CN106221626A - A kind of pressure-sensitive adhesive emulsion, preparation method and utilize its corrosion-resisting protective film prepared - Google Patents
A kind of pressure-sensitive adhesive emulsion, preparation method and utilize its corrosion-resisting protective film prepared Download PDFInfo
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- CN106221626A CN106221626A CN201610693768.0A CN201610693768A CN106221626A CN 106221626 A CN106221626 A CN 106221626A CN 201610693768 A CN201610693768 A CN 201610693768A CN 106221626 A CN106221626 A CN 106221626A
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- emulsion
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- initiator
- sensitive adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2451/00—Presence of graft polymer
Abstract
nullA kind of pressure-sensitive adhesive emulsion，It is characterized in that: comprise following components in parts by weight: water: 51 58%、Emulsifying agent: 0.6 1.2%、Silane coupler: 0.6 1.5%、Initiator: 0.1 0.5%、Acrylic acid (AA): 0.2 1%、Butyl acrylate (BA): 15 20%、Styrene (St): 0.5 2%、Methyl methacrylate (MMA): 0.5 2%、Hydroxypropyl acrylate (HPA): 1 2%、Acrylic acid 2 ethyl hexyl ester (2 EHA): 15 20%、Sodium bicarbonate: 0.05 0.2%，The useful benefit of the present invention is: 1、By using water as dispersion solvent and retarder thinner，Not only reduce production cost，And substantial amounts of VOCs can be avoided to discharge，Effectively protect environment，Reduce the air pollution in workshop，The health of protection workman；By with mono-functional compounds as primary raw material, and owing to raw material does not has crosslinking feature, by adding a small amount of organo-silicon coupling agent, improving intensity and corrosion resistance, also ensure to easily remove in subsequent processing, practical and reduce further production cost.
Description
Technical field
The present invention relates to a kind of pressure sensitive adhesive field, a kind of pressure-sensitive adhesive emulsion, preparation method and utilize it to prepare
Corrosion-resisting protective film.
Background technology
Continuous progressive along with electronics techniques, people are to the prescription of the electronic product such as mobile phone, panel computer also
Improving constantly, for improving electronic product performance, in production process, electronic product can relate to many tests, wherein outside electronic product
The process technique of shell can relate to corrosion resistance test, for the metal shell surface that adequately protects, needs to be coated with in case surface temporarily
Apply the corrosion-resisting film that can be easy to removing, play a protective role in relating to the operation containing Fluohydric acid., and be easy to removing
Characteristic corrosion-resisting film can be removed in next operation easily.
General conventional anticorrosion macromolecular material is very poor to the anticorrosion ability of Fluohydric acid., it is impossible to meet electronic product to hydrogen
The anti corrosion test of fluoric acid, more existing technology uses such as bisphenol A epoxy acrylate, epoxy soybean oil acrylate, PU
Modified epoxy acrylate resin, anhydride modified epoxy acrylate or Chinese rose acid modified epoxy acrylic ester, furane resins are main
Want base material, although meet corrosion resistance requirement, but, these resin price are expensive, are not suitable for large-scale application, and above-mentioned
Material is all that polymerisation in bulk forms, and in use in order to reduce viscosity, needs to add organic solvent and is diluted, not only increase into
This, more can discharge a large amount of VOCs, environment and workshop are caused serious pollution.It addition, in order to reach good resistant to hydrogen fluorine
Acid effect, above-mentioned material the most excessively cross-links, and causes and cannot slough after protection operation completes, and practicality is the strongest.
Summary of the invention
For the deficiencies in the prior art, the present invention provides a kind of that have lightly crosslinked structure, advantage of lower cost, resistant to hydrogen
Fluoric acid corrosivity is preferable, and adhesion is good, it is easy to the pressure-sensitive adhesive emulsion of removing, preparation method and utilize its corrosion-resistant protection prepared
Film.
The technical scheme is that a kind of pressure-sensitive adhesive emulsion, it is characterised in that: comprise group in parts by mass
Point: water: 51-58%, emulsifying agent: 0.6-1.2%, silane coupler: 0.6-1.5%, initiator: 0.1-0.5%, acrylic acid
(AA): 0.2-1%, Butyl acrylate (BA): 15-20%, styrene (St): 0.5-2%, methyl methacrylate (MMA):
0.5-2%, Hydroxypropyl acrylate (HPA): 1-2%, acrylic acid-2-ethyl hexyl ester (2-EHA): 15-20%, sodium bicarbonate:
0.05-0.2%,
Described initiator is potassium peroxydisulfate (KPS)；
Described emulsifying agent is the one or two in sodium lauryl sulphate (SDS), OPEO (OP-10)
Kind；
Described silane coupler is vinyl three (2-methoxy ethoxy) silane (A-172), acetylene thiazolinyl trimethoxy
One in silane or both.
The preparation method of a kind of pressure-sensitive adhesive emulsion, it is characterised in that comprise the following steps:
1), the preparation of pre-emulsion: add in a kettle. according to formula part water, whole emulsifying agents, acrylic acid (AA),
Butyl acrylate (BA), styrene (St), methyl methacrylate (MMA), Hydroxypropyl acrylate (HPA), acrylic acid-2-ethyl
Hexyl ester (2-EHA), after being sufficiently mixed uniformly, obtains pre-breast by the mulser stirring 10～15min that rotating speed is 250r/min
Liquid；
2), the preparation of seed emulsion: equipped with thermometer, reflux condensing tube, agitator four-hole boiling flask in add water, 8-
The pre-emulsion of preparation, whole sodium bicarbonate in 20% step one, after stirring and being warming up to 80 DEG C, add part initiator, instead
Answer the 0.5～1h seed emulsion obtaining blueing light；
3), the preparation of initiator solution: remaining initiator and remaining water are prepared as initiator solution；
4), the preparation of polyacrylate dispersion: drip remaining pre-emulsion in seed emulsion, simultaneously in seed emulsion
The initiator solution of dropping 82%, and drip off 3.5～4h both control, during dropping, keeping temperature is 80 DEG C, obtains
Polyacrylate dispersion；
5), the preparation of organosilicon-modified acrylate emulsion: add silane in the polyacrylate dispersion that step 4 obtains
Coupling agent, after stirring fully reaction 0.5h, adds remaining initiator solution, after insulation 2.5h,
Entering ammonia regulation pH value is 7～8.5, obtains organosilicon-modified acrylate emulsion.
In technique scheme, step 1) in, the part water of addition is the 40-50% of water gross mass part meter in formula.
In technique scheme, step 2) in, the water added in four-hole boiling flask is the 30-of water gross mass part meter in formula
40%.
In technique scheme, step 2) in, the part initiator of addition is initiator gross mass part meter in formula
45%.
A kind of corrosion-resisting protective film, by described pressure-sensitive adhesive emulsion, is uniformly coated on product to be used by certain spread
Surface, toasts 20min under the conditions of temperature is 90 DEG C and removes moisture, continue baking 20min, to obtain final product after then heating to 120 DEG C
Corrosion-resisting protective film.
The invention have the benefit that
1, by using water as dispersion solvent and retarder thinner, not only reduce production cost, and can avoid a large amount of
VOCs discharge, effectively protect environment, reduce the air pollution in workshop, the health of protection workman, also avoid organic molten simultaneously
The burning that agent volatilization causes, blast etc.；
2, pass through with mono-functional compounds as primary raw material, and owing to raw material does not has crosslinking feature, few by adding
The organo-silicon coupling agent of amount, is improving intensity and corrosion resistance, it is ensured that easily remove in subsequent processing, practical and
And reduce further production cost.
Detailed description of the invention
Below the detailed description of the invention of the present invention is described further:
Embodiment 1
1, formula (in parts by mass) component
Water: 55%, emulsifying agent: 1.2%, silane coupler: 1%, initiator 0.35%, acrylic acid (AA): 0.8%, third
Olefin(e) acid fourth vinegar (BA): 19%, styrene (St): 0.95%, methyl methacrylate (MMA): 1.1%, Hydroxypropyl acrylate
(HPA): 2%, acrylic acid-2-ethyl hexyl ester (2-EHA): 18.5%, sodium bicarbonate: 0.1%；
2, preparation method step
1), the preparation of pre-emulsion: add in formula the 40% of water gross mass part meter in a kettle., whole emulsifying agents,
Acrylic acid (AA), Butyl acrylate (BA), styrene (St), methyl methacrylate (MMA), Hydroxypropyl acrylate (HPA), third
Olefin(e) acid-2-ethyl hexyl ester (2-EHA), is sufficiently mixed after uniformly, by mulser stirring 10 that rotating speed is 250r/min～
15min obtains pre-emulsion；
2), the preparation of seed emulsion: equipped with thermometer, reflux condensing tube, agitator four-hole boiling flask in add formula
The pre-emulsion of preparation, whole sodium bicarbonate in 30%, 8% step one of middle water gross mass part meter, stir and be warming up to 80 DEG C
After, adding in formula the 45% of initiator mass parts meter, reaction 0.5～1h obtains the seed emulsion of blueing light；
3), the preparation of initiator solution: remaining initiator and remaining water are prepared as initiator solution；
4), the preparation of polyacrylate dispersion: drip remaining pre-emulsion in seed emulsion, simultaneously in seed emulsion
The initiator solution of dropping 82%, and drip off 3.5～4h both control, during dropping, keeping temperature is 80 DEG C, obtains
Polyacrylate dispersion；
5), the preparation of organosilicon-modified acrylate emulsion: add silane in the polyacrylate dispersion that step 4 obtains
Coupling agent, after stirring fully reaction 0.5h, adds remaining initiator solution, after insulation 2.5h,
Entering ammonia regulation pH value is 7～8.5, obtains organosilicon-modified acrylate emulsion.
Embodiment 2
1, formula (in parts by mass) component
Water: 51%, emulsifying agent: 0.8%, silane coupler: 0.6%, initiator 0.5%, acrylic acid (AA): 1%, propylene
Acid fourth vinegar (BA): 20%, styrene (St): 2%, methyl methacrylate (MMA): 2%, Hydroxypropyl acrylate (HPA): 2%,
Acrylic acid-2-ethyl hexyl ester (2-EHA): 20%, sodium bicarbonate: 0.2%,
2, preparation method step
1), the preparation of pre-emulsion: add in formula the 50% of water gross mass part meter in a kettle., whole emulsifying agents,
Acrylic acid (AA), Butyl acrylate (BA), styrene (St), methyl methacrylate (MMA), Hydroxypropyl acrylate (HPA), third
Olefin(e) acid-2-ethyl hexyl ester (2-EHA), is sufficiently mixed after uniformly, by mulser stirring 10 that rotating speed is 250r/min～
15min obtains pre-emulsion；
2), the preparation of seed emulsion: equipped with thermometer, reflux condensing tube, agitator four-hole boiling flask in add formula
The pre-emulsion of preparation, whole sodium bicarbonate in 40%, 20% step one of middle water gross mass part meter, stir and be warming up to 80 DEG C
After, 45% that in addition formula, initiator gross mass part is counted, reaction 0.5～1h obtains the seed emulsion of blueing light；
3), the preparation of initiator solution: remaining initiator and remaining water are prepared as initiator solution；
4), the preparation of polyacrylate dispersion: drip remaining pre-emulsion in seed emulsion, simultaneously in seed emulsion
The initiator solution of dropping 82%, and drip off 3.5～4h both control, during dropping, keeping temperature is 80 DEG C, obtains
Polyacrylate dispersion；
5), the preparation of organosilicon-modified acrylate emulsion: add silane in the polyacrylate dispersion that step 4 obtains
Coupling agent, after stirring fully reaction 0.5h, adds remaining initiator solution, after insulation 2.5h,
Entering ammonia regulation pH value is 7～8.5, obtains organosilicon-modified acrylate emulsion.
Embodiment 3
1, formula (in parts by mass) component
Water: 57.95%, emulsifying agent: 0.6%, silane coupler: 1.5%, initiator 0.3%, acrylic acid (AA):
0.3%, Butyl acrylate (BA): 15%, styrene (St): 2%, methyl methacrylate (MMA): 0.5%, acrylic acid hydroxypropyl
Ester (HPA): 2%, acrylic acid-2-ethyl hexyl ester (2-EHA): 20%, sodium bicarbonate: 0.05%,
2, preparation method step is with embodiment 1.
The principle of the simply explanation present invention described in above-described embodiment and description and most preferred embodiment, without departing from this
On the premise of spirit and scope, the present invention also has various changes and modifications, and these changes and improvements both fall within requirement and protect
In the scope of the invention protected.
Claims (6)
1. a pressure-sensitive adhesive emulsion, it is characterised in that: comprise following components in parts by weight: water: 51-58%, emulsifying agent:
0.6-1.2%, silane coupler: 0.6-1.5%, initiator: 0.1-0.5%, acrylic acid (AA): 0.2-1%, Butyl acrylate
(BA): 15-20%, styrene (St): 0.5-2%, methyl methacrylate (MMA): 0.5-2%, Hydroxypropyl acrylate
(HPA): 1-2%, acrylic acid-2-ethyl hexyl ester (2-EHA): 15-20%, sodium bicarbonate: 0.05-0.2%；
Described initiator is potassium peroxydisulfate (KPS)；
Described emulsifying agent is the one or two kinds of in sodium lauryl sulphate (SDS), OPEO (OP-10)；
Described silane coupler is vinyl three (2-methoxy ethoxy) silane (A-172), acetylene thiazolinyl trimethoxy silane
In one or both.
The preparation method of a kind of pressure-sensitive adhesive emulsion the most according to claim 1, it is characterised in that comprise the following steps:
1), the preparation of pre-emulsion: add part water, whole emulsifying agents, acrylic acid (AA), propylene according to formula in a kettle.
Acid fourth vinegar (BA), styrene (St), methyl methacrylate (MMA), Hydroxypropyl acrylate (HPA), acrylic acid-2-ethyl hexyl
Ester (2-EHA), after being sufficiently mixed uniformly, obtains pre-emulsion by the mulser stirring 10～15min that rotating speed is 250r/min；
2), the preparation of seed emulsion: equipped with thermometer, reflux condensing tube, agitator four-hole boiling flask in add water, 8-20%
The pre-emulsion of preparation, whole sodium bicarbonate in step one, after stirring and being warming up to 80 DEG C, add part initiator, react 0.5
～1h obtains the seed emulsion of blueing light；
3), the preparation of initiator solution: remaining initiator and remaining water are prepared as initiator solution；
4), the preparation of polyacrylate dispersion: drip remaining pre-emulsion in seed emulsion, drip in seed emulsion simultaneously
The initiator solution of 82%, and drip off 3.5～4h both control, during dropping, keeping temperature is 80 DEG C, obtains poly-third
Olefin(e) acid ester emulsion；
5), the preparation of organosilicon-modified acrylate emulsion: add silane coupled in the polyacrylate dispersion that step 4 obtains
Agent, after stirring fully reaction 0.5h, adds remaining initiator solution, after insulation 2.5h,
Water regulation pH value is 7～8.5, obtains organosilicon-modified acrylate emulsion.
The preparation method of a kind of pressure-sensitive adhesive emulsion the most according to claim 2, it is characterised in that: step 1) in, addition
Part water is the 40-50% of water gross mass part meter in formula.
The preparation method of a kind of pressure-sensitive adhesive emulsion the most according to claim 2, it is characterised in that: step 2) in, at four mouthfuls
The water added in flask is the 30-40% of water gross mass part meter in formula.
The preparation method of a kind of pressure-sensitive adhesive emulsion the most according to claim 2, it is characterised in that: step 2) in, addition
Part initiator is 45% that in formula, initiator gross mass part is counted.
6. one kind utilizes corrosion-resisting protective film prepared by pressure-sensitive adhesive emulsion as claimed in claim 1, it is characterised in that: by described
Pressure-sensitive adhesive emulsion, is uniformly coated on product surface to be used by certain spread, toasts 20min under the conditions of temperature is 90 DEG C
Remove moisture, continue baking 20min after then heating to 120 DEG C, obtain corrosion-resisting protective film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610693768.0A CN106221626A (en) | 2016-08-19 | 2016-08-19 | A kind of pressure-sensitive adhesive emulsion, preparation method and utilize its corrosion-resisting protective film prepared |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610693768.0A CN106221626A (en) | 2016-08-19 | 2016-08-19 | A kind of pressure-sensitive adhesive emulsion, preparation method and utilize its corrosion-resisting protective film prepared |
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| CN106221626A true CN106221626A (en) | 2016-12-14 |
Family
ID=57553335
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| CN201610693768.0A Pending CN106221626A (en) | 2016-08-19 | 2016-08-19 | A kind of pressure-sensitive adhesive emulsion, preparation method and utilize its corrosion-resisting protective film prepared |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114763442A (en) * | 2021-01-11 | 2022-07-19 | 天津科技大学 | Plastic base material-based water-based ink and preparation method thereof |
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| CN104342073A (en) * | 2014-10-31 | 2015-02-11 | 中科院广州化学有限公司 | Organic silicon modified phenyl emulsion pressure-sensitive adhesive with high release force and low residue as well as preparation method thereof and application |
| CN104356980A (en) * | 2014-10-31 | 2015-02-18 | 中科院广州化学有限公司 | Organic silicon modified styrene-acrylic emulsion type pressure sensitive glue with high steric hindrance and low residual, and preparation method and application thereof |
| CN104769069A (en) * | 2012-11-06 | 2015-07-08 | Lg化学株式会社 | Acryl-silicon based hybrid emulsion adhesive composition, and method for preparing same |
| CN105860884A (en) * | 2016-06-25 | 2016-08-17 | 江阴市江泰高分子新材料有限公司 | Polyacrylate emulsion pressure-sensitive adhesive and PE protection film thereof |
-
2016
- 2016-08-19 CN CN201610693768.0A patent/CN106221626A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045113A (en) * | 2012-08-31 | 2013-04-17 | 江苏创基新材料有限公司 | Preparation method of self-crosslinking IPN (interpenetrating network) organosilicone-acrylate copolymer emulsion pressure-sensitive adhesive |
| CN104769069A (en) * | 2012-11-06 | 2015-07-08 | Lg化学株式会社 | Acryl-silicon based hybrid emulsion adhesive composition, and method for preparing same |
| CN104342073A (en) * | 2014-10-31 | 2015-02-11 | 中科院广州化学有限公司 | Organic silicon modified phenyl emulsion pressure-sensitive adhesive with high release force and low residue as well as preparation method thereof and application |
| CN104356980A (en) * | 2014-10-31 | 2015-02-18 | 中科院广州化学有限公司 | Organic silicon modified styrene-acrylic emulsion type pressure sensitive glue with high steric hindrance and low residual, and preparation method and application thereof |
| CN105860884A (en) * | 2016-06-25 | 2016-08-17 | 江阴市江泰高分子新材料有限公司 | Polyacrylate emulsion pressure-sensitive adhesive and PE protection film thereof |
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| CN114763442A (en) * | 2021-01-11 | 2022-07-19 | 天津科技大学 | Plastic base material-based water-based ink and preparation method thereof |
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Application publication date: 20161214 |