A kind of thinning functional polarizing sheet and its preparation method and application
Technical field
The application relates to a kind of thinning functional polarizing sheet and its preparation method and application in liquid crystal display and AMOLED
Field of display.
Background technology
Along with the development of science and technology, all kinds of mobile terminals such as mobile phone, panel computer etc., applied more and more widely.Respectively
What class mobile terminal generally arranged that touching display screen is easy to user carries out touch control operation.Touching display screen is usually multilamellar knot
Structure, when using touching display screen to carry out touch control operation, external light source is irradiated in the multiple structure of touching display screen and is formed
Reflection light can have a strong impact on the use of touching display screen.As, there is the outdoor environment of high light, starting hand-set, panel computer etc.
During the touching display screen of mobile terminal, owing to there will be stronger touching display screen surface reflection under outdoor intense light conditions, from
And cause user cannot clearly watch touching display screen.
Additionally, LCD (LCDs) or AMOLED (active organic light-emitting display screen) is representing flexible characteristic at present
Time, often often can be able to run in this test process: the optical performance of (1) polaroid reduction own, (2) through bending, folding test
Destroy anti scuffing membrane structure.At present Polarizer (polaroid) processing technology be all with PVA (polyvinyl alcohol) with iodine staining after
Do uniaxial extension and form polarisation, do sandwich structure laminating protection PVA (polyvinyl alcohol) resin then at its most each superposition base material
In central authorities, lower base material opposite side the most sequentially sticks PSA (pressure sensitive adhesive)/circle offset compensation film/PSA (pressure sensitive adhesive), if fitting anti-finger again
Stricture of vagina/anti-glare/antireflection/scratch resistant multifunctional membrane, the thicker needs being all unable to reach flexible display screen of this polaroid thickness.Example
As prior art CN201410322853 discloses a kind of flexible OLED polaroid, including: it is sequentially formed on flexible OLED
Lower adhering agent layer, alternating layer, release film layer and upper adhering agent layer, the scattering layer being periodically alternatively formed by adhesion and resistance
Interlayer is strengthened polaroid and is stopped steam and the ability of oxygen, and preferably plays effect anti-dazzle under sunlight;Additionally, prior art
CN201110234131 also discloses a kind of thin type integrated 3D solid polaroid, wherein prevents micro-bit phase difference film (FPR)
Dazzle process, antireflection process or add HC coating, and the method that wherein anti-dazzle processes is: carry out blasting treatment formation at face
Matsurface, or it is coated with one layer of resinae binding agent at face, it is dispersed with inorganic or organic transparent microgranule in the adhesive.
Antireflection processes mainly by interference of light principle, can be to be laminated, at film surface, the hard conating being made up of metal-oxide etc.
With low-index layer or the antireflection film that defines the low-index layer such as inorganic compound or organic fluoride with monolayer.HC is coated with
The method of layer is: at face coating organosilicon etc., make material surface hardness and anti-wear performance strengthen.As can be seen here, prior art
In be all by substep, the Multifunctional protective cuticula layer of layered shaping polaroid, thereby through polaroid thickness after aforesaid operations all
More than 100 μm, this functional polarizing sheet is used for bending folding, folding product cannot meet bending radius and operate at below 5mm.
The need that cannot meet flexible display screen that are blocked up in order to solve functional polarizing sheet thickness of the prior art, that cause
Ask, present invention aim at providing a kind of thinning functional polarizing sheet and preparation method and application, with coating method at base material
Upper making line polarisation reaches thinning with the mode of circle offset compensation film, and recycling volume to volume is coated with anti-finger using polaroid as base material
Stricture of vagina, anti-glare, antireflection and anti scuffing membrane material, need not use traditional superposition polaroid film and multifunctional membrane, by existing skill
In art, multilayer functional membrane is integrated into a piece of, it is achieved that the integration of multifunctional membrane layer so that it is gross thickness drops to below 100 μm,
Achieve this functional polarizing sheet go for bending, fold product can meet bending radius operate at below 5mm.
Summary of the invention
The present invention solve a technical problem be provide thinning functional polarizing sheet, including be sequentially formed in substrate it
The round offset compensation layer of upper laminating, line polarizing layer and coat the Multifunctional protective cuticula layer on line polarizing layer, it is characterised in that
Anti-fingerprint, anti-glare, antireflection and the anti scuffing composite that described Multifunctional protective cuticula layer is integrated.
Described multifunctional membrane layer gross thickness is less than 100 μm, and further preferred thickness is 20-100 μm, and particularly preferred thickness is
40-100 μm, most preferred thickness is 40-80 μm.
Described rotatory polarization layer of compensation is the 1/2 λ wavelength liquid crystal film and 1/4 λ wavelength liquid crystal film fitted each other.
1/2 described λ and 1/4 λ wavelength liquid crystal film are coated with on PAF (light alignment film), under 1/4 λ wavelength liquid crystal film
The substrate of the PAF (light alignment film) of side is COP cyclic olefin polymer or UTG strengthening ultra-thin glass.
Described line polarizing layer includes TAC (Triafol T) substrate and coats PVA (the poly-second on substrate successively
Enol) resin, thin glue and pressure-sensing glue.
Another technical problem that the present invention solves is to provide the preparation method of thinning functional polarizing sheet, specifically includes
Following steps:
Step S1: PVA (polyvinyl alcohol) resin, thin glue and pressure-sensing glue are coated TAC (Triafol T) base successively
On material, prepare line polarizing layer;
Step S2: PAF (light alignment film) and 1/4 λ wavelength liquid crystal are coated COP cyclic olefin polymer or UTG successively
On strengthening ultra thin glass substrates, prepare 1/4 λ wavelength liquid crystal film;
Step S3: PAF (light alignment film) and 1/2 λ wavelength liquid crystal are coated PET (polyethylene terephthalate successively
Ester) on base material, prepare 1/2 λ wavelength liquid crystal film;
Step S4: remove lower section mould release membrance and the laminating of 1/2 λ wavelength liquid crystal of polarizing layer PSA (pressure sensitive adhesive), then remove PET
Base material, is fitting 1/4 λ wavelength liquid crystal coatings and 1/2 λ wavelength liquid crystal coatings with one layer of PSA (pressure sensitive adhesive), it is thus achieved that polaroid;
Step S5: be coated with the anti-fingerprint of integration, anti-glare on TAC (Triafol T) base material of polaroid, resist
Reflection and anti scuffing composite, obtain thinning functional polarizing sheet.
Described step S1 is particularly as follows: PVA (polyvinyl alcohol) resin is become with tackifier heating for dissolving by (1) with deionized water
Solution;(2) on TAC (Triafol T) base material, it is coated with one layer of PVA (polyvinyl alcohol), is dried cooling;Another priority thereon
It is coated with one layer of thin glue and pressure-sensing glue adhere to PVA (polyvinyl alcohol) and protect PVA (polyvinyl alcohol), it is thus achieved that line polarizing layer.
Described step S2 is particularly as follows: (1) strengthens the painting of ultra thin glass substrates surface at COP cyclic olefin polymer or UTG
It is dried after one layer of PAF of cloth (light alignment film), then uses grating light shield irradiation to complete light orientation, make 1/4 λ wavelength liquid crystal depend on
Arrangement mode on irradiation grid arranges;(2) on PAF, coat 1/4 λ wavelength liquid crystal with coating process, be dried after removing solvent,
Under nitrogen environment, do the solidification of UV (ultraviolet light) irradiation, defined according to PAF (light alignment film) by described solidification relief liquid crystal
Direction arrangement.
Described step S3 is particularly as follows: (1) is coated with one layer of PAF at PET (polyethylene terephthalate) substrate surface
It is dried after (light alignment film), is then used by grating light shield irradiation and completes light orientation, make 1/2 λ wavelength liquid crystal according on grating
Arrangement mode arrange;(2) on PAF, coat 1/2 λ wavelength liquid crystal with coating process, be dried after removing solvent, in nitrogen ring
Do the solidification of UV (ultraviolet light) irradiation under border, arranged according to direction defined in PAF (light alignment film) by described solidification relief liquid crystal
Row.
Described step S4 is particularly as follows: line polarizing layer and 1/2 λ wavelength liquid crystal coatings are fitted, by PSA (pressure sensitive adhesive) by (1)
Mould release membrance remove after with 1/2 λ wavelength liquid crystal film laminating, remove PET base material, then by 1/4 λ wavelength liquid crystal coatings and polarizing layer and
1/2 λ wavelength liquid crystal coatings is fitted by one layer of PSA (pressure sensitive adhesive), first PSA (pressure sensitive adhesive) glue material is affixed on 1/2 λ before laminating
After wavelength liquid crystal coatings opposite side, then fit with 1/4 λ wavelength liquid crystal coatings, it is thus achieved that polaroid.
Another technical problem that the present invention solves is to provide a kind of liquid crystal display, it is characterised in that use as above institute
The thinning functional polarizing sheet stated.
Another technical problem that the present invention solves is to provide a kind of displayer, it is characterised in that use as above
Described thinning functional polarizing sheet.
Beneficial effect
Multilayer functional membrane in prior art is integrated into a piece of by the present invention, it is achieved that the integration of multifunctional membrane layer, then
Utilize volume to volume to coat on base material using polaroid as base material, make the gross thickness of multifunctional membrane layer drop to below 100 μm,
Maintain its thickness under identical optical character thinner, thus realize being used for bending folding, folding product, bending radius operation can be met
At below 5mm.
The present invention makes line polarisation on base material with coating method further in the manufacturing process of polaroid and partially mends with circle
Repay the mode of film, make polaroid reach the effect of thinning further, can preferably be applied to liquid crystal display and AMOLED shows
Device, it is possible to better meet the demand of flexible display material.
Accompanying drawing explanation
Fig. 1: line polarizing layer;
Fig. 2: 1/4 λ wavelength liquid crystal coatings preparation process;
Fig. 3: 1/2 λ wavelength liquid crystal coatings preparation process;
Fig. 4: line polarizing layer and circle layer of compensation laminating process;
Fig. 5: polaroid overall structure.
Detailed description of the invention
Embodiment 1
Step S1:(1) PVA (polyvinyl alcohol) resin is become solution with deionized water with tackifier heating for dissolving;(2) exist
It is coated with one layer of PVA (polyvinyl alcohol) on TAC (Triafol T) base material, is dried cooling;Another successively coating one layer thereon is thin
Glue and pressure-sensing glue are adhered to PVA (polyvinyl alcohol) and protect PVA (polyvinyl alcohol), it is thus achieved that line polarizing layer;
Step S2:(1) strengthen one layer of PAF (light of ultra thin glass substrates surface coating at COP cyclic olefin polymer or UTG
Alignment film) after be dried, then use grating light shield irradiation complete light orientation, make 1/4 λ wavelength liquid crystal according to the row on grating
Row mode arranges;(3) on PAF, coat 1/4 λ wavelength liquid crystal with coating process, be dried after removing solvent, under nitrogen environment
Do the solidification of UV (ultraviolet light) irradiation, arranged according to direction defined in PAF (light alignment film) by described solidification relief liquid crystal.
Step S3:(1) after PET (polyethylene terephthalate) substrate surface one layer of PAF (light alignment film) of coating
It is dried, is then used by grating light shield irradiation and completes light orientation, make 1/2 λ wavelength liquid crystal do according to the arrangement mode on grating
Arrangement;(2) on PAF, coat 1/2 λ wavelength liquid crystal with coating process, be dried after removing solvent, under nitrogen environment, be UV (purple
Outer light) irradiation solidification, arranged according to direction defined in PAF (light alignment film) by described solidification relief liquid crystal.
Step S4:(1) line polarizing layer and 1/2 λ wavelength liquid crystal coatings are fitted, the mould release membrance of PSA (pressure sensitive adhesive) is removed
Afterwards with 1/2 λ wavelength liquid crystal film laminating, remove PET base material, then by 1/4 λ wavelength liquid crystal coatings and polarizing layer and 1/2 λ wavelength liquid crystal
Film layer is fitted by one layer of PSA (pressure sensitive adhesive), and PSA (pressure sensitive adhesive) glue material is first affixed on before laminating 1/2 λ wavelength liquid crystal coatings
After opposite side, then fit with 1/4 λ wavelength liquid crystal coatings, it is thus achieved that polaroid.
Step S5: be coated with integrated anti-fingerprint and anti-glare on TAC (Triafol T) base material of polaroid and resist
Reflection and anti scuffing composite, obtain thinning functional polarizing sheet.
The thickness of the Multifunctional protective cuticula layer of gained polaroid is 40-80 μm, and the rotatory polarization using coating process to make is mended
Repay layer can its thickness of thinning to below 10 μm, line polarizing layer PVA (polyvinyl alcohol) thickness can be thinned to below 20 μm, replaces existing
To do uniaxial extension making PVA (polyvinyl alcohol) formation polarisation after iodine staining, under maintaining identical optical character, its thickness is more
Thin, thus realize being used for bending folding, folding product, it is seen that light transmittance is 43 ± 1%, and reflectance is 5% ± 1%.Additionally, can
Directly use AMOLED encapsulation base material, if COP (cyclic olefin polymer) or UTG (strengthening ultra-thin glass) is as above-mentioned rotatory polarization
Layer of compensation base material, can realize few with one layer of PSA (pressure sensitive adhesive), directly be regarded by TAC on polaroid (Triafol T) meanwhile
Anti-fingerprint/anti-glare/antireflection/anti-scratch base material, can lack one layer of base material being more than more than 50 μm, such as: PET (poly terephthalic acid
Glycol ester)/transparent Polyimide (polyimides), finally realize polaroid and reach the optimum efficiency of thinning.