer:
[R1R2R3SiO1/2](j+2)[(R4Si(X-Z)O2/2]k[R4R4SiO2/2]m[R4SiO3/2]j
Wherein:
J is the integer of 0 to about 98；In one aspect, j is the integer of 0 to about 48；In one aspect, j is 0；
K is the integer of 0 to about 200, and in one aspect, k is the integer of 0 to about 50；As k=0, R1、R2Or R3In at least One is X Z；
M is the integer of 4 to about 5,000；M is about the integer of 10 to about 4,000 in one aspect；M is about on the other hand The integer of 50 to about 2,000；
R1、R2And R3It is each independently selected from H, OH, C1-C32Alkyl, C1-C32Substituted alkyl, C5-C32Or C6-C32Virtue Base, C5-C32Or C6-C32Substituted aryl, C6-C32Alkylaryl, C6-C32Substituted alkylaryl, C1-C32Alkoxyl, C1-C32 Substituted alkoxyl and X-Z；
Each R4Independently selected from H, OH, C1-C32Alkyl, C1-C32Substituted alkyl, C5-C32Or C6-C32Aryl, C5-C32 Or C6-C32Substituted aryl, C6-C32Alkylaryl, C6-C32Substituted alkylaryl, C1-C32Alkoxyl and C1-C32Substituted Alkoxyl；
Each X in described alkyl siloxane polymer all includes substituted or unsubstituted comprising the two of 2-12 carbon atom Valency alkylidene group, in one aspect, each divalent alkylene groups is all independently selected from-(CH2) s-, wherein s is about 2 to about 8, the integer of about 2 to about 4；In one aspect, each X in described alkyl siloxane polymer all includes substituted divalent alkylene Base group, it is selected from: CH2–CH(OH)-CH2–；–CH2–CH2-CH(OH)–；With
Each Z independently selected from
Condition is when Z is season type, and Q can not be amide, imines or urea part；
For Z, An-For suitable charge balancing anion.In one aspect, An-Selected from Cl-、Br-、I-, methyl-sulfuric acid Root, tosylate, carboxylate radical and phosphate radical；And at least one Q in described organosilicon is independently selected from CH2–CH (OH)-CH2-R5；
Each additional Q in described organosilicon is independently selected from H, C1-C32Alkyl, C1-C32Substituted alkyl, C5-C32 Or C6-C32Aryl, C5-C32Or C6-C32Substituted aryl, C6-C32Alkylaryl, C6-C32Substituted alkylaryl, CH2–CH (OH)-CH2-R5；
The most each R5Independently selected from H, C1-C32Alkyl, C1-C32Substituted alkyl, C5-C32Or C6-C32Aryl, C5- C32Or C6-C32Substituted aryl, C6-C32Alkylaryl, C6-C32Substituted alkylaryl, (CHR6-CHR6-O-)w-L and first silicon Alkoxy residue；
Each R6Independently selected from H, C1-C18Alkyl
Each L is independently selected from C (O)-R7Or R7；
W is the integer of 0 to about 500, and in one aspect, w is about the integer of 1 to about 200；In one aspect, w be about 1 to The integer of about 50；
Each R7Independently selected from H；C1-C32Alkyl；C1-C32Substituted alkyl, C5-C32Or C6-C32Aryl, C5-C32Or C6-C32Substituted aryl, C6-C32Alkylaryl；C6-C32Substituted alkylaryl and siloxy residue；
Each T independently selected from H and Further,
Each v in wherein said organosilicon is the integer of 1 to about 10, and in one aspect, v is the integer of 1 to about 5, And all v subscript sums of each Q are 1 to about 30 in described organosilicon, or 1 to about 20, or the integer of even 1 to about 10.
In one aspect, described organosilicon can include amine ABn organosilicon and season ABn organosilicon.This type of organosilicon is the most logical Prepared by the reaction crossing diamidogen and epoxide.These can be with trade namePrime、JSS、A-858 commercially available (being purchased from Momentive Silicones).
Deposition aid-in one aspect, fabric treatment composition can include about 0.01% to about 10%, and about 0.05% to about 5%, or the deposition aid of about 0.15% to about 3%.
In one aspect, deposition aid can be cation or amphiphilic polymers.In one aspect, described deposition aid can be Cationic polymer.In general, cationic polymer and their preparation method are known in the literatures.In one aspect, Described cationic polymer uses under pH in the expection of described compositions, can have about 0.005 to about 23, about 0.01 to about 12, Or about 0.1 to about 7 milliequivalent/gram cationic charge density.Wherein charge density is depended on that described compositions pH contains Amine polymer, the expection at described product uses and measures charge density under pH.This type of pH typically about 2 to about 11, more typically exist In the range of about 2.5 to about 9.5.By by the net charges of each repetitive divided by the molecular weight of described repetitive, meter Calculate charge density.Positive charge can be located on main polymer chain and/or polymer lateral chain.
One group of suitable cationic polymer includes by using suitable initiator or catalyst, unsaturated by ethylenic Monomer is polymerized those prepared.Suitable polymer be selected from cation or amphoteric polysaccharide, polymine and derivant thereof and Being polymerized, by one or more cationic monomers and optional second comonomer, the synthetic polymer prepared, described cationic monomer selects The freely group of following composition: acrylic acid N, N-dialkyl aminoalkyl ester, methacrylic acid N, N-dialkyl aminoalkyl ester, N, N-dialkylaminoalkyl acrylamide, N, N-dialkyl aminoalkyl Methacrylamide, quaternized acrylic acid N, N-bis- Alkylaminoalkyl, quaternized methacrylic acid N, N-dialkyl aminoalkyl ester, quaternized N, N-dialkyl amido Alkyl acrylamide, quaternized N, N-dialkyl aminoalkyl Methacrylamide, methacryiamidopropyl-five first Base-1,3-propylene-2-alcohol dichloride ammonium, N, N, N, N', N', N ", N " and-seven methyl-N "-3-(1-epoxide-2-methyl-2-propylene Base) aminopropyl-9-epoxide-8-azo decane-1,4,10-tri-chlorination three ammonium, vinylamine and derivant, allylamine and spread out Biology, vinyl imidazole, quatemized vinylimidazol and poly (dially dialkyl) ammonium chloride and combinations thereof, described The group of two monomer choosing freely following compositions: acrylamide, N, N-dialkylacrylamides, Methacrylamide, N, N-dialkyl group Methacrylamide, acrylic acid C1-C12Arrcostab, acrylic acid C1-C12Hydroxy alkyl ester, acrylic acid poly alkylene glycol ester, methyl Acrylic acid C1-C12Arrcostab, methacrylic acid C1-C12Hydroxy alkyl ester, methacrylic acid poly alkylene glycol ester, vinyl acetate Ester, vinyl alcohol, vinyl formamide, vinyl acetamide, vinyl alkyl ethers, vinylpyridine, vinyl pyrrolidone, second Thiazolinyl imidazoles, caprolactam and derivant, acrylic acid, methacrylic acid, maleic acid, vinyl sulfonic acid, styrene sulphur Acid, acrylamidopropyl methanesulfonic acid (AMPS) and their salt.Described polymer can be optionally through using branched and crosslinking Monomer and branched or crosslinking.Branched and cross-linking monomer includes ethylene glycol diacrylate, divinylbenzene and butadiene.It is applicable to Polymine herein is with trade nameSell by BASF AG (Lugwigschaefen, Germany) that A bit.
In yet another aspect, described treatment compositions can comprise both sexes deposition aid polymer, if described polymer tool There is clean positive charge.Described polymer can have about 0.05 to about 18 milliequivalent/gram cationic charge density.
On the other hand, described deposition aid is selected from cationic polysaccharide, polymine and derivant thereof, poly-(propylene Amide-copolymerization-diallyldimethylammonium chloride), poly-(acrylamide-methacryiamidopropyl trimethyl ammonium chloride), Poly-(acrylamide-co-acrylic acid N, N-dimethylamino ethyl ester) and quaternary ammonium derivative thereof, poly-(acrylamide-co- Methacrylic N, N-dimethylamino ethyl ester) and quaternary ammonium derivative, poly-(2-(Acryloyloxy)ethanol-copolymerization-methacrylic acid Dimethylamino ethyl ester), poly-(Hydroxypropyl acrylate-copolymerization-dimethylaminoethyl methacrylate), poly-(acrylic acid hydroxypropyl Ester-copolymerization-methacryiamidopropyl trimethyl ammonium chloride), poly-(acrylamide-co-diallyidimethylammonium chloride Ammonium-copolymerization-acrylic acid), poly-(acrylamide-methacryiamidopropyl trimethyl ammonium chloride-copolymerization-acrylic acid), poly-(two Allyl dimethyl ammonium chloride), poly-(vinylpyrrolidone-co-dimethylaminoethyl methacrylate), poly-(methyl Ethyl acrylate-copolymerization-quaternized dimethylaminoethyl methacrylate), poly-(ethyl methacrylate-copolymerization-methyl-prop Olefin(e) acid grease-copolymerization-diethyl aminoethyl methacrylate), poly-(diallyldimethylammonium chloride-copolymerization-acrylic acid), Poly-(vinylpyrrolidone-co-quatemized vinylimidazol) and poly-(acrylamide-co-methacryl amido third Base pentamethyl-1,3-propylene-2-alcohol dichloride ammonium).Suitable deposition aid includes polyquaternary ammonium salt-1, polyquaternary ammonium salt-5, poly-season Ammonium salt-6, polyquaternary ammonium salt-7, polyquaternary ammonium salt-8, polyquaternary ammonium salt-11, polyquaternary ammonium salt-14, Merquat 280, polyquaternary ammonium salt-28, Polyquaternary ammonium salt-30, polyquaternium-32 and polyquaternary ammonium salt-33, it is according to " International Nomenclature for Cosmetic Ingredients " name.
In one aspect, described deposition aid can include polymine or polyethylenimine derivates.On the other hand, Deposition aid can include based on acrylic acid cationic polymer.On the other hand, deposition aid can include cation polypropylene Amide.On the other hand, described deposition aid can include comprising polyacrylamide and PMAm base oxypropyl trimethyl The polymer of ammonium cation.In yet another aspect, described deposition aid can comprise poly-(acrylamide and acrylic acid N-dimethylamino Base ethyl ester) and quaternary ammonium derivative.In in this regard, described deposition aid can be with trade nameBy BTC Specialty Chemicals (BASF Group, Florham Park, N.J.) sell those.In a further aspect, institute State deposition aid and can include poly-(acrylamide-co-methacryiamidopropyl trimethyl ammonium chloride).On the other hand In, described deposition aid can include the polymer being not based on acrylamide, as with trade nameCDE is purchased from Ciba Those of Specialty Chemicals (BASF Group, Florham Park, N.J.).
In yet another aspect, described deposition aid is selected from cation or amphoteric polysaccharide.In one aspect, described deposition helps Agent is selected from by the following group formed: cation and amphoteric cellulose ether, cation or both sexes galactomannan, cation melon Ear glue, cation or amphoteric starch and combinations thereof.
Another kind of suitable cationic polymer can include alkylamine-epichlorohydrin polymers, and it is amine and oligomeric amine and table The product of chloropharin.Example includes with trade nameCB andTSF derive from Clariant (Basle, Switzerland) dimethylamine-epichlorohydrin-ethylenediamine.
Another kind of suitable synthetic cationic polymers can include the polyamidoamines amine of polyalkylene polyamine and polybasic carboxylic acid- Chloropropylene oxide (PAE) resin.The most frequently used PAE resin is that diethylenetriamines reacts with adipic acid, reacts with chloropropylene oxide subsequently Condensation product.They are with trade name KymeneTMPurchased from Hercules Inc. (Wilmington DE) or with trade name LuresinTMPurchased from BASF AG (Ludwigshafen, Germany).
Described cationic polymer can comprise the anion neutralizing electric charge so that during whole polymer is at ambient conditions Property.Suitable counter ion (except use during produce anionic species in addition to) non-limiting example include chloride ion, Bromide ion, sulfate radical, methyl-sulfuric acid root, sulfonate radical, methanesulfonate, carbonate, bicarbonate radical, formate, acetate, citric acid Root, nitrate anion and their mixture.
Measured by the size exclusion chromatography (SEC) relative to polyoxyethylene reference material detected with RI, described polymer Weight average molecular weight can be about 500 to about 5,000,000, or about 1, and 000 to about 2,000,000, or about 2,500 to about 1,500, 000 dalton.In one aspect, the MW of cationic polymer can be about 500 to about 37,500 dalton.
Miscellaneous auxiliary component
Various other components can be used for herein in Cleasing compositions, including other active component, carrier, hydrotropic agent, Processing aid, dyestuff or pigment, liquid preparation and solid or the solvent of other liquid filler, erythrosine, colloidal silica, Wax, probiotics, Surfactin, aminocellulose polymer, zinc ricinate, perfume microcapsule, rhamnolipid, sophorolipid, Glycopeptide, methyl ester sulfonates, methyl ester ethoxylate, sulfonation lactide, decomposable asymmetric choice net surfactant, biopolymer, organic Silicon, modified organic silicon, amido organosilicon, deposition aid, locust bean gum, cationic hydroxyethyl cellulose polymer, cation melon Your glue, hydrotropic agent (especially cumene sulfonate, toluene fulfonate, dimethylbenzene sulphur salt and naphthalene salts), antioxidant, The dyestuff of BHT, PVA granule encapsulating or spice, pearling agent, effervescent, variable color system, organic silicon polyurethane, opacifier, lamellar collapse Solve agent, biomass filler, quick-drying organosilicon, diglycol stearate, HEC polymer, the fibre of hydrophobically modified Dimension element polymer or HEC polymer, starch perfume encapsulation object, oil emulsion, bisphenol antioxidant, microfibre fiber Element structural agent, fragrance precursor, phenylethylene ethylene/propenoic acid ester polymer, triazine, soap, superoxide dismutase, benzophenone protease Inhibitor, the Ti02 of functionalization, dibutylphosphoric acid ester, silicon dioxide flavor capsule agent, and other auxiliary component.
Method of testing
Method of testing:
For the method measuring the index of recovery of organic siloxane polymer.
Use stretching and compression verification instrument apparatus such as Instron Model 5565 (Massachusetts, United States promise Wood Instron Corporation (Instron Corp., Norwood, Massachusetts, U.S.A.)) measure index of recovery.Described Apparatus is by selecting arranged below configuration: pattern extends for stretching；Waveform shape is triangle；Maximum strain is 10%, speed is 0.83mm/s, and period is 4；And respectively the retention time between circulation is 15 seconds.
1) (a kind of suitable fabric is the combing warp flush sateen through mercerization finish to measure 100% cotton Woven fabric (Mercerized Combed Cotton Warp Sateen), product code 479, derive from Pennsylvania, America west hereby Testfabrics company (Testfabrics Inc., West Pittston, PA, USA)) an about 25.4cm just The weight of square sample.
2) mensuration deposits the amount of the organic siloxane polymer needed for 5mg polymer on every gram of fabric sample, and will The organic siloxane polymer of described amount weighs in the plastic centrifuge tube with cover of 50ml.
3) by solvent (example: isopropanol, THF, N, the N-dimethyl second being completely dissolved or disperseing organic siloxane polymer Amide, water) organic siloxane polymer is diluted to 1.3 times of described sample weight.
4) vibration or vortex stirring is used thoroughly to disperse or dissolve organic silicon polyurethane urea on demand.
5) being positioned to be laid in rustless steel pallet by fabric sample, described rustless steel pallet is more than described sample.
6) organic siloxane polymer solution is poured on whole sample as homogeneously as possible.
7) sample is folded 1/4th to four size, then rolled, simultaneously gently bounce the baby up extrude to divide solution It is scattered to whole sample.
8) launch and repeat step 7, folding along contrary direction
9) in order to prepare check sample, the solvent (inactive material) of 1.3X weight is only used to repeat said process.
10) each sample is laid on single aluminium foil, is then placed in fume hood being dried overnight.
11) each sample is solidified 5 minutes in the baking oven with suitably ventilation at 90 DEG C, (a kind of suitably baking oven For Mathis Labdryer, there is the rotation speed of the fan of 1500rpm) (masis joint-stock company is received in the Wal in the primary Haas of Austria of Switzerland (Werner Mathis AG,Oberhasli,Switzerland))。
12) make fabric be in steady temperature (21 DEG C +/-2 DEG C) and the indoor conditions of humidity (50%RH+/-5%RH) is assigned At least 6 hours.
13) shear the edge of a whole side of each sample along warp-wise with shears, and carefully not to fabric Remove a fabric threads, until obtaining flat edges in the case of pressurization every time.
14) from each sample, cut 4 parallel with described flat edges piece fabric stripe (die-cut or rotary-cut), described in knit Thing band is 2.54cm width and at least 10cm length
15) arrange with the interval of 2.54cm top and bottom (the narrower edge) of described fabric stripe are clamped equably In 2.54cm holder on cupping machine apparatus, a small amount of power (0.1N-0.2N) is loaded on sample.
16) 10% is elongated and with the interval of identical rate recovery to 2.54cm with 0.83mm/s.
17) unclamp bottom jig and again clamp sample during keeping circulation, load the power of 0.1N-0.2N to sample On.
18) repetition step 15 is to 16, until having been completed 4 hysteresis cycle of sample.
19) analyze 4 fabric samples of each process sample by said method and unload 0.1N load in circulation 4 The elongation strain value of Shi Jilu is averaged.Recovery rate is calculated as follows:
20)
Embodiment
Following non-limiting examples is illustrative.Except as otherwise noted, all percentage ratios are by weight.Although lifting Example illustrate and describes concrete aspect, but can carry out in the case of without departing from spirit and scope of the present invention other change and Modification.Therefore, it is intended in claims, contain all these changes belonging in the scope of the invention and modification.
The preparation of cross-linking organic siloxane polymer
Embodiment 1
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 7.090mmol is dissolved in 1.2g IPA. In single flask, by the α of 1.754mmol, ω-diaminopropyl polydimethylsiloxane (MW=11400g/mol) (ammonia Base organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by molten for PDMS oligomer Drop is added in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 5.104mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will The 3-dimethyl Ethoxysilane of 0.400mmol is dissolved in 0.7g IPA, joins in charging hopper, then in room Temperature is stirred vigorously down, is added drop-wise in the pre-polymer solution in reactor, to complete reaction.After reaction carries out and completes, by FTIR spectrum monitoring 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.
Embodiment 2
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 7.964mmol is dissolved in 1.2g IPA. In single flask, by the α of 2.000mmol, ω-diaminopropyl polydimethylsiloxane (MW=5000g/mol) (amino Organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by PDMS oligomer solution It is added drop-wise in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 5.864mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will The 3-dimethyl Ethoxysilane of 0.200mmol is dissolved in 0.7g IPA, joins in charging hopper, then in room Temperature is stirred vigorously down, is added drop-wise in the pre-polymer solution in reactor, to complete reaction.After reaction carries out and completes, by FTIR spectrum monitoring 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.
Embodiment 3
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 1.792mmol is dissolved in 1.2g IPA. In single flask, by the α of 0.400mmol, ω-diaminopropyl polydimethylsiloxane (MW=50000g/mol) (ammonia Base organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by molten for PDMS oligomer Drop is added in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 1.221mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will The 3-dimethyl Ethoxysilane of 0.400mmol is dissolved in 0.7g IPA, joins in charging hopper, then in room Temperature is stirred vigorously down, is added drop-wise in the pre-polymer solution in reactor, to complete reaction.After reaction carries out and completes, by FTIR spectrum monitoring 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.
Embodiment 4
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 7.090mmol is dissolved in 1.2g IPA. In single flask, by the α of 1.754mmol, ω-diaminopropyl polydimethylsiloxane (MW=11400g/mol) (ammonia Base organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by molten for PDMS oligomer Drop is added in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 5.104mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will [3-(2-aminoethylamino) propyl group] trimethoxy silane of 0.400mmol is dissolved in 0.7g IPA, joins charging hopper In, then under room temperature is stirred vigorously, it is added drop-wise in the pre-polymer solution in reactor, to complete reaction.Reaction carry out and After completing, FTIR spectrum monitor 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.
Embodiment 5
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 7.964mmol is dissolved in 1.2g IPA. In single flask, by the α of 2.000mmol, ω-diaminopropyl polydimethylsiloxane (MW=5000g/mol) (amino Organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by PDMS oligomer solution It is added drop-wise in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 5.864mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will [3-(2-aminoethylamino) propyl group] trimethoxy silane of 0.200mmol is dissolved in 0.7g IPA, joins charging hopper In, then under room temperature is stirred vigorously, it is added drop-wise in the pre-polymer solution in reactor, to complete reaction.Reaction carry out and After completing, FTIR spectrum monitor 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.
Embodiment 6
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 1.792mmol is dissolved in 1.2g IPA. In single flask, by the α of 0.400mmol, ω-diaminopropyl polydimethylsiloxane (MW=50000g/mol) (ammonia Base organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by molten for PDMS oligomer Drop is added in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 1.221mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will [3-(2-aminoethylamino) propyl group] trimethoxy silane of 0.400mmol is dissolved in 0.7g IPA, joins charging hopper In, then under room temperature is stirred vigorously, it is added drop-wise in the pre-polymer solution in reactor, to complete reaction.Reaction carry out and After completing, FTIR spectrum monitor 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.
Embodiment 7
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 7.090mmol is dissolved in 1.2g IPA. In single flask, by the α of 1.754mmol, ω-diaminopropyl polydimethylsiloxane (MW=11400g/mol) (ammonia Base organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by molten for PDMS oligomer Drop is added in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 5.104mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will The 3-dimethyl Ethoxysilane of 0.400mmol is dissolved in 0.7g IPA, joins in charging hopper, then in room Temperature is stirred vigorously down, is added drop-wise in the pre-polymer solution in reactor, to complete reaction.After reaction carries out and completes, by FTIR spectrum monitoring 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.Add (the diethyl of 6.400mmol Amino) MTES with complete preparation.
Embodiment 8
In the reactor, double (4-isocyanatocyclohexyl) methane (HMDI) of 7.090mmol is dissolved in 1.2g IPA. In single flask, by the α of 1.754mmol, ω-diaminopropyl polydimethylsiloxane (MW=11400g/mol) (ammonia Base organosilicon) it is dissolved in 4.8g IPA, it is then added in charging hopper.Under room temperature is stirred vigorously, by molten for PDMS oligomer Drop is added in HMDI solution.Then 1,3-diaminourea-2-hydroxy propane (cahin extension agent) of 5.104mmol is dissolved in 1.2g IPA In, join in charging hopper, then under room temperature is stirred vigorously, be added drop-wise in the pre-polymer solution in reactor.Then will The 3-dimethyl Ethoxysilane of 0.400mmol is dissolved in 0.7g IPA, joins in charging hopper, then in room Temperature is stirred vigorously down, is added drop-wise in the pre-polymer solution in reactor, to complete reaction.After reaction carries out and completes, by FTIR spectrum monitoring 2265cm-1Place's strong absworption peak of isocyano disappears, it is thus achieved that object construction.Add the methyl three of 6.400mmol Ethoxysilane is to complete preparation.
Table II. embodiment 9-17: exemplary rinse-added fabric care compositions
By composition shown below is mixed, prepare nine (9) and plant the Fabrid care compositions that different rinsing is added:
Owing to there are eight kinds of different polymer, add their mixture, prepare nine kinds of different compositionss.
Table III. embodiment 18-26: exemplary rinse-added fabric care compositions
By composition shown below is mixed, prepare nine (9) and plant the Fabrid care compositions that different rinsing is added:
Owing to there are eight kinds of different polymer, add their mixture, prepare nine kinds of different compositionss.
Table IV. embodiment 27-36: exemplary fluids detergent Fabrid care composition: by shown ratio by listed Composition mixes, and prepares nine (9) and plants different liquid detergent Fabrid care compositions.
Owing to there are eight kinds of different polymer, add their mixture, prepare nine kinds of different compositionss.
Table IV. embodiment 37-46: exemplary fluids detergent Fabrid care composition: by shown ratio by listed Composition mixes, and prepares nine (9) and plants different liquid detergent Fabrid care compositions.
Owing to there are eight kinds of different polymer, add their mixture, prepare nine kinds of different compositionss.
1Purchased from Degussa Corporation (Hopewell, VA).
2Purchased from Sigma Aldrich (Milwaukee, WI).
3Purchased from Nalco Chemicals (Naperville, IL).
4Purchased from Shell Chemicals (Houston, TX).
5Purchased from Degussa Corporation (Hopewell, VA).
6Purchased from Shell Chemicals (Houston, TX).
7Purchased from Genencor International (South San Francisco, CA).
8Purchased from Ciba Specialty Chemicals (High Point, NC).
9Purchased from Procter&Gamble.
10Purchased from Huntsman Chemicals (Salt Lake City, UT).
11Chelating agen, with trade nameSell, derive from BASF (Ludwigshafen, Germany) and retouch It is set forth in WO 01/05874.
12Purchased from Dow Chemicals (Edgewater, NJ).
13Purchased from Stepan Chemicals (Northfield, IL).
Dimension disclosed herein and value are not understood as being strictly limited to cited exact numerical.On the contrary, unless additionally Indicating, the most each such dimension is intended to indicate that described value and around the functionally equivalent scope of this value.Such as, it is disclosed as The dimension of " 40mm " is intended to indicate that " about 40mm ".
Unless expressly excluded or limit, by every herein cited document, including any cross reference or Patents or Patent application, is incorporated by reference in its entirety herein.Any document quote be not to its as disclosure any with the present invention or The accreditation of the most claimed prior art, or be not to himself or with any other list of references or multiple The combination of list of references proposes, advises or discloses this accreditation inventing any aspect.Additionally, as term any in the present invention When implication or definition and any implication of same term in the file that is incorporated by reference or definition contradiction, it should obey at this Invention gives implication or the definition of this term.
Although having illustrate and described specific embodiments of the present invention, but those skilled in the art are come Say it is readily apparent that multiple other can be made in the case of without departing from spirit and scope of the present invention to be changed and amendment.Therefore, It is intended in claims, contain all these changes belonging in the scope of the invention and modification.

Claims (15)

1. a Fabrid care composition, described Fabrid care composition comprises:
A) based on total Fabrid care composition weight meter 0.01% to 30%, preferably 0.01% to 20%, more preferably 0.1% To 10%, the most preferably organic siloxane polymer with following formula I, Formula II or formula III of 0.5% to 5%:
Described Formulas I comprises totally 1 to 200 Q, and each Q that described Formula II comprises 2 to 200 Q, Formulas I and Formula II selects independently From following formula I V, Formula V and Formula IV:
Wherein for each of Formulas I to Formula IV:
(i) each X independently selected fromAnd combinations thereof；
(ii) each L is divalent alkyl linking group, the most each L independently selected from-(CH2)s-；Most preferably L is-(CH2)s-；
(iii) at least one, preferably at least two, more preferably at least three R-portion be-OR2, and other R-portion all Independently selected from H, C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted aryl base Group, C7-C20Kiki fang alkyl group and combinations thereof, preferably 1 to 6, preferably 2 to 6, more preferably 2 to 4 R-portion For-OR2, and described R-portion and end Si covalent bond；
(iv) each R1Independently selected from H, C1-C20Alkyl group, C6-C10Aromatic yl group, C1-C4Substituted alkyl group and C6- C10Group of naphthene base；Preferably, each R1Independently selected from H and C1-C4Alkyl group；It is highly preferred that each R1For H；
(v) each R2Independently selected from H, C1-C4Alkyl group ,-C (O) R6, the most each R6Independently selected from C1-C20Alkyl base Group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted aromatic yl group and C7-C20Kiki fang alkyl group；
(vi) each R3Independently selected from comprise 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, more preferably 6 to 14 The aromatic group of carbon atom, comprises 2 to 30 carbon atoms, preferably 2 to 20 carbon atoms, more preferably 2 to 14 carbon atoms Aliphatic group, and comprise 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, more preferably 6 to 14 carbon atoms Alicyclic group；And
(vii) each R4Independently selected from H, C1-C20Alkyl group, C6-C10Aromatic yl group, C1-C4Substituted alkyl group and C6-C10Group of naphthene base；Preferably, each R4Independently selected from H and C1-C4Alkyl group；It is highly preferred that each R4For H；
(viii) each R5Independently selected from H, C1-C4Alkyl group, C1-C4Substituted alkyl group, C6-C10Aromatic yl group and C6-C10Substituted aromatic yl group；Preferably, each R5Independently selected from H and C1-C2Alkyl group；
(ix) each W inserts described C independently selected from optionally comprising at least one1-C200The heteroatomic C of chain1-C200Alkylene Base group, or optionally comprise the described C of at least one insertion1-C200The hetero atom of chain and/or optionally comprise at least one and insert Enter the heteroatomic substituted C of described substituent group1-C200Alkylidene group；Preferably, each W is independently selected from optionally comprising At least one inserts described C1-C100The heteroatomic C of chain1-C100Alkylidene group, or optionally comprise at least one insertion institute State C1-C100The hetero atom of chain and/or optionally comprise at least one heteroatomic substituted C inserting described substituent group1-C100 Alkylidene group；Preferably, described C1-C100Chain is inserted by least one hetero atom；It is highly preferred that each W is independently selected from appointing Selection of land comprises at least one and inserts described C1-C10The hetero atom of chain and/or optionally comprise at least one and insert described substituent group Heteroatomic substituted C1-C10Alkylidene group；Preferably, each W independently selected from Wherein forR5With y the most previous institute State
X () p is 2 to 2000, preferably 2 to 1000, more preferably 10 to 400, and the most preferably integer of 20 to 200；
(xi) s is 2 to 83, preferably 2 to 10, and the integer of more preferably 2 to 4；
(xii) y is 1 to 50, preferably 1 to 20, and the integer of more preferably 1 to 10；
(xiii) n is 0 to 50, preferably 1 to 50, more preferably 1 to 20, and the most preferably integer of 1 to 10；
(xiv) k is selected from 0 to 100, preferably 1 to 50, and the integer of more preferably 5 to 20；With
The most optionally, there is formula Si (R7)m(OR8)jMaterial, wherein said index j is 1 to 4, and described exponent m=4-j, And each R7Independently selected from C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Replace Aromatic yl group and C7-C20Kiki fang alkyl group, it is preferable that R7Comprise double bond, and each R8Independently selected from H, C1-C20Alkane Base group, C1-C20Substituted alkyl group, C6-C20Aromatic yl group, C6-C20Substituted aromatic yl group, C7-C20Alkylaryl base Group and-C (O) R9, the most each R9Independently selected from C1-C20Alkyl group, C1-C20Substituted alkyl group, C6-C20Aryl base Group, C6-C20Substituted aromatic yl group and C7-C20Kiki fang alkyl group；
The most optionally, dicyandiamide solution
The most optionally, carrier, the most described carrier is selected from polymer, wax, salt and their mixture, it is preferable that described Polymer is selected from polysaccharide, Polyethylene Glycol and their mixture, and described salt is selected from detergent builders；With
The most optionally, surfactant based on total Fabrid care composition weight meter 0.1% to 95%, it is preferable that described table Face activating agent is selected from: anion surfactant, and the most described anion surfactant is selected from alkylbenzenesulfonate, alkyl Sulfate and alkyl aryl sulfate, alkyl carboxylate and alkylaryl carboxylic acids's salt, alkyl ethoxy sulfate, alkyl glycerol base Sulfonate, ammonium lauryl sulfate, sodium lauryl sulfate, sodium laureth sulfate, linear alkylbenzene sulfonate (LAS) and Their mixture；Cationic surfactant, the most described cationic surfactant is selected from alkyl trimethyl ammonium salt, whale Cerul trimethylammonium bromide, CTAB, cetyl pyridinium chloride, quaternary surfactant, ester quaternary ammonium compounds Thing and their mixture；Amphoteric surfactant, the most described amphoteric surfactant is selected from Cocamidopropyl Glycine betaine, lauramido propyl betaine, oleoyl amidopropyl betaine, ricinoleic acid amido propyl betaine, spermaceti Base glycine betaine and dimerization Asia oleoyl amidopropyl betaine, sulfobetaines, hydroxyl sulfo betaine and thetine, oxidation Amine and their mixture；Nonionic surfactant, the most described nonionic surfactant is selected from polyoxyalkylene Glycol alkyl ether, alkyl ethoxylate, glucoside alkyl ether, polyoxyalkylene glycol octyl phenol ether, polyoxyalkylene two Alcohol alkylbenzene 2, 2-Oxydiphenol and their mixture；And their mixture, it is highly preferred that described surfactant is selected from straight chain Or branch-alkylbenzene sulfonate, alkyl sulfate, alkyl ethoxy sulfate, alkyl ethoxylate, alkyl glycerol base sulfonic acid Salt, quaternary surfactant, ester quaternary ammonium compound and their mixture.
Fabrid care composition the most according to claim 1, wherein said organic siloxane polymer comprises based on always having Organic siloxane polymer weight meter 5% to 100%, preferably 20% to 100%, or more preferably 50% to 100% have The described repetitive of formula (I).
3. according to Fabrid care composition in any one of the preceding claims wherein, wherein 1 to 20, preferably 1 to 10, more excellent The R-portion of 2 to 6 Formulas I of selection of land is-OR2。
4., according to Fabrid care composition in any one of the preceding claims wherein, wherein said dicyandiamide solution is selected from ClogP For the solvent of-0.180 to 3.764, the most described solvent is selected from water, glycerol, polyglycereol, ethylene glycol, diethylene glycol, poly-second two Alcohol, propylene glycol, dipropylene glycol, polypropylene glycol, butanediol, monoethanolamine, diethanolamine and triethanolamine, methyl diethanolamine, Diethylene glycol monomethyl ether, an acetin and diacetine, methanol and their mixture.
Fabrid care composition the most according to claim 3, wherein said solvent selected from ethanol, acetic acid, 1-propanol, 1-fourth Alcohol, 2-propanol, acetonitrile, the tert-butyl alcohol, dimethylformamide, acetone, 1,2-dichloroethanes, dichloromethane, chloroform, ethyl acetate, Oxolane, dioxane, methyl tertiary butyl ether(MTBE), ether, benzene, toluene, butyl cellosolve, butyl carbitol, hexanediol, Water, glycerol, polyglycereol, ethylene glycol, diethylene glycol, Polyethylene Glycol, propylene glycol, dipropylene glycol, polypropylene glycol, butanediol, monoethanol Amine, diethanolamine and triethanolamine, methyl diethanolamine, diethylene glycol monomethyl ether, an acetin and diacetine, first Alcohol and their mixture.
6., according to Fabrid care composition in any one of the preceding claims wherein, wherein there is described formula Si (R7)mO(R8)j Described material selected from monoalkoxysilane, monovinylphenyl silane, dialkoxy silicane, diacetoxy silane, three alcoxyls Base silane, triacetoxysilane, tetraalkoxysilane, four acetoxylsilanes and their mixture；Preferably,
A) described monoalkoxysilane is selected from methoxytrimethylsilane, ethoxytrimethylsilane, (3-aminopropyl) ethoxy Base dimethylsilane, (3-aminopropyl) methoxyl group dimethylsilane, 2-(trimethylsiloxy)-1-aminoethane, with And their mixture；
B) described monovinylphenyl silane is acetoxytrimethylsilane；
C) described dialkoxy silicane is selected from dimethoxydimethylsilane, 2-amino-ethyl-3-amino propyl methyl dimethoxy Base silane, dimethyldiethoxysilane, (3-aminopropyl) methyldiethoxysilane, 3-amino propyl methyl dimethoxy Silane and their mixture；
D) described diacetoxy silane is diacetoxy dimethylsilane；
E) described trialkoxy silane selected from (3-aminopropyl) triethoxysilane, (3-aminopropyl) trimethoxy silane, 3-(N-amino-ethyl) TSL 8330, MTMS, MTES, (amino first Base) trimethoxy silane and (diethylamino) MTES and their mixture；
F) selected from triacetoxyl group methyl-monosilane, triacetoxyl group ethylsilane and theirs is mixed for described triacetoxysilane Compound；And
G) described tetraalkoxysilane is selected from tetramethoxy-silicane, tetraethoxysilane and their mixture.
7., according to Fabrid care composition in any one of the preceding claims wherein, wherein said compositions comprises delivery and strengthens Agent, the most described delivery enhancer comprises the cationic polymerization that clean cationic charge density is 0.05meq/g to 23meq/g Thing.
8., according to Fabrid care composition in any one of the preceding claims wherein, wherein said compositions comprises 0.01 weight The stabilizer of amount % to 0.3 weight %, the most described stabilizer comprises the hydroxyl stabilizer of crystallization.
9., according to Fabrid care composition in any one of the preceding claims wherein, wherein said compositions is rinsing interpolation group Solvate form or laundry detergent compositions form.
10. according to Fabrid care composition in any one of the preceding claims wherein, described Fabrid care composition have to Index of recovery (the I of few 1.1, preferably 1.1 to 2.2, preferably 1.2 to 1.8R)。
11. according to Fabrid care composition in any one of the preceding claims wherein, described Fabrid care composition comprise by The quaternary ammonium compound being suitable to softening fabrics of the weight meter 1% to 49% of described compositions, and the spice of 0.1% to 3%.
12. comprise base according to Fabrid care composition in any one of the preceding claims wherein, described Fabrid care composition In total Fabrid care composition weight meter less than 2% containing aldehyde and/or the material of ketone groups.
13. comprise auxiliary agent according to Fabrid care composition in any one of the preceding claims wherein, wherein said compositions, institute State auxiliary agent selected from delivery enhancer, fluorescent whitening agent, enzyme, rheology modifier, builder and their mixture.
14. 1 kinds of methods providing beneficial effect to fabric, described method includes making described fabric connect with Fabrid care composition Touch, described Fabrid care composition selected from according to Fabrid care composition in any one of the preceding claims wherein and they Mixture, it is preferable that described fabric is the form of finished garment, and will described clothes transmission or after being sold to consumer, Described clothes is made to contact with described Fabrid care composition.
15. 1 kinds of positions, described position comprises the condensation product of organic siloxane polymer, described organic siloxane polymer bag Containing at least one, there is the repetitive of formula according to claim 1 (I), it is preferable that described position comprises 20 micrograms and gathers Compound/gram position to 0.1 gram polymer/gram position, it is highly preferred that described position comprises 100 microgram polymer/gram position to 3, 000 microgram polymer/gram position, it is preferable that described position is fabric and/or clothes.
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