CN106219622A - A kind of novel sewage treatment agent and preparation method thereof - Google Patents

A kind of novel sewage treatment agent and preparation method thereof Download PDF

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Publication number
CN106219622A
CN106219622A CN201610695592.2A CN201610695592A CN106219622A CN 106219622 A CN106219622 A CN 106219622A CN 201610695592 A CN201610695592 A CN 201610695592A CN 106219622 A CN106219622 A CN 106219622A
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China
Prior art keywords
parts
sewage treatment
treatment agent
novel sewage
water
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Pending
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CN201610695592.2A
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Chinese (zh)
Inventor
黄云鸿
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Guilin Chunxiao Environmental Protection Technology Co Ltd
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Guilin Chunxiao Environmental Protection Technology Co Ltd
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Priority to CN201610695592.2A priority Critical patent/CN106219622A/en
Publication of CN106219622A publication Critical patent/CN106219622A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/286Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of novel sewage treatment agent and preparation method thereof, belong to sewage treatment area.It is made up of the raw material of following parts by weight: flyash 4~10 parts, silication sodium 4~10 parts, sodium polyacrylate 4~10 parts, polymer phosphate ferrum 5~10 parts, adsorbate 2~6 parts, poly-aluminum calcium chloride 3~9 parts, Ammonium persulfate. 4~10 parts, disodium hydrogen phosphate 3~9 parts, zeolite 4~12 parts and water 80~100 parts.The novel sewage treatment agent of the present invention, Pollutant Treatment scope is wide, respond well, raw material sources wide, low cost, can be widely used for municipal wastewater, the process of all types of industries waste water and contaminated rivers and lakes water treatment, and the water quality after process can realize recycling.

Description

A kind of novel sewage treatment agent and preparation method thereof
Technical field
The present invention relates to a kind of novel sewage treatment agent and preparation method thereof, belong to water treatment agent field.
Background technology
Sewage-treating agent is chemical assistant conventional in sewage treatment area, by thick, thin by water of sewage-treating agent Magazins' layout, thus realize the effect of purification of water quality.But, in the modern life, the kind of sewage is more, include life, doctor The waste water of the industry-by-industry such as treatment, industry, agricultural, chemical industry, machinery.Due to the demand of every profession and trade, the composition of sewage-treating agent is each not Identical, but be all required alone, reach respective purposes.Although such inorganic agent high treating effect, Impurity removal are thorough, but It is functional comparison is single, it is achieved can again can the function of purifying domestic sewage except industry class sewage.
Summary of the invention
It is an object of the invention to make up the deficiencies in the prior art, it is provided that a kind of novel sewage treatment agent and preparation method thereof. The high efficiency sewage treating agent of the present invention, Pollutant Treatment scope is wide, respond well, raw material sources wide, low cost, can be widely used for Municipal wastewater, all types of industries waste water process and contaminated rivers and lakes water treatment, and the water quality after process can realize circulation to be made With.
The technical scheme is that a kind of novel sewage treatment agent, by following weight portion The raw material of number is made: flyash 4~10 parts, silication sodium 4~10 parts, sodium polyacrylate 4~10 parts, polymer phosphate ferrum 5~10 parts, Adsorbate 2~6 parts, poly-aluminum calcium chloride 3~9 parts, Ammonium persulfate. 4~10 parts, disodium hydrogen phosphate 3~9 parts, zeolite 4~12 parts With water 80~100 parts.
On the basis of technique scheme, the present invention can also do following improvement.
Further, it is made up of the raw material of following parts by weight: 7 parts of flyash, 7 parts of silication sodium, sodium polyacrylate 7 parts, poly- Close iron phosphate 7 parts, adsorbate 4 parts, poly-aluminum calcium chloride 6 parts, Ammonium persulfate. 7 parts, disodium hydrogen phosphate 6 parts, 8 parts of zeolite and water 90 Part.
Further, one or more during described adsorbate is wood flour, straw end, activated carbon, rice husk.
The preparation method of a kind of novel sewage treatment agent, comprises the steps: to take the raw material of following parts by weight: flyash 4~10 parts, silication sodium 4~10 parts, sodium polyacrylate 4~10 parts, polymer phosphate ferrum 5~10 parts, adsorbate 2~6 parts, polymerization chlorine Change aluminum calcium 3~9 parts, Ammonium persulfate. 4~10 parts, disodium hydrogen phosphate 3~9 parts, zeolite 4~12 parts, after mix homogeneously, pulverize, add Parts by weight are the water of 80~100 parts, after ball milling, dry, sieve, obtain described novel sewage treatment agent.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the parts by weight of described raw material are: 7 parts of flyash, 7 parts of silication sodium, sodium polyacrylate 7 parts, polymerization phosphorus Acid ferrum 7 parts, adsorbate 4 parts, poly-aluminum calcium chloride 6 parts, Ammonium persulfate. 7 parts, disodium hydrogen phosphate 6 parts, 8 parts of zeolite, described water Parts by weight are 90 parts, described in the mesh number that sieves be 100~200 mesh.
Further, one or more during described adsorbate is wood flour, straw end, activated carbon, rice husk.
The invention has the beneficial effects as follows:
(1) novel sewage treatment agent of the present invention, Pollutant Treatment scope is wide, respond well, raw material sources wide, cost Low, can be widely used for municipal wastewater, the process of all types of industries waste water and contaminated rivers and lakes water treatment, the water quality after process Can realize recycling.
(2) formula of the present invention is simple, with low cost, function admirable, is suitable for large-scale production.
Detailed description of the invention
Being described principle and the feature of the present invention below in conjunction with specific embodiment, example is served only for explaining this Bright, it is not intended to limit the scope of the present invention.
Embodiment 1:
The novel sewage treatment agent of the present embodiment, including the raw material of following weight: flyash 4kg, silication sodium 10kg, poly-third Olefin(e) acid sodium 4kg, polymer phosphate ferrum 10kg, adsorbate 2kg, poly-aluminum calcium chloride 9kg, Ammonium persulfate. 4kg, disodium hydrogen phosphate 9kg, Zeolite 4kg and water 100kg, wherein, described adsorbate is wood flour.
The preparation method of the novel sewage treatment agent of above-described embodiment, comprises the steps: to take the raw material of following weight: powder Coal ash 4kg, silication sodium 10kg, sodium polyacrylate 4kg, polymer phosphate ferrum 10kg, adsorbate 2kg, poly-aluminum calcium chloride 9kg, mistake Ammonium sulfate 4kg, disodium hydrogen phosphate 9kg, zeolite 4kg, after mix homogeneously, pulverize, add the water of 100kg, after ball milling, dries, crosses 100 Mesh sieve, obtains described novel sewage treatment agent, and wherein, described adsorbate is wood flour.
After taking 200mL soil mud draining, experimental group 1 and experimental group 2 are set: experimental group 1 adds at the present embodiment sewage Reason agent 200mg, experimental group 2 adds commercially available sewage-treating agent 200mg, respectively stirring and evenly mixing, is precipitated to clarification, then detects.
Wherein the process water ph value of experimental group 1 is 7.1, and percent of decolourization is 96.8%, COD clearance 89.2%, BOD clearance Being 73.4%, total tp removal rate 90.6%, total ammonia clearance 45.2%, 20 microns of solid content residual rates 19.6%, flocculant is residual Stay rate 9.6%.
The process water ph value of experimental group 2 is 7.5, and percent of decolourization is 61%, COD clearance 53%, and BOD clearance is 38%, Total tp removal rate 52%, total ammonia clearance 14%, 20 microns of solid content residual rates 67%, flocculant residual rate 55%.
Embodiment 2:
The novel sewage treatment agent of the present embodiment, including the raw material of following weight: flyash 7kg, silication sodium 7kg, poly-third Olefin(e) acid sodium 7kg, polymer phosphate ferrum 7kg, adsorbate 4kg, poly-aluminum calcium chloride 6kg, Ammonium persulfate. 7kg, disodium hydrogen phosphate 6kg, Zeolite 8kg and water 90kg, wherein, described adsorbate is 2kg straw end and 2kg activated carbon.
The preparation method of the novel sewage treatment agent of above-described embodiment, comprises the steps: to take the raw material of following weight: powder Coal ash 7kg, silication sodium 7kg, sodium polyacrylate 7kg, polymer phosphate ferrum 7kg, adsorbate 4kg, poly-aluminum calcium chloride 6kg, over cure Acid ammonium 7kg, disodium hydrogen phosphate 6kg, zeolite 8kg, after mix homogeneously, pulverize, add the water of 90kg, after ball milling, dries, crosses 100 mesh Sieve, obtains described novel sewage treatment agent, and wherein, described adsorbate is 2kg straw end and 2kg activated carbon.
After taking 200mL soil mud draining, experimental group 1 and experimental group 2 are set: experimental group 1 adds at the present embodiment sewage Reason agent 200mg, experimental group 2 adds commercially available sewage-treating agent 200mg, respectively stirring and evenly mixing, is precipitated to clarification, then detects.
Wherein the process water ph value of experimental group 1 is 7.1, and percent of decolourization is 97.2%, COD clearance 89.3%, BOD clearance Being 74.2%, total tp removal rate 90.4%, total ammonia clearance 45.3%, 20 microns of solid content residual rates 19.8%, flocculant is residual Stay rate 9.8%.
The process water ph value of experimental group 2 is 7.6, and percent of decolourization is 62%, COD clearance 53%, and BOD clearance is 39%, Total tp removal rate 52%, total ammonia clearance 14%, 20 microns of solid content residual rates 67%, flocculant residual rate 55%.
Embodiment 3:
The novel sewage treatment agent of the present embodiment, including the raw material of following weight: flyash 10kg, silication sodium 4kg, poly-third Olefin(e) acid sodium 10kg, polymer phosphate ferrum 5kg, adsorbate 6kg, poly-aluminum calcium chloride 3kg, Ammonium persulfate. 10kg, disodium hydrogen phosphate 3kg, zeolite 12kg and water 80kg, wherein, described adsorbate be 1.5kg wood flour, 1.5kg straw end, 1.5kg activated carbon and 1.5kg rice husk.
The preparation method of the novel sewage treatment agent of above-described embodiment, comprises the steps: to take the raw material of following weight: powder Coal ash 10kg, silication sodium 4kg, sodium polyacrylate 10kg, polymer phosphate ferrum 5kg, adsorbate 6kg, poly-aluminum calcium chloride 3kg, mistake Ammonium sulfate 10kg, disodium hydrogen phosphate 3kg, zeolite 12kg, after mix homogeneously, pulverize, add the water of 80kg, after ball milling, dries, mistake 100 mesh sieves, obtain described novel sewage treatment agent, and wherein, described adsorbate is 1.5kg wood flour, 1.5kg straw is last, 1.5kg is alive Property charcoal and 1.5kg rice husk.
After taking 200mL soil mud draining, experimental group 1 and experimental group 2 are set: experimental group 1 adds at the present embodiment sewage Reason agent 200mg, experimental group 2 adds commercially available sewage-treating agent 200mg, respectively stirring and evenly mixing, is precipitated to clarification, then detects.
Wherein the process water ph value of experimental group 1 is 7.1, and percent of decolourization is 97.2%, COD clearance 89.2%, BOD clearance Being 72.8%, total tp removal rate 91.2%, total ammonia clearance 44.6%, 20 microns of solid content residual rates 19.8%, flocculant is residual Stay rate 10.2%.
The process water ph value of experimental group 2 is 7.4, and percent of decolourization is 60%, COD clearance 53%, and BOD clearance is 37%, Total tp removal rate 53%, total ammonia clearance 15%, 20 microns of solid content residual rates 68%, flocculant residual rate 55%.
In sum, the novel sewage treatment agent of the present invention has efficient flocculating effect, can effectively remove in water Colloid and particle, have turbidity removal except algae function simultaneously, reach preferable purifying water effect.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (6)

1. a novel sewage treatment agent, it is characterised in that be made up of the raw material of following parts by weight: flyash 4~10 parts, silicon Change sodium 4~10 parts, sodium polyacrylate 4~10 parts, polymer phosphate ferrum 5~10 parts, adsorbate 2~6 parts, poly-aluminum calcium chloride 3~9 Part, Ammonium persulfate. 4~10 parts, disodium hydrogen phosphate 3~9 parts, zeolite 4~12 parts and water 80~100 parts.
A kind of novel sewage treatment agent the most according to claim 1, it is characterised in that by the raw material system of following parts by weight Become: 7 parts of flyash, 7 parts of silication sodium, sodium polyacrylate 7 parts, polymer phosphate ferrum 7 parts, adsorbate 4 parts, poly-aluminum calcium chloride 6 parts, Ammonium persulfate. 7 parts, disodium hydrogen phosphate 6 parts, 8 parts of zeolite and 90 parts of water.
A kind of novel sewage treatment agent the most according to claim 1 and 2, it is characterised in that described adsorbate is wood flour, straw One or more in stalk end, activated carbon, rice husk.
4. the preparation method of a novel sewage treatment agent, it is characterised in that comprise the steps: to take the former of following parts by weight Material: flyash 4~10 parts, silication sodium 4~10 parts, sodium polyacrylate 4~10 parts, polymer phosphate ferrum 5~10 parts, adsorbate 2~6 Part, poly-aluminum calcium chloride 3~9 parts, Ammonium persulfate. 4~10 parts, disodium hydrogen phosphate 3~9 parts, zeolite 4~12 parts, mix homogeneously After, pulverize, add the water that parts by weight are 80~100 parts, after ball milling, dry, sieve, obtain described novel sewage treatment agent.
The preparation method of a kind of novel sewage treatment agent the most according to claim 4, it is characterised in that the weight of described raw material Amount number is: 7 parts of flyash, 7 parts of silication sodium, sodium polyacrylate 7 parts, polymer phosphate ferrum 7 parts, adsorbate 4 parts, aluminium polychlorid Calcium 6 parts, Ammonium persulfate. 7 parts, disodium hydrogen phosphate 6 parts, 8 parts of zeolite, the parts by weight of described water are 90 parts, described in the mesh number that sieves It is 100~200 mesh.
6. according to the preparation method of a kind of novel sewage treatment agent described in claim 4 or 5, it is characterised in that described absorption Thing is one or more in wood flour, straw end, activated carbon, rice husk.
CN201610695592.2A 2016-08-18 2016-08-18 A kind of novel sewage treatment agent and preparation method thereof Pending CN106219622A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110921756A (en) * 2019-12-13 2020-03-27 西安润川环保科技有限公司 Sewage treatment material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0947749A (en) * 1995-08-07 1997-02-18 Hitachi Ltd Local water area purifying system, method therefor and purifier therefor
CN105152238A (en) * 2015-08-28 2015-12-16 邓忆凯 Novel wastewater treatment agent and preparation method thereof
CN105198059A (en) * 2015-10-13 2015-12-30 桂林市春晓环保科技有限公司 Water treatment coagulant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0947749A (en) * 1995-08-07 1997-02-18 Hitachi Ltd Local water area purifying system, method therefor and purifier therefor
CN105152238A (en) * 2015-08-28 2015-12-16 邓忆凯 Novel wastewater treatment agent and preparation method thereof
CN105198059A (en) * 2015-10-13 2015-12-30 桂林市春晓环保科技有限公司 Water treatment coagulant

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110921756A (en) * 2019-12-13 2020-03-27 西安润川环保科技有限公司 Sewage treatment material and preparation method thereof

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