CN106221669A - Health type footwear white packet header cloth binding agent and preparation method thereof - Google Patents
Health type footwear white packet header cloth binding agent and preparation method thereof Download PDFInfo
- Publication number
- CN106221669A CN106221669A CN201610715542.6A CN201610715542A CN106221669A CN 106221669 A CN106221669 A CN 106221669A CN 201610715542 A CN201610715542 A CN 201610715542A CN 106221669 A CN106221669 A CN 106221669A
- Authority
- CN
- China
- Prior art keywords
- cloth
- packet header
- binding agent
- adhesive
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of health type footwear white packet header cloth binding agent and preparation method thereof.The present invention uses water as disperse medium, this adhesive is mainly used in bonding rubber overshoes liner packet header cloth and upper of a shoe, for the cloth material that surface is dense, the adhesive wetting property to cloth cover can be improved, eliminate the health type footwear white packet header cloth binding agent surface tension to fine and close cloth cover, after shoes vulcanization, adhesive forms one layer of sulfuration glue-line under cloth cover, entity is constituted with the adhesive main body on surface, and shoe last surface measuring fiber is strapped among adhesive slurry, make adhesive slurry to shoe last surface cloth firm attachment.Cloth count is little, the surface of cloth is with regard to time relatively rough, loose, the macromolecule that carboxymethyl cellulose sodium is formed after water-swellable is furnished with bridging effect to loose face, binding agent is stoped to permeate in loose cloth layer gap, make adhesive thicken in the accumulation of cloth cover, improve the bonding effect of adhesive and foxing film.
Description
Technical field
The present invention relates to a kind of adhesive material preparation field, especially a kind of health type footwear with white packet header cloth binding agent and
Its preparation method.
Background technology
The upper of a shoe packet header cloth adhesive of rubber overshoes, its purposes is adhesive glue shoe last surface and toe-cap liner cloth, makes rubber overshoes liner cloth
Firm entirety is formed with upper of a shoe.The leading indicator of judgement upper of a shoe packet header cloth Adhensive performance is rubber overshoes upper textile and toe-cap liner
After cloth bonding, both bond site do not produce and depart from glue from mouth, and during upper of a shoe sews, both will not produce separation, simultaneously energy
Both can be detained de-with finger.
Generally, cloth bonding rubber cement in rubber overshoes white packet header is as solute, with organic solvent work with rubber mixed
The solvent-borne type rubber cement of solvent, solvent-borne type rubber cement is generally with 120# gasoline or toluene etc. as solvent, and the primary raw material of rubber cement is natural
The broken-down rubber of rubber and relevant compounding ingredient.Solvent-borne type rubber cement exists that difficulty of processing is big, energy consumption is many, cost is high, process-cycle length, poison
Property the shortcoming such as big, also have the mass defect that the lowest, the most viscous intensity of the most viscous strength is little simultaneously, process of producing product be easily caused rubber overshoes
The quality problems such as seep through, cause conforming product rate low.Deposit inflammability simultaneously, there is potential safety hazard.
Summary of the invention
It is an object of the invention to: providing a kind of health type footwear white packet header cloth binding agent and preparation method thereof, it improves
Upper of a shoe and the bonding intensity of shoe lining toe box cloth, reduce production cost, reduce toxicity and the flammability hazard of adhesive, for rubber overshoes
Production operation personnel provide healthy and safe working environment, to overcome the deficiencies in the prior art.
The present invention is achieved in that health type footwear white packet header cloth binding agent, calculates in parts by weight, it include with
Antistatic environment-friendly adhesive 100 parts, sodium carboxymethyl cellulose 1.4-1.6 part, titanium dioxide 4-5 part, ultramarine 0.15-0.25 part, hydrogen
Potassium oxide 0.3-0.4 part, penetrating agent JFC 0.4-0.5 part, diffusant 0.1-0.3 part, acid anhydride casein 0.1-0.3 part and soft water 30-35
Part is for preparing raw material.
It includes in case electrostatic environment-protecting binding agent 100 parts, sodium carboxymethyl cellulose 1.5 parts, titanium dioxide 4.5 parts, ultramarine 0.2
Part, potassium hydroxide 0.35 part, penetrating agent JFC 0.45 part, diffusant 0.2 part, acid anhydride casein 0.2 part and soft water 32 parts are former for preparing
Material.
Also include fatty alcohol-polyoxyethylene ether 1-2 part, antifungus agent BCM 0.04-0.06 part and age resistor KY-405L 0.4-
0.6 part.
The health type footwear preparation method of white packet header cloth binding agent, takes each component by above-mentioned mass fraction, including as follows
Step:
1) preparing titanium dioxide water suspension: add potassium hydroxide in the ball grinder equipped with 3-5 part soft water, stirring makes hydroxide
Potassium dissolves complete, then is sequentially added into titanium dioxide, ultramarine, diffusant and acid anhydride casein wherein, and stirring allows water be moistened by pulverulent material,
Ball grinder is covered, is put on ball mill operating ball milling 2.5 hours, takes out standby, obtain A product；
2) preparation of compounding ingredient dispersion: add A product in latex mixer, then add carboxymethyl in A product dispersedly
Sodium cellulosate, stirs while adding, and makes A product fully be infiltrated by sodium carboxymethyl cellulose, obtains B product；To be mixed to B product without granule
Time, in B product, add soft water part under agitation in three times, wherein, add soft water 4-6 part for the first time, be stirred to material and divide
Dissipate uniformly, add soft water 8-12 part then at second time, to be mixed to homogeneous body time, last add all remaining soft water,
Continue to be stirred to all material and be uniformly mixed into when being integrated, to compounding ingredient dispersion；
3) preparation of health type footwear white packet header cloth binding agent: add in antistatic environment-friendly adhesive under agitation
Entering penetrating agent and compounding ingredient dispersion, until stirring, obtaining health type footwear white packet header cloth binding agent.
Step 1 described) in when preparing titanium dioxide water suspension, add antifungus agent BCM0.04-0.06 part and age resistor
KY-405L 0.4-0.6 part；In step 2) in fatty alcohol-polyoxyethylene ether and A product are together added in latex mixer.
Inventor solves problems with during the present invention developing:
1, adhesive and upper of a shoe, the impermeable stability of packet header cloth.
1) anti-permeability:
If health type footwear are with white packet header cloth binding agent to the infiltration of different size shoe last surface cloth and reverse osmosis performance not
Unanimously, the bonding to different size shoe last surface cloth just it is difficult to.This is accomplished by studying the cloth bonding of health type footwear white packet header
Agent is to the permeance property of upper of a shoe cloth cover and reverse osmosis performance, when making adhesive brushing on upper of a shoe cloth cover, produces the most enough
The permeability needed.
Different white shoe last surface cloth, owing to its warp thread is different with weft count, thickness different, weave is different, causes footwear
Distance between the density difference of upper textile, cloth surface roughness difference, yarn is different, and cloth cover chemical property also differs.These
Difference, all can cause health type footwear white packet header cloth binding agent different with permeability to the wellability of design on fabric surface.Finally lead
Cause adhesive different to the degree of adhesion of cloth.
When the warp thread of cloth and the diameter of weft yarn compared with thin, rugosity is low, cloth count is big time, the surface of cloth is just compared
Densification, health type footwear white packet header cloth binding agent is due to low to this kind of cloth infiltration wetting capacity, to the degree of adhesion of cloth just
Difference, the rubber overshoes bonding strength produced is the most relatively low.For this kind of situation, the method that inventor takes is to reduce in adhesive to divide greatly
The consumption of sub-material, increases the consumption of surfactant, improves the adhesive wetting property to cloth cover.Surface active material
It is relatively big that penetrating agent JFC infiltrates contribution to the infiltration of this cloth, eliminates health type footwear white packet header cloth binding agent to densification
The surface tension of cloth cover, makes adhesive penetrate among woven design from cloth cover easily, forms one layer of adhesive slurry, so,
After shoes vulcanization, adhesive forms one layer of sulfuration glue-line under cloth cover, constitutes entity with the adhesive main body on surface, and by footwear
Upper textile fiber is strapped among adhesive slurry, makes adhesive slurry to shoe last surface cloth firm attachment.
When the warp thread of cloth and the diameter of weft yarn compared with thick, rugosity is high, cloth count is little time, the surface of cloth is just compared
Coarse, loose, health type footwear are high to this kind of cloth infiltration wellability with white packet header cloth binding agent, it is easy to form excessive permeation,
The adhesive slurry overwhelming majority all can penetrate in the gap of cloth, and the adhesive slurry being attached on cloth surface is seldom.This
Kind of situation produces two results, and one is that on cloth cover, adhesive adhesion amount is low, and the poor adhesion of laminating glue component, the most adjoint
There are the quality problems of product seep through.Drawing through lot of experiments, the macromolecule that carboxymethyl cellulose sodium is formed after water-swellable is to dredging
The face of pine is furnished with bridging effect, stops binding agent to permeate in loose cloth layer gap, makes adhesive thicken in the accumulation of cloth cover,
Improve the bonding effect of adhesive and foxing film.
2) stability
Health type footwear white packet header cloth binding agent produces for rubber overshoes, first has to ensure adhesive and upper of a shoe, bag
Head lining cloth, on the premise of bonding firmly, does not produce seep through, and this adhesive uses sodium carboxymethyl cellulose to carry out thickening, reduces thing
Agent is to upper of a shoe and the permeability of packet header lining cloth, and the degree of stability of adhesive becomes the key factor affecting bonding quality.
Inventor have studied the corresponding relation of acid or alkali environment and adhesive degree of stability, draws: the acidity of adhesive is the highest,
Bonding strength is the lowest, and produces qualitative change during depositing, and it is the best that alkalescence is in rational scope then adhesive degree.Make footwear
Side is the best but also stable with packet header lining cloth bonding intensity, fully ensures the gap quality of upper of a shoe.
The impact on adhesive degree of stability of the table 1 alkali consumption
By table 1, adhesive uses 0.35 part of potassium hydroxide to can ensure that its enough stabilization time, fully ensures that viscous
The impermeable slurry of mixture, non-yellowing, have the safety operation time of abundance to guarantee rubber overshoes bonding intensity is the highest but also stable simultaneously.
2, easy brushing workability
Aqueous packet header cloth binding agent, in swabbing application process, generally there are swabbing operating difficulties, mainly binding agent
Relatively big to the frictional force of shoe last surface cloth and upper of a shoe and packet header lining cloth material, harder in painting process, increase hand labor strong
Degree.The present invention uses and adds in binding agentFatty alcohol-polyoxyethylene ether, reach to put forward the purpose of binding agent brushing performance.
The health type footwear formulating of white packet header cloth binding agent
1, health type footwear white packet header cloth adhesive formula test
1) formula: antistatic environment-friendly adhesive 100 parts, sodium carboxymethyl cellulose 1.5 parts, titanium dioxide 4.5 parts, ultramarine 0.2
Part, potassium hydroxide 0.35 part, penetrating agent JFC 0.45 part, diffusant 0.2 part, acid anhydride casein 0.2 part,Fatty alcohol-polyoxyethylene ether1.5
Part, antifungus agent BCM0.05 part, age resistor KY-405L 0.5 part.
2) experimental formula data
(1) material of main part research
Table 1
Table 1 draws, health type footwear white packet header cloth binding agent selects antistatic environment-friendly adhesive as material of main part, energy
Guarantee optimum performance and the technology stability of binding agent.
(2) performance study such as whiteness and permeation-proof slurry
Table 2
Table 2 draws, the optimum formula of health type footwear white packet header cloth binding agent is: antistatic environment-friendly adhesive 100 parts,
Sodium carboxymethyl cellulose 1.5 parts, titanium dioxide 4.5 parts, fatty alcohol-polyoxyethylene ether 1.5 parts, penetrating agent JFC 0.45 part.
(3) form and aspect and mildew-resistant anti-aging research
Table 3
Table 3 draws, form and aspect and anti-old, mildew-resistant best fit agent consumption be: 0.2 part of ultramarine, antifungus agent BCM 0.05 part, anti-
Old agent KY-405L 0.5 part.
(4) bond properties further investigation
Table 4
Table 4 draws, it is ensured that binder performance stably reaches requirement, and it is 0.2 part, optimal acid anhydride cheese that jasmine obtains optimal diffusant consumption
Element consumption is 0.2 part.
3) Study on Preparation:
(1) titanium dioxide water suspension is prepared
Table 5
Drawing from table 5, the optimal production process of titanium dioxide water suspension is: add hydrogen-oxygen in the ball grinder equipped with 4 parts of soft water
Changing 0.35 part of potassium, penetrating agent JFC 0.45 part, it is complete that stirring uses potassium hydroxide to dissolve, then is sequentially added into titanium dioxide 4.5 wherein
Part, 0.2 part of ultramarine, diffusant 0.2 part, acid anhydride casein 0.2 part, antifungus agent BCM 0.05 part, age resistor KY-405L 0.5 part, stir
Mix and allow water be moistened by pulverulent material, ball grinder is covered, be put on ball mill operating ball milling 3.5 hours.
(2) compounding ingredient dispersion is prepared
Table 5
Through fully test, show that preparing compounding ingredient dispersion has the optimal case to be: add in latex mixer A product and
1.5 partFatty alcohol-polyoxyethylene ether, then in A product, add sodium carboxymethyl cellulose 1.5 parts dispersedly, stir while adding, make A
Sodium carboxymethyl cellulose is fully infiltrated by product, obtains B product.To be mixed to B product substantially become body time, under agitation in B product
Add soft water 28 parts altogether in three times, wherein add soft water 5 parts for the first time, be stirred to material and be uniformly dispersed, add then at second time
Enter soft water 10 parts, to be mixed to homogeneous body time, last add 13 parts of soft water, continue to be stirred to all material and be uniformly mixed into
When being integrated, to compounding ingredient dispersion.
3) health type footwear white packet header cloth binding agent preparation: drawing through fully test, packet header cloth binding agent optimal
Preparation program is: add penetrating agent and compounding ingredient dispersion under agitation in antistatic environment-friendly adhesive 100 parts, until
Stir, obtain health type footwear white packet header cloth binding agent.
Owing to have employed technique scheme, compared with prior art, the present invention uses water as disperse medium, this adhesive
Being mainly used in bonding rubber overshoes liner packet header cloth and upper of a shoe, inventor decreases the consumption of macromolecular material in adhesive, increases table
The consumption of face active agent penetration agent JFC, for the surface of cloth with regard to dense material, can improve adhesive to cloth cover
Wetting property.It is relatively big that surface active material infiltrates contribution to the infiltration of this cloth, eliminates health type footwear white packet header
The cloth binding agent surface tension to fine and close cloth cover, makes adhesive penetrate among woven design from cloth cover easily, forms one layer of glue
Stick slurry, so, after shoes vulcanization, adhesive forms one layer of sulfuration glue-line under cloth cover, constitutes with the adhesive main body on surface
Entity, and shoe last surface measuring fiber is strapped among adhesive slurry, make adhesive slurry to shoe last surface cloth firm attachment.Cloth
Material count is little, the surface of cloth just relatively rough, when loosening, the macromolecule pair that carboxymethyl cellulose sodium is formed after water-swellable
Loose face is furnished with bridging effect, stops binding agent to permeate in loose cloth layer gap, makes adhesive add in the accumulation of cloth cover
Thickness, improves the bonding effect of adhesive and foxing film.The present invention is simple, with low cost, and using effect is good.
Detailed description of the invention
Embodiments of the invention 1: health type footwear white packet header cloth binding agent, calculate in parts by weight, it include in case
Electrostatic environment-protecting binding agent 100 parts, sodium carboxymethyl cellulose 1.5 parts, titanium dioxide 4.5 parts, 0.2 part of ultramarine, potassium hydroxide 0.35 part,
Penetrating agent JFC 0.45 part, diffusant 0.2 part, acid anhydride casein 0.2 part, soft water 32 parts, fatty alcohol-polyoxyethylene ether 1.5 parts, antifungus agent
BCM 0.05 part and age resistor KY-405L 0.5 part is for preparing raw material.
The health type footwear preparation method of white packet header cloth binding agent, takes each component by above-mentioned mass fraction, including as follows
Step:
1) preparing titanium dioxide water suspension: add potassium hydroxide in the ball grinder equipped with 4 parts of soft water, stirring makes potassium hydroxide
Dissolve complete, then be sequentially added into titanium dioxide, ultramarine, diffusant, acid anhydride casein, antifungus agent BCM and age resistor KY-405L wherein,
Stirring allows water be moistened by pulverulent material, is covered by ball grinder, is put on ball mill operating ball milling 2.5 hours, takes out standby, obtain A
Product；
2) preparation of compounding ingredient dispersion: add A product and fatty alcohol-polyoxyethylene ether in latex mixer, then to A product
In add sodium carboxymethyl cellulose dispersedly, stir while adding, make A product fully be infiltrated by sodium carboxymethyl cellulose, obtain B product；
To be mixed to B product without granule time, in B product, add soft water part under agitation in three times, wherein, add soft water 5 for the first time
Part, be stirred to material and be uniformly dispersed, then at second time add soft water 10 parts, to be mixed to homogeneous body time, add institute for the last time
There are remaining 13 parts of soft water, continue to be stirred to all material and be uniformly mixed into when being integrated, to compounding ingredient dispersion；
3) the health type footwear preparation of white packet header cloth binding agent: under agitation to antistatic environment-friendly adhesive 100
Adding penetrating agent JFC and compounding ingredient dispersion in Fen, until stirring, obtaining health type footwear white packet header cloth binding agent.
The health type footwear white packet header cloth binding agent of gained has the highest stability, can enter many specifications shoe last surface cloth
Row bonding, has higher tack and whole viscous force.
Application with upper of a shoe packet header cloth binding agent: the health type footwear of preparation white packet header cloth binding agent is coated with gluing brush
Brush is on cloth to be bonded, after adhesive is dried 45～50min under the conditions of 55～60 DEG C, then by rubber overshoes upper of a shoe and packet header cloth brush
Slurry part is bonded together.
Embodiments of the invention 2: health type footwear white packet header cloth binding agent, calculate in parts by weight, it include in case
Electrostatic environment-protecting binding agent 100 parts, sodium carboxymethyl cellulose 1.6 parts, titanium dioxide 4.3 parts, 0.2 part of ultramarine, potassium hydroxide 0.35 part,
Penetrating agent JFC 0.45 part, diffusant 0.2 part, acid anhydride casein 0.2 part, soft water 32 parts, fatty alcohol-polyoxyethylene ether 1.6 parts, antifungus agent
BCM 0.05 part and age resistor KY-405L 0.4 part is for preparing raw material.
Health type footwear use the preparation method of white packet header cloth binding agent with embodiment 1.
Claims (5)
1. a health type footwear white packet header cloth binding agent, it is characterised in that: calculating in parts by weight, it includes with antistatic
Environment-friendly adhesive 100 parts, sodium carboxymethyl cellulose 1.4-1.6 part, titanium dioxide 4-5 part, ultramarine 0.15-0.25 part, potassium hydroxide
0.3-0.4 part, penetrating agent JFC 0.4-0.5 part, diffusant 0.1-0.3 part, acid anhydride casein 0.1-0.3 part and soft water 30-35 part are
Prepare raw material.
Health type footwear the most according to claim 1 white packet header cloth binding agent, it is characterised in that: it includes with antistatic
Environment-friendly adhesive 100 parts, sodium carboxymethyl cellulose 1.5 parts, titanium dioxide 4.5 parts, 0.2 part of ultramarine, potassium hydroxide 0.35 part, infiltration
Agent JFC 0.45 part, diffusant 0.2 part, acid anhydride casein 0.2 part and soft water 32 parts are for preparing raw material.
Health type footwear the most according to claim 1 and 2 white packet header cloth binding agent, it is characterised in that: also include fat
Polyoxyethylenated alcohol 1-2 part, antifungus agent BCM 0.04-0.06 part and age resistor KY-405L 0.4-0.6 part.
4. a preparation method for health type footwear as claimed in claim 1 or 2 white packet header cloth binding agent, its feature exists
In: take each component by above-mentioned mass fraction, comprise the steps:
1) preparing titanium dioxide water suspension: add potassium hydroxide in the ball grinder equipped with 3-5 part soft water, stirring makes potassium hydroxide molten
Solving complete, then be sequentially added into titanium dioxide, ultramarine, diffusant and acid anhydride casein wherein, stirring allows water be moistened by pulverulent material, by ball
Grinding jar covers, and is put on ball mill operating ball milling 2.5 hours, takes out standby, obtain A product；
2) preparation of compounding ingredient dispersion: add A product in latex mixer, then add carboxymethyl cellulose in A product dispersedly
Element sodium, stirs while adding, makes A product fully be infiltrated by sodium carboxymethyl cellulose, obtain B product；To be mixed to B product without granule time,
In B product, add soft water part under stirring condition in three times, wherein, add soft water 4-6 part for the first time, be stirred to material dispersion all
Even, add soft water 8-12 part then at second time, to be mixed to homogeneous body time, last add all remaining soft water, continue
It is stirred to all material and is uniformly mixed into when being integrated, to compounding ingredient dispersion；
3) preparation of health type footwear white packet header cloth binding agent: add in antistatic environment-friendly adhesive under agitation and infiltrate
Agent and compounding ingredient dispersion thoroughly, until stirring, obtains health type footwear white packet header cloth binding agent.
Preparation method the most according to claim 4, it is characterised in that: the step 1 described) in prepare titanium dioxide water suspension
Time, add antifungus agent BCM 0.05 part and age resistor KY-405L 0.5 part；In step 2) in by fatty alcohol-polyoxyethylene ether and
A product together add in latex mixer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610715542.6A CN106221669A (en) | 2016-08-24 | 2016-08-24 | Health type footwear white packet header cloth binding agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610715542.6A CN106221669A (en) | 2016-08-24 | 2016-08-24 | Health type footwear white packet header cloth binding agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221669A true CN106221669A (en) | 2016-12-14 |
Family
ID=57554522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610715542.6A Pending CN106221669A (en) | 2016-08-24 | 2016-08-24 | Health type footwear white packet header cloth binding agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221669A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107227118A (en) * | 2017-06-13 | 2017-10-03 | 合肥远科服装设计有限公司 | A kind of leather shoe sole adhesive and preparation method thereof |
| CN107286862A (en) * | 2017-07-28 | 2017-10-24 | 合肥布竹梦依服装贸易有限公司 | A kind of leather shoe sole adhesive and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08112109A (en) * | 1994-10-17 | 1996-05-07 | Moon Star Co | Bonding method between instep cover of shoe and lower peripheral rubber tape |
| CN101486882A (en) * | 2009-03-04 | 2009-07-22 | 际华三五三七制鞋有限责任公司 | Water soluble adhesive and preparation method thereof |
| CN102199414A (en) * | 2011-03-29 | 2011-09-28 | 际华三五一七橡胶制品有限公司 | Macromolecular adhesive |
| CN102807830A (en) * | 2012-08-09 | 2012-12-05 | 际华三五三七制鞋有限责任公司 | Spraying-type environment-friendly rubber adhesive cement and preparation method thereof |
| CN103265910A (en) * | 2013-06-18 | 2013-08-28 | 际华三五三七制鞋有限责任公司 | Water-based anti-static bonding agent for shoes and preparation method thereof |
-
2016
- 2016-08-24 CN CN201610715542.6A patent/CN106221669A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08112109A (en) * | 1994-10-17 | 1996-05-07 | Moon Star Co | Bonding method between instep cover of shoe and lower peripheral rubber tape |
| CN101486882A (en) * | 2009-03-04 | 2009-07-22 | 际华三五三七制鞋有限责任公司 | Water soluble adhesive and preparation method thereof |
| CN102199414A (en) * | 2011-03-29 | 2011-09-28 | 际华三五一七橡胶制品有限公司 | Macromolecular adhesive |
| CN102807830A (en) * | 2012-08-09 | 2012-12-05 | 际华三五三七制鞋有限责任公司 | Spraying-type environment-friendly rubber adhesive cement and preparation method thereof |
| CN103265910A (en) * | 2013-06-18 | 2013-08-28 | 际华三五三七制鞋有限责任公司 | Water-based anti-static bonding agent for shoes and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107227118A (en) * | 2017-06-13 | 2017-10-03 | 合肥远科服装设计有限公司 | A kind of leather shoe sole adhesive and preparation method thereof |
| CN107286862A (en) * | 2017-07-28 | 2017-10-24 | 合肥布竹梦依服装贸易有限公司 | A kind of leather shoe sole adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101486882B (en) | Water soluble adhesive and preparation method thereof | |
| CN106221669A (en) | Health type footwear white packet header cloth binding agent and preparation method thereof | |
| US4244847A (en) | Fibrated admix or polymer and process therefore | |
| CN104371091B (en) | The adhesive powder being dispersed among in water | |
| CN102807830B (en) | Spraying-type environment-friendly rubber adhesive cement and preparation method thereof | |
| CN105143318B (en) | Manufacture method, rubber composition, vulcanization rubber and the tire of rubber composition | |
| CN106189926A (en) | Rubber overshoes black system mouth sponge binding agent and preparation method and application | |
| CN109112846A (en) | A kind of high-strength abrasion-proof plated film PVC artificial leather | |
| KR20140020874A (en) | Coating compositions comprising spheroid silica or silicate | |
| CN109322169A (en) | A kind of aqueous cloudy surface, scratch resistance, soft synthetic leather | |
| CN106336831A (en) | White adhesive for shoe upper coating sponge and preparation method thereof | |
| CN104773980B (en) | A kind of concrete interface agent and its manufacture method and application method | |
| CN106220910B (en) | Hot vulcanized rubber boots base fabric new type rubber slurry and preparation method and application in sponge | |
| CN106336830A (en) | Environment-friendly mass-colour coating sponge adhesive for shoes and preparation method thereof | |
| CN107722384A (en) | Polyester filament microgroove rubber shoes with cloth upper high-efficiency binder and preparation method thereof and application method | |
| CN106318263B (en) | Water base shoes true qualities packet header cloth adhesive and preparation method thereof | |
| CN107674610A (en) | Environmental protection type high viscosity closes effect hot vulcanized rubber boots emulsified epoxy and preparation method thereof | |
| CN109401675A (en) | Suede type cow split skin hot vulcanized rubber boots water based adhesive system and its shoemaking technique for applying | |
| CN108824006A (en) | The preparation method of waterborne polyurethane synthetic leather | |
| KR101667041B1 (en) | Insole board manufacture method using leather powder and recycled non woven fabrics | |
| CN107652480A (en) | Antistatic dust suction blocks water rubber shoes with cloth upper adhesive and preparation method thereof and application method | |
| CN107778550A (en) | Hot vulcanized rubber boots high-efficiency binder and preparation method thereof and application method | |
| CN106318270B (en) | Waterproof boots black bonding slurry and preparation method and application | |
| CN117120520A (en) | Composite powder and method for producing same | |
| CN107746480A (en) | Dust-proof canvas rubber shoes heat cure adhesive and preparation method thereof and the application method of blocking water |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161214 |