CN106192002B - Rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation method and purposes - Google Patents
Rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation method and purposes Download PDFInfo
- Publication number
- CN106192002B CN106192002B CN201510233452.9A CN201510233452A CN106192002B CN 106192002 B CN106192002 B CN 106192002B CN 201510233452 A CN201510233452 A CN 201510233452A CN 106192002 B CN106192002 B CN 106192002B
- Authority
- CN
- China
- Prior art keywords
- crystal
- carbon oxygen
- boron carbon
- oxygen iodine
- rubidium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
The present invention relates to a kind of compound rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation method and purposes, the molecular formula of the compound is Rb9[B4O5(OH)4]3(CO3)I•7H2O, molecular weight 1656.07, the molecular formula of the crystal is Rb9[B4O5(OH)4]3(CO3)I•7H2O, molecular weight 1656.07 belong to trigonal system, and space group isP‑62c, using hydro-thermal method, rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal can obtain by the method for program cooling or Temperature fall.The crystal nonlinear optical effect is 0.5 times of KDP crystal, transmission region 319nm to 2600nm.The crystal growing process has the advantages that easy to operate, cost is low, and reagent used is inorganic raw material, and toxicity is low, and growth cycle is short, and physico-chemical property is stablized.The rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal of the present invention is used widely in the device for non-linear optical such as frequency-doubled conversion, optical parametric oscillator.
Description
Technical field
The present invention relates to a kind of compound rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation side
Method and purposes, belong to domain of inorganic chemistry, fall within materials science field and optical field.
Technical background
The development of nonlinear optics and its crystalline material and the development of laser technology are closely related.In laser technology, directly
Connect that to can be obtained laser wavelength using laser crystal limited, frequency conversion is carried out using nonlinear optical crystal, can will be complete
The laser of solid-state laser output is converted into new wave band of laser, so that the application range of laser is expanded significantly, in laser technology
There are huge application prospect and economic value in field.Nonlinear optical material is also the material base of photoelectronic industry just because of this
Plinth, is the mainstay of the fields such as Solid State Laser technology, optic communication and information processing development.
Up to the present, nonlinear optical material is extended to organic by inorganic, has block to develop into film, fiber and super
Lattice material.Explored by decades, domestic and international researcher has found a series of nonlinear optical material of excellent performances, such as
KDP, KB5, β-BBO, LBO, CBO, LN and KTP etc., have carried out large-scale production and have been applied widely.But these materials
In growing technology and upper also this certain limitation of application：As KDP and KB5 laser damage thresholds are not high, water is dissolved in；β-BBO exist
There are phase transformation in growth course；Easy deliquescence of CBO etc..And with the development of laser technology, laser light source further to deep ultraviolet,
Ultraviolet and infrared band is expanded, and which greatly enhances the demand of the nonlinear optical crystal to excellent combination property, therefore, explores
Novel nonlinear optical crystal material becomes research hotspot both domestic and external.
Problem to be solved by this invention is to provide that a kind of transmission region is wider, and nonlinear second-order optical susceptibility is larger, energy
Enough realize phase matched, easily prepare and the preferable compound rubidium boron carbon oxygen iodine hydrogen non-linear optical crystal material of stability and its
Preparation method and purposes.
The content of the invention
Present invention aims to solve need of the all-solid state laser system to the crystalline material with nonlinear optical effect
Will, there is provided a kind of compound rubidium boron carbon oxygen iodine hydrogen, the compound chemical formula are：Rb9[B4O5(OH)4]3(CO3)I·7H2O, molecule
Measure as 1656.07, prepared using hydro-thermal method, products therefrom is directly crystal.
It is a further object of the present invention to provide a kind of compound rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal, the crystal chemistry
Formula is Rb9[B4O5(OH)4]3(CO3)I·7H2O, molecular weight 1656.07 belong to hexagonal crystal system, and space group isUnit cell
Parameter isZ=2.
Another object of the present invention is to provide a kind of preparation method of compound rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal,
Prepared using hydro-thermal method.
It is yet another object of the invention to provide the purposes of rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal.
A kind of compound rubidium boron carbon oxygen iodine hydrogen of the present invention, the chemical formula of the compound is Rb9[B4O5(OH)4]3
(CO3)I·7H2O, molecular weight 1656.07, is prepared using hydro-thermal method, and products therefrom is crystal.
A kind of compound rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal, the molecular formula of the crystal is Rb9[B4O5(OH)4]3
(CO3)I·7H2O, molecular weight 1656.07 belong to hexagonal crystal system, and space group isCell parameter isZ=2.
The preparation method of the compound rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal, crystal is prepared using hydro-thermal method,
Concrete operations follow these steps to carry out：
A, it is Rb that will contain rubidium compound2CO3It is added to the polytetrafluoroethyllining lining for the autoclave that volume is 25-100mL
In, addition boron-containing compound is H3BO3Or B2O3, add the compound PbI containing iodine2, acid iodide that KI or mass fraction are 45%
HI, is eventually adding deionized water 5-50mL, it is sufficiently mixed uniformly, wherein raw material Rb2CO3With H3BO3In BO3 3-Mole
Than for 1:0.5-2, raw material Rb2CO3With B2O3Molar ratio be 1:0.2-1；
B, the solution in step a is added into alkali metal hydroxide LiOH, NaOH or KOH as mineralizer, stirred evenly,
Wherein LiOH, NaOH or KOH and Rb in step a2CO3Molar ratio be 3:0.2；
C, the polytetrafluoroethyllining lining lid for loading mixed solution in step b is screwed, is reloaded into corresponding reaction under high pressure
In kettle, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, is risen to the heating rate of 20-60 DEG C/h of temperature
150-200 DEG C, constant temperature 1-15 days, then rate of temperature fall or cooled to room temperature with 4-50 DEG C/h of temperature；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Solution is placed on clean free of contamination autoclave in step c.
The rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal is preparing times frequency generator, up or down frequency converter or light
Purposes in parametric oscillator.
A kind of rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal of the present invention, the molecular formula of the crystal is Rb9[B4O5
(OH)4]3(CO3)I·7H2O, belongs to hexagonal crystal system, and space group isMolecular weight is 1656.07, and cell parameter isZ=2. its powder SHG effect reaches KDP (KH2PO4)
0.5 times, there is wider transparency range, still have higher transmission in the range of the 319-2600nm of UV, visible light region.The crystalline substance
Body is prepared simply, and growth cycle is short, and used starting material toxicity is low small to human body murder by poisoning.
Method used in the present invention is hydro-thermal method, i.e., after starting material is mixed in proportion, leads in certain temperature range
The reaction kettle high temperature reaction under high pressure of sealing is crossed, transparent rubidium boron carbon oxygen iodine can obtain by the method for program cooling or constant temperature
Hydrogen nonlinear optical crystal.
It is that several can typically obtain Rb below9[B4O5(OH)4]3(CO3)I·7H2The chemical equation of O compounds：
(1)3Rb2CO3+2H3BO3+0.2LiOH+0.5PbI2→Rb9[B4O5(OH)4]3(CO3)I·7H2O+Li++Pb2++
H2O
(2)3Rb2CO3+4H3BO3+0.2NaOH+0.5PbI2→Rb9[B4O5(OH)4]3(CO3)I·7H2O+Na++Pb2++
H2O(3)3Rb2CO3+6H3BO3+0.2KOH+PbI2→Rb9[B4O5(OH)4]3(CO3)I·7H2O+K++Pb2++H2O
(4)3Rb2CO3+B2O3+0.2KOH+0.5KI→Rb9[B4O5(OH)4]3(CO3)I·7H2O+K++H2O
(5)3Rb2CO3+2B2O3+0.2KOH+1.5KI→Rb9[B4O5(OH)4]3(CO3)I·7H2O+K++H2O
(6)3Rb2CO3+4H3BO3+0.2NaOH+HI→Rb9[B4O5(OH)4]3(CO3)I·7H2O+Na++H2O
(7)3Rb2CO3+3B2O3+0.2NaOH+HI→Rb9[B4O5(OH)4]3(CO3)I·7H2O+Na++H2O
Raw material is to use commercially available reagent in the present invention, and the crystal obtained by method of the present invention is transparent, has
Easy to operate, the speed of growth is fast, and growth cycle is short, the advantages such as cost is low.
Rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal prepared by the present invention, which is used as, prepares device for non-linear optical, including makes
Times frequency generator, up or down frequency converter and optical parametric oscillator.Described uses rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal
The nonlinear device of making, which includes, will transmit through the phase that at least at least a branch of frequency of a branch of incident fundamental wave generation is different from incident light
Dry light.
The rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal is to optical manufacturing precision without particular/special requirement.
Brief description of the drawings
Fig. 1 is the X-ray diffracting spectrum of the present invention；
Fig. 2 is crystal pattern of the present invention；
Fig. 3 is the fundamental diagram for the device for non-linear optical that the present invention makes, and is laser including (1), (2) are
Convex lens, (3) are rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal, and (4) are Amici prism, and (5) are filter plate, and ω is refraction light
Frequency be equal to 3 times of incident light frequency or incident light frequency.
Embodiment
Below in conjunction with drawings and examples, the present invention is described in detail：
Embodiment 1：
With chemical equation 3Rb2CO3+2H3BO3+0.2LiOH+0.5PbI2→Rb9[B4O5(OH)4]3(CO3)I·7H2O+
Li++Pb2++H2O prepares crystal, and concrete operation step is as follows：
A, by Rb2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 25mL, adds H3BO3With
PbI2, deionized water 5mL is added, it is sufficiently mixed uniformly, wherein Rb2CO3, H3BO3With PbI2Molar ratio is 3:2:0.5；
B, the solution in step a is added into mineralizer LiOH, stirred evenly, Rb in wherein LiOH and step a2CO3Mole
Than for 3:0.2；
C, and then it is loaded into the polytetrafluoroethyllining lining lids of step b mixed solutions and screws, loads clean free of contamination height
Press in reaction kettle, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 120 is risen to the heating rate of 20 DEG C/h of temperature
DEG C, constant temperature 1 day, then be cooled to room temperature with the rate of temperature fall of 4 DEG C/h of temperature；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Embodiment 2：
With chemical equation 3Rb2CO3+4H3BO3+0.2NaOH+0.5PbI2→Rb9[B4O5(OH)4]3(CO3)I·7H2O+
Na++Pb2++H2O prepares crystal：
A, by Rb2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 25mL, adds H3BO3With
PbI2, deionized water 5mL is added, it is sufficiently mixed uniformly, wherein Rb2CO3, H3BO3With PbI2Molar ratio is 3:4:0.5；
B, the solution in step a is added into mineralizer NaOH, stirred evenly, Rb in wherein NaOH and step a2CO3Mole
Than for 3:0.2；
C, and then it is loaded into the polytetrafluoroethyllining lining lids of step b mixed solutions and screws, loads clean free of contamination height
Press in reaction kettle, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 150 is risen to the heating rate of 30 DEG C/h of temperature
DEG C, constant temperature 5 days, cooled to room temperature；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Embodiment 3：
With chemical equation 3Rb2CO3+6H3BO3+0.2KOH+PbI2→Rb9[B4O5(OH)4]3(CO3)I·7H2O+K++Pb2 ++H2O prepares crystal：
A, by Rb2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 50mL, adds H3BO3With
PbI2, deionized water 25mL is added, it is sufficiently mixed uniformly, wherein Rb2CO3, H3BO3With PbI2Molar ratio is 3:6:1；
B, the solution in step a is added into KOH and is used as mineralizer, Rb in wherein KOH and step a2CO3Molar ratio be 3:
0.2；
C, and then it is loaded into the polytetrafluoroethyllining lining lids of step b mixed solutions and screws, loads clean free of contamination height
Press in reaction kettle, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 140 is risen to the heating rate of 35 DEG C/h of temperature
DEG C, constant temperature 8 days, then be cooled to room temperature with the rate of temperature fall of 15 DEG C/h of temperature；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Embodiment 4：
With chemical equation 3Rb2CO3+B2O3+0.2KOH+0.5KI→Rb9[B4O5(OH)4]3(CO3)I·7H2O+K++H2O
Prepare crystal：
A, by Rb2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 75mL, adds B2O3And KI,
Deionized water 35mL is added, it is sufficiently mixed uniformly, wherein Rb2CO3, B2O3It is 3 with KI molar ratios:1:0.5；
B, the solution in step a is added into KOH mineralizers, stirred evenly, Rb in wherein KOH and step a2CO3Molar ratio
For 3:0.2；
C, and then it is loaded into the polytetrafluoroethyllining lining lid of mixed solution in step b and screws, loads clean free of contamination
In autoclave, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 180 is risen to the heating rate of 30 DEG C/h of temperature
DEG C, constant temperature 5 days, then room temperature is down to the rate of temperature fall of 20 DEG C/h of temperature；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Embodiment 5：
With chemical equation 3Rb2CO3+2B2O3+0.2KOH+1.5KI→Rb9[B4O5(OH)4]3(CO3)I·7H2O+K++
H2O prepares crystal：
A, by Rb2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 100mL, adds B2O3With
KI, adds deionized water 50mL, it is sufficiently mixed uniformly, wherein Rb2CO3, B2O3Molar ratio with KI is 3:2:1.5；
B, the solution in step a is added into mineralizer LiOH, stirred evenly, Rb in wherein LiOH and step a2CO3Mole
Than for 3:0.2；
C, and then it is loaded into the polytetrafluoroethyllining lining lids of step b mixed solutions and screws, loads clean free of contamination height
Press in reaction kettle, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 180 is risen to the heating rate of temperature 50 C/h
DEG C, constant temperature 10 days, cooled to room temperature；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Embodiment 6：
With chemical equation 3Rb2CO3+4H3BO3+0.2NaOH+HI→Rb9[B4O5(OH)4]3(CO3)I·7H2OO+Na++
H2O prepares crystal：
A, by Rb2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 85mL, adds H3BO3And matter
The hydroiodic acid 1.5mL that fraction is 45% is measured, deionized water 45mL is added, it is sufficiently mixed uniformly, wherein Rb2CO3With
H3BO3Molar ratio is 3:4；
B, the solution in step a is added into mineralizer NaOH, stirred evenly, Rb in wherein NaOH and step a2CO3Mole
Than for 3:0.2；
C, and then it is loaded into the polytetrafluoroethyllining lining lids of step b mixed solutions and screws, loads clean free of contamination height
Press in reaction kettle, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 170 is risen to the heating rate of temperature 50 C/h
DEG C, constant temperature 12 days, then be cooled to room temperature with the rate of temperature fall of temperature 45 C/h；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Embodiment 7：
With chemical equation 3Rb2CO3+3B2O3+0.2NaOH+HI→Rb9[B4O5(OH)4]3(CO3)I·7H2O+Na++H2O
Prepare crystal：
A, by Rb2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 25mL, adds B2O3And matter
The hydroiodic acid 0.5mL that fraction is 45% is measured, deionized water 5mL is added, it is sufficiently mixed uniformly, wherein Rb2CO3With B2O3
Molar ratio is 3:3；
B, the solution in step a is added into mineralizer NaOH, stirred evenly, Rb in wherein NaOH and step a2CO3Mole
Than for 3:0.2；
C, and then it is loaded into the polytetrafluoroethyllining lining lids of step b mixed solutions and screws, loads clean free of contamination height
Press in reaction kettle, reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 200 is risen to the heating rate of temperature 60 C/h
DEG C, constant temperature 15 days, then be cooled to room temperature with the rate of temperature fall of temperature 50 C/h；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
Embodiment 8
By any one crystal of gained in embodiment 1-7, it is placed in as shown in attached drawing 3 on 3 position, at room temperature,
With tune Q Nd:Light source is made in the 1064nm outputs of YAG laser, it was observed that obvious 532nm frequency doubling green lights output, output intensity is about
For 0.5 times of equal conditions KDP；
Fig. 3 is shown, by adjusting Q Nd:YAG laser 1 sends the infrared beam that wavelength is 1064nm and is penetrated through convex lens 2
Enter rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal, generation wavelength is the green frequency doubled light of 532nm, and outgoing beam 4 is containing wavelength
The infrared light of 1064nm and the green light of 532nm, obtain the frequency doubled light that wavelength is 532nm after filtered 5 elimination.
Claims (5)
1. a kind of compound rubidium boron carbon oxygen iodine hydrogen, it is characterised in that the chemical formula of the compound is Rb9[B4O5(OH)4]3(CO3)I•
7H2O, molecular weight 1656.07, is prepared using hydro-thermal method, and products therefrom is crystal.
2. a kind of compound rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal, it is characterised in that the molecular formula of the crystal is Rb9[B4O5
(OH)4]3(CO3)I•7H2O, molecular weight 1656.07, belongs to hexagonal crystal system, space group P2c, cell parameter for a=
11.451 (3), b=11.451 (3), c=17.476 (7), Z=2.
3. the preparation method of compound rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal according to claim 2, its feature exist
In preparing crystal using hydro-thermal method, concrete operations follow these steps to carry out：
A, it is Rb that will contain rubidium compound2CO3It is added in the polytetrafluoroethyllining lining for the autoclave that volume is 25-100mL,
Addition boron-containing compound is H3BO3Or B2O3, add the compound PbI containing iodine2, HI that KI or mass fraction are 45%, finally
Deionized water 5-50 mL are added, it is sufficiently mixed uniformly, wherein raw material Rb2CO3With H3BO3In BO3 3-Molar ratio be 1:
0.5-2, raw material Rb2CO3With B2O3Molar ratio be 1:0.2-1；
B, the solution in step a is added into alkali metal hydroxide LiOH, NaOH or KOH as mineralizer, stirred evenly, wherein
LiOH, NaOH or KOH and Rb in step a2CO3Molar ratio be 3:0.2；
C, the polytetrafluoroethyllining lining lid for loading mixed solution in step b is screwed, is reloaded into corresponding autoclave,
Reaction kettle piston is screwed；
D, the autoclave in step c is placed in insulating box, 150-200 DEG C is risen to the heating rate of 20-60 DEG C/h,
Constant temperature 1-15 days, then rate of temperature fall or cooled to room temperature with 4-50 DEG C/h；
E, autoclave is opened, the solution containing crystal is filtered, you can obtain rubidium boron carbon oxygen iodine hydrogen transparent crystal.
4. according to the method described in claim 3, it is characterized in that solution is placed on clean free of contamination reaction under high pressure in step c
Kettle.
5. rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal according to claim 2 is preparing times frequency generator, up or down frequency
Purposes in rate converter or optical parametric oscillator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510233452.9A CN106192002B (en) | 2015-05-09 | 2015-05-09 | Rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation method and purposes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510233452.9A CN106192002B (en) | 2015-05-09 | 2015-05-09 | Rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation method and purposes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106192002A CN106192002A (en) | 2016-12-07 |
| CN106192002B true CN106192002B (en) | 2018-05-11 |
Family
ID=57460032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510233452.9A Active CN106192002B (en) | 2015-05-09 | 2015-05-09 | Rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation method and purposes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106192002B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109112612A (en) * | 2018-09-21 | 2019-01-01 | 中国科学院新疆理化技术研究所 | Compound potassium boron carbon oxygen chlorine hydrogen and potassium boron carbon oxygen chlorine hydrogen nonlinear optical crystal and preparation method and purposes |
| CN109183154A (en) * | 2018-09-21 | 2019-01-11 | 中国科学院新疆理化技术研究所 | Compound potassium boron carbon oxygen bromine hydrogen and potassium boron carbon oxygen bromine hydrogen nonlinear optical crystal and preparation method and purposes |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106917141A (en) * | 2017-03-29 | 2017-07-04 | 中国科学院新疆理化技术研究所 | Compound strontium boron oxygen hydrogen and strontium boron oxygen hydrogen nonlinear optical crystal and preparation method and purposes |
| CN113981534B (en) * | 2021-10-27 | 2023-07-21 | 上海应用技术大学 | Sodium rubidium carbon nitrogen oxygen chlorine hexahydrate birefringent optical crystal, and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225952A (en) * | 1998-02-11 | 1999-08-18 | 中国科学院福建物质结构研究所 | Non-linear optical crystal Ba2Be2B2O7 |
| CN101702069A (en) * | 2009-11-19 | 2010-05-05 | 中国科学院新疆理化技术研究所 | Strontium rubidium tartrate tetrahydrate compound nonlinear optical crystal as well as preparation method and application thereof |
| CN105668577A (en) * | 2016-01-11 | 2016-06-15 | 中国科学院福建物质结构研究所 | K3Ba3Li2Al4B6O20F compound, K3Ba3Li2Al4B6O20F nonlinear optical crystal, preparation method and application thereof |
-
2015
- 2015-05-09 CN CN201510233452.9A patent/CN106192002B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225952A (en) * | 1998-02-11 | 1999-08-18 | 中国科学院福建物质结构研究所 | Non-linear optical crystal Ba2Be2B2O7 |
| CN101702069A (en) * | 2009-11-19 | 2010-05-05 | 中国科学院新疆理化技术研究所 | Strontium rubidium tartrate tetrahydrate compound nonlinear optical crystal as well as preparation method and application thereof |
| CN105668577A (en) * | 2016-01-11 | 2016-06-15 | 中国科学院福建物质结构研究所 | K3Ba3Li2Al4B6O20F compound, K3Ba3Li2Al4B6O20F nonlinear optical crystal, preparation method and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109112612A (en) * | 2018-09-21 | 2019-01-01 | 中国科学院新疆理化技术研究所 | Compound potassium boron carbon oxygen chlorine hydrogen and potassium boron carbon oxygen chlorine hydrogen nonlinear optical crystal and preparation method and purposes |
| CN109183154A (en) * | 2018-09-21 | 2019-01-11 | 中国科学院新疆理化技术研究所 | Compound potassium boron carbon oxygen bromine hydrogen and potassium boron carbon oxygen bromine hydrogen nonlinear optical crystal and preparation method and purposes |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106192002A (en) | 2016-12-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103696006B (en) | It is hydrated hydroxyl strontium borate and hydration hydroxyl strontium borate nonlinear optical crystal and preparation method and purposes | |
| CN101545141B (en) | Gallium and barium sulfide monocrystal as well as growing method and infrared nonlinear optical device thereof | |
| CN101514479B (en) | Large size hydrate potassium borate nonlinear optical crystal, preparation and use thereof | |
| CN106192002B (en) | Rubidium boron carbon oxygen iodine hydrogen and rubidium boron carbon oxygen iodine hydrogen nonlinear optical crystal and preparation method and purposes | |
| CN103114334B (en) | Compound tetrahydroxy barium borate and tetrahydroxy barium borate nonlinear optical crystal as well as preparation method and application | |
| US20160145769A1 (en) | Deep ultraviolet non-linear optical crystal of barium borate hydrate, preparation method therefor and use thereof | |
| CN103031607A (en) | Infrared nonlinear optical crystal AB4C5Se12 | |
| CN103205811B (en) | Large size chlorine barium fluoborate non-linear optic crystal and its production and use | |
| CN104562196A (en) | Compound lead borate hydrate nonlinear optical crystal and preparation method and use thereof | |
| CN105133012B (en) | It is hydrated the preparation method and purposes of lithium borate nonlinear optical crystal | |
| CN106011994B (en) | The nonlinear optics fluorine boron potassium phosphate crystal of dark purple outskirt and preparation method and application | |
| CN101603203A (en) | Lithium metaborate octo-hydrate nonlinear optical crystal and its production and use | |
| CN101591809B (en) | Large-size hydrated sodium borate non-linear optical crystal, preparation method and application thereof | |
| CN102071465B (en) | Large-dimension non-linear optical crystal hydrated potassium borate, and preparation method and application thereof | |
| CN110129876B (en) | Compound lead boron oxygen iodine and lead boron oxygen iodine nonlinear optical crystal, preparation method and application | |
| CN112746327B (en) | Compound barium tellurium fluorine hydroxyl and barium tellurium fluorine hydroxyl nonlinear optical crystal, preparation method and application | |
| CN103088424B (en) | Compound sodium borate monohydrate nonlinear optical crystal, and preparation method and application thereof | |
| CN101984149A (en) | Method for preparing large chlorine barium borate nonlinear optic crystal and application thereof | |
| CN104562208A (en) | Compound mono-boric dihydroxyl calcium decaborate monohydrate nonlinear optical crystal and preparation method and use thereof | |
| CN109183154A (en) | Compound potassium boron carbon oxygen bromine hydrogen and potassium boron carbon oxygen bromine hydrogen nonlinear optical crystal and preparation method and purposes | |
| CN109112612A (en) | Compound potassium boron carbon oxygen chlorine hydrogen and potassium boron carbon oxygen chlorine hydrogen nonlinear optical crystal and preparation method and purposes | |
| CN102650075B (en) | Non-linear optical crystal cadmium fluoroborate | |
| CN106917141A (en) | Compound strontium boron oxygen hydrogen and strontium boron oxygen hydrogen nonlinear optical crystal and preparation method and purposes | |
| CN105316764B (en) | One water monohydroxy of compound, five line borate nonlinear optical crystal and preparation method and purposes | |
| CN104514033B (en) | A kind of method that microwave hydrothermal prepares lead fluoborate monocrystalline |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |