CN106192393A - Treating agent for polyester synthetic fiber, method for treating polyester synthetic fiber, and polyester synthetic fiber - Google Patents
Treating agent for polyester synthetic fiber, method for treating polyester synthetic fiber, and polyester synthetic fiber Download PDFInfo
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- CN106192393A CN106192393A CN201610185122.1A CN201610185122A CN106192393A CN 106192393 A CN106192393 A CN 106192393A CN 201610185122 A CN201610185122 A CN 201610185122A CN 106192393 A CN106192393 A CN 106192393A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a treating agent for polyester synthetic fiber, a method for treating polyester synthetic fiber using the treating agent, and polyester synthetic fiber obtained by the treating method, which satisfy emulsion stability, heat resistance, antistatic property in carding process in textile process and scum accumulation resistance in drawing process, and do not cause fiber strength to decrease with time. The treating agent for polyester synthetic fibers comprises 40 to 80% by mass of a specific alkyl phosphate, 10 to 50% by mass of a specific surfactant, and 0.01 to 10% by mass of a monohydric aliphatic alcohol having an alkyl group with 12 to 22 carbon atoms in the molecule, wherein the total amount of these components is 100% by mass.
Description
Technical field
The present invention relates to Polyester synthetic fibers inorganic agent, use the process side of the Polyester synthetic fibers of this inorganic agent
Method and the Polyester synthetic fibers obtained by this processing method.
Background technology
In the past, as Polyester synthetic fibers inorganic agent, it is proposed that use the various oil preparationes of potassium alkyl phosphate.Right
In this inorganic agent, it is proposed that (1) potassium alkyl phosphate and the two-component system of alkyl amino ether type non-ionic phosphoric acid corrective
System (referring for example to patent documentation 1), (2) potassium alkyl phosphate and the two-component system of high molecular weight peo compound
(referring for example to patent documentation 2), (3) potassium alkyl phosphate, Emulsification of Paraffin thing and three components of cationic surface active agent
The schemes such as system (referring for example to patent documentation 3).But, it is steady to there is emulsifying in these conventional Polyester synthetic fibers inorganic agents
It is not enough that the antistatic behaviour of the carding step in qualitative, thermostability, weaving operation and the resistance to scum silica frost (scum) of mixing in doubling step pile up property
Problem.
Prior art literature
Patent documentation
Patent documentation 1: Japanese Laid-Open Patent Publication 60-224867 publication
Patent documentation 2: Japanese Unexamined Patent Publication 3-174067 publication
Patent documentation 3: Japanese Unexamined Patent Publication 6-108361 publication.
Summary of the invention
The problem that invention is to be solved
The problem to be solved in the present invention is, it is provided that meet the carding step in emulsion stability, thermostability, weaving operation simultaneously
Antistatic behaviour and mixing in doubling step resistance to scum silica frost pile up property, and will not occur fibre strength through time decline Polyester synthesis
Fiber inorganic agent, use the Polyester synthetic fibers of this inorganic agent processing method and by this processing method obtain poly-
Ester system synthetic fibers.
For solving the scheme of problem
The present inventor is studied for solving the problems referred to above, forms found that contain specific three kinds of components with special ratios
Polyester synthetic fibers inorganic agent the most suitable.
That is, the present invention relates to Polyester synthetic fibers inorganic agent, it is characterised in that contain with the ratio of 40 ~ 80 mass %
Following alkyl phosphoric acid esters, contain lower surfactant and the ratio with 0.01 ~ 10 mass % with the ratio of 10 ~ 50 mass %
Example contains the unitary fatty alcohol of the alkyl in molecule with carbon number 12 ~ 22, and these compositions amount to 100 mass %.It addition, this
Invention further relates to use the processing method of the Polyester synthetic fibers of this Polyester synthetic fibers inorganic agent, by this processing method
The Polyester synthetic fibers obtained.
Alkyl phosphoric acid esters: have in molecule in alkyl phosphate and the salt thereof of the alkyl of carbon number 12 ~ 22
At least one, acid number is 0.01 ~ 80KOHmg/g.
Surfactant: selected from polyoxyalkylene alkyl ether, polyoxy alkylidene alkene ether, polyoxyalkylene alkyl ester, gather
Oxyalkylene alkenyl esters, polyoxyalkylene alkyl phenyl ether, polyoxyalkylene alkyl amino ethers, polyoxy alkylidene alkenyl amino
In the salt of ether, polyoxyalkylene alkyl amino ethers and the salt of mineral acid and polyoxy alkylidene alkenyl amino ether and mineral acid
At least one.
First, Polyester synthetic fibers inorganic agent of the present invention (the hereinafter referred to as inorganic agent of the present invention) is carried out
Explanation.Alkyl phosphoric acid esters for the inorganic agent of the present invention has the alkyl of the alkyl of carbon number 12 ~ 22 in molecule
Phosphate ester and salt thereof, wherein can list such as 1-isobutyl-3,5-dimethylhexylphosphoric acid, myristyl phosphate ester, hexadecanyl phosphate, whale
Wax stearyl (cetostearyl) phosphate ester, octadecyl phosphate ester, iso stearyl phosphate ester, docosyl phosphate ester with
And their alkali metal salt etc..Wherein, as the alkyl in alkyl phosphoric acid esters, preferably molecule with carbon number 16 ~ 18
Alkyl phosphoric acid esters, wherein can list such as hexadecanyl phosphate, cetearyl phosphate, octadecyl phosphate ester with
And their alkali metal salt etc..These alkyl phosphoric acid esters are by aliphatic monobasic alcohol and the phosphoric acid agent representated by phosphoric anhydride
Reaction and obtain, and then reacted by neutralization with alkali metal hydroxide thereafter and obtain, aliphatic monobasic alcohol used can
It is alternatively mixture of more than two kinds for single component.It addition, generally alkyl phosphoric acid esters is for including monoesters, diester and containing P-O-P
The mixture of the polymer of key, its composition ratio is not particularly limited.As the alkali metal salt of alkyl phosphate, sodium can be listed
Salt, potassium salt etc., preferably potassium salt.For impurity contained in synthesis material, if the most acceptable in convenient source standard.Its
In in one of sodium composition contained in such as potassium hydroxide, phosphoric acid agent i.e. phosphoric anhydride contained heavy metal or arsenic compound etc. each
Plant impurity and by-product meets.
Acid number for the alkyl phosphoric acid esters of the inorganic agent of the present invention is 0.01 ~ 80KOHmg/g.If acid number is too high,
The most easily cause emulsifying bad, and if acid number is too low, the most easily cause fibre strength through time decline.In the present invention, acid number is
Refer to, alkyl phosphoric acid esters is dissolved in the mixed solvent of ethanol/dimethylbenzene=1/2 (volume ratio), is assemblied in potentiometric titrimeter
On, titrate with the methanolic potassium hydroxide standard solution of 0.1mol/L, following mathematical expression 1 value calculated;
[mathematical expression 1]
In mathematical expression 1,
The coefficient (factor) of the methanolic potassium hydroxide standard solution of f:0.1mol/L
S: sampling amount (g, solid constituent conversion amount)
R: until the usage amount (mL) of the methanolic potassium hydroxide standard solution of the 0.1mol/L of flex point.
As the surfactant of the inorganic agent for the present invention, can include: 1) 2-Ethylhexyl Alcohol, lauryl alcohol, 14
Saturated or the unsaturated aliphatic monohydric alcohol of the carbon numbers 8 ~ 18 such as alcohol, hexadecanol, stearyl alcohol, oleyl alcohol and alkylene oxide carry out addition
Polyoxyalkylene alkyl (or thiazolinyl) ether reacted and obtain;2) octanoic acid, dodecylic acid, myristic acid, Palmic acid, stearic acid,
It is anti-that the saturated or unsaturated fatty acid of the carbon numbers 8 ~ 18 such as oleic acid, linoleic acid, erucic acid, castor oil acid and alkylene oxide carry out addition
Polyoxyalkylene alkyl (or thiazolinyl) ester answered and obtain;3) alkyl phenol such as octyl phenol, nonyl phenol adds with alkylene oxide
Become the polyoxyalkylene alkyl phenyl ether reacted and obtain;4) carbon number 8 ~ 18 such as octylame, lauryl amine, stearylamine, oleyl amine
Polyoxyalkylene alkyl (or thiazolinyl) amino ethers that saturated or unsaturated aliphatic amine carries out additive reaction with alkylene oxide and obtains;
5) salt etc. of the mineral acid of polyoxyalkylene alkyl (or thiazolinyl) amino ethers as above and such as phosphoric.More than for
Any surface activating agent illustrated, is not particularly limited as polyoxy alkylidene (polyoxyalkylene), preferential oxidation thiazolinyl
(oxyalkylene) averaged repeating numbers is 2 ~ 150, further preferably oxyalkylene group be only oxyethylene group or for oxyethylene group with
The mixing of oxypropylene group.
As the unitary fatty alcohol of the alkyl in the molecule for the inorganic agent of the present invention with carbon number 12 ~ 22, can
List: 1) straight chain alcohol such as lauryl alcohol, myristyl alcohol, spermol, cetearyl alcohol, stearyl alcohol, mountain alcohol;2) different tridecanol,
The branched-chain alcohos such as isooctadecanol.Wherein, as unitary fatty alcohol, the preferably unitary fatty alcohol of carbon number 16 ~ 18, wherein can enumerate
Go out hexadecanol, stearyl alcohol and their mixture.
The ratio of each composition of the inorganic agent of the composition present invention is: abovementioned alkyl phosphoric acid ester 40 ~ 80 mass %, above-mentioned table
Face activating agent 10 ~ 50 mass % and molecule have unitary fatty alcohol 0.01 ~ 10 mass % of the alkyl of carbon number 12 ~ 22,
These compositions amount to 100 mass %, are wherein preferably: alkyl phosphoric acid esters 40 ~ 80 mass %, surfactant 10 ~ 50 mass %,
And molecule has unitary fatty alcohol 0.01 ~ 6 mass % of the alkyl of carbon number 12 ~ 22, these compositions amount to 100 matter
Amount %, more preferably: alkyl phosphoric acid esters 50 ~ 70 mass %, surfactant 25 ~ 45 mass % and molecule have carbon atom
Unitary fatty alcohol 0.01 ~ 4 mass % of the alkyl of several 12 ~ 22, these compositions amount to 100 mass %.
Then, the processing method (the hereinafter referred to as processing method of the present invention) to Polyester synthetic fibers of the present invention
Illustrate.The processing method of the present invention is to make the inorganic agent of the present invention be attached to Polyester synthetic fibers, makes the place of the present invention
The method that reason agent reaches 0.01 ~ 0.5 mass %.Attachment operation can be arbitrary work of spinning process, stretching process, curling process etc.
Sequence, preferably adhered to before or after spinning process, curling process.Adherence method can be to impregnate to oil process, spraying oil supply
Method, roller, to oil process, the either method being directed to oil process (ガ イ De oil process) etc. of use dosing pump, preferably impregnate oil supply
Method, spraying to oil process or roller to oil process.
Finally, Polyester synthetic fibers of the present invention (the hereinafter referred to as synthetic fibers of the present invention) are illustrated.
The synthetic fibers of the present invention are the Polyester synthetic fibers obtained by the processing method of the present invention.As synthetic fibers, can enumerate
Go out the Polyester synthetic fibers such as pet fiber, PTT fiber, the most preferably
Pet fiber.
The effect of invention
The present invention from the description above, has the carding step that simultaneously meets in emulsion stability, thermostability, weaving operation
The resistance to scum silica frost of antistatic behaviour and mixing in doubling step piles up property, and will not occur fibre strength through time the effect that declines.
Embodiment
Hereinafter, composition and effect in order to make the present invention are more specific and enumerate embodiment etc., but the present invention is not limited to
These embodiments.Should illustrate, in following example and comparative example, part refers to mass parts, and additionally % refers to quality %.
Kind of test 1 (preparation of the aqueous liquid of Polyester synthetic fibers inorganic agent)
The preparation of the aqueous liquid of inorganic agent (embodiment 1) of Polyester synthetic fibers
By octadecyl phosphate kalium salt (acid number 10KOHmg/g) (A-1) 66.5 parts, α-nonyl phenyl-ω-hydroxyl (polyoxy second
Alkene) (n=10, n are the quantity of ethylene oxide unit, the most identical) and α-dodecylamino-ω-hydroxyl (polyoxyethylene) (n
=10) 30 parts of mixture (B-1) and the stearyl alcohol (C-1) 3.5 parts of 70:30 (mass ratio) are put in beaker, the most mixed
Closing, be heated to the ion exchange water of the half amount of the ormal weight of 80 DEG C, stirring makes it be completely dissolved.After dissolving, without a break
The ion exchange water adding remaining half amount stirs, and makes the 5% of Polyester synthetic fibers inorganic agent (embodiment 1)
Aqueous liquid.
The preparation of the aqueous liquid of inorganic agent (embodiment 2 ~ 10 and comparative example 1 ~ 6) of Polyester synthetic fibers
As the Polyester synthetic fibers preparation method with 5% aqueous liquid of inorganic agent (embodiment 1), make Polyester synthesis
Fiber 5% aqueous liquid of inorganic agent (embodiment 2 ~ 10 and comparative example 1 ~ 6).The Polyester synthesis of each example in the aqueous liquid made
The content aggregation of fiber inorganic agent is shown in table 1.
[table 1]
。
In table 1,
A-1: octadecyl phosphate kalium salt (acid number=10KOHmg/g)
A-2: cetearyl phosphate potassium salt (acid number=5KOHmg/g)
A-3: hexadecanyl phosphate potassium salt (acid number=10KOHmg/g)
A-4: octadecyl phosphate kalium salt (acid number=25KOHmg/g)
A-5: docosyl phosphate kalium salt (acid number=10KOHmg/g)
A-6: 1-isobutyl-3,5-dimethylhexylphosphoric acid potassium salt (acid number=50KOHmg/g)
A-7: octyl phosphate potassium salt (acid number=20KOHmg/g)
A-8: octadecyl phosphate kalium salt (acid number=90KOHmg/g)
A-9: octadecyl phosphate kalium salt (acid number=0KOHmg/g).
B-1: α-nonyl phenyl-ω-hydroxyl (polyoxyethylene) (n=10)/α-dodecylamino-ω-hydroxyl (polyoxy second
Alkene) (n=10)=70/30
B-2: α-dodecyl-ω-hydroxyl (polyoxyethylene) (n=10)/α-dodecyl-ω-hydroxyl (polyoxyethylene) (polyoxy
Propylene) (m+n=10, m are the quantity of propylene oxide unit)/α-dodecylamino-ω-hydroxyl (polyoxyethylene) (n=10)
The mixture of=25/25/50 (mass ratio)
B-3: α-dodecyl-ω-hydroxyl (polyoxyethylene) (n=10)/α-dodecylamino-ω-hydroxyl (polyoxyethylene)
(n=10) with the mixture of salt=50/50 (mass ratio) of phosphoric acid
B-4: coco-nut oil fatty acid-polyoxyethylene (n=10)/α-dodecylamino-ω-hydroxyl (polyoxyethylene) (n=10)
The mixture of=50/50 (mass ratio)
B-5: Polyethylene Glycol (number-average molecular weight: 1000).
C-1: stearyl alcohol
C-2: cetearyl alcohol
C-3: spermol
C-4: mountain alcohol
C-5: lauryl alcohol
C-6: capryl alcohol.
Kind of test 2
The evaluation of emulsion stability
For 5% aqueous liquid of the Polyester synthetic fibers inorganic agent of each example of preparation in kind of test 1, detect by an unaided eye it
Stability, is evaluated according to following standard.Result collects and is shown in table 2.
The evaluation criterion of emulsion stability
◎: entirely without muddiness, uniformly, excellent stability
Zero: slightly muddy, but stability in the large is good
×: producing precipitation and float, stability is bad.
The evaluation of thermostability
For 5% aqueous liquid of Polyester synthetic fibers inorganic agent of each example of preparation in kind of test 1, take 10g and put into accompany and replace
In family name's culture dish (シ ャ レ), after being dried 2 hours at 105 DEG C, detect by an unaided eye the situation of being fuming when being heated to 180 DEG C, presses
It is evaluated according to following standard.Result collects and is shown in table 2.
The evaluation criterion of thermostability
◎: be not almost fuming
Zero: be slightly fuming, but in unchallenged level
×: substantially occur being fuming.
Kind of test 3 (inorganic agent is to the attachment of polyester staple fiber and evaluation thereof)
The inorganic agent attachment to polyester staple fiber
5% aqueous liquid of the Polyester synthetic fibers weaving inorganic agent of each example of preparation in kind of test 1 is used ion further
Exchanged water dilutes, and makes 2% aqueous liquid.Spraying is used to make 2% aqueous liquid made be attached to cotton process processed obtains to oil process
Fiber number 1.3 × 10-4G/m (1.2 danier), semimat (semidull) polyester staple fiber of the long 38mm of fiber so that as poly-
The adhesion amount of ester system synthetic fibers inorganic agent reaches 0.15%, after being dried 2 hours with the air drier of 80 DEG C, 25 DEG C ×
Under the atmosphere of 40%RH, at regulation humidity one night, obtain being attached with the processed polyester staple fiber of Polyester synthetic fibers inorganic agent.
The evaluation of the antistatic behaviour of carding step
Use the processed polyester staple fiber 10kg of above-mentioned gained, (rich for flat card under the atmosphere of 25 DEG C × 40%RH
With industry society system), at spinning speed=be passed under conditions of 140m/ minute.The electrostatic of spun carding fiber net is entered
Row measures, according to following standard determination antistatic behaviour.Result collects and is shown in table 2.
The evaluation criterion of antistatic behaviour
◎: electrostatic generation amount is less than 0.3kV
Zero: electrostatic generation amount is that 0.3kV is less than 0.6kV
×: electrostatic generation amount is more than 0.6kV.
The evaluation of the resistance to scum silica frost of mixing in doubling step accumulation property
Use the processed polyester staple fiber 10kg of above-mentioned gained, for flat card (Fenghe industry society system), obtain carded
Strip.By the card sliver of gained 30 DEG C, under the atmosphere of 70%RH for PDF type drawing frame (Ishikawa makes society of institute system), spinning
Silk speed=make it repeatedly pass through for 5 times under conditions of 250m/ minute.With the naked eye judge the rubber rollers of PDF type drawing frame, fly frame
(reducer) and the scum silica frost degree of fibre-condensing conduit (trumpet) each several part, property is piled up according to the resistance to scum silica frost of following standard evaluation.Knot
Really collect and be shown in table 2.
The evaluation criterion of accumulation property
◎: pile up almost without scum silica frost
Zero: slightly have scum silica frost to pile up, but in unchallenged level
×: substantially occur that scum silica frost is piled up.
The evaluation of fibre strength
Use strength and elongation analyzer that the initial strength of the processed polyester staple fiber of above-mentioned gained is measured, it addition, use
Strength and elongation analyzer to same fiber 30 DEG C, place under the atmosphere of 70%RH 3 months of 3 months after intensity be measured.Will
Intensity after 3 months compares with initial strength, according to following standard evaluation fibre strength.Result collects and is shown in table 2.
The evaluation criterion of fibre strength
◎: be the intensity of more than 95% relative to initial strength
×: it is the intensity less than 95% relative to initial strength.
[table 2]
。
The result of the table 2 corresponding with table 1 also indicates that, according to the present invention, have meet simultaneously emulsion stability, thermostability,
The antistatic behaviour of the carding step in weaving operation and the resistance to scum silica frost accumulation property of mixing in doubling step, and fibre strength will not occur
Through time decline effect.
Claims (8)
1. Polyester synthetic fibers inorganic agent, it is characterised in that
Contain following alkyl phosphoric acid esters with the ratio of 40 ~ 80 mass %, contain following surface activity with the ratio of 10 ~ 50 mass %
Agent and contain the unitary fatty alcohol of the alkyl in molecule with carbon number 12 ~ 22 with the ratio of 0.01 ~ 10 mass %, these
Composition amounts to 100 mass %,
Alkyl phosphoric acid esters: have in the alkyl phosphate of the alkyl of carbon number 12 ~ 22 and salt thereof at least in molecule
One, acid number is 0.01 ~ 80KOHmg/g;
Surfactant: selected from polyoxyalkylene alkyl ether, polyoxy alkylidene alkene ether, polyoxyalkylene alkyl ester, polyoxy Asia
Alkylalkenyl ester, polyoxyalkylene alkyl phenyl ether, polyoxyalkylene alkyl amino ethers, polyoxy alkylidene alkenyl amino ether, poly-
Oxyalkylene alkyl amino ether and at least in the salt of mineral acid and the salt of polyoxy alkylidene alkenyl amino ether and mineral acid
Kind.
Polyester synthetic fibers inorganic agent the most according to claim 1, wherein, the alkyl of unitary fatty alcohol and alkyl phosphorus
The alkyl of esters of gallic acid is the alkyl of carbon number 16 ~ 18.
Polyester synthetic fibers inorganic agent the most according to claim 1 and 2, wherein, contains with the ratio of 40 ~ 80 mass %
There is alkyl phosphoric acid esters, contain surfactant with the ratio of 10 ~ 50 mass % and contain one with the ratio of 0.01 ~ 6 mass %
Unit's fatty alcohol, these compositions amount to 100 mass %.
Polyester synthetic fibers inorganic agent the most according to any one of claim 1 to 3, wherein, with 50 ~ 70 mass %
Ratio contain alkyl phosphoric acid esters, contain surfactant and the ratio with 0.01 ~ 4 mass % with the ratio of 25 ~ 45 mass %
Example contains unitary fatty alcohol, and these compositions amount to 100 mass %.
Polyester synthetic fibers inorganic agent the most according to any one of claim 1 to 4, wherein, Polyester synthesis fibre
Dimension is pet fiber.
6. the processing method of Polyester synthetic fibers, it is characterised in that make the Polyester according to any one of claim 1 to 5
Synthetic fibers inorganic agent is attached to polyester fiber so that this inorganic agent reaches 0.05 ~ 0.5 mass %.
7. Polyester synthetic fibers, it is characterised in that it is by the processing method of the Polyester synthetic fibers described in claim 6
The Polyester synthetic fibers obtained.
Polyester synthetic fibers the most according to claim 7, wherein, Polyester synthetic fibers are poly terephthalic acid second two
Alcohol ester fiber.
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CN115997055A (en) * | 2020-12-25 | 2023-04-21 | 竹本油脂株式会社 | Treatment agent 1 for synthetic fibers, treatment agent for synthetic fibers, method for preparing aqueous liquid, method for treating synthetic fibers, staple fibers, spun yarns, and nonwoven fabric |
CN116209806A (en) * | 2020-10-30 | 2023-06-02 | 竹本油脂株式会社 | Treating agent for short fiber, synthetic fiber, and method for producing nonwoven fabric |
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JP6057489B1 (en) * | 2016-05-25 | 2017-01-11 | 竹本油脂株式会社 | Polyolefin synthetic fiber treatment agent, aqueous solution thereof, polyolefin synthetic fiber treatment method, polyolefin synthetic fiber, and thermal bond nonwoven fabric |
JP7152363B2 (en) * | 2018-07-03 | 2022-10-12 | 三洋化成工業株式会社 | antistatic agent |
JP7055495B1 (en) | 2021-02-26 | 2022-04-18 | 竹本油脂株式会社 | Synthetic fiber treatment agent, synthetic fiber first treatment agent, synthetic fiber second treatment agent, synthetic fiber treatment agent aqueous solution, synthetic fiber treatment method, and synthetic fiber |
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JP2003183563A (en) * | 2001-12-18 | 2003-07-03 | Mitsui Chemicals Inc | Aqueous flame-retardant coating material |
CN102182059A (en) * | 2011-03-21 | 2011-09-14 | 桐乡市恒隆化工有限公司 | Antistatic agent for polyester elasticizing oiling agent and manufacturing method thereof |
CN102776786A (en) * | 2012-07-11 | 2012-11-14 | 陕西海安实业有限责任公司 | Non-emulsion type pure oiling agent for high speed spinning of polyamide-6 filaments |
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CN116209806A (en) * | 2020-10-30 | 2023-06-02 | 竹本油脂株式会社 | Treating agent for short fiber, synthetic fiber, and method for producing nonwoven fabric |
CN116209806B (en) * | 2020-10-30 | 2024-02-27 | 竹本油脂株式会社 | Treating agent for short fiber, synthetic fiber, and method for producing nonwoven fabric |
CN115997055A (en) * | 2020-12-25 | 2023-04-21 | 竹本油脂株式会社 | Treatment agent 1 for synthetic fibers, treatment agent for synthetic fibers, method for preparing aqueous liquid, method for treating synthetic fibers, staple fibers, spun yarns, and nonwoven fabric |
CN115997055B (en) * | 2020-12-25 | 2024-04-12 | 竹本油脂株式会社 | Treatment agent 1 for synthetic fibers, treatment agent for synthetic fibers, method for preparing aqueous liquid, method for treating synthetic fibers, staple fibers, spun yarns, and nonwoven fabric |
Also Published As
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JP2016223035A (en) | 2016-12-28 |
JP5796923B1 (en) | 2015-10-21 |
CN106192393B (en) | 2018-01-02 |
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