CN106221295A - A kind of tolerance to cold composite calcium carbonate and preparation method thereof - Google Patents
A kind of tolerance to cold composite calcium carbonate and preparation method thereof Download PDFInfo
- Publication number
- CN106221295A CN106221295A CN201610635291.0A CN201610635291A CN106221295A CN 106221295 A CN106221295 A CN 106221295A CN 201610635291 A CN201610635291 A CN 201610635291A CN 106221295 A CN106221295 A CN 106221295A
- Authority
- CN
- China
- Prior art keywords
- parts
- calcium carbonate
- modifying agent
- preparation
- tolerance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
- C09C1/022—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of tolerance to cold composite calcium carbonate and preparation method thereof, including following raw material: calcium carbonate, polyimides, magnesium hydroxide, kieselguhr, phenolic resin, amino resins, glycerol, purified petroleum benzin, diethylene glycol, modifying agent, water are appropriate；Its preparation method comprises the following steps: it is stand-by that (1) prepares premix material；(2) mixed liquor is prepared；(3) modifying agent is prepared；(4) premix material, mixed liquor and modifying agent are mixed, stir, grind, dry, be ground into superfines and get final product.The present invention, by being combined by the combination property preferably materials such as calcium carbonate and phenolic resin, polyimides, magnesium hydroxide, amino resins, improves production technology, uses modifying agent etc. to effectively increase the cold tolerance of compositions；Its production technology is simple, and with short production cycle, steady quality, production cost is low, and using value is higher.
Description
Technical field
The present invention relates to industrial filler field, particularly relate to a kind of tolerance to cold composite calcium carbonate and preparation method thereof.
Background technology
Calcium carbonate is a kind of inorganic compound, CaCO3It is commonly called as: lime stone, limestone, stone powder, marble etc., be by calcium ion
Combining with carbanion and to generate, be the important functional inorganic filling of a class, industrial purposes is very wide, has price low
Honest and clean, rich reserves, stable performance, easily processing, the advantage such as nontoxic, it is possible to significantly improve drawing abillity, physical property
And reduce production cost etc., it is widely used in the fields such as plastics, rubber, coating, papermaking.
In the application of calcium carbonate, most products belongs to the category of polymer, but, calcium carbonate particle surface distributed
There is the hydroxyl of strongly hydrophilic, show as alkalescence, different with the interfacial property of organic polymer host material, poor compatibility, it is difficult to
Host material it is uniformly dispersed and forms strong adhesion with host material, causing the boundary defect between two materials, make
Some mechanical properties decrease of composite.It is thus desirable to change the performance of tradition calcium carbonate product, improve its application performance with full
Foot new material, the needs of development of new techniques, be calcium carbonate industry urgent problem.
Summary of the invention
It is an object of the invention to, it is provided that a kind of tolerance to cold composite calcium carbonate and preparation method thereof, by by combination property
Preferably material is combined, and improves production technology, uses modifying agent etc. to effectively increase the cold tolerance of compositions.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of tolerance to cold composite calcium carbonate and preparation method thereof, including the raw material of following weight portion: calcium carbonate 50～80 parts,
Polyimides 2～4 parts, magnesium hydroxide 1～3 parts, kieselguhr 1～3 parts, phenolic resin 3～5 parts, amino resins 4～6 parts, glycerol
2～3 parts, purified petroleum benzin 1～1.5 parts, diethylene glycol 1～2 parts, modifying agent 5～8 parts, water are appropriate；Wherein said modifying agent is by following weight
The raw material of part is made: nano silicon 30～50 parts, bamboo charcoal powder 2～4 parts, carbon fiber 3～5 parts, acrylate and vinyl acetate emulsion 2～5 parts, amber
Amber anhydride 1～3 parts, sodium sulfite 3～5 parts, butanone 2～4 parts；
Its preparation method comprises the following steps:
(1) calcium carbonate, polyimides, magnesium hydroxide, kieselguhr mix homogeneously are added in sand mill, be ground to 300～
400 mesh, obtain premix material stand-by；
(2) putting in batch mixer by phenolic resin, amino resins, glycerol, be warming up to 75～85 DEG C, mix and blend half is little
Time, it is subsequently adding purified petroleum benzin, diethylene glycol, is continuously heating to 120～140 DEG C, stirs, obtain mixed liquor；
(3) nano silicon, bamboo charcoal powder, carbon fiber, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 75～85
DEG C, it is stirring evenly and then adding into succinic anhydrides, sodium sulfite, butanone, continues to be heated to 120～140 DEG C, mixing and stirring,
Obtain modifying agent；
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent that step (3) obtains mix
Close, stir, grind, dry, be ground into superfines and get final product.
The invention have the benefit that
The present invention is by by preferable with combination properties such as phenolic resin, polyimides, magnesium hydroxide, amino resins for calcium carbonate
Material be combined, improve production technology, use modifying agent etc. to effectively increase the cold tolerance of compositions；The present invention is raw
Production. art is simple, and production process is environment friendly and pollution-free, it is achieved that making full use of of resource and the energy, with short production cycle, steady quality,
Production cost is low, and using value is higher.
Detailed description of the invention:
With specific embodiment, technical scheme is described below, but protection scope of the present invention is not limited to this:
Embodiment 1:
A kind of tolerance to cold composite calcium carbonate and preparation method thereof, including the raw material of following weight portion: calcium carbonate 50 parts, polyamides
Imines 2 parts, 1 part of magnesium hydroxide, 1 part of kieselguhr, 3 parts of phenolic resin, 4 parts of amino resins, glycerol 2 parts, purified petroleum benzin 1 part, diethylene glycol 1
Part, modifying agent 5 parts, water are appropriate；Wherein said modifying agent is made up of the raw material of following weight portion: nano silicon 30 parts, bamboo
Powdered carbon 2 parts, 3 parts of carbon fiber, acrylate and vinyl acetate emulsion 2 parts, succinic anhydrides 1 part, sodium sulfite 3 parts, butanone 2 parts；
Its preparation method comprises the following steps:
(1) calcium carbonate, polyimides, magnesium hydroxide, kieselguhr mix homogeneously are added in sand mill, be ground to 300～
400 mesh, obtain premix material stand-by；
(2) phenolic resin, amino resins, glycerol are put in batch mixer, be warming up to 75 DEG C, mix and blend half an hour, so
Rear addition purified petroleum benzin, diethylene glycol, be continuously heating to 140 DEG C, stir, obtain mixed liquor；
(3) nano silicon, bamboo charcoal powder, carbon fiber, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 85 DEG C, stir
Add succinic anhydrides, sodium sulfite, butanone after mixing uniformly, continue to be heated to 120 DEG C, mixing and stirring, obtain modifying agent；
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent that step (3) obtains mix
Close, stir, grind, dry, be ground into superfines and get final product.
Embodiment 2:
A kind of tolerance to cold composite calcium carbonate and preparation method thereof, including the raw material of following weight portion: calcium carbonate 80 parts, polyamides
Imines 4 parts, 3 parts of magnesium hydroxide, 3 parts of kieselguhr, 5 parts of phenolic resin, 6 parts of amino resins, glycerol 3 parts, purified petroleum benzin 1.5 parts, two sweet
Alcohol 2 parts, modifying agent 8 parts, water are appropriate；Wherein said modifying agent is made up of the raw material of following weight portion: nano silicon 50 parts,
Bamboo charcoal powder 4 parts, 5 parts of carbon fiber, acrylate and vinyl acetate emulsion 5 parts, succinic anhydrides 3 parts, sodium sulfite 5 parts, butanone 4 parts；
Its preparation method comprises the following steps:
(1) calcium carbonate, polyimides, magnesium hydroxide, kieselguhr mix homogeneously are added in sand mill, be ground to 300～
400 mesh, obtain premix material stand-by；
(2) phenolic resin, amino resins, glycerol are put in batch mixer, be warming up to 85 DEG C, mix and blend half an hour, so
Rear addition purified petroleum benzin, diethylene glycol, be continuously heating to 120 DEG C, stir, obtain mixed liquor；
(3) nano silicon, bamboo charcoal powder, carbon fiber, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 75 DEG C, stir
Add succinic anhydrides, sodium sulfite, butanone after mixing uniformly, continue to be heated to 140 DEG C, mixing and stirring, obtain modifying agent；
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent that step (3) obtains mix
Close, stir, grind, dry, be ground into superfines and get final product.
Above example is only in order to illustrate technical scheme, rather than limiting the scope of the invention, although
Make to explain to the present invention with reference to preferred embodiment, it will be understood by those within the art that, can be to this
Bright technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Claims (1)
1. tolerance to cold composite calcium carbonate and preparation method thereof, it is characterised in that include the raw material of following weight portion: calcium carbonate
50～80 parts, polyimides 2～4 parts, magnesium hydroxide 1～3 parts, kieselguhr 1～3 parts, phenolic resin 3～5 parts, amino resins 4
～6 parts, glycerol 2～3 parts, purified petroleum benzin 1～1.5 parts, diethylene glycol 1～2 parts, modifying agent 5～8 parts, water are appropriate；Wherein said modifying agent
It is made up of the raw material of following weight portion: nano silicon 30～50 parts, bamboo charcoal powder 2～4 parts, carbon fiber 3～5 parts, vinegar the third breast
Liquid 2～5 parts, succinic anhydrides 1～3 parts, sodium sulfite 3～5 parts, butanone 2～4 parts；
Its preparation method comprises the following steps:
(1) calcium carbonate, polyimides, magnesium hydroxide, kieselguhr mix homogeneously are added in sand mill, be ground to 300～400
Mesh, obtains premix material stand-by；
(2) phenolic resin, amino resins, glycerol are put in batch mixer, be warming up to 75～85 DEG C, mix and blend half an hour, so
Rear addition purified petroleum benzin, diethylene glycol, be continuously heating to 120～140 DEG C, stir, obtain mixed liquor；
(3) nano silicon, bamboo charcoal powder, carbon fiber, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 75～85 DEG C, stir
Add succinic anhydrides, sodium sulfite, butanone after mixing uniformly, continue to be heated to 120～140 DEG C, mixing and stirring, obtain modified
Agent；
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent mixing that step (3) obtains, stir
Mix uniformly, grind, dry, be ground into superfines and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610635291.0A CN106221295A (en) | 2016-08-05 | 2016-08-05 | A kind of tolerance to cold composite calcium carbonate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610635291.0A CN106221295A (en) | 2016-08-05 | 2016-08-05 | A kind of tolerance to cold composite calcium carbonate and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221295A true CN106221295A (en) | 2016-12-14 |
Family
ID=57546930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610635291.0A Pending CN106221295A (en) | 2016-08-05 | 2016-08-05 | A kind of tolerance to cold composite calcium carbonate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221295A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292547A (en) * | 2014-09-25 | 2015-01-21 | 青岛美嘉隆包装机械有限公司 | Antiaging seal rubber ring |
| CN104530766A (en) * | 2014-12-09 | 2015-04-22 | 广西贺州弘任机械节能科技有限公司 | Production method of geotechnical cloth superfine heavy calcium carbonate |
| CN104844069A (en) * | 2015-04-12 | 2015-08-19 | 李孟平 | Building thermal insulation and flame retardant composite material and preparation method thereof |
| CN105154748A (en) * | 2015-09-02 | 2015-12-16 | 安徽万年针织有限公司 | Aluminum oxide porcelain eye containing light calcium carbonate and having high plasticity |
-
2016
- 2016-08-05 CN CN201610635291.0A patent/CN106221295A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292547A (en) * | 2014-09-25 | 2015-01-21 | 青岛美嘉隆包装机械有限公司 | Antiaging seal rubber ring |
| CN104530766A (en) * | 2014-12-09 | 2015-04-22 | 广西贺州弘任机械节能科技有限公司 | Production method of geotechnical cloth superfine heavy calcium carbonate |
| CN104844069A (en) * | 2015-04-12 | 2015-08-19 | 李孟平 | Building thermal insulation and flame retardant composite material and preparation method thereof |
| CN105154748A (en) * | 2015-09-02 | 2015-12-16 | 安徽万年针织有限公司 | Aluminum oxide porcelain eye containing light calcium carbonate and having high plasticity |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105038502A (en) | Self-healing epoxy powdery coating containing microcapsule and preparation method thereof | |
| CN104059390B (en) | Modified calcium carbonate with high specific surface area and preparation method thereof | |
| CN101914229B (en) | Method for preparing kieselguhr/natural rubber composite material | |
| CN104312212A (en) | Corrosion-resistant modified calcium carbonate with good comprehensive properties and preparation method of modified calcium carbonate | |
| CN106752239A (en) | A kind of outer wall flexible water proof putty and preparation method thereof | |
| CN104059392B (en) | Porous material modified calcium carbonate and preparation method thereof | |
| CN102337098A (en) | Sealant and preparation method thereof | |
| CN104059389B (en) | Modified calcium carbonate with improved toughness and preparation method of modified calcium carbonate | |
| CN106349760A (en) | High-flame-retardancy composite calcium carbonate and preparation method thereof | |
| CN106349761A (en) | Abrasion-resistant composite calcium carbonate and preparation method thereof | |
| CN106189266A (en) | A kind of hydrophobic type composite calcium carbonate and preparation method thereof | |
| CN106221295A (en) | A kind of tolerance to cold composite calcium carbonate and preparation method thereof | |
| CN106280553A (en) | A kind of can the composite calcium carbonate that purify air and preparation method thereof | |
| CN106349757A (en) | Sound-absorption compound calcium carbonate and preparation method thereof | |
| CN106280557A (en) | A kind of high tenacity composite calcium carbonate and preparation method thereof | |
| CN106349759A (en) | High-temperature-resistant composite calcium carbonate and preparation method thereof | |
| CN106280556A (en) | A kind of anticorrosion composite calcium carbonate and preparation method thereof | |
| CN106280558A (en) | A kind of antistatic composite calcium carbonate and preparation method thereof | |
| CN106280554A (en) | A kind of heat insulation composite calcium carbonate and preparation method thereof | |
| CN106221294A (en) | A kind of insulation composite calcium carbonate and preparation method thereof | |
| CN102337013B (en) | Modified epoxy resin plate | |
| CN106280561A (en) | A kind of high resiliency composite calcium carbonate and preparation method thereof | |
| CN106221293A (en) | A kind of mildew-resistant composite calcium carbonate and preparation method thereof | |
| CN106280562A (en) | A kind of composite calcium carbonate of graphitiferous and preparation method thereof | |
| CN106280555A (en) | A kind of high stability composite calcium carbonate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161214 |