CN106192430A - A kind of protection composite of spray mo(u)lding and preparation method thereof - Google Patents
A kind of protection composite of spray mo(u)lding and preparation method thereof Download PDFInfo
- Publication number
- CN106192430A CN106192430A CN201610572542.5A CN201610572542A CN106192430A CN 106192430 A CN106192430 A CN 106192430A CN 201610572542 A CN201610572542 A CN 201610572542A CN 106192430 A CN106192430 A CN 106192430A
- Authority
- CN
- China
- Prior art keywords
- fabric
- preparation
- binding material
- protection composite
- rigid particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 48
- 239000007921 spray Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000004744 fabric Substances 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 53
- 239000002245 particle Substances 0.000 claims abstract description 50
- 238000007731 hot pressing Methods 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 21
- 238000005507 spraying Methods 0.000 claims abstract description 19
- 238000005488 sandblasting Methods 0.000 claims abstract description 16
- 229920006253 high performance fiber Polymers 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 239000003960 organic solvent Substances 0.000 claims abstract description 11
- 238000005245 sintering Methods 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 26
- 239000011248 coating agent Substances 0.000 claims description 24
- 239000012528 membrane Substances 0.000 claims description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 19
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 12
- 238000005520 cutting process Methods 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 5
- 229920006231 aramid fiber Polymers 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920002748 Basalt fiber Polymers 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- 239000002313 adhesive film Substances 0.000 claims description 2
- 239000006121 base glass Substances 0.000 claims description 2
- 239000010431 corundum Substances 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 2
- 239000010432 diamond Substances 0.000 claims description 2
- 229910003460 diamond Inorganic materials 0.000 claims description 2
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 claims description 2
- 229920001684 low density polyethylene Polymers 0.000 claims description 2
- 239000004702 low-density polyethylene Substances 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- -1 polypropylene Polymers 0.000 claims description 2
- 230000001012 protector Effects 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 230000001681 protective effect Effects 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 description 10
- 239000010410 layer Substances 0.000 description 10
- 239000002759 woven fabric Substances 0.000 description 7
- 239000004831 Hot glue Substances 0.000 description 6
- 239000008187 granular material Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000006378 damage Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- 208000014674 injury Diseases 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 239000011358 absorbing material Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003139 buffering effect Effects 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 208000031968 Cadaver Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000004835 fabric adhesive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002365 multiple layer Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000004223 radioprotective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000009498 subcoating Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0022—Glass fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
- D06N2201/0272—Aromatic polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/08—Inorganic fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/08—Inorganic fibres
- D06N2201/082—Glass fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/10—Particulate form, e.g. powder, granule
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
- D06N2211/103—Gloves
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses the preparation method of the protection composite of a kind of spray mo(u)lding, comprise the steps: that (1) uses organic solvent that high-performance fiber fabric is carried out surface process, dry；(2) on the high-performance fiber fabric dried, cover one layer of binding material and be fixed on the positioning；(3) use sandblasting machine at the surface spraying rigid particles of the binding material fixed, prepare compound fabric grey cloth；(4) the continuous flat board pressure sintering of above-mentioned compound fabric grey cloth employing is carried out hot-pressing processing, prepare protection composite finished product.The protection composite using the one even application technology of the present invention to prepare, has higher bulletproof function and the anti-stab performance of excellence, compared with existing material, it is possible to be effectively improved protective capacities, alleviating equipment weight, reduces thickness, reduces cost.
Description
Technical field
The present invention relates to shellproof and stab-resistant material field, particularly relate to protection composite and the system thereof of a kind of spray mo(u)lding
Preparation Method.
Background technology
Along with socioeconomic development, social safety problem becomes increasingly to highlight, and country and individual have become increasingly aware of
The importance of security protection.Not only can run into the injury of bullet at police aspect, police and other peace preservation corps's body, but also can be subject to
The threat of the sharp instruments such as the most increasing cutter, dagger.The most common bullet-proof vest cannot fully meet vast public security to be done
The alert demand to final safety, also cannot obtain useful anti-stab effect.And at civilian aspect, the living standard of people is continuous
Improving, the kind of personal protective equipment also gets more and more, and bulletproof stab-resistant clothes can play protection personal safety and property safety
Effect, so the market demand of bulletproof stab-resistant clothes is huge.
It is primarily present hard stab-resistance body armor, flexible puncture-proof clothes and these several classes of liquid stab-resistance body armor in the market.Such as patent CN
99802570.4 disclose a kind of bulletproof anti-puncturing material, can meet again anti-cutter and stab PSDB standard by anti-bullet, with metal be
Basic component, can be made up of the molectron of the becket of mutually tight lock or ring with metallic plate；Comprise impact energy absorbing material, prevent
Stab material auxiliary layer and anti-shooting assembly.Becket or ring by mutually locking make cutter or bullet be passivated with metallic plate,
Then formed energy-absorbing material and stab-resistant material by high-intensity fiber, be used for absorbing dump energy.This protective material becket and metal
It is inevitably present anti-stab shellproof vulnerable area between the molectron of plate, and likely clashes into mistake because of bullet with becket, plate
" spring " is surely occurred to cause secondary damage.CN 200710122028.2 discloses one STF and is immersed in height
On strength fabric, single or multiple lift superposition and the soft ballistic stab-resistant chip made, although STF light weight is soft,
Excellent performance, but relatively costly, and during depositing, liquid easily flows, and anti-stab performance is had a greatly reduced quality.Additionally, patent
CN 103358659 A discloses a kind of shear thickening liquid/aramid fiber composite material preparation method, and it " is made by many group roller bearing extruding
Shear thickening liquid is the most compound with aramid fiber, then sprays dimethicone at composite material surface, and the intelligence of preparation resists
Impact material has that normality is soft, impact hardening characteristic, moisture resistance properties is excellent, the feature of strong shock resistance, but this composite wood
It is bad to there is heat resistance in material, and stands for a long time, and shear thickening liquid there will be layering, and dimethicone serves profit
Sliding effect, it is easier to bullet penetrates the problems such as composite.Therefore, for the defect existing for current protective material, how to grind
It is comfortable and easy to wear to send out a kind of, flexible, barrier propterty is excellent and formation highly effective, protection composite that production cost is low, becomes ability
The technical barrier that field technique personnel are the most urgently to be resolved hurrily.
Summary of the invention
The bulletproof function that the present invention is directed to the soft protective material in the presence of technology is low, the most do not possess effective anti-stab function
Technical problem, it is provided that protection composite of a kind of spray mo(u)lding and preparation method thereof.
The invention provides the preparation method of the protection composite of a kind of spray mo(u)lding, it employed technical scheme comprise that profit
By Novel integrated even application technology, rigid particles is coated uniformly on fabric surface, utilizes hot melt adhesive film or other bonding
Agent thermocompression forming realizes；Use efficient spraying technology by the organic knot of high intensity of the high rigidity of rigid particles Yu fabric
Altogether, rigid particles material can denude, be passivated sharp instrument tip, weakens shearing force and the penetration power of sharp instrument, and can subtract
Speed bullet, apparatus with shock absorbing, reduce the degree of injury after being hit, fabric then can play and support and the work of buffering
With, form the protection effect that lancination, bullet are had " soft or hard combination " feature；Utilize new and effective spraying technology, can make
Rigid particles is evenly distributed on fabric, and thickness is controlled, improves production efficiency, and the monolayer composite composite generated has
Have the feature of anti-cutting, rub resistance, or MULTILAYER COMPOSITE protective material carry out lamination, can reach police bulletproof stab-resistant clothes one-level and
Two grades, anti-stab GA68 ~ 2008 " police stab-resistance body armor " the standard 24J energy that can reach does not penetrates through, and shellproof can stop 7.62mm hands
Bullet is attacked.
Present invention also offers the protection composite of a kind of spray mo(u)lding using said method to prepare, this composite
Having higher bulletproof function, have excellent anti-stab performance simultaneously concurrently, the spraying of this rigid particles forms the protection of protective coating and is combined
Material can be used for preparing bulletproof stab-resistant clothes, has anti-anti-cutting function of cutting when being used alone, and during multilayer build-up use, anti-stab effect is more
Good, and there is the bulletproof function of excellence simultaneously；Compared with existing material, it is possible in the case of equivalent weight, it is effectively improved anti-
Protect ability；Under equal protection level, effectively alleviate equipment weight, reduce thickness, reduce cost.
For achieving the above object, the present invention is by the following technical solutions:
The first aspect of the invention is to provide the preparation method of the protection composite of a kind of spray mo(u)lding, including walking as follows
Rapid:
(1) use organic solvent that high-performance fiber fabric carries out surface process, remove the slurry of fabric face, waxiness and miscellaneous
Matter, dry for standby；
(2) on the high-performance fiber fabric dried, cover one layer of binding material and be fixed on the positioning so that high-performance fiber
Tight between fabric and binding material；
(3) use sandblasting machine at the surface spraying rigid particles of the binding material fixed, make rigid particles be evenly distributed on viscous
Knot material surface, prepares compound fabric grey cloth；
(4) the continuous flat board pressure sintering of above-mentioned compound fabric grey cloth employing is carried out hot-pressing processing, make binding material fine with high-performance
Dimensional fabric is the most compound, prepares protection composite finished product.
Further, described high-performance fiber fabric selected from base glass fiber, basalt fibre, aramid fiber, poly-third
One or more fibers in alkene fiber, high-strength nylon fiber, polyster fibre, cotton fiber, the thread fabric of yarn.
Further, described process of surface treatment is: high-performance fiber fabric is soaked in organic solvent 10min ~
60min, temperature is 30 ~ 60 DEG C；Preferably, described immersion 20min ~ 30min, temperature is 45 ~ 50 DEG C, and described organic solvent is selected from
The mixture of one or more in dehydrated alcohol, acetone, dimethyl acetylamide (DMAC), methyl diisocyanate (TDI).
Further, described binding material is selected from EVA adhesive film, PA glued membrane, PES glued membrane, TPU glued membrane, PUR glued membrane, LDPE
One or more in rubber powder, EVA rubber powder, PES rubber powder, PA rubber powder, PC glue, PET glue, ABS glue or EVA glue；Institute
The thickness stating binding material is 0.2 ~ 2mm, and hot pressing temperature is 130 ~ 180 DEG C.
Further, described rigid particles is selected from aluminium oxide, silicon nitride, pink fused alumina, fused alumina zirconia, carborundum, diamond, glass
The mixture of one or more in glass, its particle diameter is 20 ~ 500 μm, and preferably 50 ~ 300 μm more elect 80 ~ 100 μm as.
Further, the spraying coating process of described sandblasting machine is: the translational speed of shower nozzle is 10mm ~ 100mm/s, and nozzle is uniform
Ejection rigid particles, flow is 10mm ~ 50mm/s, and spraying range is the border circular areas of diameter 5 ~ 50mm, coating thickness is 0.1 ~
3mm。
Preferably, the translational speed of described shower nozzle is 30mm ~ 80mm/s, and nozzle uniformly sprays rigid particles, and flow is
30mm ~ 40mm/s, spraying range is the border circular areas of diameter 25 ~ 35mm, and coating thickness is 0.5 ~ 1.5mm.
It is further preferable that the translational speed of described shower nozzle is 50mm/s, nozzle uniformly sprays rigid particles, and flow is
35mm/s, spraying range is the border circular areas of diameter 30mm, and coating thickness is 1.2mm.
Further, described hot-pressing processing technique is: carry out on continuous flat-bed press, and hot pressing temperature is 100 ~ 180
DEG C, hot pressing time is 5 ~ 40s；Preferably, described hot pressing temperature is 120 ~ 160 DEG C, and hot pressing time is 5 ~ 30s；It is further preferable that
Described hot pressing temperature is 145 ~ 150 DEG C, and hot pressing time is 15 ~ 20s.
Further, coat described binding material and rigid particles at described high property fabric single or double, prepare
The thickness of described protection composite be 0.5 ~ 5mm；It is preferably 0.8 ~ 3mm；It is preferably 1 ~ 2.5mm；It is preferably 1.2 ~ 2mm；
It is more preferably 1.5mm.
The second aspect of the invention is to provide the protection composite of a kind of spray mo(u)lding using said method to prepare.
Further, the thickness of the protection composite of described spray mo(u)lding is 0.5 ~ 5mm, preferably 1 ~ 4mm, more has choosing
It is 2 ~ 3mm.
Further, the protection composite of described spray mo(u)lding is binding material and rigid particles described in dual coating,
Its thickness is 1 ~ 6mm, preferably 3 ~ 5mm, more elects 4mm as.
The third aspect of the invention is to provide the protection that the protection composite of a kind of described spray mo(u)lding is prepared as
Inner core application in stab-resistance body armor, flak jackets and anti-cutting gloves, protector product.
When using the protection composite of spray mo(u)lding of the present invention, by 1 ~ 50 layer of composite material sheet according to certain angle
Degree cross laminates, the Nomenclature Composition and Structure of Complexes is separate between layers, do not interfere with each other；When monolayer uses, light softness, movable spirit
Live, possess good anti-cutting and the effect of rub resistance；Multiple-layer stacked is combined, and can reach GA68-2008 " police stab-resistance body armor "
24J energy does not penetrates through, and can reach GA141-2010 " police flak jackets " standard two grades and three grades.Use high-performance fiber
During textile material, it is also possible to play fire retardation, and decorative coating or functional can also be coated on composite coating surface
Coating, to reach the effects such as attractive in appearance, stealthy, radioprotective；The protection protective material that invention relates to has the anti-stab bullet-proof of excellence
Can, compared with traditional material, can significantly reduce cost, reduce weight, improve production efficiency, improve protective capacities.
The present invention uses technique scheme, compared with prior art, has the following technical effect that
The present invention uses novel efficient spraying technology the high intensity of the high rigidity of rigid particles with fabric to be organically combined
Get up, excellent performance, formation highly effective, pollutes few；The rigid particles material of spraying can denude, be passivated sharp instrument tip, and can
With deceleration bullet, reducing the degree of injury after being hit, fabric then can play and support and the effect of buffering, has
The protection effect of " soft or hard combination "；And rigid particles is cheap, raw material sources are extensive, and production cost is low；Use is the most flat
Plate hot press possesses self monitor and control system, it is possible to achieve continuous prodution, and efficiency is high, excellent product performance.
Accompanying drawing explanation
Fig. 1 is the front schematic view of the protection composite of a kind of spray mo(u)lding of the present invention；
Fig. 2 is the schematic cross-section of the protection composite of a kind of spray mo(u)lding of the present invention.
Detailed description of the invention
As shown in Figure 1 and 2, the invention provides the protection composite of a kind of spray mo(u)lding, this composite includes high property
Can the binding material 2 such as fabric 1, hot melt adhesive film and be coated in the rigid particles coating of fabric surface by spraying technology
3。
Present invention also offers the preparation method of the protection composite of a kind of spray mo(u)lding, its main production is:
First with acetone and other organic solvent, high-performance fiber fabric carried out surface process, remove the slurry of fabric face, cured matter and
Impurity, after completing, fabric drying is standby；Then fabric face is covered one layer of binding material, and is fixed on the positioning, it is ensured that
There is no space between binding material and fabric, and will not deform or misplace in subsequent technique；Then by fabric and hot melt adhesive film
Deng binding material fixation, use sand blasting machine at binding material surface spraying rigid particles granule, control the spray of sandblasting machine
The technological parameters such as head flow velocity, spray time, coating thickness, make rigid particles uniform in binding material surface distributed, and thickness is suitable；
Finally carry out heat pressing process, use continuous flat board pressure sintering to carry out continuous prodution, utilize crawler belt transmission will be covered with rigid particles
Fabric be sent to hot pressing workshop by sand-blast shop, regulate the hot pressing temperature of continuous flat-bed press and pressure and the transmission of crawler belt
Speed, makes binding material the most compound with fabric and rigid particles, and rigid particles is evenly distributed, and prepares a kind of Novel soft
Property is anti-stab cuts, puncture resistant and the protection composite material of bulletproof function.
Below by specific embodiment, the present invention is carried out detailed and concrete introduction, so that being better understood from the present invention,
But following embodiment is not limiting as the scope of the invention.
Embodiment 1
Using Fanglun l414 woven fabric, surface density is 200g/m2, thickness is 0.34mm, thread count be 110*110/(root/
10cm), yarn linear density is 930D.The hot melt adhesive film used is PES glued membrane, and thickness is 0.25mm；Select carborundum as just
Property particulate material, particle diameter is 80 μm；The translational speed of the shower nozzle of sandblasting machine is 18mm/s, and nozzle uniformly sprays rigid particles, stream
Amount is 20mm/s, and spraying range is the border circular areas of diameter 50mm, and coating thickness is 0.4mm.The hot pressing of flat-bed press continuously
Temperature is 150 DEG C, and hot pressing time is 15s.
The preparation process of the rigid particles coating composite protective material of the present embodiment is as follows:
(1) utilize organic solvent that Fanglun l414 woven fabric carries out surface process, remove the slurry of fabric face, cured matter and miscellaneous
Matter, after completing, fabric drying is standby；
(2) then by smooth for fabric lay, cover one layer of PES glued membrane on surface, fix PES glued membrane, it is ensured that PES glued membrane and virtue
There is no space between synthetic fibre 1414 woven fabric, and will not deform or misplace in subsequent technique；
(3) use sand blasting machine PES film surface spray silicon-carbide particle, control the shower nozzle flow velocity of sandblasting machine, spray time,
The technological parameters such as coating thickness, make silicon-carbide particle be evenly distributed at PES film surface, consistency of thickness；
(4) material is taken out from sand-blast shop, pressurized, heated on continuous flat-bed press, make Fanglun l414 woven fabric and carbonization
Silicon grain is the most adhesion-molded, and silicon-carbide particle is evenly distributed, and prepares soft flexible, the rigidity grain of bulletproof anti-puncturing excellent performance
Sub-coating protection composite.
(5) use 13 layers of aramid fiber coating protection composite to carry out lamination to fix, make protection inner core through cutting, use this
Plant 0.3m prepared by protection inner core2Bulletproof stab-resistant clothes, can reach GA68-2008 police stab-resistance body armor 24J energy and not penetrate through, and
Reaching the police flak jackets of GA141-2010 2 grades, weight is 2.2kg, and thickness is 7.6mm.
Embodiment 2
Employing fiberglass woven is weaved cotton cloth, and surface density is 240g/m2, thickness is 0.4mm, and thread count is 85*85/(root/10cm),
Yarn linear density is 1600D.The hot melt adhesive film used is PA glued membrane, and thickness is 0.3mm；Select fused alumina zirconia as rigid particles material
Material, particle diameter is 100 μm；The translational speed of the shower nozzle of sandblasting machine is 16mm/s, and nozzle uniformly sprays rigid particles, and flow is
20mm/s, spraying range is the border circular areas of diameter 50mm, and coating thickness is 0.5mm.The hot pressing temperature of flat-bed press continuously
Being 165 DEG C, hot pressing time is 20s.
The preparation process of the rigid particles coating composite protective material of the present embodiment is as follows:
(1) use organic solvent fiberglass woven is weaved cotton cloth to carry out surface process, remove the slurry of fabric face, cured matter and miscellaneous
Matter, after completing, fabric drying is standby；
(2) then by smooth for fabric lay, cover one layer of PA glued membrane on surface, fix PA glued membrane, it is ensured that PA glued membrane and glass
There is no space between woven cloth, and will not deform or misplace in subsequent technique；
(3) use sand blasting machine PA film surface spray fused alumina zirconia granule, control the shower nozzle flow velocity of sandblasting machine, spray time,
The technological parameters such as coating thickness, make fused alumina zirconia granule be evenly distributed at PA film surface, consistency of thickness；
(4) material is taken out from sand-blast shop, pressurized, heated on continuous flat-bed press, make fiberglass woven weave cotton cloth and zirconium
Corundum in granules is the most adhesion-molded, fused alumina zirconia even particle distribution, prepares soft flexible, the rigidity of bulletproof anti-puncturing excellent performance
Particle coating protection composite.
(5) use 16 layers of glass coating protection composite to carry out lamination to fix, make protection inner core through cutting, use this
Plant 0.3m prepared by protection inner core2Bulletproof stab-resistant clothes, can reach GA68-2008 police stab-resistance body armor 24J energy and not penetrate through, and
Disclosure satisfy that the indices requirement of prescribed by standard, weight is 2.4kg, and thickness is 9.2mm.
Embodiment 3
Using basalt fibre woven fabric, surface density is 180g/m2, thickness is 0.28mm, thread count be 130*130/(root/
10cm) unknown, yarn linear density is 600D.The hot melt adhesive film used is PUR glued membrane, and thickness is 0.3mm；Select aluminium oxide conduct
Rigid particles material, particle diameter is 60 μm；The translational speed of the shower nozzle of sandblasting machine is 16mm/s, and nozzle uniformly sprays rigid particles,
Flow is 24mm/s, and spraying range is the border circular areas of diameter 50mm, and coating thickness is 0.2mm.The heat of flat-bed press continuously
Pressure temperature is 150 DEG C, and hot pressing time is 25s.
The preparation process of the rigid particles coating composite protective material of the present embodiment is as follows:
(1) utilize organic solvent that basalt fibre woven fabric carries out surface process, remove the slurry of fabric face, cured matter and miscellaneous
Matter, after completing, fabric drying is standby；
(2) then by smooth for fabric lay, cover one layer of PUR glued membrane on surface, fix PUR glued membrane, it is ensured that PUR glued membrane is with profound
There is no space between military rock woven cloth, and will not deform or misplace in subsequent technique；
(3) use sand blasting machine at PUR film surface spray aluminum oxide granule, control the shower nozzle flow velocity of sandblasting machine, spray time,
The technological parameters such as coating thickness, make alumina particle be evenly distributed at PUR film surface, consistency of thickness；
(4) material is taken out from sand-blast shop, pressurized, heated on continuous flat-bed press, make PUR glued membrane fine with basalt
Dimension woven fabric and alumina particle are the most compound, and alumina particle is evenly distributed, prepare soft flexibly, bulletproof anti-puncturing performance excellent
Different rigid particles coating protection composite.
Using this coating protection composite of monolayer to be processed cutting, can prepare anti-cutting armlet, anti-cutting performance can
To reach Europe EN388 anti-cutting performance 5 grades and soft flexible, wear conveniently.Above the specific embodiment of the present invention is carried out
Describing in detail, but it is intended only as example, the present invention is not restricted to particular embodiments described above.For this area skill
For art personnel, any equivalent modifications carrying out the present invention and replacement are the most all among scope of the invention.Therefore, do not taking off
The impartial conversion made under the spirit and scope of the present invention and amendment, all should contain within the scope of the invention.
Claims (10)
1. the preparation method of the protection composite of a spray mo(u)lding, it is characterised in that comprise the steps:
(1) use organic solvent that high-performance fiber fabric carries out surface process, remove the slurry of fabric face, waxiness and miscellaneous
Matter, dries；
(2) on the high-performance fiber fabric dried, cover one layer of binding material and be fixed on the positioning so that high-performance fiber
Tight between fabric and binding material；
(3) use sandblasting machine at the surface spraying rigid particles of the binding material fixed, make rigid particles be evenly distributed on viscous
Knot material surface, prepares compound fabric grey cloth；
(4) the continuous flat board pressure sintering of above-mentioned compound fabric grey cloth employing is carried out hot-pressing processing, make binding material fine with high-performance
Dimensional fabric is the most compound, prepares protection composite finished product.
Preparation method the most according to claim 1, it is characterised in that described high-performance fiber fabric is fine selected from base glass
One or more in dimension, basalt fibre, aramid fiber, polypropylene fibre, high-strength nylon fiber, polyster fibre, cotton fiber
The thread fabric of fiber, yarn.
Preparation method the most according to claim 1, it is characterised in that described process of surface treatment is: by high-performance fiber
Fabric soaks 10min ~ 60min in organic solvent, and temperature is 30 ~ 60 DEG C；Described organic solvent selected from dehydrated alcohol, acetone,
The mixture of one or more in dimethyl acetylamide (DMAC), methyl diisocyanate (TDI).
Preparation method the most according to claim 1, it is characterised in that described binding material selected from EVA adhesive film, PA glued membrane,
PES glued membrane, TPU glued membrane, PUR glued membrane, LDPE rubber powder, EVA rubber powder, PES rubber powder, PA rubber powder, PC glue, PET glue, ABS glue
One or more in water or EVA glue；The thickness of described binding material is 0.2 ~ 2mm.
Preparation method the most according to claim 1, it is characterised in that described rigid particles is selected from aluminium oxide, silicon nitride, chromium
The mixture of one or more in corundum, fused alumina zirconia, carborundum, diamond, glass, its particle diameter is 20 ~ 500 μm.
Preparation method the most according to claim 1, it is characterised in that the spraying coating process of described sandblasting machine is: the shifting of shower nozzle
Dynamic speed is 10mm ~ 100mm/s, and nozzle uniformly sprays rigid particles, and flow is 10mm ~ 50mm/s, spraying range be diameter 5 ~
The border circular areas of 50mm, coating thickness is 0.1 ~ 3mm.
Preparation method the most according to claim 1, it is characterised in that described hot-pressing processing technique is: in continuous flat board heat
Carrying out on press, hot pressing temperature is 100 ~ 180 DEG C, and hot pressing time is 5 ~ 40s.
Preparation method the most according to claim 1, it is characterised in that coat at described high property fabric single or double
Described binding material and rigid particles, the thickness of prepared described protection composite is 0.5 ~ 5mm.
9. the protection composite of the spray mo(u)lding that prepared by method as described in any one of claim 1-8.
10. the protection inner core that the protection composite of spray mo(u)lding as claimed in claim 9 is prepared as is at stab-resistance body armor, flak jackets
And the application in anti-cutting gloves, protector product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572542.5A CN106192430B (en) | 2016-07-20 | 2016-07-20 | A kind of protection composite of spray mo(u)lding and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572542.5A CN106192430B (en) | 2016-07-20 | 2016-07-20 | A kind of protection composite of spray mo(u)lding and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106192430A true CN106192430A (en) | 2016-12-07 |
| CN106192430B CN106192430B (en) | 2018-04-06 |
Family
ID=57493576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610572542.5A Active CN106192430B (en) | 2016-07-20 | 2016-07-20 | A kind of protection composite of spray mo(u)lding and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106192430B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108914554A (en) * | 2018-08-21 | 2018-11-30 | 徐培培 | A kind of novel environment friendly fire resisting basalt fiber cloth |
| WO2021189179A1 (en) * | 2020-03-23 | 2021-09-30 | 李辉 | Nano-titanium and hemp fiber composite material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101936684A (en) * | 2010-07-13 | 2011-01-05 | 北京同益中特种纤维技术开发有限公司 | Thorn-proof composite material and preparation method thereof |
| CN102493202A (en) * | 2011-12-01 | 2012-06-13 | 山东三达科技发展公司 | Composite puncture-proof sheet and bulletproof puncture-proof composite material |
| CN202648534U (en) * | 2012-05-24 | 2013-01-02 | 东华大学 | Bullet-proof and puncture-proof material |
-
2016
- 2016-07-20 CN CN201610572542.5A patent/CN106192430B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101936684A (en) * | 2010-07-13 | 2011-01-05 | 北京同益中特种纤维技术开发有限公司 | Thorn-proof composite material and preparation method thereof |
| CN102493202A (en) * | 2011-12-01 | 2012-06-13 | 山东三达科技发展公司 | Composite puncture-proof sheet and bulletproof puncture-proof composite material |
| CN202648534U (en) * | 2012-05-24 | 2013-01-02 | 东华大学 | Bullet-proof and puncture-proof material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108914554A (en) * | 2018-08-21 | 2018-11-30 | 徐培培 | A kind of novel environment friendly fire resisting basalt fiber cloth |
| WO2021189179A1 (en) * | 2020-03-23 | 2021-09-30 | 李辉 | Nano-titanium and hemp fiber composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106192430B (en) | 2018-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104677194B (en) | A kind of modularity multidimensional bullet proof composite plating and preparation method thereof | |
| CN102706219A (en) | Micron and nano material-enhancing bionic layered composite material and manufacturing method thereof | |
| CN110588094B (en) | Waste fiber, fabric and inorganic particle four-layer fusion-casting composite anti-puncture sheet and preparation method and application thereof | |
| CN104356416B (en) | A kind of preparation method of special type protection material | |
| CN103791778B (en) | The molding bonded method of flexible puncture-proof material, stab-proof body | |
| CN102490416B (en) | High strength and high modulus polyethylene fiber resin composite sheet and bulletproof and stab-resistant armor containing same | |
| CN205619831U (en) | Shellproofly prevent that thorn clothes and shellproof prevent thorn clothes protection inner core | |
| EP3112797B1 (en) | Composite ballistic-resistant unit material and preparation method for same | |
| CN106192430B (en) | A kind of protection composite of spray mo(u)lding and preparation method thereof | |
| CN102058188B (en) | Assorted fiber fabric composite material with high nanometer content and preparation method thereof | |
| CN201045890Y (en) | A bulletproof helmets | |
| CN110500918B (en) | Micron-scale inorganic powder layer-by-layer composite stepped stab-resistant resin sheet and preparation method and application thereof | |
| CN101922893A (en) | Stab-resistant material and manufacturing method thereof | |
| CN106218143B (en) | A kind of resin base polyethylene felt thorn-proof composite material | |
| CN110553546B (en) | Method for preparing composite stab-resistant sheet by layered bedding and fusion casting of inorganic particles and waste fabrics and application | |
| CN110591290B (en) | Inorganic particle filled reverse cutting type anti-piercing thermosetting resin sheet and preparation method and application thereof | |
| CN109357571B (en) | Comfortable stab-resistant garment and manufacturing method thereof | |
| CN102632665B (en) | A kind of aramid fiber strengthens resin-based thorn-proof composite material | |
| CN109506518A (en) | A kind of liquid flak jackets production technology | |
| CN110641054B (en) | Forming method for pressing inorganic particles into softened resin membrane layer by layer, anti-puncturing composite resin sheet and application | |
| CN110654079B (en) | Inorganic particle and thermoplastic resin powder interval-laying hot-melt die-casting composite resin sheet and preparation method and application thereof | |
| CN206648524U (en) | A kind of bulletproof composite stab-resistant material | |
| CN204461220U (en) | A kind of Portable individual protection shield | |
| CN218764864U (en) | High-performance soft bulletproof layer composite structure | |
| CN110657709B (en) | Method for preparing anti-puncturing composite sheet by hot pressing of waste fiber cut sections and inorganic particle mixed laying layer and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |