CN106206053A - There is the fabric of multistage conductive channel and utilize its method preparing ultracapacitor - Google Patents
There is the fabric of multistage conductive channel and utilize its method preparing ultracapacitor Download PDFInfo
- Publication number
- CN106206053A CN106206053A CN201610646826.4A CN201610646826A CN106206053A CN 106206053 A CN106206053 A CN 106206053A CN 201610646826 A CN201610646826 A CN 201610646826A CN 106206053 A CN106206053 A CN 106206053A
- Authority
- CN
- China
- Prior art keywords
- fabric
- channel
- conductive channel
- nano
- multistage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title description 3
- 239000000835 fiber Substances 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 8
- 239000011245 gel electrolyte Substances 0.000 claims abstract description 8
- 239000011149 active material Substances 0.000 claims abstract description 6
- 239000004020 conductor Substances 0.000 claims abstract description 5
- 238000009940 knitting Methods 0.000 claims abstract description 4
- 238000009954 braiding Methods 0.000 claims abstract description 3
- 238000005538 encapsulation Methods 0.000 claims abstract description 3
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- 239000000126 substance Substances 0.000 claims abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 18
- 229910052802 copper Inorganic materials 0.000 claims description 17
- 239000010949 copper Substances 0.000 claims description 17
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003575 carbonaceous material Substances 0.000 claims description 4
- 239000002322 conducting polymer Substances 0.000 claims description 4
- 229920001940 conductive polymer Polymers 0.000 claims description 4
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
- 150000004692 metal hydroxides Chemical class 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 239000002070 nanowire Substances 0.000 claims description 4
- 229920000128 polypyrrole Polymers 0.000 claims description 3
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910021389 graphene Inorganic materials 0.000 claims description 2
- 229920005615 natural polymer Polymers 0.000 claims description 2
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 2
- 229920000767 polyaniline Polymers 0.000 claims description 2
- 229920000123 polythiophene Polymers 0.000 claims description 2
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000003990 capacitor Substances 0.000 abstract description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 20
- 239000004372 Polyvinyl alcohol Substances 0.000 description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 description 10
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 5
- 238000005452 bending Methods 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009941 weaving Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 238000004146 energy storage Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- -1 graphite alkene Chemical class 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The invention provides a kind of fabric with multistage conductive channel, pass through braiding or the knitting fabric formed including by macromolecular fibre；Enroll described fabric in a grid, form the metal wire of leading electric channel；It is coated in the regional that leading electric channel surrounds, forms the nanometer conductive material teaching electric channel.Present invention also offers the preparation method of a kind of ultracapacitor, choose two pieces of identical above-mentioned fabrics of area, directly as electrode or first load electrochemical active material be re-used as electrode, then at two electrode central filler gel electrolytes, last package encapsulation, obtains ultracapacitor.In fabric of the present invention, leading electric channel makes the arbitrary region that electronics is quick, be transferred to low-loss fabric, and teach electric channel that electronics is transmitted to low-loss in the regional area surrounded by leading electric channel, the design of multistage conductive channel makes capacitor be sized to super large, and has good chemical property and flex capability.
Description
Technical field
The present invention relates to a kind of fabric with multistage conductive channel, and it is super to utilize this fabric to prepare oversize textile-like
The method of level capacitor, belongs to flexible super capacitor technical field.
Background technology
Along with wearable electronic and the fast development of flexible electronic devices in recent years, people increasingly focus in
Flexible energy storage device.Flexible energy storage device is the necessary assembly of above-mentioned novel electron equipment, i.e. supply unit.Wherein, flexible super
Level capacitor has high power density, long circulation life and advantages of environment protection due to it, becomes the flexible storage of current main flow
One of energy device.
Flexible super capacitor is typically implemented on flexible substrates, such as plastic base, thin metal matrix plate and macromolecule
Fabric.Wherein the load capacity of plastic base and thin metal matrix plate is limited, thus causes low energy storage density.Additionally plastic base and
The flexibility of thin metal matrix plate is limited, particularly cannot bear torsional deflection.Therefore high-molecular fabric is considered as a kind of preferable
Being applicable to the flexible substrates of flexible super capacitor, it has the advantages such as high intensity, high flexibility, high load capability and transparency.
But high-molecular fabric is typically all the insulator of electricity, needs to carry out conductive treatment, such as document (Longyan Yuan, Xu
Xiao, Tianpeng Ding, Junwen Zhong, Xianghui Zhang, Yue Shen, Bin Hu, Yunhui Huang,
Jun Zhou, and Zhong Lin Wang, Angew.Chem.Int.Ed.2012,51,4934) gold-plated on fabric；Document
(Liangbing Hu, Mauro Pasta, Fabio La Mantia, LiFeng Cui, Sangmoo Jeong, Heather
Dawn Deshazer, Jang Wook Choi, Seung Min Han, and Yi Cui, Nano Lett.2010,10,708)
Use carbon nano tube modified bafta；Document (Jie Xu, Daxiang Wang, Ye Yuan, Wei Wei, Lanlan Duan,
Luoxin Wang, Haifeng Bao, and Weilin Xu, Org.Electron.2015,24,153) on fabric, apply stone
Ink alkene.But the surface resistance that conductive treatment is obtained at present is bigger so that the area of prepared ultracapacitor is less than
100cm2, once exceed this size, the internal resistance rapid increase of ultracapacitor thus cause the dramatic decrease of performance.
Therefore, making a general survey of existing patent and document report, the conductive treatment of fabric substrate is the most perfect, it is impossible to obtain
Large scale (>=100cm2) even oversize (>=1m2) textile-like ultracapacitor, cause the textile-like ultracapacitor cannot
Meet practical application request.
Summary of the invention
The technical problem to be solved in the present invention is how to prepare large scale (>=100cm2) even oversize (>=1m2)
Textile-like ultracapacitor.
In order to solve above-mentioned technical problem, the technical scheme is that offer is a kind of and there is knitting of multistage conductive channel
Thing, it is characterised in that: include
By macromolecular fibre by braiding or the knitting fabric formed；
Enroll described fabric in a grid, form the metal wire of leading electric channel；
It is coated in the regional that leading electric channel surrounds, forms the nanometer conductive material teaching electric channel.
Preferably, during described macromolecular fibre is natural polymer subbundle, artificial macromolecular fibre, synthesis macromolecular fibre
Any one.
Preferably, described fabric thickness is 0.1～5mm, and porosity is 10%～90%.
Preferably, described metal wire is silver wire, copper cash or stainless steel wire.
Preferably, a diameter of 1～2000 μm of described metal wire.
Preferably, the coverage coefficient of described grid is 5%～50%.
Preferably, described nanometer conductive material includes nano-carbon material and nano metal material；Nano-carbon material includes carbon
Nanotube, Graphene, nano carbon black；Nano metal material includes nano silver wire, nanowires of gold, copper nano-wire, silver nano-powder, copper
Nano powder.
A kind of preparation method of ultracapacitor, it is characterised in that: choose two pieces of areas identical and not less than 1m2Above-mentioned
The fabric with multistage conductive channel, directly as the electrode of ultracapacitor, or first load electrochemical active material again
As the electrode of ultracapacitor, then at two pieces of described fabric central filler gel electrolytes, last package encapsulation, i.e. obtain
Area is not less than 1m2The ultracapacitor of oversize textile-like.
Preferably, described electrochemical active material is metal-oxide, metal hydroxides or conducting polymer.
Preferably, described metal-oxide includes copper oxide, manganese oxide, ruthenium-oxide, stannum oxide, and metal hydroxides includes
Nickel hydroxide, cobalt hydroxide, conducting polymer includes polypyrrole, polyaniline, polythiophene.
The fabric with multistage conductive channel that the present invention provides, leading electric channel in a grid is divided into crowd fabric
Multizone, each region dominated electric channel surround, therefore, electronics can quickly, low-loss be transferred to any one of fabric
Individual region.Teaching electric channel by being dominated the regional that electric channel is surrounded, its effect is to provide electronics at this regional area
Interior transmission channel.
The present invention uses has the fabric of multistage conductive channel to build textile-like ultracapacitor, wherein dominates electric channel
Enable to the arbitrary region that electronics is quick, be transferred to low-loss oversize fabric, and teach electric channel to enable to electricity
Son transmits to low-loss in the regional area surrounded by leading electric channel, the design of this multistage conductive channel so that textile-like
The size of ultracapacitor breaks through existing restriction (＜ 100cm2), it is possible to reach oversize (>=1m2), and at oversize
This textile-like ultracapacitor lower has good chemical property and flex capability, for flexible electronic devices and wearable electronic
Equipment provides practicable flexible supply unit.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments are merely to illustrate the present invention
Rather than restriction the scope of the present invention.In addition, it is to be understood that after having read the content that the present invention lectures, people in the art
The present invention can be made various changes or modifications by member, and these equivalent form of values fall within the application appended claims equally and limited
Scope.
Embodiment 1
The fabric of multistage conductive channel is formed by weaving by cotton fiber, and fabric thickness is 1mm, and porosity is
80%, then copper cash (diameter 100 μm) is enrolled the leading electric channel of formation of fabrics grid, the coverage coefficient of copper cash is
5%, in the region that copper cash surrounds, then apply CNT form guidance electric channel.
A kind of textile-like ultracapacitor with multistage conductive channel, directly choosing two pieces of areas is all 1m2Above-mentioned
Fabric is electrode of super capacitor, both central filler contain phosphoric acid polyvinyl alcohol gel electrolyte (phosphoric acid: polyvinyl alcohol:
The mass ratio of water is 1: 1: 10), finally with laminated aluminum film, the area ratio electric capacity of this textile-like ultracapacitor is 160mF/
cm2, voltage range is 0-0.8V, and area ratio capacity retention reaches 98% in the case of bending 360 ° and torsion 180 °.
Embodiment 2
The fabric of multistage conductive channel is formed by weaving by cotton fiber, and fabric thickness is 1mm, and porosity is
80%, then copper cash (100 μm) is enrolled the leading electric channel of formation of fabrics grid, the coverage coefficient of copper cash is 15%,
Then in the region that copper cash surrounds, apply CNT form guidance electric channel.
A kind of textile-like ultracapacitor with multistage conductive channel, directly choosing two pieces of areas is all 10m2Above-mentioned
Fabric is electrode of super capacitor, both central filler contain phosphoric acid polyvinyl alcohol gel electrolyte (phosphoric acid: polyvinyl alcohol:
The mass ratio of water is 1: 1: 10), finally with laminated aluminum film, the area ratio electric capacity of this textile-like ultracapacitor is 120mF/
cm2, voltage range is 0-0.8V, and area ratio capacity retention reaches 98% in the case of bending 360 ° and torsion 180 °.
Embodiment 3
The fabric of multistage conductive channel is formed by weaving by polyster fibre, and fabric thickness is 1mm, and porosity is
75%, then stainless steel wire (200 μm) is enrolled the leading electric channel of formation of fabrics grid, the coverage coefficient of stainless steel wire
Being 10%, then in the region that stainless steel wire surrounds, coated graphite alkene is formed and teaches electric channel.
A kind of textile-like ultracapacitor with multistage conductive channel, directly choosing two pieces of areas is all 1m2Above-mentioned
Fabric is electrode of super capacitor, both central filler contain phosphoric acid polyvinyl alcohol gel electrolyte (phosphoric acid: polyvinyl alcohol:
The mass ratio of water is 1: 1: 10), finally with laminated aluminum film, the area ratio electric capacity of this textile-like ultracapacitor is 800mF/
cm2, voltage range is 0-0.8V, and area ratio capacity retention reaches 98% in the case of bending 360 ° and torsion 180 °.
Embodiment 4
The fabric of multistage conductive channel is formed by weaving by cotton fiber, and fabric thickness is 1mm, and porosity is
80%, then copper cash (100 μm) is enrolled the leading electric channel of formation of fabrics grid, the coverage coefficient of copper cash is 10%,
Then in the region that copper cash surrounds, apply CNT form guidance electric channel.
A kind of textile-like ultracapacitor with multistage conductive channel, choosing two pieces of areas is all 1m2Above-mentioned fabrics,
And loading manganese oxide electrochemical active material and constitute electrode of super capacitor, both central filler contain the polyvinyl alcohol of phosphoric acid
Gel electrolyte (phosphoric acid: polyvinyl alcohol: the mass ratio of water is 1: 1: 10), finally with laminated aluminum film, the super electricity of this textile-like
The area ratio electric capacity of container is 1030mF/cm2, voltage range is 0-0.8V, and in the case of bending 360 ° and reversing 180 °
Area ratio capacity retention reaches 98%.
Embodiment 5
The fabric of multistage conductive channel is formed by weaving by cotton fiber, and fabric thickness is 1mm, and porosity is
80%, then copper cash (100 μm) is enrolled the leading electric channel of formation of fabrics grid, the coverage coefficient of copper cash is 10%,
Then in the region that copper cash surrounds, apply CNT form guidance electric channel.
A kind of textile-like ultracapacitor with multistage conductive channel, choosing two pieces of areas is all 1m2Above-mentioned fabrics,
And loading polypyrrole electrochemical active material and constitute electrode of super capacitor, both central filler contain the polyvinyl alcohol of phosphoric acid
Gel electrolyte (phosphoric acid: polyvinyl alcohol: the mass ratio of water is 1: 1: 10), finally with laminated aluminum film, the super electricity of this textile-like
The area ratio electric capacity of container is 2500mF/cm2, voltage range is 0-0.8V, and in the case of bending 360 ° and reversing 180 °
Area ratio capacity retention reaches 98%.
Claims (10)
1. a fabric with multistage conductive channel, it is characterised in that include
By macromolecular fibre by braiding or the knitting fabric formed；
Enroll described fabric in a grid, form the metal wire of leading electric channel；
It is coated in the regional that leading electric channel surrounds, forms the nanometer conductive material teaching electric channel.
A kind of fabric with multistage conductive channel, it is characterised in that: described macromolecular fibre is
Natural polymer subbundle, artificial macromolecular fibre, synthesis macromolecular fibre in any one.
A kind of fabric with multistage conductive channel, it is characterised in that: described fabric thickness is
0.1～5mm, porosity is 10%～90%.
A kind of fabric with multistage conductive channel, it is characterised in that: described metal wire is silver
Line, copper cash or stainless steel wire.
5. a kind of fabric with multistage conductive channel as described in claim 1 or 4, it is characterised in that: described metal wire
A diameter of 1～2000 μm.
A kind of fabric with multistage conductive channel, it is characterised in that: the covering system of described grid
Number is 5%～50%.
A kind of fabric with multistage conductive channel, it is characterised in that: described nanometer conductive material
Including nano-carbon material and nano metal material；Nano-carbon material includes CNT, Graphene, nano carbon black；Nano metal
Material includes nano silver wire, nanowires of gold, copper nano-wire, silver nano-powder, copper nano.
8. the preparation method of a ultracapacitor, it is characterised in that: choose two pieces of areas identical and not less than 1m2Such as right
Require the fabric with multistage conductive channel described in 1～7 any one, directly as the electrode of ultracapacitor, or first bear
Carry electrochemical active material and be re-used as the electrode of ultracapacitor, then at two pieces of described fabric central filler gel electrolytes,
Last package encapsulation, i.e. obtains area not less than 1m2The ultracapacitor of oversize textile-like.
A kind of fabric with multistage conductive channel, it is characterised in that: described electro-chemical activity material
Material is metal-oxide, metal hydroxides or conducting polymer.
A kind of fabric with multistage conductive channel, it is characterised in that: described metal-oxide
Including copper oxide, manganese oxide, ruthenium-oxide, stannum oxide, metal hydroxides includes nickel hydroxide, cobalt hydroxide, conducting polymer
Including polypyrrole, polyaniline, polythiophene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610646826.4A CN106206053A (en) | 2016-08-09 | 2016-08-09 | There is the fabric of multistage conductive channel and utilize its method preparing ultracapacitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610646826.4A CN106206053A (en) | 2016-08-09 | 2016-08-09 | There is the fabric of multistage conductive channel and utilize its method preparing ultracapacitor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106206053A true CN106206053A (en) | 2016-12-07 |
Family
ID=57514478
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610646826.4A Pending CN106206053A (en) | 2016-08-09 | 2016-08-09 | There is the fabric of multistage conductive channel and utilize its method preparing ultracapacitor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106206053A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109036866A (en) * | 2018-08-09 | 2018-12-18 | 盐城工学院 | A kind of flexible fabric base electrode material and preparation method thereof |
| CN111033659A (en) * | 2017-09-25 | 2020-04-17 | 国立大学法人千叶大学 | Porous conductor having conductive nanostructure, and electricity storage device using same |
| CN111128559A (en) * | 2019-12-13 | 2020-05-08 | 东华大学 | Preparation method of fabric-based metal/metal hydroxide flexible composite material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102881463A (en) * | 2012-08-14 | 2013-01-16 | 北京大学 | Fibrous supercapacitor and manufacturing method thereof |
| CN104485234A (en) * | 2014-12-26 | 2015-04-01 | 浙江理工大学 | Method for preparing flexible super capacitor based on textile fibers and electrodeposited polypyrrole |
| CN104900422A (en) * | 2015-05-13 | 2015-09-09 | 复旦大学 | Fabric-like super capacitor based on graphene and polyaniline and preparation method thereof |
| CN105244188A (en) * | 2015-10-22 | 2016-01-13 | 东莞市鸿愃实业有限公司 | Preparation method of carbon nano tube yarn flexible super capacitor composite electrode material |
| CN105679555A (en) * | 2016-01-12 | 2016-06-15 | 东华大学 | Preparation method for three-dimensional aminated carbon nanotube array/stretchable textile fiber electrode material |
-
2016
- 2016-08-09 CN CN201610646826.4A patent/CN106206053A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102881463A (en) * | 2012-08-14 | 2013-01-16 | 北京大学 | Fibrous supercapacitor and manufacturing method thereof |
| CN104485234A (en) * | 2014-12-26 | 2015-04-01 | 浙江理工大学 | Method for preparing flexible super capacitor based on textile fibers and electrodeposited polypyrrole |
| CN104900422A (en) * | 2015-05-13 | 2015-09-09 | 复旦大学 | Fabric-like super capacitor based on graphene and polyaniline and preparation method thereof |
| CN105244188A (en) * | 2015-10-22 | 2016-01-13 | 东莞市鸿愃实业有限公司 | Preparation method of carbon nano tube yarn flexible super capacitor composite electrode material |
| CN105679555A (en) * | 2016-01-12 | 2016-06-15 | 东华大学 | Preparation method for three-dimensional aminated carbon nanotube array/stretchable textile fiber electrode material |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111033659A (en) * | 2017-09-25 | 2020-04-17 | 国立大学法人千叶大学 | Porous conductor having conductive nanostructure, and electricity storage device using same |
| CN111033659B (en) * | 2017-09-25 | 2023-01-03 | 国立大学法人千叶大学 | Porous conductor having conductive nanostructure, and electricity storage device using same |
| US11948740B2 (en) | 2017-09-25 | 2024-04-02 | National University Corporation Chiba University | Porous conductor having conductive nanostructure and electricity storage device using same |
| CN109036866A (en) * | 2018-08-09 | 2018-12-18 | 盐城工学院 | A kind of flexible fabric base electrode material and preparation method thereof |
| CN111128559A (en) * | 2019-12-13 | 2020-05-08 | 东华大学 | Preparation method of fabric-based metal/metal hydroxide flexible composite material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Sun et al. | A single robust hydrogel film based integrated flexible supercapacitor | |
| Gao et al. | Preparation of NiMoO4-PANI core-shell nanocomposite for the high-performance all-solid-state asymmetric supercapacitor | |
| Xu et al. | Stretchable wire-shaped asymmetric supercapacitors based on pristine and MnO2 coated carbon nanotube fibers | |
| Zhang et al. | Recent advances and challenges of stretchable supercapacitors based on carbon materials | |
| Singh et al. | High-performance supercapacitor electrode based on cobalt oxide–manganese dioxide–nickel oxide ternary 1D hybrid nanotubes | |
| Gui et al. | Scalable Wire‐Type Asymmetric Pseudocapacitor Achieving High Volumetric Energy/Power Densities and Ultralong Cycling Stability of 100 000 Times | |
| Li et al. | Core-double-shell, carbon nanotube@ polypyrrole@ MnO2 sponge as freestanding, compressible supercapacitor electrode | |
| Miao et al. | Electrospun carbon nanofibers/carbon nanotubes/polyaniline ternary composites with enhanced electrochemical performance for flexible solid-state supercapacitors | |
| Yun et al. | Polypyrrole–MnO2-coated textile-based flexible-stretchable supercapacitor with high electrochemical and mechanical reliability | |
| Bao et al. | Flexible Zn2SnO4/MnO2 core/shell nanocable− carbon microfiber hybrid composites for high-performance supercapacitor electrodes | |
| Yang et al. | All-solid-state high-energy asymmetric supercapacitors enabled by three-dimensional mixed-valent MnO x nanospike and graphene electrodes | |
| Wang et al. | Three-dimensional kenaf stem-derived porous carbon/MnO2 for high-performance supercapacitors | |
| Meng et al. | Microfluidic‐Architected Nanoarrays/Porous Core–Shell Fibers toward Robust Micro‐Energy‐Storage | |
| Shahrokhian et al. | High-performance fiber-shaped flexible asymmetric microsupercapacitor based on Ni (OH) 2 nanoparticles-decorated porous dendritic Ni–Cu film/Cu wire and reduced graphene oxide/carbon fiber electrodes | |
| Luo et al. | Carbon fibers surface-grown with helical carbon nanotubes and polyaniline for high-performance electrode materials and flexible supercapacitors | |
| Sami et al. | Electrodeposited nickel–cobalt sulfide nanosheet on polyacrylonitrile nanofibers: a binder-free electrode for flexible supercapacitors | |
| Zhou et al. | Sandwich-structured transition metal oxide/graphene/carbon nanotube composite yarn electrodes for flexible two-ply yarn supercapacitors | |
| Chen et al. | Facile fabrication of three-dimensional hierarchical nanoarchitectures of VO2/graphene@ NiS2 hybrid aerogel for high-performance all-solid-state asymmetric supercapacitors with ultrahigh energy density | |
| Wang et al. | Fabrication of Supercapacitors from NiCo2O4 Nanowire/Carbon‐Nanotube Yarn for Ultraviolet Photodetectors and Portable Electronics | |
| Deng et al. | Yolk–shell structured nickel cobalt sulfide and carbon nanotube composite for high-performance hybrid supercapacitors | |
| Gao et al. | All-in-one compact architecture toward wearable all-solid-state, high-volumetric-energy-density supercapacitors | |
| Boruah et al. | Internal asymmetric tandem supercapacitor for high working voltage along with superior rate performance | |
| Lee et al. | Flexible multiwalled carbon nanotubes/conductive polymer composite electrode for supercapacitor applications | |
| Wan et al. | Three-dimensional cotton-like nickel nanowire@ Ni–Co hydroxide nanosheet arrays as binder-free electrode for high-performance asymmetric supercapacitor | |
| Cherusseri et al. | Nanotechnology advancements on carbon nanotube/polypyrrole composite electrodes for supercapacitors |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |