CN106206039A - A kind of solar powered photographic head - Google Patents
A kind of solar powered photographic head Download PDFInfo
- Publication number
- CN106206039A CN106206039A CN201610605986.4A CN201610605986A CN106206039A CN 106206039 A CN106206039 A CN 106206039A CN 201610605986 A CN201610605986 A CN 201610605986A CN 106206039 A CN106206039 A CN 106206039A
- Authority
- CN
- China
- Prior art keywords
- dye
- electrode
- solar
- substrate
- photographic head
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052799 carbon Inorganic materials 0.000 claims description 69
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 64
- 239000002086 nanomaterial Substances 0.000 claims description 59
- 239000007788 liquid Substances 0.000 claims description 2
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 239000000758 substrate Substances 0.000 description 107
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 74
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 45
- 239000000975 dye Substances 0.000 description 43
- 238000000034 method Methods 0.000 description 39
- 235000013339 cereals Nutrition 0.000 description 37
- 239000000243 solution Substances 0.000 description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 35
- 239000010409 thin film Substances 0.000 description 28
- 239000000463 material Substances 0.000 description 25
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 20
- 239000003792 electrolyte Substances 0.000 description 20
- 239000002002 slurry Substances 0.000 description 20
- 230000008569 process Effects 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 15
- 229960004756 ethanol Drugs 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 12
- 238000004140 cleaning Methods 0.000 description 12
- 230000005611 electricity Effects 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- 244000137852 Petrea volubilis Species 0.000 description 10
- 238000001354 calcination Methods 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 239000008151 electrolyte solution Substances 0.000 description 10
- 239000011259 mixed solution Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000004576 sand Substances 0.000 description 10
- 238000007650 screen-printing Methods 0.000 description 10
- 238000004506 ultrasonic cleaning Methods 0.000 description 10
- 238000006555 catalytic reaction Methods 0.000 description 9
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 7
- 230000008859 change Effects 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 229910052740 iodine Inorganic materials 0.000 description 7
- 239000011630 iodine Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000005622 photoelectricity Effects 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 7
- 239000004141 Sodium laurylsulphate Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000001755 magnetron sputter deposition Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 230000009466 transformation Effects 0.000 description 6
- 230000007704 transition Effects 0.000 description 6
- 241000209094 Oryza Species 0.000 description 5
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- DYAHQFWOVKZOOW-UHFFFAOYSA-N Sarin Chemical compound CC(C)OP(C)(F)=O DYAHQFWOVKZOOW-UHFFFAOYSA-N 0.000 description 5
- XXEHYFFPWVBUIG-UHFFFAOYSA-N [I].CN1CN(C=C1)CCC Chemical compound [I].CN1CN(C=C1)CCC XXEHYFFPWVBUIG-UHFFFAOYSA-N 0.000 description 5
- 229960000583 acetic acid Drugs 0.000 description 5
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 5
- 150000001721 carbon Chemical class 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229960000935 dehydrated alcohol Drugs 0.000 description 5
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 5
- 238000005538 encapsulation Methods 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 239000012362 glacial acetic acid Substances 0.000 description 5
- ZJYYHGLJYGJLLN-UHFFFAOYSA-N guanidinium thiocyanate Chemical compound SC#N.NC(N)=N ZJYYHGLJYGJLLN-UHFFFAOYSA-N 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 238000003760 magnetic stirring Methods 0.000 description 5
- 238000003801 milling Methods 0.000 description 5
- 239000002105 nanoparticle Substances 0.000 description 5
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 5
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 5
- 230000010412 perfusion Effects 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- 238000004544 sputter deposition Methods 0.000 description 5
- 229940116411 terpineol Drugs 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- -1 wherein Substances 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000005431 greenhouse gas Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000005619 thermoelectricity Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2022—Light-sensitive devices characterized by he counter electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2045—Light-sensitive devices comprising a semiconductor electrode comprising elements of the fourth group of the Periodic System (C, Si, Ge, Sn, Pb) with or without impurities, e.g. doping materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
Abstract
The application relates to a kind of solar powered photographic head, including camera body power supply circuits, also include solaode, controller for solar, accumulator and inverter, described solaode and described controller for solar connect, described controller for solar is connected with accumulator and camera body power supply circuits respectively, and described controller for solar is separately leaded up to inverter and is connected with described camera body power supply circuits.
Description
Technical field
The application relates to photographic head field, particularly relates to a kind of solar powered photographic head.
Background technology
At present, the power supply of photographic head still uses tradition electrical network power supply mode, but, the generating meeting such as thermoelectricity, water power
Environment is caused certain pollution,
The resource of present stage solar energy is the abundantest, and the most universal, it is affected less by season, landform, and solar energy
Use cleaning, the generation of greenhouse gases and toxic gas etc. can be significantly reduced.Along with the development of sophisticated technologies today, the sun
The research of energy technology is just processing the flourish stage, and solar battery technology is the most effective mode nowadays utilizing solar energy.
Summary of the invention
For overcoming problem present in correlation technique, the application provides a kind of solar powered photographic head.
The application is achieved through the following technical solutions:
A kind of solar powered photographic head, including camera body power supply circuits, it is characterised in that also include solar energy
Battery, controller for solar, accumulator and inverter, described solaode and described controller for solar connect, described too
Sun can be connected with accumulator and camera body power supply circuits by controller respectively, and described controller for solar separately leads up to inversion
Device is connected with described camera body power supply circuits.
The technical scheme that embodiments herein provides can include following beneficial effect:
1., in the photographic head of the application, dye-sensitized solar cells uses carbon nanomaterial as the conduction of light anode
Layer, one layer of bulky grain TiO2 of its surface screen-printed；Carbon nanomaterial uses simple spin-coating method and flame method to prepare, wherein,
Using sodium lauryl sulphate (K12) as pore creating material, prepared carbon nanomaterial contains CNT and carbon Nanowire simultaneously
Tieing up, it has layering loose structure, and resistance value is relatively low, and the layering loose structure of carbon nanomaterial has big surface area, is beneficial to
Improve the uniformity of bulky grain TiO2, dispersibility, it is possible to further more adsorpting dye molecule, from improving dye molecule
Density aspect be conducive to improve sunlight photoelectric transformation efficiency.
2. in the photographic head that the application relates to, dye-sensitized solar cells to electrode in terms of, simultaneously use with light sun
The most identical carbon nanomaterial and W metal are as the Catalytic Layer to electrode, and carbon nanomaterial has the loose structure of layering, gold
Belong to Ni can well be dispersed therein, substantially increase the catalytic efficiency to electrolyte reduction reaction；And to electrode Ti
One layer of Cr film of magnetron sputtering between substrate and carbon nanomaterial；Carbon nanomaterial is owing to having the loose structure of layering, and it is favourable
In the raising to electrolyte reduction reaction catalytic efficiency；Additionally, to increasing by one layer of Cr film between electrode basement and carbon nanomaterial,
It is as transition zone, adds the absorption viscosity of carbon nanomaterial and Ti substrate, forms two Ohmic contact in interface simultaneously,
Add the electric conductivity to electrode.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description
Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe
It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
Accompanying drawing herein is merged in description and constitutes the part of this specification, it is shown that meet the enforcement of the present invention
Example, and for explaining the principle of the present invention together with description.
Fig. 1 is the electrical block diagram of photographic head of the present invention.
Fig. 2 is the dye-sensitized solar cells Making programme figure in photographic head of the present invention.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to
During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended
The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Following disclosure provides many different embodiments or example for realizing the different structure of the application.For letter
Changing disclosure herein, hereinafter parts and setting to specific examples are described.Certainly, they are the most merely illustrative, and
It is not intended to limit the application.Additionally, the application can in different examples repeat reference numerals and/or letter.This heavy
It is for purposes of simplicity and clarity again, itself is more than the relation between various embodiment being discussed and/or arranging.This
Outward, the various specific technique that this application provides and the example of material, but those of ordinary skill in the art it can be appreciated that
The applicability of other techniques and/or the use of other materials.It addition, fisrt feature described below Second Eigenvalue " on "
Structure can include that the first and second features are formed as the embodiment directly contacted, it is also possible to include that other feature is formed at
Embodiment between first and second features, such first and second features are not likely to be directly contact.
In the description of the present application, it should be noted that unless otherwise prescribed and limit, term " is installed ", " being connected ",
" connect " and should be interpreted broadly, for example, it may be mechanically connected or electrical connection, it is also possible to be the connection of two element internals, can
Being to be joined directly together, it is also possible to be indirectly connected to by intermediary, for the ordinary skill in the art, can basis
Concrete condition understands the concrete meaning of above-mentioned term.
It is known that traditional energy includes various fossil energy, such as coal, oil, natural gas etc., traditional energy is in short-term
In do not possess recyclability, along with lasting exploitation, its reserves gradually decrease；On the other hand, the refinement of traditional energy
Process typically can produce noxious substance, greenhouse gases etc., thus destroys ecological environment, causes environmental pollution, and nowadays ecology is asked
Topic and extreme climate, use the mode of traditional energy to beat alarm bell to the mankind.Therefore, actively find, developing can
Substitute new forms of energy become in the urgent need to.
Now, study more new forms of energy and include water energy, wind energy, nuclear energy, tide energy, biomass energy and solar energy.This its
In, the resource of solar energy is the abundantest, and the most universal, it is affected less by season, landform, and solar energy uses cleaning, can
To be significantly reduced the generation of greenhouse gases and toxic gas etc..Along with the development of sophisticated technologies today, grinding of heliotechnics
Studying carefully and just process the flourish stage, solar battery technology is the most effective mode nowadays utilizing solar energy.Solaode
Experienced by general three developmental stage: silicon solar cell, thin-film solar cells and DSSC.The silicon sun
Energy battery is the most most widely used general, and its conversion efficiency is high, stable performance, but refines HIGH-PURITY SILICON and need to consume mass energy；Thin
It is higher that the manufacturing cost of film solar cell compares traditional energy price, how toxic prepares raw material, and production process can produce sternly
The environmental pollution of weight, limits it and applies on a large scale.
Dye-sensitized solar cells (DSSC) is generally sandwich structure, including light anode, to electrode and electrolyte.Light sun
Pole is usually and is made up of electrically conducting transparent substrate and the nano thin-film being positioned in conductive substrates, and conductive substrates is generally ITO, FTO etc.
Electro-conductive glass, nano thin-film surface adsorption has dye molecule, dye molecule Main Function to be the energy absorbing photon, produces electricity
Son；Typically being made up of electrode conductive substrates and the catalysis material being positioned at its surface, identical with light anode, conductive substrates is generally
The electro-conductive glass such as ITO, FTO or other conductive material, catalysis material is generally noble metal platinum, and catalysis material is used for going back original electrolyte
Middle oxidation-reduction pair, it is ensured that the circulation of dye cell can be smoothed out；Electrolyte generally contains the liquid of oxidation-reduction pair
Body, be wherein typical for iodine negative/iodine three anion, by oxidized be reduced participation cyclic process.
At present, the research to dye-sensitized solar cells is concentrated mainly on optimization selection and the structure of each several part material
Design aspect, such as, light anode research aspect, scattering layer can be introduced, increase the dyestuff absorption region to spectrum, electrode is ground
Study carefully aspect, have the improvement etc. of the replacement of Catalytic Layer material, electrode structure.Traditional DSSC uses expensive gold to electrode
Genus platinum is catalysis material, and due to Cost Problems, it is unfavorable for large-scale application；It addition, light anode construction is to DSSC opto-electronic conversion
Efficiency has a great impact, and the structure of autotelic change nano material is that a kind of DSSC photoelectricity that improves turns
Change the effective means of efficiency.
Dye-sensitized solar cells involved by photographic head in the present invention, exists in existing dye-sensitized solar cells
Problem, design is prepared for a kind of dye-sensitized solar cells with novel electrode structure, uses carbon nanomaterial as light
The bearing bed of anode dye molecule, simultaneously as the Catalytic Layer to electrode, its carbon nanomaterial preparation process is simple, the dye of preparation
The photoelectric transformation efficiency of material sensitization solar cell is high, solar cell good operating stability.
Embodiment one:
By Fig. 1, embodiments herein relates to a kind of solar powered photographic head, powers electricity including camera body
Road, it is characterised in that also include solaode, controller for solar, accumulator and inverter, described solaode and institute
Stating controller for solar to connect, described controller for solar is connected with accumulator and camera body power supply circuits respectively, described
Controller for solar is separately leaded up to inverter and is connected with described camera body power supply circuits.
Preferably, described solaode is dye-sensitized solar cells.
Preferably, electrode by light anode, electrolyte and is constituted by described dye-sensitized solar cells；Described smooth anode is by outward
ITO substrate, carbon nanomaterial, bulky grain TiO2, dye molecule it is followed successively by and；Described electrode is followed successively by from outside to inside Ti base
The end, Cu thin film, carbon nanomaterial, Ni thin film；Described smooth anode with described be 100 μm to electrode spacing；Described Ni thickness is
5nm。
Preferably, Fig. 2 shows described dye-sensitized solar cells Making programme figure, and its concrete preparation process is as follows:
S1, makes electrode:
A) clean, process Ti substrate:
Use Ti as the substrate to electrode, choose the Ti sheet of suitable size (such as 5cm × 5cm), after cleaning, then use sand
Paper is polished, and the mesh number of sand paper is incremented by, the sand papering 20min of every kind of mesh number so that Ti substrate surface removes obvious impurity, and
And there is camber, and utilize magnetron sputtering method to be deposited with layer of metal Cu thin film on its surface, thickness is 300nm, then, by Ti base
The end, is put into hydrochloric acid solution and soaks 30min, distinguishes ultrasonic cleaning 20min with acetone, ethanol and deionized water, subsequently by Ti substrate certainly
So dry；
B) Ti substrate surface growth carbon nanomaterial:
At 80 DEG C, preparation NiSO4 solution and sodium lauryl sulphate (K12) solution, concentration is respectively 21%～42% He
18%～35% (mass fraction), respectively takes 200ml, under magnetic stirring mix homogeneously, utilizes sol evenning machine to be spun on a
The Ti substrate surface that step obtains, after being dried 2h, places it in flame surface and processes 20min, i.e. form carbon at Ti substrate surface and receive
Rice material；
C) catalyst n i thin film is made
Taking Ti substrate obtained above, put in magnetic control sputtering device, be deposited with layer of Ni thin film, wherein, base vacuum is 1.5
× 10-3pa, obtains electrode；
S2, making light anode:
A) clean, process ITO substrate:
Light anode substrate uses ito glass, chooses and the ITO substrate to electrode Ti substrate same size, according to step one
In, use sand papering ITO substrate, then with acetone, ethanol and deionized water ultrasonic cleaning 20min respectively, subsequently by ITO substrate
Naturally dry；
B) ITO substrate superficial growth carbon nanomaterial:
Same procedure in using step one b), at ITO substrate superficial growth carbon nanomaterial,
C) silk screen printing bulky grain TiO2:
Take bulky grain (500nm) TiO2 nano-particle and the 5ml glacial acetic acid mix homogeneously of 18g, be then added dropwise over from
Sub-water and ethanol grind, and milling time is 4h, by adding terpineol in ground mixed solution, carry out in supersonic cleaning machine
Ultrasonic disperse, is placed in solution in Rotary Evaporators subsequently and is steamed by unnecessary dehydrated alcohol, then continued by remaining slurry
Grind 3h, i.e. obtain bulky grain TiO2 slurry；Utilize the method for silk screen printing by prepared bulky grain TiO2 slurry for rotary coating in life
Long have in the ITO substrate of carbon nanomaterial, and bulky grain TiO2 slurry thickness is 2500nm, then ITO substrate is put into Muffle furnace
In 400 DEG C calcining 30min
D) absorbing dye:
The mixed solution (volume ratio 1:1) taking N719 and the tert-butyl alcohol and acetonitrile is configured to the dye solution of 0.6mM, will calcining
After ITO substrate put in dye solution, through 28h dyestuff soak after take out, rinse 2min with acetonitrile, dry, obtain light
Anode；
S3, filling electrolyte solution and encapsulation:
The light anode of absorbing dye is staggered relatively with to electrode, be encapsulated together with sarin resin, light anode with
Being 100 μm to thickness between electrode, the most backward gap therebetween perfusion electrolyte, electrolyte solution is the iodine of 0.06M, 1.2M's
1-methyl-3 propyl imidazole iodine, the guanidine thiocyanate of 0.7M, the acetonitrile solution of the tert .-butylpyridine of 0.6M, closure electricity after fill
Solve matter perfusing hole, complete the preparation of dye-sensitized solar cells.
Preferably, electrode and light anode all be have employed identical by the dye-sensitized solar cells in photographic head of the present invention
Carbon nanomaterial.The bottom of carbon nanomaterial is relatively compact even in hardening close to base part, presents compacted zone, upper part,
Being separated from each other, present porous layer, compacted zone and porous layer thickness ratio are 1:3.This dye-sensitized solar cells is carried out photoelectricity
Conversion efficiency is measured, and simulated solar irradiation is formed by simulated solar photogenerator, and light intensity is 100mWcm-2, and spectrum meets
AM1.5 standard, arriving of test, the open-circuit voltage of this dye-sensitized solar cells is 0.72 ± 0.05V, and short-circuit current density is
9.6 ± 0.1mAcm-2, conversion efficiency is 12.1%.
In the photographic head of the present invention, dye-sensitized solar cells uses the carbon nanometer material that manufacturing process is simple, with low cost
Material is as to the Catalytic Layer of electrode and the conductive layer of light anode, and this carbon nanomaterial has compacted zone and the porous layer of uniqueness, answers
For to electrode, its loose structure is conducive to the catalysis of electrolyte reduction reaction, and it forms Ohmic contact with transition zone Cr,
Having relatively low resistance, be applied to light anode, it considerably increases the dispersibility of bulky grain TiO2, uniformity, carries further
The high adsorption rate of dyestuff, uses the dye-sensitized solar cells of this electrode structure to show higher sunlight conversion efficiency.
The photographic head of the present invention is capable of the efficient utilization of sunlight, and this repeatability, has good stability, and photoelectricity turns
Change efficiency high, possess the biggest market application foreground.
Embodiment two:
By Fig. 1, embodiments herein relates to a kind of solar powered photographic head, powers electricity including camera body
Road, it is characterised in that also include solaode, controller for solar, accumulator and inverter, described solaode and institute
Stating controller for solar to connect, described controller for solar is connected with accumulator and camera body power supply circuits respectively, described
Controller for solar is separately leaded up to inverter and is connected with described camera body power supply circuits.
Preferably, described solaode is dye-sensitized solar cells.
Preferably, electrode by light anode, electrolyte and is constituted by described dye-sensitized solar cells；Described smooth anode is by outward
ITO substrate, carbon nanomaterial, bulky grain TiO2, dye molecule it is followed successively by and；Described electrode is followed successively by from outside to inside Ti base
The end, Cu thin film, carbon nanomaterial, Ni thin film；Described smooth anode with described be 100 μm to electrode spacing；Described Ni thickness is
5nm。
Preferably, Fig. 2 shows described dye-sensitized solar cells Making programme figure, and its concrete preparation process is as follows:
S1, makes electrode:
A) clean, process Ti substrate:
Use Ti as the substrate to electrode, choose the Ti sheet of suitable size (such as 5cm × 5cm), after cleaning, then use sand
Paper is polished, and the mesh number of sand paper is incremented by, the sand papering 20min of every kind of mesh number so that Ti substrate surface removes obvious impurity, and
And there is camber, and utilize magnetron sputtering method to be deposited with layer of metal Cu thin film on its surface, thickness is 300nm, then, by Ti base
The end, is put into hydrochloric acid solution and soaks 30min, distinguishes ultrasonic cleaning 20min with acetone, ethanol and deionized water, subsequently by Ti substrate certainly
So dry；
B) Ti substrate surface growth carbon nanomaterial:
At 80 DEG C, preparation NiSO4 solution and sodium lauryl sulphate (K12) solution, concentration is respectively 21%～42% He
18%～35% (mass fraction), respectively takes 200ml, under magnetic stirring mix homogeneously, utilizes sol evenning machine to be spun on a
The Ti substrate surface that step obtains, after being dried 2h, places it in flame surface and processes 20min, i.e. form carbon at Ti substrate surface and receive
Rice material；
C) catalyst n i thin film is made
Taking Ti substrate obtained above, put in magnetic control sputtering device, be deposited with layer of Ni thin film, wherein, base vacuum is 1.5
× 10-3pa, obtains electrode；
S2, making light anode:
A) clean, process ITO substrate:
Light anode substrate uses ito glass, chooses and the ITO substrate to electrode Ti substrate same size, according to step one
In, use sand papering ITO substrate, then with acetone, ethanol and deionized water ultrasonic cleaning 20min respectively, subsequently by ITO substrate
Naturally dry；
B) ITO substrate superficial growth carbon nanomaterial:
Same procedure in using step one b), at ITO substrate superficial growth carbon nanomaterial,
C) silk screen printing bulky grain TiO2:
Take bulky grain (500nm) TiO2 nano-particle and the 5ml glacial acetic acid mix homogeneously of 18g, be then added dropwise over from
Sub-water and ethanol grind, and milling time is 4h, by adding terpineol in ground mixed solution, carry out in supersonic cleaning machine
Ultrasonic disperse, is placed in solution in Rotary Evaporators subsequently and is steamed by unnecessary dehydrated alcohol, then continued by remaining slurry
Grind 3h, i.e. obtain bulky grain TiO2 slurry；Utilize the method for silk screen printing by prepared bulky grain TiO2 slurry for rotary coating in life
Long have in the ITO substrate of carbon nanomaterial, and bulky grain TiO2 slurry thickness is 2500nm, then ITO substrate is put into Muffle furnace
In 400 DEG C calcining 30min
D) absorbing dye:
The mixed solution (volume ratio 1:1) taking N719 and the tert-butyl alcohol and acetonitrile is configured to the dye solution of 0.6mM, will calcining
After ITO substrate put in dye solution, through 28h dyestuff soak after take out, rinse 2min with acetonitrile, dry, obtain light
Anode；
S3, filling electrolyte solution and encapsulation:
The light anode of absorbing dye is staggered relatively with to electrode, be encapsulated together with sarin resin, light anode with
Being 100 μm to thickness between electrode, the most backward gap therebetween perfusion electrolyte, electrolyte solution is the iodine of 0.06M, 1.2M's
1-methyl-3 propyl imidazole iodine, the guanidine thiocyanate of 0.7M, the acetonitrile solution of the tert .-butylpyridine of 0.6M, closure electricity after fill
Solve matter perfusing hole, complete the preparation of dye-sensitized solar cells.
Preferably, the dye-sensitized solar cells of photographic head of the present invention all have employed identical carbon to electrode and light anode
Nano material.The bottom of carbon nanomaterial is relatively compact even in hardening close to base part, presents compacted zone, upper part, that
This separately presents porous layer, and compacted zone and porous layer thickness ratio are 1:3.Dye-sensitized solar cells of the present invention is carried out light
Photoelectric transformation efficiency is measured, and simulated solar irradiation is formed by simulated solar photogenerator, and light intensity is 100mWcm-2, and spectrum meets
AM1.5 standard, arriving of test, the open-circuit voltage of this dye-sensitized solar cells is 0.72 ± 0.05V, and short-circuit current density is
9.6 ± 0.1mAcm-2, conversion efficiency is 10.6%.
In the photographic head of the present invention, dye-sensitized solar cells uses the carbon nanometer material that manufacturing process is simple, with low cost
Material is as to the Catalytic Layer of electrode and the conductive layer of light anode, and this carbon nanomaterial has compacted zone and the porous layer of uniqueness, answers
For to electrode, its loose structure is conducive to the catalysis of electrolyte reduction reaction, and it forms Ohmic contact with transition zone Cr,
Having relatively low resistance, be applied to light anode, it considerably increases the dispersibility of bulky grain TiO2, uniformity, carries further
The high adsorption rate of dyestuff, uses the dye-sensitized solar cells of this electrode structure to show higher sunlight conversion efficiency.
The photographic head of the present invention is capable of the efficient utilization of sunlight, and this repeatability, has good stability, and photoelectricity turns
Change efficiency high, possess the biggest market application foreground.
Embodiment three:
By Fig. 1, embodiments herein relates to a kind of solar powered photographic head, powers electricity including camera body
Road, it is characterised in that also include solaode, controller for solar, accumulator and inverter, described solaode and institute
Stating controller for solar to connect, described controller for solar is connected with accumulator and camera body power supply circuits respectively, described
Controller for solar is separately leaded up to inverter and is connected with described camera body power supply circuits.
Preferably, described solaode is dye-sensitized solar cells.
Preferably, electrode by light anode, electrolyte and is constituted by described dye-sensitized solar cells；Described smooth anode is by outward
ITO substrate, carbon nanomaterial, bulky grain TiO2, dye molecule it is followed successively by and；Described electrode is followed successively by from outside to inside Ti base
The end, Cu thin film, carbon nanomaterial, Ni thin film；Described smooth anode with described be 100 μm to electrode spacing；Described Ni thickness is
5nm。
Preferably, Fig. 2 shows described dye-sensitized solar cells Making programme figure, and its concrete preparation process is as follows:
S1, makes electrode:
A) clean, process Ti substrate:
Use Ti as the substrate to electrode, choose the Ti sheet of suitable size (such as 5cm × 5cm), after cleaning, then use sand
Paper is polished, and the mesh number of sand paper is incremented by, the sand papering 20min of every kind of mesh number so that Ti substrate surface removes obvious impurity, and
And there is camber, and utilize magnetron sputtering method to be deposited with layer of metal Cu thin film on its surface, thickness is 300nm, then, by Ti base
The end, is put into hydrochloric acid solution and soaks 30min, distinguishes ultrasonic cleaning 20min with acetone, ethanol and deionized water, subsequently by Ti substrate certainly
So dry；
B) Ti substrate surface growth carbon nanomaterial:
At 80 DEG C, preparation NiSO4 solution and sodium lauryl sulphate (K12) solution, concentration is respectively 21%～42% He
18%～35% (mass fraction), respectively takes 200ml, under magnetic stirring mix homogeneously, utilizes sol evenning machine to be spun on a
The Ti substrate surface that step obtains, after being dried 2h, places it in flame surface and processes 20min, i.e. form carbon at Ti substrate surface and receive
Rice material；
C) catalyst n i thin film is made
Taking Ti substrate obtained above, put in magnetic control sputtering device, be deposited with layer of Ni thin film, wherein, base vacuum is 1.5
× 10-3pa, obtains electrode；
S2, making light anode:
A) clean, process ITO substrate:
Light anode substrate uses ito glass, chooses and the ITO substrate to electrode Ti substrate same size, according to step one
In, use sand papering ITO substrate, then with acetone, ethanol and deionized water ultrasonic cleaning 20min respectively, subsequently by ITO substrate
Naturally dry；
B) ITO substrate superficial growth carbon nanomaterial:
Same procedure in using step one b), at ITO substrate superficial growth carbon nanomaterial,
C) silk screen printing bulky grain TiO2:
Take bulky grain (500nm) TiO2 nano-particle and the 5ml glacial acetic acid mix homogeneously of 18g, be then added dropwise over from
Sub-water and ethanol grind, and milling time is 4h, by adding terpineol in ground mixed solution, carry out in supersonic cleaning machine
Ultrasonic disperse, is placed in solution in Rotary Evaporators subsequently and is steamed by unnecessary dehydrated alcohol, then continued by remaining slurry
Grind 3h, i.e. obtain bulky grain TiO2 slurry；Utilize the method for silk screen printing by prepared bulky grain TiO2 slurry for rotary coating in life
Long have in the ITO substrate of carbon nanomaterial, and bulky grain TiO2 slurry thickness is 2500nm, then ITO substrate is put into Muffle furnace
In 400 DEG C calcining 30min
D) absorbing dye:
The mixed solution (volume ratio 1:1) taking N719 and the tert-butyl alcohol and acetonitrile is configured to the dye solution of 0.6mM, will calcining
After ITO substrate put in dye solution, through 28h dyestuff soak after take out, rinse 2min with acetonitrile, dry, obtain light
Anode；
S3, filling electrolyte solution and encapsulation:
The light anode of absorbing dye is staggered relatively with to electrode, be encapsulated together with sarin resin, light anode with
Being 100 μm to thickness between electrode, the most backward gap therebetween perfusion electrolyte, electrolyte solution is the iodine of 0.06M, 1.2M's
1-methyl-3 propyl imidazole iodine, the guanidine thiocyanate of 0.7M, the acetonitrile solution of the tert .-butylpyridine of 0.6M, closure electricity after fill
Solve matter perfusing hole, complete the preparation of dye-sensitized solar cells.
Preferably, the dye-sensitized solar cells of photographic head of the present invention all have employed identical carbon to electrode and light anode
Nano material.The bottom of carbon nanomaterial is relatively compact even in hardening close to base part, presents compacted zone, upper part, that
This separately presents porous layer, and compacted zone and porous layer thickness ratio are 1:3.Dye-sensitized solar cells of the present invention is carried out light
Photoelectric transformation efficiency is measured, and simulated solar irradiation is formed by simulated solar photogenerator, and light intensity is 100mWcm-2, and spectrum meets
AM1.5 standard, arriving of test, the open-circuit voltage of this dye-sensitized solar cells is 0.72 ± 0.05V, and short-circuit current density is
9.6 ± 0.1mAcm-2, conversion efficiency is 9.1%.
In the photographic head of the present invention, dye-sensitized solar cells uses the carbon nanometer material that manufacturing process is simple, with low cost
Material is as to the Catalytic Layer of electrode and the conductive layer of light anode, and this carbon nanomaterial has compacted zone and the porous layer of uniqueness, answers
For to electrode, its loose structure is conducive to the catalysis of electrolyte reduction reaction, and it forms Ohmic contact with transition zone Cr,
Having relatively low resistance, be applied to light anode, it considerably increases the dispersibility of bulky grain TiO2, uniformity, carries further
The high adsorption rate of dyestuff, uses the dye-sensitized solar cells of this electrode structure to show higher sunlight conversion efficiency.
The photographic head of the present invention is capable of the efficient utilization of sunlight, and this repeatability, has good stability, and photoelectricity turns
Change efficiency high, possess the biggest market application foreground.
Embodiment four:
By Fig. 1, embodiments herein relates to a kind of solar powered photographic head, powers electricity including camera body
Road, it is characterised in that also include solaode, controller for solar, accumulator and inverter, described solaode and institute
Stating controller for solar to connect, described controller for solar is connected with accumulator and camera body power supply circuits respectively, described
Controller for solar is separately leaded up to inverter and is connected with described camera body power supply circuits.
Preferably, described solaode is dye-sensitized solar cells.
Preferably, electrode by light anode, electrolyte and is constituted by described dye-sensitized solar cells；Described smooth anode is by outward
ITO substrate, carbon nanomaterial, bulky grain TiO2, dye molecule it is followed successively by and；Described electrode is followed successively by from outside to inside Ti base
The end, Cu thin film, carbon nanomaterial, Ni thin film；Described smooth anode with described be 100 μm to electrode spacing；Described Ni thickness is
5nm。
Preferably, Fig. 2 shows described dye-sensitized solar cells Making programme figure, and its concrete preparation process is as follows:
S1, makes electrode:
A) clean, process Ti substrate:
Use Ti as the substrate to electrode, choose the Ti sheet of suitable size (such as 5cm × 5cm), after cleaning, then use sand
Paper is polished, and the mesh number of sand paper is incremented by, the sand papering 20min of every kind of mesh number so that Ti substrate surface removes obvious impurity, and
And there is camber, and utilize magnetron sputtering method to be deposited with layer of metal Cu thin film on its surface, thickness is 300nm, then, by Ti base
The end, is put into hydrochloric acid solution and soaks 30min, distinguishes ultrasonic cleaning 20min with acetone, ethanol and deionized water, subsequently by Ti substrate certainly
So dry；
B) Ti substrate surface growth carbon nanomaterial:
At 80 DEG C, preparation NiSO4 solution and sodium lauryl sulphate (K12) solution, concentration is respectively 21%～42% He
18%～35% (mass fraction), respectively takes 200ml, under magnetic stirring mix homogeneously, utilizes sol evenning machine to be spun on a
The Ti substrate surface that step obtains, after being dried 2h, places it in flame surface and processes 20min, i.e. form carbon at Ti substrate surface and receive
Rice material；
C) catalyst n i thin film is made
Taking Ti substrate obtained above, put in magnetic control sputtering device, be deposited with layer of Ni thin film, wherein, base vacuum is 1.5
× 10-3pa, obtains electrode；
S2, making light anode:
A) clean, process ITO substrate:
Light anode substrate uses ito glass, chooses and the ITO substrate to electrode Ti substrate same size, according to step one
In, use sand papering ITO substrate, then with acetone, ethanol and deionized water ultrasonic cleaning 20min respectively, subsequently by ITO substrate
Naturally dry；
B) ITO substrate superficial growth carbon nanomaterial:
Same procedure in using step one b), at ITO substrate superficial growth carbon nanomaterial,
C) silk screen printing bulky grain TiO2:
Take bulky grain (500nm) TiO2 nano-particle and the 5ml glacial acetic acid mix homogeneously of 18g, be then added dropwise over from
Sub-water and ethanol grind, and milling time is 4h, by adding terpineol in ground mixed solution, carry out in supersonic cleaning machine
Ultrasonic disperse, is placed in solution in Rotary Evaporators subsequently and is steamed by unnecessary dehydrated alcohol, then continued by remaining slurry
Grind 3h, i.e. obtain bulky grain TiO2 slurry；Utilize the method for silk screen printing by prepared bulky grain TiO2 slurry for rotary coating in life
Long have in the ITO substrate of carbon nanomaterial, and bulky grain TiO2 slurry thickness is 2500nm, then ITO substrate is put into Muffle furnace
In 400 DEG C calcining 30min
D) absorbing dye:
The mixed solution (volume ratio 1:1) taking N719 and the tert-butyl alcohol and acetonitrile is configured to the dye solution of 0.6mM, will calcining
After ITO substrate put in dye solution, through 28h dyestuff soak after take out, rinse 2min with acetonitrile, dry, obtain light
Anode；
S3, filling electrolyte solution and encapsulation:
The light anode of absorbing dye is staggered relatively with to electrode, be encapsulated together with sarin resin, light anode with
Being 100 μm to thickness between electrode, the most backward gap therebetween perfusion electrolyte, electrolyte solution is the iodine of 0.06M, 1.2M's
1-methyl-3 propyl imidazole iodine, the guanidine thiocyanate of 0.7M, the acetonitrile solution of the tert .-butylpyridine of 0.6M, closure electricity after fill
Solve matter perfusing hole, complete the preparation of dye-sensitized solar cells.
Preferably, the dye-sensitized solar cells of photographic head of the present invention all have employed identical carbon to electrode and light anode
Nano material.The bottom of carbon nanomaterial is relatively compact even in hardening close to base part, presents compacted zone, upper part, that
This separately presents porous layer, and compacted zone and porous layer thickness ratio are 1:3.Dye-sensitized solar cells of the present invention is carried out light
Photoelectric transformation efficiency is measured, and simulated solar irradiation is formed by simulated solar photogenerator, and light intensity is 100mWcm-2, and spectrum meets
AM1.5 standard, arriving of test, the open-circuit voltage of this dye-sensitized solar cells is 0.72 ± 0.05V, and short-circuit current density is
9.6 ± 0.1mAcm-2, conversion efficiency is 10.8%.
In the photographic head of the present invention, dye-sensitized solar cells uses the carbon nanometer material that manufacturing process is simple, with low cost
Material is as to the Catalytic Layer of electrode and the conductive layer of light anode, and this carbon nanomaterial has compacted zone and the porous layer of uniqueness, answers
For to electrode, its loose structure is conducive to the catalysis of electrolyte reduction reaction, and it forms Ohmic contact with transition zone Cr,
Having relatively low resistance, be applied to light anode, it considerably increases the dispersibility of bulky grain TiO2, uniformity, carries further
The high adsorption rate of dyestuff, uses the dye-sensitized solar cells of this electrode structure to show higher sunlight conversion efficiency.
The photographic head of the present invention is capable of the efficient utilization of sunlight, and this repeatability, has good stability, and photoelectricity turns
Change efficiency high, possess the biggest market application foreground.
Embodiment five:
By Fig. 1, embodiments herein relates to a kind of solar powered photographic head, powers electricity including camera body
Road, it is characterised in that also include solaode, controller for solar, accumulator and inverter, described solaode and institute
Stating controller for solar to connect, described controller for solar is connected with accumulator and camera body power supply circuits respectively, described
Controller for solar is separately leaded up to inverter and is connected with described camera body power supply circuits.
Preferably, described solaode is dye-sensitized solar cells.
Preferably, electrode by light anode, electrolyte and is constituted by described dye-sensitized solar cells；Described smooth anode is by outward
ITO substrate, carbon nanomaterial, bulky grain TiO2, dye molecule it is followed successively by and；Described electrode is followed successively by from outside to inside Ti base
The end, Cu thin film, carbon nanomaterial, Ni thin film；Described smooth anode with described be 100 μm to electrode spacing；Described Ni thickness is
5nm。
Preferably, Fig. 2 shows described dye-sensitized solar cells Making programme figure, and its concrete preparation process is as follows:
S1, makes electrode:
A) clean, process Ti substrate:
Use Ti as the substrate to electrode, choose the Ti sheet of suitable size (such as 5cm × 5cm), after cleaning, then use sand
Paper is polished, and the mesh number of sand paper is incremented by, the sand papering 20min of every kind of mesh number so that Ti substrate surface removes obvious impurity, and
And there is camber, and utilize magnetron sputtering method to be deposited with layer of metal Cu thin film on its surface, thickness is 300nm, then, by Ti base
The end, is put into hydrochloric acid solution and soaks 30min, distinguishes ultrasonic cleaning 20min with acetone, ethanol and deionized water, subsequently by Ti substrate certainly
So dry；
B) Ti substrate surface growth carbon nanomaterial:
At 80 DEG C, preparation NiSO4 solution and sodium lauryl sulphate (K12) solution, concentration is respectively 21%～42% He
18%～35% (mass fraction), respectively takes 200ml, under magnetic stirring mix homogeneously, utilizes sol evenning machine to be spun on a
The Ti substrate surface that step obtains, after being dried 2h, places it in flame surface and processes 20min, i.e. form carbon at Ti substrate surface and receive
Rice material；
C) catalyst n i thin film is made
Taking Ti substrate obtained above, put in magnetic control sputtering device, be deposited with layer of Ni thin film, wherein, base vacuum is 1.5
× 10-3pa, obtains electrode；
S2, making light anode:
A) clean, process ITO substrate:
Light anode substrate uses ito glass, chooses and the ITO substrate to electrode Ti substrate same size, according to step one
In, use sand papering ITO substrate, then with acetone, ethanol and deionized water ultrasonic cleaning 20min respectively, subsequently by ITO substrate
Naturally dry；
B) ITO substrate superficial growth carbon nanomaterial:
Same procedure in using step one b), at ITO substrate superficial growth carbon nanomaterial,
C) silk screen printing bulky grain TiO2:
Take bulky grain (500nm) TiO2 nano-particle and the 5ml glacial acetic acid mix homogeneously of 18g, be then added dropwise over from
Sub-water and ethanol grind, and milling time is 4h, by adding terpineol in ground mixed solution, carry out in supersonic cleaning machine
Ultrasonic disperse, is placed in solution in Rotary Evaporators subsequently and is steamed by unnecessary dehydrated alcohol, then continued by remaining slurry
Grind 3h, i.e. obtain bulky grain TiO2 slurry；Utilize the method for silk screen printing by prepared bulky grain TiO2 slurry for rotary coating in life
Long have in the ITO substrate of carbon nanomaterial, and bulky grain TiO2 slurry thickness is 2500nm, then ITO substrate is put into Muffle furnace
In 400 DEG C calcining 30min
D) absorbing dye:
The mixed solution (volume ratio 1:1) taking N719 and the tert-butyl alcohol and acetonitrile is configured to the dye solution of 0.6mM, will calcining
After ITO substrate put in dye solution, through 28h dyestuff soak after take out, rinse 2min with acetonitrile, dry, obtain light
Anode；
S3, filling electrolyte solution and encapsulation:
The light anode of absorbing dye is staggered relatively with to electrode, be encapsulated together with sarin resin, light anode with
Being 100 μm to thickness between electrode, the most backward gap therebetween perfusion electrolyte, electrolyte solution is the iodine of 0.06M, 1.2M's
1-methyl-3 propyl imidazole iodine, the guanidine thiocyanate of 0.7M, the acetonitrile solution of the tert .-butylpyridine of 0.6M, closure electricity after fill
Solve matter perfusing hole, complete the preparation of dye-sensitized solar cells.
Preferably, the dye-sensitized solar cells of photographic head of the present invention all have employed identical carbon to electrode and light anode
Nano material.The bottom of carbon nanomaterial is relatively compact even in hardening close to base part, presents compacted zone, upper part, that
This separately presents porous layer, and compacted zone and porous layer thickness ratio are 1:3.Dye-sensitized solar cells of the present invention is carried out light
Photoelectric transformation efficiency is measured, and simulated solar irradiation is formed by simulated solar photogenerator, and light intensity is 100mWcm-2, and spectrum meets
AM1.5 standard, arriving of test, the open-circuit voltage of this dye-sensitized solar cells is 0.72 ± 0.05V, and short-circuit current density is
9.6 ± 0.1mAcm-2, conversion efficiency is 8.4%.
In the photographic head of the present invention, dye-sensitized solar cells uses the carbon nanometer material that manufacturing process is simple, with low cost
Material is as to the Catalytic Layer of electrode and the conductive layer of light anode, and this carbon nanomaterial has compacted zone and the porous layer of uniqueness, answers
For to electrode, its loose structure is conducive to the catalysis of electrolyte reduction reaction, and it forms Ohmic contact with transition zone Cr,
Having relatively low resistance, be applied to light anode, it considerably increases the dispersibility of bulky grain TiO2, uniformity, carries further
The high adsorption rate of dyestuff, uses the dye-sensitized solar cells of this electrode structure to show higher sunlight conversion efficiency.
The photographic head of the present invention is capable of the efficient utilization of sunlight, and this repeatability, has good stability, and photoelectricity turns
Change efficiency high, possess the biggest market application foreground.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention
Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or
Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application
Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following
Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and
And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.
Claims (3)
1. a solar powered photographic head, including camera body power supply circuits, it is characterised in that also include solar-electricity
Pond, controller for solar, accumulator and inverter, described solaode and described controller for solar connect, the described sun
Can be connected with accumulator and camera body power supply circuits respectively by controller, described controller for solar separately leads up to inverter
It is connected with described camera body power supply circuits.
Photographic head the most according to claim 1, it is characterised in that described solaode is dye-sensitized solar cells.
Photographic head the most according to claim 2, it is characterised in that described dye-sensitized solar cells is by light anode, electrolysis
Liquid and electrode is constituted, described in electrode and light anode containing carbon nanomaterial.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610605986.4A CN106206039A (en) | 2016-07-27 | 2016-07-27 | A kind of solar powered photographic head |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610605986.4A CN106206039A (en) | 2016-07-27 | 2016-07-27 | A kind of solar powered photographic head |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106206039A true CN106206039A (en) | 2016-12-07 |
Family
ID=57496205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610605986.4A Pending CN106206039A (en) | 2016-07-27 | 2016-07-27 | A kind of solar powered photographic head |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106206039A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005158380A (en) * | 2003-11-25 | 2005-06-16 | Sony Corp | Photoelectric conversion element, its manufacturing method, electronic apparatus and its manufacturing method |
| CN201274524Y (en) * | 2008-10-14 | 2009-07-15 | 天津三星电子有限公司 | Camera head supplying electricity by solar energy |
| CN202102522U (en) * | 2011-06-29 | 2012-01-04 | 杭州自力太阳能科技有限公司 | Solar energy-driven driving recorder |
| CN103824697A (en) * | 2014-03-11 | 2014-05-28 | 西安工业大学 | Dye-sensitized solar cell photoanode active membrane and preparation method thereof |
| CN105529191A (en) * | 2016-01-13 | 2016-04-27 | 张志华 | High-conversion-efficiency solar cell based vehicle license plate recognition device of parking lot |
-
2016
- 2016-07-27 CN CN201610605986.4A patent/CN106206039A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005158380A (en) * | 2003-11-25 | 2005-06-16 | Sony Corp | Photoelectric conversion element, its manufacturing method, electronic apparatus and its manufacturing method |
| CN201274524Y (en) * | 2008-10-14 | 2009-07-15 | 天津三星电子有限公司 | Camera head supplying electricity by solar energy |
| CN202102522U (en) * | 2011-06-29 | 2012-01-04 | 杭州自力太阳能科技有限公司 | Solar energy-driven driving recorder |
| CN103824697A (en) * | 2014-03-11 | 2014-05-28 | 西安工业大学 | Dye-sensitized solar cell photoanode active membrane and preparation method thereof |
| CN105529191A (en) * | 2016-01-13 | 2016-04-27 | 张志华 | High-conversion-efficiency solar cell based vehicle license plate recognition device of parking lot |
Non-Patent Citations (2)
| Title |
|---|
| "碳纳米管负载金属镍催化剂的制备表征及性能研究": ""碳纳米管负载金属镍催化剂的制备表征及性能研究"", 《中国硕士学位论文全文数据库（电子期刊）工程科技I辑》 * |
| 邹小平: "《纳米材料与敏化太阳电池》", 31 December 2014 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100511718C (en) | Nanometer oxide porous membrane electrode and preparing method and application thereof | |
| CN101901693A (en) | Graphene composite dye-sensitized solar cell light anode and preparation method thereof | |
| CN107833752B (en) | It is a kind of for dye-sensitized solar cells to the material and preparation method thereof of electrode | |
| Dong et al. | A nanostructure-based counter electrode for dye-sensitized solar cells by assembly of silver nanoparticles | |
| CN106847513B (en) | The preparation method of sulfide nano-composite counter electrode based on porous C uS frameworks | |
| CN104465113A (en) | Nitrogen-doped graphene counter electrode preparing method and application of nitrogen-doped graphene counter electrode in dye-sensitized solar cell | |
| CN104332315A (en) | Preparation method of porous nanocrystalline Cu2S counter electrode of quantum-dot-sensitized solar cell | |
| CN106128772B (en) | A kind of preparation method of vulcanized lead quantum dot photovoltaic battery | |
| CN108172401A (en) | Dye-sensitized cell combined counter electrode and its preparation method and application | |
| CN105977035A (en) | Dye-sensitized solar cell of novel electrode structure | |
| CN100541822C (en) | DSSC of a kind of nano-crystal film and preparation method thereof | |
| CN107887169B (en) | A kind of dye-sensitized solar cell anode and preparation method thereof based on ferroelectric material | |
| Effendi et al. | Studies on graphene zinc-oxide nanocomposites photoanodes for high-efficient dye-sensitized solar cells | |
| CN106195885B (en) | A kind of Solar lamp | |
| CN106206037A (en) | A kind of exhaust system based on solaode | |
| CN115064388A (en) | Dye-sensitive solar cell based on composite structure photo-anode and preparation method and application thereof | |
| CN106068963A (en) | A kind of Minitype granary utilizing solar energy to have ventilation function | |
| CN106803460A (en) | A kind of CuS for quantum dot sensitized solar cell is to electrode and preparation method thereof | |
| CN106206039A (en) | A kind of solar powered photographic head | |
| CN103165290A (en) | Dye sensitized solar cell and preparation method thereof | |
| Hu et al. | Fabrication of quantum dot sensitized solar cells based on transparent TiO2 photoanodes | |
| CN106128775A (en) | A kind of monitoring system based on solar energy | |
| CN106287529A (en) | A kind of LED light device based on solar energy | |
| CN106206041A (en) | A kind of solar switch cabinet | |
| CN101630595B (en) | Preparation method of composite membrane counter electrode used for dye-sensitized solar cells |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |