CN106205850A - A kind of high reliability power cable - Google Patents

A kind of high reliability power cable Download PDF

Info

Publication number
CN106205850A
CN106205850A CN201610516539.1A CN201610516539A CN106205850A CN 106205850 A CN106205850 A CN 106205850A CN 201610516539 A CN201610516539 A CN 201610516539A CN 106205850 A CN106205850 A CN 106205850A
Authority
CN
China
Prior art keywords
parts
outside described
mean diameter
kilograms
power cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610516539.1A
Other languages
Chinese (zh)
Other versions
CN106205850B (en
Inventor
戴亮祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuyang Power Supply Co of State Grid Anhui Electric Power Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610516539.1A priority Critical patent/CN106205850B/en
Publication of CN106205850A publication Critical patent/CN106205850A/en
Application granted granted Critical
Publication of CN106205850B publication Critical patent/CN106205850B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/02Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
    • H01B9/022Power cables with screens or conductive layers, e.g. for avoiding large potential gradients composed of longitudinal lapped tape-conductors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/02Disposition of insulation
    • H01B7/0275Disposition of insulation comprising one or more extruded layers of insulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/282Preventing penetration of fluid, e.g. water or humidity, into conductor or cable
    • H01B7/2825Preventing penetration of fluid, e.g. water or humidity, into conductor or cable using a water impermeable sheath
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/14Extreme weather resilient electric power supply systems, e.g. strengthening power lines or underground power cables

Landscapes

  • Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The high reliability power cable of the present invention, including conductor, around the lapping layer wrapped in outside described conductor, it is extruded in the insulating barrier outside described lapping layer, around the screen layer wrapped in outside described insulating barrier, coat the waterproof layer outside described screen layer, be wrapped in the flame retardant coating outside described waterproof layer, be extruded in the oversheath outside described flame retardant coating.The high reliability power cable of the present invention, has high temperature resistant, fire protection flame retarding, waterproof oil resistant, ageing-resistant, the feature of length in service life.The most also there is good physical and mechanical properties tearing toughness and processing characteristics.Can apply to the places such as skyscraper, airport, harbour, underground railway, in order to ensure fire pump, Fire lift, local lighting, emergency evacuation instruction, security surveillance in case of fire, anti-, smoke evacuation system and the fire power such as power autonomous and visual plant run without interruption.It is applicable to immersible pump, colliery, underwater performance, the water treatment facilities such as scape light modulation in water.

Description

A kind of high reliability power cable
Technical field
The present invention relates to a kind of cable, particularly relate to a kind of high reliability power cable.
Background technology
Power cable is for transmitting and distribute the cable of electric energy.Be usually used in Urban Underground electrical network, the lead line of electric station, The in-line power of industrial and mining establishment and the submarine transmission line in mistake river, excessively sea.In power circuit, the proportion shared by cable the most gradually increases Add.Power cable be the master of power system in circuit in order to transmit and to distribute the cable product of high-power power, wherein wrap Include 1-500KV and any of the above electric pressure, the power cable of various insulation.Wires and cables industry is that China is only second to automobile The second largest industry of industry, product variety Service Efficiency and domestic market occupation rate are all more than 90%.Worldwide, China's electricity The line cable gross output value has exceeded the U.S., becomes the first big electric wire manufacturing country in the world.Along with China's wires and cables industry High speed development, creation of new enterprise quantity constantly rises, and industry overall technology level is largely increased.China's economic is continuously and healthily Increase, provide the huge market space for cable products, the allure that Chinese market is strong so that the world all focuses on sight In Chinese market, in the decades that reform and opening-up is short, the huge production capacity that China's cable manufacturing industry is formed allows the world scrape Mesh is seen mutually.Along with industry sizes such as China electric power industry, data communication industry, urban track traffic industry, car industry and shipbuildings Constantly expanding, also will increase the demand of electric wire rapidly, following electric wire industry also has huge development potentiality.Ternary second Third rubber is ethylene, propylene and the terpolymer of non-conjugated diene hydrocarbon, and 1963 start to commercially produce.Topmost spy Property is exactly its superior resistance to oxidation, ozone-resistant and erosion-resistant ability.Ethylene propylene diene rubber, in terms of electric wire, is mainly used in Civilian and the input line of commercial building, building wire, mine cable, used in nuclear power station electric wire, automobile ignition wire, control and signal Cable etc..) ethylene propylene diene rubber compares with XLPE with PVC electric wire, lear energy is poor.And owing to being prone to bloom, bonding Property and autohension are poor, affect following process.
Summary of the invention
It is an object of the invention to overcome the technological deficiency of existing cable, it is provided that one has high temperature resistant, fire protection flame retarding, waterproof Oil resistant, ageing-resistant, the feature of length in service life.The most also there is good physical and mechanical properties tearing toughness and processing characteristics High reliability power cable.
The high reliability power cable of the present invention, including conductor, around the lapping layer wrapped in outside described conductor, is extruded in described Insulating barrier outside lapping layer, around the screen layer wrapped in outside described insulating barrier, coats the waterproof layer outside described screen layer, is wrapped in institute State the flame retardant coating outside waterproof layer, be extruded in the oversheath outside described flame retardant coating.
As optimization, this high reliability power cable, including multiply tin plating soft copper stranded conductor, around wrapping in the plating of described multiply Teflon adhesive tape lapping layer outside stannum soft copper stranded conductor, is extruded in the rubber insulation outside described Teflon adhesive tape lapping layer, Around the aluminium-plastic tape screen layer wrapped in outside described rubber insulation, coat outside described aluminium-plastic tape screen layer is elastic insulated Resin waterproof layer, the PET being wrapped in outside described elastic insulated resin waterproof layer weaves webmaster flame retardant coating, is extruded in described PET and compiles Rubber outer protection set outside knitmesh pipe flame retardant coating.
As optimization, this high reliability power cable, described rubber insulation and rubber outer protection set are by following weight portion The component of number is made: ethylene propylene diene rubber 75~80 parts, POE polyolefin elastomer 32~35 parts, mean diameter 40nm nano aluminum Acid yttrium 2~2.5 parts, mean diameter 50nm nanometer lanthanum sesquioxide 3~3.5 parts, isopropanol 5~6 parts, hexadecyl trimethoxy Silane 1.5~2 parts, diethylene glycol monobutyl ether 4~5 parts, mean diameter 20um hydroxyapatite 8~10 parts, mean diameter 2um bis- Silicon oxide 28~32 parts, mean diameter 5um dolomite dust 20~22 parts, mean diameter 2um magnesium hydroxide 8~10 parts, secondary alcohol gather Oxygen vinyl Ether 2~2.5 parts, propylgallate 2~2.5 parts, cyclohexanhexanol phosphate ester 3~3.5 parts, potassium metabisulfite 1.5~2 Part, benzoin dimethylether 1.5~2 parts.
Rubber insulation described in this high reliability power cable and rubber outer protection set rubber used are made by following steps:
(1) by mean diameter 40nm nanometer yttrium aluminate 2.2 parts, mean diameter 50nm nanometer lanthanum sesquioxide 3.2 parts, isopropanol 5.5 parts, hexadecyl trimethoxy silane 1.6 parts, 4.5 parts of mixing magnetic stirrers of diethylene glycol monobutyl ether, stir 5 points Clock, then ultrasonic wave concussion 150 minutes under the conditions of 60~70 DEG C;
(2) by secondary alcohol polyoxyethylene ether 2.2 parts, join in the pure water of 50 times of weight, be subsequently adding mean diameter 20um hydroxyl 9 parts of base apatite, mean diameter 2um silicon dioxide 30 parts, mean diameter 5um dolomite dust 21 parts, mean diameter 2um hydroxide 9 parts of mix homogeneously of magnesium;Ultrasonic wave concussion 200 minutes under the conditions of 85 DEG C;Then it is dried 24 hours in 90 DEG C of baking ovens;
(3) ethylene propylene diene rubber 78 parts, POE polyolefin elastomer 33 parts are joined in banbury, at 100~110 DEG C mixing 3 ~4min;The mixture being subsequently adding in step (2) continues mixing 3~4min;Cool to 80~90 DEG C add in step (1) Mixture continues mixing 4~5min;It is eventually adding propylgallate 2.4 parts, cyclohexanhexanol phosphate ester 3.2 parts, pyrosulfurous acid 1.6 parts of potassium, benzoin dimethylether 1.8 parts mixing 3~4min;It is cooled to 50 DEG C~55 DEG C of dischargings;
(4) compound of step (3) is put into double screw extruder and carry out extruding pelletization, the spout of double screw extruder, the Two bringing-up sections, the 3rd bringing-up section, the temperature of the 4th bringing-up section to head be respectively set to 160 DEG C, 162 DEG C, 165 DEG C, 170 DEG C, 162℃。
The high reliability power cable of the present invention, have employed special structure and designs and novel elastomeric material: building ring Border temperature :-60 DEG C~200 DEG C;Against weather: UV;Fire-retardant: single vertical burning (IEC60332-1);Resistance to day optical tests: HD605/A1;Fire resistance, meets GB12666.6-A class.Flame 950 ± 40 DEG C 180 minutes, circuit did not punctured, and circuit leads to Electrical property keeps complete;At 650 ± 40 DEG C after 30 minutes, bearing 30 minutes Water spray or water logging, circuit energising property retention is complete Whole.Under long-term immersion and bigger hydraulic pressure, there is good electrical insulation properties.
The high reliability power cable of the present invention, has high temperature resistant, fire protection flame retarding, waterproof oil resistant, ageing-resistant, service life Long feature.The most also there is good physical and mechanical properties tearing toughness and processing characteristics.Can apply to skyscraper, The places such as airport, harbour, underground railway, in order to ensure fire pump, Fire lift, local lighting, emergent in case of fire Exit signs, security surveillance, anti-, smoke evacuation system and the fire power such as power autonomous and visual plant run without interruption.It is applicable to Immersible pump, colliery, underwater performance, the water treatment facilities such as scape light modulation in water.
Accompanying drawing explanation
Fig. 1 is the structural representation of high reliability power cable of the present invention.
Detailed description of the invention
The invention will be further described for example given below plan, but is not to be construed as scope Restriction, those skilled in the art, according to some nonessential improvement and adjustment to the present invention of present invention, still fall within this The protection domain of invention.
Embodiment 1: as it is shown in figure 1, include multiply tin plating soft copper stranded conductor 1, around wrapping in, the tin plating soft copper of multiply is stranded leads Teflon adhesive tape lapping layer 2 outside body 1, is extruded in the rubber insulation 3 outside Teflon adhesive tape lapping layer 2, exhausted around wrapping in rubber Aluminium-plastic tape screen layer 4 outside edge layer 3, the 3M 8882 elastic insulated waterproof resin layer outside coated with aluminum plastic composite strip screen layer 4 5, the PET being wrapped in outside 3M 8882 elastic insulated waterproof resin layer 5 weaves webmaster flame retardant coating 6, is extruded in described PET mesh grid Rubber outer protection set 7 outside pipe flame retardant coating 6.
Rubber insulation described in this high reliability power cable and the elastomeric material used by rubber outer protection set are by following step Suddenly make:
(1) by mean diameter 40nm nanometer yttrium aluminate 2.2 kilograms, mean diameter 50nm nanometer lanthanum sesquioxide 3.2 kilograms, isopropyl Alcohol 5.5 kilograms, Nanjing Quan Xi Chemical Co., Ltd. (QX-1613) hexadecyl trimethoxy silane 1.6 kilograms, diethylene glycol list 4.5 kilograms of mixing magnetic stirrers of butyl ether, stir 5 minutes, then ultrasonic wave concussion 150 minutes under the conditions of 60~70 DEG C;
(2) by secondary alcohol polyoxyethylene ether (S-50) 2.2 kilograms, join in the pure water of 50 times of weight, be subsequently adding average particle Footpath 20um hydroxyapatite 9 kilograms, mean diameter 2um silicon dioxide 30 kilograms, mean diameter 5um dolomite dust 21 kilograms, flat All 9 kilograms of mix homogeneously of particle diameter 2um magnesium hydroxide;Ultrasonic wave concussion 200 minutes under the conditions of 85 DEG C;Then in 90 DEG C of baking ovens It is dried 24 hours;
(3) by LG-DOW EPDM3720P ethylene propylene diene rubber 78 kilograms, Exxon Mobil 0201POE polyolefin elastomer 33 Kilogram join in banbury, at 100~110 DEG C mixing 3~4min;The mixture being subsequently adding in step (2) continues mixing 3 ~4min;Cool to 80~90 DEG C of mixture added in step (1) and continue mixing 4~5min;It is eventually adding gallic acid third Ester 2.4 kilograms, cyclohexanhexanol phosphate ester 3.2 kilograms, potassium metabisulfite 1.6 kilograms, benzoin dimethylether 1.8 kilograms mixing 3~ 4min;It is cooled to 50 DEG C~55 DEG C of dischargings;
(4) compound of step (3) is put into double screw extruder and carry out extruding pelletization, the spout of double screw extruder, the Two bringing-up sections, the 3rd bringing-up section, the temperature of the 4th bringing-up section to head be respectively set to 160 DEG C, 162 DEG C, 165 DEG C, 170 DEG C, 162℃.Elastomeric material of the present invention, uses unique formula, and between each component, synergism highlights;There is good mechanical performance With prominent tearing strength;There is the heat-proof aging oil resistance of excellence and beyond thought fire resistance, and without bloom, reach Other components of employing and the unapproachable performance of auxiliary combination are arrived.This elastomeric material hot strength: 16.77Mpa;Extension at break Rate 401%;Tearing strength 35.3KN/m;After 185 DEG C × 168 h hot air agings, hot strength rate of change: 5.2%, extension at break Rate rate of change-4.3%;Oil resistant test IRM903 125 DEG C × 168 h, hot strength rate of change: 7.2%, elongation at break change Rate-8.3%;Oxygen index (OI) 42.1, flame retardant rating FV-0, without bloom.
Embodiment 2: high reliability power cable structure is such as embodiment 1, and difference is, rubber insulation and rubber Elastomeric material used by oversheath is made by following steps:
(1) by mean diameter 40nm nanometer yttrium aluminate 2 kilograms, mean diameter 50nm nanometer lanthanum sesquioxide 3 kilograms, isopropanol 5 Kilogram, Nanjing Quan Xi Chemical Co., Ltd. (QX-1613) hexadecyl trimethoxy silane 1.5 kilograms, diethylene glycol monobutyl ether 4 Kilogram mixing magnetic stirrer, stirs 5 minutes, then ultrasonic wave concussion 150 minutes under the conditions of 60~70 DEG C;
(2) by secondary alcohol polyoxyethylene ether (S-50) 2 kilograms, join in the pure water of 50 times of weight and stir, be subsequently adding Mean diameter 20um hydroxyapatite 8 kilograms, mean diameter 2um silicon dioxide 28 kilograms, mean diameter 5um dolomite dust 20,000 Gram, 8 kilograms of mix homogeneously of mean diameter 2um magnesium hydroxide;Ultrasonic wave concussion 200 minutes under the conditions of 85 DEG C;Then at 90 DEG C Baking oven is dried 24 hours;
(3) by LG-DOW EPDM3720P ethylene propylene diene rubber 75 kilograms, Exxon Mobil 0201POE polyolefin elastomer 32 Kilogram join in banbury, at 100~110 DEG C mixing 3~4min;The mixture being subsequently adding in step (2) continues mixing 3 ~4min;Cool to 80~90 DEG C of mixture added in step (1) and continue mixing 4~5min;It is eventually adding gallic acid third Ester 2 kilograms, cyclohexanhexanol phosphate ester 3 kilograms, potassium metabisulfite 1.5 kilograms, benzoin dimethylether 1.5 kilograms mixing 3~4min; It is cooled to 50 DEG C~55 DEG C of dischargings;
(4) compound of step (3) is put into double screw extruder and carry out extruding pelletization, the spout of double screw extruder, the Two bringing-up sections, the 3rd bringing-up section, the temperature of the 4th bringing-up section to head be respectively set to 160 DEG C, 162 DEG C, 165 DEG C, 170 DEG C, 162℃.Elastomeric material of the present invention, uses unique formula, and between each component, synergism highlights;There is good mechanical performance With prominent tearing strength;There is the heat-proof aging oil resistance of excellence and beyond thought fire resistance, and without bloom, reach Other components of employing and the unapproachable performance of auxiliary combination are arrived.This elastomeric material hot strength: 16.75Mpa;Extension at break Rate 402%;Tearing strength 35.2KN/m;After 185 DEG C × 168 h hot air agings, hot strength rate of change: 5.2%, extension at break Rate rate of change-4.3%;Oil resistant test IRM903 125 DEG C × 168 h, hot strength rate of change: 7.2%, elongation at break change Rate-8.3%;Oxygen index (OI) 42.2, flame retardant rating FV-0, without bloom.
Embodiment 3: high reliability power cable structure is such as embodiment 1, and difference is, rubber insulation and rubber Elastomeric material used by oversheath is made by following steps:
(1) by mean diameter 40nm nanometer yttrium aluminate 2.5 kilograms, mean diameter 50nm nanometer lanthanum sesquioxide 3.5 kilograms, isopropyl Alcohol 6 kilograms, Nanjing Quan Xi Chemical Co., Ltd. (QX-1613) hexadecyl trimethoxy silane 2 kilograms, diethylene glycol monobutyl ether 5 kilograms of mixing magnetic stirrers, stir 5 minutes, then ultrasonic wave concussion 150 minutes under the conditions of 60~70 DEG C;
(2) by secondary alcohol polyoxyethylene ether (S-50) 2.5 kilograms, join in the pure water of 50 times of weight, be subsequently adding average particle Footpath 20um hydroxyapatite 10 kilograms, mean diameter 2um silicon dioxide 32 kilograms, mean diameter 5um dolomite dust 22 kilograms, flat All 10 kilograms of mix homogeneously of particle diameter 2um magnesium hydroxide;Ultrasonic wave concussion 200 minutes under the conditions of 85 DEG C;Then at 90 DEG C of baking ovens In be dried 24 hours;
(3) by LG-DOW EPDM3720P ethylene propylene diene rubber 80 kilograms, Exxon Mobil 0201POE polyolefin elastomer 35 Kilogram join in banbury, at 100~110 DEG C mixing 3~4min;The mixture being subsequently adding in step (2) continues mixing 3 ~4min;Cool to 80~90 DEG C of mixture added in step (1) and continue mixing 4~5min;It is eventually adding gallic acid third Ester 2.5 kilograms, cyclohexanhexanol phosphate ester 3.5 kilograms, potassium metabisulfite 2 kilograms, benzoin dimethylether 2 kilograms mixing 3~4min; It is cooled to 50 DEG C~55 DEG C of dischargings;
(4) compound of step (3) is put into double screw extruder and carry out extruding pelletization, the spout of double screw extruder, the Two bringing-up sections, the 3rd bringing-up section, the temperature of the 4th bringing-up section to head be respectively set to 160 DEG C, 162 DEG C, 165 DEG C, 170 DEG C, 162℃.Elastomeric material of the present invention, uses unique formula, and between each component, synergism highlights;There is good mechanical performance With prominent tearing strength;There is the heat-proof aging oil resistance of excellence and beyond thought fire resistance, and without bloom, reach Other components of employing and the unapproachable performance of auxiliary combination are arrived.This elastomeric material hot strength: 16.72Mpa;Extension at break Rate 401%;Tearing strength 35.4KN/m;After 185 DEG C × 168 h hot air agings, hot strength rate of change: 5.2%, extension at break Rate rate of change-4.3%;Oil resistant test IRM903 125 DEG C × 168 h, hot strength rate of change: 7.2%, elongation at break change Rate-8.3%;Oxygen index (OI) 42.2, flame retardant rating FV-0, without bloom.
Comparative example 1: power cable structure is such as embodiment 1, and difference is, rubber insulation and rubber outer protection set Elastomeric material used is made by following steps:
(1) by mean diameter 40nm nanometer yttrium aluminate 2.5 kilograms, mean diameter 50nm nanometer lanthanum sesquioxide 3.5 kilograms, isopropyl Alcohol 6 kilograms, Nanjing Quan Xi Chemical Co., Ltd. (QX-1613) hexadecyl trimethoxy silane 2 kilograms, diethylene glycol monobutyl ether 5 kilograms, secondary alcohol polyoxyethylene ether (S-50) 2.5 kilograms, mean diameter 20um hydroxyapatite 10 kilograms, mean diameter 2um bis- Silicon oxide 32 kilograms, mean diameter 5um dolomite dust 22 kilograms, 10 kilograms of mixing and stirring of mean diameter 2um magnesium hydroxide;
(2) by LG-DOW EPDM3720P ethylene propylene diene rubber 80 kilograms, Exxon Mobil 0201POE polyolefin elastomer 35 Kilogram join in banbury, at 100~110 DEG C mixing 3~4min;The mixture being subsequently adding in step (1) continues mixing 3 ~4min;It is eventually adding propylgallate 2.5 kilograms, cyclohexanhexanol phosphate ester 3.5 kilograms, potassium metabisulfite 2 kilograms, rests in peace Fragrant double methyl ether 2 kilograms mixing 3~4min;It is cooled to 50 DEG C~55 DEG C of dischargings;
(3) compound of step (2) is put into double screw extruder and carry out extruding pelletization, the spout of double screw extruder, the Two bringing-up sections, the 3rd bringing-up section, the temperature of the 4th bringing-up section to head be respectively set to 160 DEG C, 162 DEG C, 165 DEG C, 170 DEG C, 162℃.This elastomeric material performance is significantly lower than embodiment 1,2,3, this elastomeric material hot strength: 13.11Mpa;Extension at break Rate 381%;Tearing strength 26.3KN/m;After 185 DEG C × 168 h hot air agings, hot strength rate of change: 7.2%, extension at break Rate rate of change-6.3%;Oil resistant test IRM903 125 DEG C × 168 h, hot strength rate of change: 8.9%, elongation at break change Rate-10.3%;Oxygen index (OI) 37.1, flame retardant rating FV-0, slight bloom.
Comparative example 2: power cable structure is such as embodiment 1, and difference is, rubber insulation and rubber outer protection set Elastomeric material used is made by following steps:
(1) by mean diameter 50nm nanometer lanthanum sesquioxide 6 kilograms, isopropanol 6 kilograms, Nanjing Quan Xi Chemical Co., Ltd. (QX- 1613) hexadecyl trimethoxy silane 2 kilograms, 5 kilograms of mixing magnetic stirrers of diethylene glycol monobutyl ether, stir 5 minutes, Then ultrasonic wave concussion 150 minutes under the conditions of 60~70 DEG C;
(2) by secondary alcohol polyoxyethylene ether (S-50) 2.5 kilograms, join in the pure water of 50 times of weight, be subsequently adding average particle Footpath 2um silicon dioxide 42 kilograms, mean diameter 5um dolomite dust 32 kilograms;Ultrasonic wave concussion 200 minutes under the conditions of 85 DEG C; Then it is dried 24 hours in 90 DEG C of baking ovens;
(3) by LG-DOW EPDM3720P ethylene propylene diene rubber 80 kilograms, Exxon Mobil 0201POE polyolefin elastomer 35 Kilogram join in banbury, at 100~110 DEG C mixing 3~4min;The mixture being subsequently adding in step (2) continues mixing 3 ~4min;Cool to 80~90 DEG C of mixture added in step (1) and continue mixing 4~5min;It is cooled to 50 DEG C~55 DEG C go out Material;
(4) compound of step (3) is put into double screw extruder and carry out extruding pelletization, the spout of double screw extruder, the Two bringing-up sections, the 3rd bringing-up section, the temperature of the 4th bringing-up section to head be respectively set to 160 DEG C, 162 DEG C, 165 DEG C, 170 DEG C, 162℃.This elastomeric material performance is significantly lower than embodiment 1,2,3, this elastomeric material hot strength: 14.17Mpa;Extension at break Rate 381%;Tearing strength 27.4KN/m;After 185 DEG C × 168 h hot air agings, hot strength rate of change: 5.9%, extension at break Rate rate of change-5.2%;Oil resistant test IRM903 125 DEG C × 168 h, hot strength rate of change: 8.6%, elongation at break change Rate-9.4%;Oxygen index (OI) 38.1, flame retardant rating FV-0, slight bloom.

Claims (4)

1. a high reliability power cable, it is characterised in that: include conductor, around the lapping layer wrapped in outside described conductor, extrude Insulating barrier outside described lapping layer, around the screen layer wrapped in outside described insulating barrier, coats the waterproof layer outside described screen layer, bag It is rolled in the flame retardant coating outside described waterproof layer, is extruded in the oversheath outside described flame retardant coating.
High reliability power cable the most according to claim 1, it is characterised in that: include that the tin plating soft copper of multiply is stranded and lead Body, around the Teflon adhesive tape lapping layer wrapped in outside described multiply tin plating soft copper stranded conductor, be extruded in described Teflon adhesive tape around Rubber insulation outside covering, around the aluminium-plastic tape screen layer wrapped in outside described rubber insulation, coats described plastic-aluminum combined Elastic insulated resin waterproof layer outside with screen layer, the PET being wrapped in outside described elastic insulated resin waterproof layer braiding webmaster is resistance to Fire bed, is extruded in the rubber outer protection set outside described PET braiding webmaster flame retardant coating.
High reliability power cable the most according to claim 1, it is characterised in that described rubber insulation and rubber outer protection Overlap the component by following parts by weight to make: ethylene propylene diene rubber 78 parts, POE polyolefin elastomer 33 parts, mean diameter 40nm nanometer yttrium aluminate 2.2 parts, mean diameter 50nm nanometer lanthanum sesquioxide 3.2 parts, isopropanol 5.5 parts, cetyl front three TMOS 1.6 parts, diethylene glycol monobutyl ether 4.5 parts, mean diameter 20um hydroxyapatite 9 parts, mean diameter 2um titanium dioxide Silicon 30 parts, mean diameter 5um dolomite dust 21 parts, 9 parts of mean diameter 2um magnesium hydroxide, secondary alcohol polyoxyethylene ether 2.2 parts, do not have Propyl galate 2.4 parts, cyclohexanhexanol phosphate ester 3.2 parts, potassium metabisulfite 1.6 parts, benzoin dimethylether 1.8 parts.
High reliability power cable the most according to claim 3, it is characterised in that described rubber insulation and rubber outer protection Set rubber used is made by following steps:
(1) by mean diameter 40nm nanometer yttrium aluminate 2.2 parts, mean diameter 50nm nanometer lanthanum sesquioxide 3.2 parts, isopropanol 5.5 parts, hexadecyl trimethoxy silane 1.6 parts, 4.5 parts of mixing magnetic stirrers of diethylene glycol monobutyl ether, stir 5 points Clock, then ultrasonic wave concussion 150 minutes under the conditions of 60~70 DEG C;
(2) by secondary alcohol polyoxyethylene ether 2.2 parts, join in the pure water of 50 times of weight, be subsequently adding mean diameter 20um hydroxyl 9 parts of base apatite, mean diameter 2um silicon dioxide 30 parts, mean diameter 5um dolomite dust 21 parts, mean diameter 2um hydroxide 9 parts of mix homogeneously of magnesium;Ultrasonic wave concussion 200 minutes under the conditions of 85 DEG C;Then it is dried 24 hours in 90 DEG C of baking ovens;
(3) ethylene propylene diene rubber 78 parts, POE polyolefin elastomer 33 parts are joined in banbury, at 100~110 DEG C mixing 3 ~4min;The mixture being subsequently adding in step (2) continues mixing 3~4min;Cool to 80~90 DEG C add in step (1) Mixture continues mixing 4~5min;It is eventually adding propylgallate 2.4 parts, cyclohexanhexanol phosphate ester 3.2 parts, pyrosulfurous acid 1.6 parts of potassium, benzoin dimethylether 1.8 parts mixing 3~4min;It is cooled to 50 DEG C~55 DEG C of dischargings;
(4) compound of step (3) is put into double screw extruder and carry out extruding pelletization, the spout of double screw extruder, the Two bringing-up sections, the 3rd bringing-up section, the temperature of the 4th bringing-up section to head be respectively set to 160 DEG C, 162 DEG C, 165 DEG C, 170 DEG C, 162℃。
CN201610516539.1A 2016-07-04 2016-07-04 A kind of high reliability power cable Active CN106205850B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610516539.1A CN106205850B (en) 2016-07-04 2016-07-04 A kind of high reliability power cable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610516539.1A CN106205850B (en) 2016-07-04 2016-07-04 A kind of high reliability power cable

Publications (2)

Publication Number Publication Date
CN106205850A true CN106205850A (en) 2016-12-07
CN106205850B CN106205850B (en) 2017-09-01

Family

ID=57465150

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610516539.1A Active CN106205850B (en) 2016-07-04 2016-07-04 A kind of high reliability power cable

Country Status (1)

Country Link
CN (1) CN106205850B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107342137A (en) * 2017-07-20 2017-11-10 安徽华宝电缆有限责任公司 Photovoltaic thermal conductivity flame retardant cable
CN111138746A (en) * 2018-11-05 2020-05-12 日立金属株式会社 Flame-retardant insulated wire and flame-retardant cable

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202258525U (en) * 2011-09-16 2012-05-30 安徽明星电缆有限公司 Fireproof and waterproof flexible direct-current power transmission cable
CN103739925A (en) * 2013-12-24 2014-04-23 上海至正道化高分子材料有限公司 Environment-friendly low-temperature anti-twisting and low-smoke halogen-free flame retardant cable material and preparation method thereof
KR20140095155A (en) * 2013-01-23 2014-08-01 엘에스전선 주식회사 fire resistant cable

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202258525U (en) * 2011-09-16 2012-05-30 安徽明星电缆有限公司 Fireproof and waterproof flexible direct-current power transmission cable
KR20140095155A (en) * 2013-01-23 2014-08-01 엘에스전선 주식회사 fire resistant cable
CN103739925A (en) * 2013-12-24 2014-04-23 上海至正道化高分子材料有限公司 Environment-friendly low-temperature anti-twisting and low-smoke halogen-free flame retardant cable material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107342137A (en) * 2017-07-20 2017-11-10 安徽华宝电缆有限责任公司 Photovoltaic thermal conductivity flame retardant cable
CN107342137B (en) * 2017-07-20 2018-05-25 安徽华宝电缆有限责任公司 Photovoltaic thermal conductivity flame retardant cable
CN111138746A (en) * 2018-11-05 2020-05-12 日立金属株式会社 Flame-retardant insulated wire and flame-retardant cable
CN111138746B (en) * 2018-11-05 2023-08-29 株式会社博迈立铖 Flame-retardant insulated wire and flame-retardant cable

Also Published As

Publication number Publication date
CN106205850B (en) 2017-09-01

Similar Documents

Publication Publication Date Title
CN202996349U (en) Novel fireproof cable
CN106205850A (en) A kind of high reliability power cable
CN204516455U (en) A kind of waterproof anti-corrosion power cable
CN201812509U (en) Signal cable for solar photovoltaic power generating system
CN102184761B (en) Mouse-proof, termite-proof, high-antiflaming, fireproof and environment-friendly concentric conductor cable
CN204480781U (en) A kind of tight type LSOH anti-flaming composite cable
CN203397721U (en) High current-carrying warp-resistance weather-proof type middling pressure flexible cable for aerogenerator
CN215496059U (en) Novel environment-friendly high-flame-retardant flexible fireproof cable
CN203787197U (en) Antiflaming polyolefin sheath power cable
CN208400545U (en) A kind of novel weathering resistant flexible mineral insulation fireproof cable
CN215577765U (en) Novel environment-friendly high-flame-retardant carbon fiber woven flexible fireproof cable
CN204102621U (en) A kind of lv power cable
CN202189613U (en) LSOH (low smoke zero halogen) irradiation crosslinking high inflaming retarding fire-resisting power cable
CN205069215U (en) Vertical watertight control cable
CN219085707U (en) 6-35kV rated voltage crosslinked polyethylene insulation flame-retardant environment-friendly power cable
CN202662369U (en) Compound insulated high-temperature resistant power cable
CN104795146A (en) Solar photovoltaic cable
CN217086236U (en) Special silicon rubber insulation cable
CN203982857U (en) A kind of specified alternating voltage 750V water proof fire retardant cable
CN220651682U (en) Multilayer bonding insulated cable
CN103426557A (en) Two-core low-smoke low-halogen flame-retardant power cable
CN201868128U (en) Solar photovoltaic flame resistant cable
CN211906996U (en) Oxygen-isolating layer copper core aluminum sheath fireproof cable
CN215577762U (en) Flame-retardant B1-grade flexible control cable
CN219202826U (en) High-strength flame-retardant control cable for subway

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Cui Baoyan

Inventor after: Zhu Xinju

Inventor after: Wang Zhenyun

Inventor after: Cao Qinghua

Inventor after: Hu Xiaoxia

Inventor after: An Ling

Inventor after: Hu Qiang

Inventor after: Liu Xiaojing

Inventor after: Wang Yonghui

Inventor after: Wang Dongdong

Inventor after: Liu Jigang

Inventor before: Dai Liangxiang

CB03 Change of inventor or designer information
TA01 Transfer of patent application right

Effective date of registration: 20170804

Address after: 236046 Anhui province Fuyang City Yingzhou District Ying Road No. 30

Applicant after: FUYANG POWER SUPPLY COMPANY, STATE GRID ANHUI ELECTRIC POWER COMPANY

Address before: 516000 No. 40 Jiangbei District, Guangdong, Huizhou, Huicheng

Applicant before: Dai Liangxiang

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant