CN106206794A - A kind of solar cell encapsulation structure and preparation method thereof and there is its solaode - Google Patents
A kind of solar cell encapsulation structure and preparation method thereof and there is its solaode Download PDFInfo
- Publication number
- CN106206794A CN106206794A CN201610834781.3A CN201610834781A CN106206794A CN 106206794 A CN106206794 A CN 106206794A CN 201610834781 A CN201610834781 A CN 201610834781A CN 106206794 A CN106206794 A CN 106206794A
- Authority
- CN
- China
- Prior art keywords
- solar cell
- cell encapsulation
- encapsulation structure
- solaode
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005538 encapsulation Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 238000000034 method Methods 0.000 claims description 33
- 239000000243 solution Substances 0.000 claims description 27
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 20
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 20
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims description 20
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 claims description 20
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 20
- 241000196324 Embryophyta Species 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 241000684239 Canna x generalis Species 0.000 claims description 10
- 239000003292 glue Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 5
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 5
- 239000011425 bamboo Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 210000004907 gland Anatomy 0.000 claims description 4
- 238000007711 solidification Methods 0.000 claims description 4
- 230000008023 solidification Effects 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 239000003595 mist Substances 0.000 abstract description 5
- 238000002834 transmittance Methods 0.000 abstract description 5
- 210000004027 cell Anatomy 0.000 description 14
- 241001330002 Bambuseae Species 0.000 description 4
- 240000002853 Nelumbo nucifera Species 0.000 description 4
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 4
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 230000003667 anti-reflective effect Effects 0.000 description 3
- 230000003592 biomimetic effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000013518 transcription Methods 0.000 description 1
- 230000035897 transcription Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/1876—Particular processes or apparatus for batch treatment of the devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention discloses a kind of solar cell encapsulation structure and preparation method thereof and there is its solaode, encapsulating structure one side has the structure on plant leaf blade surface, it is provided simultaneously with the highest light transmittance and mist degree rate, the package surface of solaode has ultra-hydrophobicity, improves the efficiency of solaode.
Description
Technical field
The invention belongs to technical field of solar batteries, particularly relate to a kind of solar cell encapsulation structure and making side thereof
Method and there is its solaode.
Background technology
Along with the pressure of lack of energy crisis is increasing and global warming is all the more serious, the research of clean type new forms of energy
The most urgent.Wherein, solar energy is inexhaustible clean energy resource, and the application of solar energy has become solution energy danger
One of important method of machine and global warming, but, the conversion ratio of the optics such as current solaode is relatively low and absorbs
Layer material is expensive, and use cost is too high is difficult to popularization and application, therefore improves optics efficiency and becomes the important of Solar use
Task.
Solar cell package technology is the most all plate glass or smooth Organic substance at present,
During realizing the present invention, inventor finds that prior art at least there is problems in that plate glass or light
Sliding Organic substance does not possess anti-reflection ability, uses ultra-clear glasses to carry out solar cell package, and ultra-clear glasses can improve the throwing of light
Penetrating rate, but its effect is the most limited, it is the highest that the power of solaode improves cost.
Summary of the invention
The technical problem to be solved is to provide and a kind of is provided simultaneously with the highest light transmittance and mist degree rate, the sun
Can package surface solar cell encapsulation structure with ultra-hydrophobicity and preparation method thereof of battery and there is its sun
Can battery.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is: a kind of solar cell encapsulation structure,
Encapsulating structure one side has the structure on plant leaf blade surface.
Described plant leaf blade includes Canna generalis Bailey and bamboo leaf.
The manufacture method of a kind of above-mentioned solar cell encapsulation structure, comprises the steps:
1) fresh plant blade is taken, standby after cleaning；
2) configuration reverse solution；
3) by the 1st) plant leaf blade of step is attached to the bottom of mould, by the 2nd) the reverse solution that configures of step is uniformly poured into
The surface of plant leaf blade；
4) after reverse is solution cured, stripping blade, i.e. obtain the antistructure template of leaf surface structure；
5) encapsulating structure material is coated in equably by the 4th) in the antistructure template for preparing of step, and by encapsulating structure material
Upper surface gland is on the sensitive surface of solaode；
6) peel off antistructure template, obtain the solaode with solar cell encapsulation structure.
1st) in step, the dehydrated alcohol wiping of the plant leaf blade after cleaning, and dry up rear standby with hair-dryer.
Reverse solution is the mixed solution of PDMS solution and firming agent, and carries out evacuation process.
4th) in step, after reverse solution solidifies after at room temperature standing 24 hours, stripping blade.
Described encapsulating structure material is transparent ultra-violet curing glue, the 6th), in step, use Burdick lamp from antistructure template one
After face is irradiated 6-8 minute, careful stripping antistructure template.
After PDMS solution uniformly mixes according to the ratio of volume ratio 10:1 with firming agent, carry out evacuation process, will
In solution, gas is removed；After standing half an hour, it is poured into the surface of blade equably, and again carries out evacuation process, often
Being spaced takes out once in 5 minutes, stops evacuation after three times, and after being placed on left at room temperature 24 hours, PDMS solidifies completely.
5th) solaode of step includes silica-based solar cell, inorganic thin film solaode, perovskite solar energy
Battery.
A kind of solaode, has above-mentioned solar cell encapsulation structure.
A technical scheme in technique scheme has the advantage that or beneficial effect, simple to operate, production efficiency
Height, and can be with large-scale production.The encapsulating structure prepared is provided simultaneously with the highest light transmittance and mist degree rate, and both can be simultaneously
Up to more than 90%.The package surface of solaode has ultra-hydrophobicity, and the efficiency of solaode can be made to improve extremely
More than 13%.
Accompanying drawing explanation
Fig. 1 is the process chart of the manufacture method of the solar cell encapsulation structure of offer in the embodiment of the present invention；
Fig. 2 is the I-V curve figure of biomimetic features encapsulation solaode；
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing to embodiment party of the present invention
Formula is described in further detail.
Embodiment one
A kind of solar cell encapsulation structure, encapsulating structure one side has the structure on plant leaf blade surface.Encapsulating structure is same
Time possess and have the highest light transmittance and mist degree rate, it is provided that the efficiency of solaode.
Plant leaf blade includes Canna generalis Bailey and bamboo leaf.The size of Canna generalis Bailey and bamboo leaf is big, can be bionical as large area
The template of antireflective film prepares large-area bionical antireflective film.Additionally, Canna generalis Bailey and bamboo leaf all have higher hydrophobic performance, its
Bionical antireflective film also has corresponding high hydrophobicity energy.
Embodiment two
As shown in technological process Fig. 1 figure, the fresh Canna generalis Bailey blade that will pluck, after rinsing with clear water, dry up with hair-dryer,
Clean leaf surfaces again with ethanol solution carefully, after drying up, its smooth being pasted onto is fixed on microscope slide, be with it
One template.
As shown in technological process Fig. 1, the microscope slide posting Canna generalis Bailey blade is installed in mould.PDMS is solidified with it
Agent mixes according to the ratio of volume ratio 10:1 so that it is stir, and is subsequently placed in vacuum tank and carries out at evacuation
Reason, removes bubble, thus prepares required reverse solution.
As shown in technological process Fig. 1, the reverse solution above prepared is poured in plant leaf template, places into true
Empty drying baker carries out evacuation, removes bubble, stands half an hour and makes the bubble produced during cast discharge, left at room temperature the most again
24 hours.
After PDMS solution is mixed homogeneously according to the ratio of 10:1 with supporting firming agent, then carry out at evacuation
Reason, removes gas in solution, it is to avoid anti-film bubble produces.After standing half an hour, it is poured into the surface of leaf equably, and
Again carry out evacuation process, took out once at interval of 5 minutes, the when that equal difference seldom being seen and do not had bubble after three times, stop
Evacuation, and after being placed on left at room temperature 24 hours, in order to PDMS solidifies completely, and careful peels away, and the most both may be used
Prepare the PDMS reverse with blade construction, and on reverse, do not have bubble.
Use PDMS as transcription material, nontoxic, will not the inflammable and simplicity that operates, have the most elastic and pliable and tough
Property, in order to the demoulding processes.
PDMS solidification can use room temperature or elevated cure, uses the left at room temperature method of 24 hours to prepare in the present invention
PDMS reverse, in order to avoid bubble occurs in heat temperature raising in an oven, and intensification causes leaf template to deform, thus leads
Cause antitemplate deforms.The shortcoming of left at room temperature is that the cycle prepared is the longest.
As shown in technological process Fig. 1, careful lift-off stencil, i.e. obtain the antistructure of Canna generalis Bailey leaf surface structure.
Clean load glass is fixed in stickup smooth for the PDMS reverse of the Canna generalis Bailey blade surface antistructure previously prepared
On sheet, put in the middle of homemade mould, use NOA 63 type ultra-violet curing glue be spin-coated on uniformly make there is plant leaf
Above the PDMS reverse of surface texture, then NOA 63 will be scribbled solidify reverse gland being subject at solar panel of glue lightly
On bright finish.Use ultraviolet (UV) lamp that NOA 63 carries out from PDMS cured, UV light irradiation 6-8 minute first, close electricity
Source, carefully peels off reverse after taking out, so have Canna generalis Bailey blade biomimetic features and copied to solar cell surface.
Ultra-violet curing glue is the solidification glue of NORLAND OPTICAL ADHESIVE63 model produced in USA, is called for short NOA
63 types.This kind of model solidification glue there is under UV light irradiation the most superior guide-lighting performance, curing rate quickly, typically at purple
Under outer light irradiation 6-8 minute.Prepolymerization when ultra-violet curing glue eliminates other optical bondings, the operation sequence such as it is dried.
By the time it is fully cured later colloid and can have the characteristic of fabulous optical transport at 320nm-3000nm.
The I-V curve of silica-based solar cell bionical encapsulation battery is as in figure 2 it is shown, have the solar energy of biomimetic features encapsulation
Its efficiency of battery has greatly improved.
Embodiment three
As shown in technological process Fig. 1, the new new lotus leaf that will pluck, dry up with hair-dryer after rinsing with clear water, then use second
Alcoholic solution cleans its leaf surfaces carefully, the stickup that it is smooth is fixed on microscope slide after drying up, and is the first template with it.
As shown in technological process Fig. 1, the microscope slide posting Folium Nelumbinis is installed in mould.
PDMS is mixed according to the ratio of 10:1 with its firming agent, stirs, be subsequently placed in vacuum tank
Carry out evacuation process, remove bubble, prepare required reverse solution.
As shown in technological process Fig. 1, the reverse solution above prepared is poured in Folium Nelumbinis template, places into vacuum and do
Dry case carries out evacuation, removes bubble, stands and makes half an hour the bubble of cast discharge, is subsequently placed in left at room temperature 24 hours.
As shown in technological process Fig. 1, careful lift-off stencil, i.e. obtain the antistructure of lotus leaf surface structure.
Smooth the pasting of PDMS of the lotus leaf surface antistructure previously prepared is fixed on clean microscope slide, puts into
Enter in the middle of homemade mould, use NOA 63 type ultra-violet curing glue be spin-coated on uniformly make there is plant leaf surface texture
PDMS reverse above, then gland solar battery sheet on reverse gently, carry out the operation of UV lamp cured, be placed in UV
After irradiating 6-8 minute under lamp, closing power supply, carefully peel off reverse after taking out, such Folium Nelumbinis bionic surface structure is the most permissible
It is encapsulated on the sensitive surface of solaode.
As shown in technological process Fig. 1, cooling is taken out, and peels off PDMS template carefully, i.e. obtains and have lotus leaf surface knot
The inorganic bionical encapsulation battery of structure.
After using above-mentioned scheme, simple to operate, production efficiency is high, and can be with large-scale production.The encapsulating structure prepared
Being provided simultaneously with the highest light transmittance and mist degree rate, both can be up to more than 90% simultaneously.The package surface of solaode
There is ultra-hydrophobicity, the efficiency of solaode can be made to improve to more than 13%.
Above in conjunction with accompanying drawing, the present invention is exemplarily described, it is clear that the present invention implements not by aforesaid way
Restriction, as long as have employed the method design of the present invention and the improvement of various unsubstantialities that technical scheme is carried out, or without changing
Enter and design and the technical scheme of the present invention are directly applied to other occasion, all within protection scope of the present invention.
Claims (10)
1. a solar cell encapsulation structure, it is characterised in that encapsulating structure one side has the structure on plant leaf blade surface.
2. solar cell encapsulation structure as claimed in claim 1, it is characterised in that described plant leaf blade include Canna generalis Bailey and
Bamboo leaf.
3. the manufacture method of a solar cell encapsulation structure as claimed in claim 1 or 2, it is characterised in that include as
Lower step:
1) fresh plant blade is taken, standby after cleaning；
2) configuration reverse solution；
3) by the 1st) plant leaf blade of step is attached to the bottom of mould, by the 2nd) the reverse solution that configures of step is uniformly poured into plant
The surface of blade；
4) after reverse is solution cured, stripping blade, i.e. obtain the antistructure template of leaf surface structure；
5) encapsulating structure material is coated in equably by the 4th) in the antistructure template for preparing of step, and by table on encapsulating structure material
Face gland is on the sensitive surface of solaode；
6) peel off antistructure template, obtain the solaode with solar cell encapsulation structure.
4. the manufacture method of solar cell encapsulation structure as claimed in claim 3, it is characterised in that the 1st) in step, clean
After plant leaf blade dehydrated alcohol wiping, and with hair-dryer dry up after the most standby.
5. the manufacture method of solar cell encapsulation structure as claimed in claim 3, it is characterised in that reverse solution is PDMS
Solution and the mixed solution of firming agent, and carry out evacuation process.
6. the manufacture method of solar cell encapsulation structure as claimed in claim 3, it is characterised in that the 4th) in step, reverse
After solution solidifies after at room temperature standing 24 hours, stripping blade.
7. the manufacture method of solar cell encapsulation structure as claimed in claim 4, it is characterised in that described encapsulating structure material
Material for transparent ultra-violet curing glue, the 6th) in step, use Burdick lamp after antistructure template one side is irradiated 6-8 minute, little
The heart peels off antistructure template.
8. the manufacture method of solar cell encapsulation structure as claimed in claim 5, it is characterised in that PDMS solution and solidification
After agent uniformly mixes according to the ratio of volume ratio 10:1, carry out evacuation process, gas in solution is removed；Wait to stand half
After hour, it is poured into the surface of blade equably, and again carries out evacuation process, took out once at interval of 5 minutes, after three times
Stop evacuation, and after being placed on left at room temperature 24 hours, PDMS solidifies completely.
9. the manufacture method of solar cell encapsulation structure as claimed in claim 3, it is characterised in that the 5th) solar energy of step
Battery includes silica-based solar cell, inorganic thin film solaode, perovskite solaode.
10. a solaode, it is characterised in that there is solar cell encapsulation structure as claimed in claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834781.3A CN106206794A (en) | 2016-09-19 | 2016-09-19 | A kind of solar cell encapsulation structure and preparation method thereof and there is its solaode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834781.3A CN106206794A (en) | 2016-09-19 | 2016-09-19 | A kind of solar cell encapsulation structure and preparation method thereof and there is its solaode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106206794A true CN106206794A (en) | 2016-12-07 |
Family
ID=58068083
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610834781.3A Pending CN106206794A (en) | 2016-09-19 | 2016-09-19 | A kind of solar cell encapsulation structure and preparation method thereof and there is its solaode |
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| Country | Link |
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| CN (1) | CN106206794A (en) |
Cited By (3)
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| CN107611209A (en) * | 2017-10-26 | 2018-01-19 | 赖连容 | A kind of solar cell backboard and its production method |
| CN107746181A (en) * | 2017-06-23 | 2018-03-02 | 安徽工程大学 | A kind of solar cell package devitrified glass with anti-reflection characteristic and preparation method thereof and the solar cell with it |
| CN111063808A (en) * | 2019-12-17 | 2020-04-24 | 东南大学 | Preparation method of photoelectric detector for regulating morphology of perovskite thin film based on solvent ratio difference |
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| CN111063808A (en) * | 2019-12-17 | 2020-04-24 | 东南大学 | Preparation method of photoelectric detector for regulating morphology of perovskite thin film based on solvent ratio difference |
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Application publication date: 20161207 |
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