CN106207056A - A kind of corrosion resistant composite battery separator film material compositions - Google Patents

A kind of corrosion resistant composite battery separator film material compositions Download PDF

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Publication number
CN106207056A
CN106207056A CN201610557692.9A CN201610557692A CN106207056A CN 106207056 A CN106207056 A CN 106207056A CN 201610557692 A CN201610557692 A CN 201610557692A CN 106207056 A CN106207056 A CN 106207056A
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CN
China
Prior art keywords
parts
corrosion resistant
film material
present
battery separator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610557692.9A
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Chinese (zh)
Inventor
陈平
陈一平
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Wuxi Baolai Battery Co
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Wuxi Baolai Battery Co
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Filing date
Publication date
Application filed by Wuxi Baolai Battery Co filed Critical Wuxi Baolai Battery Co
Priority to CN201610557692.9A priority Critical patent/CN106207056A/en
Publication of CN106207056A publication Critical patent/CN106207056A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/446Composite material consisting of a mixture of organic and inorganic materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Cell Separators (AREA)

Abstract

A kind of corrosion resistant composite battery separator film material compositions, it includes the raw material of following parts by weight: matrix resin 100 parts, inorganic assistant 20 ~ 40 parts, modifying agent 2 ~ 10 parts, aerosil 2 ~ 6 parts, diethylenetriamines 1 ~ 5 part, titante coupling agent 1 ~ 5 part and dodecylbenzene sodium sulfonate 1 ~ 3 part.The battery diaphragm composite of the present invention possesses heat stability, mechanical strength, fatigue performance and the resistance to chemical corrosion of excellence;Battery diaphragm material of the present invention contains inorganic additive, interacts strong;It addition, battery diaphragm composite porosity of the present invention is up to 60 90%, and while aperture is big, tack is good, can effectively avoid coating shedding;Meanwhile, present invention, avoiding the micropore caused due to barrier film isolation and tail off, the impact that battery capacity reduces;The separator composite product of the present invention has higher safety in utilization.

Description

A kind of corrosion resistant composite battery separator film material compositions
Technical field
The present invention relates to battery diaphragm material field, be specifically related to the composite battery separator film material of a kind of high performance corrosion-proof Compositions.
Background technology
Battery diaphragm battery separator, refers to one layer of diaphragm material between anode and negative pole, is electricity Part the most crucial in pond, has a direct impact battery security and cost, and its Main Function is: isolation positive and negative electrode also makes Electronics in battery can not pass freely through, and allows the ion in electrolyte pass freely through between both positive and negative polarity.Battery diaphragm from Sub-conducting power is directly connected to the overall performance of battery, and the effect of its isolation both positive and negative polarity makes battery overcharge or temperature The rising of electric current can be limited in the case of rising, prevent battery short circuit from setting off an explosion, there is the self-closing protective effect of micropore, to battery User and equipment play the effect of safeguard protection.Existing battery diaphragm material is high temperature resistant, resistance to chemical attack, endurance and machine Tool intensity is poor, defines that it is applied to a certain extent.
Summary of the invention
The invention aims to solve current battery diaphragm material about above-mentioned problem, it is provided that a kind of corrosion resistant The composite battery separator film material compositions of erosion.
The present invention solves the technical scheme of above-mentioned technical problem employing: a kind of corrosion resistant composite battery separator film material group Compound, including the raw material of following parts by weight: matrix resin 100 parts, inorganic assistant 20 ~ 40 parts, modifying agent 2 ~ 10 parts, gas phase two Silicon oxide 2 ~ 6 parts, diethylenetriamines 1 ~ 5 part, titante coupling agent 1 ~ 5 part and dodecylbenzene sodium sulfonate 1 ~ 3 part.
Further, described matrix resin includes PPTA and N-Methyl pyrrolidone, its quality Part ratio is 1 ~ 3:1.
Further, described inorganic assistant includes calcium carbonate and nano-grade hydroxy apatite powder, and its mass parts ratio is 1 ~ 3: 1。
Further, described modifying agent is the mixing of fire retardant, dispersant, antioxidant, initiator, firming agent and age resistor Thing.
Compared with prior art, what the present invention possessed has the beneficial effect that
The battery diaphragm composite of the present invention possesses heat stability, mechanical strength, fatigue performance and the chemically-resistant of excellence Corrosive nature;Battery diaphragm material of the present invention contains inorganic additive, interacts strong;It addition, battery diaphragm of the present invention is combined Material porosity is up to 60-90%, and while aperture is big, tack is good, can effectively avoid coating shedding;Meanwhile, the present invention Avoid the micropore caused due to barrier film isolation to tail off, the impact that battery capacity reduces;The separator composite of the present invention Product has higher safety in utilization.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: a kind of corrosion resistant composite battery separator film material compositions, including the raw material of following parts by weight: base Body resin 100 parts, inorganic assistant 30 parts, modifying agent 6 parts, aerosil 4 parts, diethylenetriamines 3 parts, titanate ester are even Connection agent 3 parts and dodecylbenzene sodium sulfonate 2 parts.
Further, described matrix resin includes PPTA and N-Methyl pyrrolidone, its quality Part ratio is 2:1.
Further, described inorganic assistant includes calcium carbonate and nano-grade hydroxy apatite powder, and its mass parts is than for 2:1.
Further, described modifying agent is the mixing of fire retardant, dispersant, antioxidant, initiator, firming agent and age resistor Thing.
Embodiment 2: a kind of corrosion resistant composite battery separator film material compositions, including the raw material of following parts by weight: base Body resin 100 parts, inorganic assistant 20 parts, modifying agent 2 parts, aerosil 2 parts, diethylenetriamines 1 part, titanate ester are even Connection agent 1 part and dodecylbenzene sodium sulfonate 1 part.
Further, described matrix resin includes PPTA and N-Methyl pyrrolidone, its quality Part ratio is 1:1.
Further, described inorganic assistant includes calcium carbonate and nano-grade hydroxy apatite powder, and its mass parts is than for 1:1.
Further, described modifying agent is the mixing of fire retardant, dispersant, antioxidant, initiator, firming agent and age resistor Thing.
Embodiment 3: a kind of corrosion resistant composite battery separator film material compositions, including the raw material of following parts by weight: base Body resin 100 parts, inorganic assistant 40 parts, modifying agent 10 parts, aerosil 6 parts, diethylenetriamines 5 parts, titanate ester Coupling agent 5 parts and dodecylbenzene sodium sulfonate 3 parts.
Further, described matrix resin includes PPTA and N-Methyl pyrrolidone, its quality Part ratio is 3:1.
Further, described inorganic assistant includes calcium carbonate and nano-grade hydroxy apatite powder, and its mass parts is than for 3:1.
Further, described modifying agent is the mixing of fire retardant, dispersant, antioxidant, initiator, firming agent and age resistor Thing.
Embodiment 4: a kind of corrosion resistant composite battery separator film material compositions, including the raw material of following parts by weight: base Body resin 100 parts, inorganic assistant 20 parts, modifying agent 10 parts, aerosil 2 parts, diethylenetriamines 5 parts, titanate ester Coupling agent 1 part and dodecylbenzene sodium sulfonate 3 parts.
Further, described matrix resin includes PPTA and N-Methyl pyrrolidone, its quality Part ratio is 1:1.
Further, described inorganic assistant includes calcium carbonate and nano-grade hydroxy apatite powder, and its mass parts is than for 3:1.
Further, described modifying agent is the mixing of fire retardant, dispersant, antioxidant, initiator, firming agent and age resistor Thing.
Skilled person will appreciate that of the industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle of the simply present invention described in book, without departing from the spirit and scope of the present invention, also have various change and Improving, these changes and improvements fall within scope of the claimed invention.The scope of protection of present invention is by appended Claims and equivalent define.

Claims (5)

1. a corrosion resistant composite battery separator film material compositions, it is characterised in that include the raw material of following parts by weight: base Body resin 100 parts, inorganic assistant 20 ~ 40 parts, modifying agent 2 ~ 10 parts, aerosil 2 ~ 6 parts, diethylenetriamines 1 ~ 5 part, Titante coupling agent 1 ~ 5 part and dodecylbenzene sodium sulfonate 1 ~ 3 part.
One the most according to claim 1 corrosion resistant composite battery separator film material compositions, it is characterised in that include with The raw material of lower parts by weight: matrix resin 100 parts, inorganic assistant 30 parts, modifying agent 6 parts, aerosil 4 parts, two sub-second Base triamine 3 parts, titante coupling agent 3 parts and dodecylbenzene sodium sulfonate 2 parts.
One the most according to claim 1 and 2 corrosion resistant composite battery separator film material compositions, it is characterised in that: institute Stating matrix resin and include PPTA and N-Methyl pyrrolidone, its mass parts ratio is 1 ~ 3:1.
One the most according to claim 1 and 2 corrosion resistant composite battery separator film material compositions, it is characterised in that: institute Stating inorganic assistant and include calcium carbonate and nano-grade hydroxy apatite powder, its mass parts ratio is 1 ~ 3:1.
One the most according to claim 1 and 2 corrosion resistant composite battery separator film material compositions, it is characterised in that: institute State the mixture that modifying agent is fire retardant, dispersant, antioxidant, initiator, firming agent and age resistor.
CN201610557692.9A 2016-07-15 2016-07-15 A kind of corrosion resistant composite battery separator film material compositions Pending CN106207056A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610557692.9A CN106207056A (en) 2016-07-15 2016-07-15 A kind of corrosion resistant composite battery separator film material compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610557692.9A CN106207056A (en) 2016-07-15 2016-07-15 A kind of corrosion resistant composite battery separator film material compositions

Publications (1)

Publication Number Publication Date
CN106207056A true CN106207056A (en) 2016-12-07

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Family Applications (1)

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CN201610557692.9A Pending CN106207056A (en) 2016-07-15 2016-07-15 A kind of corrosion resistant composite battery separator film material compositions

Country Status (1)

Country Link
CN (1) CN106207056A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108630869A (en) * 2017-03-17 2018-10-09 微宏动力系统(湖州)有限公司 A kind of diaphragm, preparation method and lithium battery

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102150297A (en) * 2008-06-30 2011-08-10 住友化学株式会社 Sodium secondary battery
CN102209632A (en) * 2008-11-10 2011-10-05 三菱树脂株式会社 Laminated porous film, separator for lithium cell, and cell
CN103339757A (en) * 2010-11-30 2013-10-02 日本瑞翁株式会社 Slurry for secondary battery porous membranes, secondary battery porous membrane, secondary battery electrode, secondary battery separator, secondary battery, and method for producing secondary battery porous membrane
CN103403919A (en) * 2011-02-25 2013-11-20 日本瑞翁株式会社 Porous membrane for secondary battery, slurry for secondary battery porous membrane and secondary battery
CN103515564A (en) * 2013-10-15 2014-01-15 深圳市星源材质科技有限公司 Composite diaphragm and method for preparing same
CN104393217A (en) * 2014-10-20 2015-03-04 佛山荷韵特种材料有限公司 Composite stacked and coated lithium ion battery diaphragm and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102150297A (en) * 2008-06-30 2011-08-10 住友化学株式会社 Sodium secondary battery
CN102209632A (en) * 2008-11-10 2011-10-05 三菱树脂株式会社 Laminated porous film, separator for lithium cell, and cell
CN103339757A (en) * 2010-11-30 2013-10-02 日本瑞翁株式会社 Slurry for secondary battery porous membranes, secondary battery porous membrane, secondary battery electrode, secondary battery separator, secondary battery, and method for producing secondary battery porous membrane
CN103403919A (en) * 2011-02-25 2013-11-20 日本瑞翁株式会社 Porous membrane for secondary battery, slurry for secondary battery porous membrane and secondary battery
CN103515564A (en) * 2013-10-15 2014-01-15 深圳市星源材质科技有限公司 Composite diaphragm and method for preparing same
CN104393217A (en) * 2014-10-20 2015-03-04 佛山荷韵特种材料有限公司 Composite stacked and coated lithium ion battery diaphragm and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108630869A (en) * 2017-03-17 2018-10-09 微宏动力系统(湖州)有限公司 A kind of diaphragm, preparation method and lithium battery
CN108630869B (en) * 2017-03-17 2022-02-22 微宏动力系统(湖州)有限公司 Diaphragm, preparation method thereof and lithium battery

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Application publication date: 20161207