CN106223564A - A kind of fiber reinforcement high-impact ceramic tile - Google Patents
A kind of fiber reinforcement high-impact ceramic tile Download PDFInfo
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- CN106223564A CN106223564A CN201610812973.4A CN201610812973A CN106223564A CN 106223564 A CN106223564 A CN 106223564A CN 201610812973 A CN201610812973 A CN 201610812973A CN 106223564 A CN106223564 A CN 106223564A
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
- E04F13/142—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of ceramics or clays
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3215—Barium oxides or oxide-forming salts thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3293—Tin oxides, stannates or oxide forming salts thereof, e.g. indium tin oxide [ITO]
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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- Dispersion Chemistry (AREA)
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Abstract
The invention discloses a kind of fibre reinforced high-impact ceramic tile, belong to Domestic building material field, aim to solve the problem that existing ceramic tile toughness is not enough, problem easy to crack, including ceramic matrix and enhanced carbon fiber, preparation method is as follows: step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer: 20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, magnesium carbonate 5 parts, forms mixture；Step 2: enhanced carbon fiber is carried out surface coated treatment with chemical vapor infiltration, described unstripped gas is the mixed gas of fuel gas, boron chloride, hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min 200ml/min, and depositing temperature is 900 DEG C 1200 DEG C；Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses physical method to mix it；Step 4: prepare ceramic tile.
Description
Technical field
The present invention relates to ceramic tile, be specifically a kind of fibre reinforced high-impact ceramic tile.
Background technology
Along with the raising of people's living standard, the requirement to residential environment is more and more higher, and the resource of consumption the most about arrives the most,
Causing serious environmental pollution, wherein in construction material and goods thereof, ceramic tile occupies the biggest ratio, annual digestion amount
The hugest.But existing ceramic tile is mainly prepared by inorganic material such as Kaolin, although the rigidity of material is bigger, when
Time material fragility big, toughness is not enough, permanent uses and be easy under the collision of enormous power cracking, damaged, needs further exist for
Change, cause the waste of resource.
Summary of the invention
It is an object of the invention to: for the problem of above-mentioned existence, it is provided that a kind of fibre reinforced high-impact ceramic tile,
The method adding enhanced carbon fiber material in existing ceramic tile, described enhanced carbon fiber material is used to use fibre reinforced
Prepared by nylon material, it is best that the precondition in cost economy is issued to the toughening effect to pottery, solves existing domestic
The problem that ceramic tile toughness is not enough.
The technical solution used in the present invention is as follows:
The invention discloses a kind of fibre reinforced high-impact ceramic tile, it is characterised in that described fibre reinforced height is resistance to
Impact ceramic tile includes ceramic matrix and enhanced carbon fiber.
Further, described enhanced carbon fiber (2) is carbon fiber reinforced nylon fiber, carbon fiber and nylon fiber
Mass ratio is 1:1-1:3.
The highest to the requirement of strength of carbon fibre reinforcement in tile base, if so use pure carbon fiber prepare time
Wait, will cause high cost, after multiple enhanced carbon fiber material is made a service test by inventor and cost is considered,
Bright carbon fiber reinforced nylon fiber can be in the case of lower-cost, and its ceramic tile made has preferable performance.
Further, the preparation method of described fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be fuel gas,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min-
200ml/min, depositing temperature is 900 DEG C-1200 DEG C；
Why the ceramic tile of carbon fiber and ceramic matrix material synthesis has preferable toughness, and it is mainly due to carbon fiber
With ceramic matrix interface phase, interface can be good at coupling together carbon fiber and ceramic matrix mutually, and can be by suffered by material
Stress well transmits, and increases the resistance to impact of product, by chemical vapor infiltration at enhanced carbon fiber material and ceramic base
Forming the cross section phase containing boron carbide between body material, when stress is delivered in interface phase in the product when, interface is formed mutually
Boron carbide coating to surrounding crack occurs, dispersive stress, increase the toughness of product.
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses physical method to it
Mix；
Step 4: prepare ceramic tile, the described technique preparing ceramic tile uses conventional methods, but in the middle of the process of preparation, can
With the situation according to raw material, the concrete technology preparing ceramic tile is carried out suitable adjustment.
Further, described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed.
As preferably, described organic solvent is Methanamide, trifluoroacetic acid, DMSO, DMF, hexamethyl-phosphoramide, first
Alcohol, ethanol, acetic acid, trichloro ethylene, n-butyl alcohol, ether, n-butyl ether, carbon tetrachloride, hexamethylene, the one of hexane.
As preferentially, above-mentioned physical method includes high speed shear, ultrasonic blending, aiming at enhancing in mixed thing
Carbon fibre material and preferably mixing, prevents from occurring between carbon fiber being wound around and mixing uneven problem, as mixed
Close the preferred of physical method, use the method for high speed shear or ultrasonic blending to can be good at allowing each component be sufficiently mixed.
As preferably, above-mentioned fuel gas is methane or acetylene.
As preferably, the carbon fiber of described carbon fiber reinforced nylon fiber is chopped carbon fiber.
As preferably, the described nylon talking fiber reinforced nylon fiber uses nylon 6.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows:
One. the present invention provides carbon fibre reinforcement to be used for preparing in the middle of the preparation technology of ceramic tile particularly domestic ceramic tile, made
Standby ceramic tile has the rigidity of excellence, is difficult to the situations such as cut occur when in use；
Two. special interface characteristics by being formed between enhanced carbon fiber material and ceramic matrix, it is possible to well dispersion
Suffered stress, greatly increases the toughness of ceramic tile under the precondition not changing respective performances, is receiving the work of external force
The situations such as cracking, fracture it are difficult under with.
Accompanying drawing explanation
Fig. 1 is the cross-sectional view of the ceramic tile that the present invention provides；
Labelling in figure: 1-ceramic matrix, 2-enhanced carbon fiber.
Detailed description of the invention
Below in conjunction with the accompanying drawings, the present invention is described in detail.
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, right
The present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, and
It is not used in the restriction present invention.
Specific embodiment 1: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, it is special
Levying and be, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhancing carbon
Fiber is carbon fiber reinforced nylon fiber, and the mass ratio with nylon of described carbon fiber is 1:1, and described carbon fiber reinforced nylon is fine
The carbon fiber of dimension is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is Methanamide.
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is methane, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min, depositing temperature
It is 900 DEG C DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Step 4: prepare ceramic tile.
Specific embodiment 2: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, it is special
Levying and be, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhancing carbon
Fiber is carbon fiber reinforced nylon fiber, and the mass ratio with nylon of described carbon fiber is 1:1, and described carbon fiber reinforced nylon is fine
The carbon fiber of dimension is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is Methanamide n-butyl alcohol.
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be methane,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, deposition
Temperature is 1200 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 3: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:3, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is ether.
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be methane,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 150ml/min, deposition
Temperature 1000 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 4: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:3, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon66 fiber.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is acetylene, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, depositing temperature
It is 900 DEG C DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 5: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:2, described carbon fiber reinforced nylon fiber
Carbon fiber is filament carbon fibre, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is Methanamide methanol.
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be methane,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, deposition
Temperature is 900 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 6: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:1, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon66 fiber.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is methane, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, depositing temperature
It it is 1000 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 7: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:1.5, described carbon fiber reinforced nylon fiber
Carbon fiber be chopped carbon fiber, nylon use nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is acetylene, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min, depositing temperature
It it is 90 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 8: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:3, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is methane, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min, depositing temperature
It it is 1100 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 9: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:1, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon66 fiber.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is acetylene, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100/min, and depositing temperature is
90℃；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Any amendment, equivalent and the improvement etc. made within principle, should be included within the scope of the present invention.
Claims (9)
1. a fibre reinforced high-impact ceramic tile, it is characterised in that described fibre reinforced high-impact ceramic tile
Including ceramic matrix (1) and enhanced carbon fiber (2).
Fibre reinforced high-impact ceramic tile the most according to claim 1, it is characterised in that described enhanced carbon fiber
(2) being carbon fiber reinforced nylon fiber, the mass ratio with nylon fiber of carbon fiber is 1:1-1:3.
Fibre reinforced high-impact ceramic tile the most according to claim 2, it is characterised in that preparation method is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be fuel gas,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min-
200ml/min, depositing temperature is 900 DEG C-1200 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses physical method to carry out it
Mixing；
Step 4: prepare ceramic tile.
Fibre reinforced high-impact ceramic tile the most according to claim 3, it is characterised in that described magnesium carbonate is
The magnesium carbonate of coupling agent modified mistake, magnesium carbonate is joined in coupling reaction tank by method of modifying as follows, opens agitating device, stirring
Make magnesium carbonate rotate, after silane coupler and water, organic solvent are configured to solution according to 1:1:0.5, be sprayed directly on carbonic acid
In magnesium, the rotary speed controlling agitating device is 4000 revs/min-6000 revs/min so that the temperature of mixture reaches 120
Degree Celsius, after reacting 10-20 minute, at 100-150 DEG C, dry the magnesium carbonate that 10-30 minute prepared coupling modifier is crossed.
Fibre reinforced high-impact ceramic tile the most according to claim 4, it is characterised in that described organic solvent
For Methanamide, trifluoroacetic acid, DMSO, DMF, hexamethyl-phosphoramide, methanol, ethanol, acetic acid, trichloro ethylene, n-butyl alcohol, second
Ether, n-butyl ether, carbon tetrachloride, hexamethylene, the one of hexane.
Fibre reinforced high-impact ceramic tile the most according to claim 3, it is characterised in that physical method include
High speed shear, ultrasonic blending.
Fibre reinforced high-impact ceramic tile the most according to claim 3, it is characterised in that described fuel gas is
Methane or acetylene.
8. according to the fibre reinforced high-impact ceramic tile one of right 1-5 to be gone Suo Shu, it is characterised in that described carbon fiber
The carbon fiber strengthening nylon fiber is chopped carbon fiber.
9. according to the fibre reinforced high-impact ceramic tile one of right 1-5 to be gone Suo Shu, it is characterised in that described what is said or talked about is fine
Dimension strengthens the nylon of nylon fiber and uses nylon 6.
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| CN201610812973.4A CN106223564A (en) | 2016-09-09 | 2016-09-09 | A kind of fiber reinforcement high-impact ceramic tile |
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| CN201610812973.4A CN106223564A (en) | 2016-09-09 | 2016-09-09 | A kind of fiber reinforcement high-impact ceramic tile |
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| CN108558379A (en) * | 2018-04-11 | 2018-09-21 | 南安市创培电子科技有限公司 | A kind of processing method of ceramic tile |
| CN112536909A (en) * | 2020-11-19 | 2021-03-23 | 唐玉明 | Preparation method of large-size ultrathin high-strength ceramic large plate |
| CN112851384A (en) * | 2021-01-29 | 2021-05-28 | 中南大学 | Preparation method of low-temperature sintered ceramic matrix composite based on silicon carbide fiber reinforcement |
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