CN106191667B - A kind of preparation method of high-quality mechanical performance stamping parts material - Google Patents

A kind of preparation method of high-quality mechanical performance stamping parts material Download PDF

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Publication number
CN106191667B
CN106191667B CN201610530412.5A CN201610530412A CN106191667B CN 106191667 B CN106191667 B CN 106191667B CN 201610530412 A CN201610530412 A CN 201610530412A CN 106191667 B CN106191667 B CN 106191667B
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steel
stamping parts
melting
warming
preparation
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CN106191667A (en
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余昌国
李克顺
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Anhui Hongqiao Metal Manufacturing Co Ltd
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Anhui Hongqiao Metal Manufacturing Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

The invention discloses a kind of preparation method of high-quality mechanical performance stamping parts material, it is made up of following raw material:Aluminum oxide, silica, calcium oxide, cupric oxide, ferromanganese, chromium steel, molybdenum steel, nickel steel, borax, steel scrap, each element mass percent is after the raw material melting:Aluminium 0.2 1%, silicon 0.12 0.8%, calcium 0.15 0.47%, copper 0.05 0.18%, manganese 0.9 2%, chromium 0.6 1.8%, molybdenum 0.8 1.5%, nickel 0.5 1.2%, carbon 0.1 0.5%, phosphorus 0.01 0.04%, sulphur 0.01 0.05%, boron 0.01 0.04%, remaining is iron and inevitable impurity.Its preparation method is included ordinary scrap steel melting, adds cupric oxide etc. after molten steel is melting down and is warming up to 1,490 1520 DEG C and is changed into liquid molten steel, is cooled and shaped and clears up after burr and is warming up to 900 950 DEG C of progress Quenching Treatments, then is cooled to room temperature after being warming up to 600 DEG C.Stamping parts material of the present invention and preparation method are easily achieved, and can be greatly improved the yield rate of stamping parts material, be had broad application prospects.

Description

A kind of preparation method of high-quality mechanical performance stamping parts material
Technical field
The present invention relates to stamping parts technical field of material, and in particular to a kind of high-quality mechanical performance stamping parts material Preparation method.
Background technology
Punching press is that depended on pressure machine and mould apply external force to sheet material, band, tubing and section bar etc., is allowed to produce plastic deformation Or separation, so that the forming and machining method of the workpiece of shape and size needed for obtaining.Stamping parts material is in mechanical industry production In extremely important status, such as in automobile manufacturing process by 60%-70% metallic element need punch process into Type.And the mechanical performance of stamping parts material in itself, such as hardness, ductility etc. will determine whether it can expire after the completion of punching press Sufficient product is used and technical performance.
During plate heat treatment, the martensitic phase intensity obtained after quenching is higher, can effectively promote heat to add The hardness of work backlash laminate materia is substantially improved.However, excessive high hardness easily increases the fragility of stamping parts, in punching course Easily there is local micro-crack, greatly reduce the yield rate and service life of stamping parts;Opposite, if obtaining softer iron Ferritic phase, although reduce the hardness and fragility of material body, but excessively excellent ductility can cause material to be easy in punching Plastic deformation is produced at compression mould cutting edge, and then causes stamping parts edge to produce excessive excessive overlap and burr so that punching press Part can not meet use requirement.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of preparation method of high-quality mechanical performance stamping parts material.
To achieve the above object, the present invention is achieved through the following technical solutions:
A kind of high-quality mechanical performance stamping parts material, is made up of following raw material:Aluminum oxide, silica, calcium oxide, oxidation Copper, ferromanganese, chromium steel, molybdenum steel, nickel steel, borax, steel scrap, each element mass percent is after the raw material melting:Aluminium 0.2-1%, Silicon 0.12-0.8%, calcium 0.15-0.47%, copper 0.05-0.18%, manganese 0.9-2%, chromium 0.6-1.8%, molybdenum 0.8-1.5%, nickel 0.5-1.2%, carbon 0.1-0.5%, phosphorus 0.01-0.04%, sulphur 0.01-0.05%, boron 0.01-0.04%, remaining is for iron and not Evitable impurity.
It is preferred that, each element mass percent is after the raw material melting:Aluminium 0.6%, silicon 0.55%, calcium 0.24%, copper 0.09%th, manganese 1.6%, chromium 1.1%, molybdenum 0.9%, nickel 1%, carbon 0.16%, phosphorus 0.02%, sulphur 0.01%, boron 0.03%, remaining For iron and inevitable impurity.
Preparation process is as follows:
1) by ordinary scrap steel melting, cupric oxide, chromium steel, molybdenum steel, nickel steel, borax is added after molten steel is melting down, 1490- is warming up to 1520 DEG C are changed into liquid molten steel, go out to add for 10 minutes before molten steel aluminum oxide, silica, calcium oxide, ferromanganese progress precipitation desoxydation, Adjusting component makes each element composition meet the mass fraction requirement of chemical composition in above-mentioned high-quality stamping parts material, skims, cast Shaping, pouring temperature is 1340-1390 DEG C, is cooled to room temperature, and cleaning burr obtains casting;
2) by step 1) medium casting is warming up to 900-950 DEG C of insulation makes within 30-60 minutes microstructure homogenization, then with 200-300 DEG C/min is quickly cooled to room temperature, obtain quenching casting.
3) by step 2) in quenching casting be warming up to 600 DEG C again, be incubated 10 minutes, be air-cooled to room temperature.
It is preferred that, the step 1) in ordinary scrap steel melting, molten steel it is melting down after add cupric oxide, chromium steel, molybdenum steel, nickel steel, Borax, is warming up to 1500 DEG C and is changed into liquid molten steel, the pouring temperature is 1350 DEG C.
It is preferred that, the step 2) medium casting is warming up to 935 DEG C, is incubated 45 minutes.
It is preferred that, the step 2) in cooling velocity be 280 DEG C/min.
The invention provides a kind of preparation method of high-quality mechanical performance stamping parts material, its advantage is:The present invention Feed components Combination preferably, when material body is warming up to 935 DEG C, mainly exists in material with austenite, due to nickel, molybdenum Incorporation effectively increases the stability of austenite, hinders the precipitation of carbide, then with the fast quickly cooling of 280 DEG C/min cooldown rate When but, also cause a part of carbide because cooling velocity is too fast and can not separate out in time, and then form the martensite of high rigidity Phase;Another part carbon separates out to form the soft phase of ferrite, and chromium can be solid-solution in ferrite to play and stablize ferritic work With.The present invention is combined using the soft phase of ferrite mutually coordinated and high hard martensitic phase, needed for both having ensure that stamping parts material Hardness, also obtained preferable plasticity.Stamping parts material of the present invention and preparation method are easily achieved, and can be greatly improved The yield rate of stamping parts material, has broad application prospects.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the implementation of the present invention Example, the technical scheme in the embodiment of the present invention is clearly and completely described.Based on the embodiment in the present invention, this area The every other embodiment that those of ordinary skill is obtained under the premise of creative work is not made, belongs to protection of the present invention Scope.
Embodiment 1:
A kind of high-quality mechanical performance stamping parts material, is made up of following raw material:Aluminum oxide, silica, calcium oxide, oxidation Copper, ferromanganese, chromium steel, molybdenum steel, nickel steel, borax, steel scrap, each element mass percent is after the raw material melting:Aluminium 0.6%, silicon 0.55%th, calcium 0.24%, copper 0.09%, manganese 1.6%, chromium 1.1%, molybdenum 0.9%, nickel 1%, carbon 0.16%, phosphorus 0.02%, sulphur 0.01%th, boron 0.03%, remaining is iron and inevitable impurity.
Preparation process is as follows:
1) by ordinary scrap steel melting, cupric oxide, chromium steel, molybdenum steel, nickel steel, borax is added after molten steel is melting down, 1500 are warming up to DEG C it is changed into liquid molten steel, goes out to add for 10 minutes before molten steel aluminum oxide, silica, calcium oxide, ferromanganese and carry out precipitation desoxydation, adjustment Composition makes each element composition meet the mass fraction requirement of chemical composition in above-mentioned high-quality stamping parts material, skims, moulding by casting, Pouring temperature is 1350 DEG C, is cooled to room temperature, and cleaning burr obtains casting;
2) by step 1) medium casting is warming up to 935 DEG C of insulations makes within 45 minutes microstructure homogenization, then with the fast quickly coolings of 280 DEG C/min But to room temperature, obtain quenching casting.
3) by step 2) in quenching casting be warming up to 600 DEG C again, be incubated 10 minutes, be air-cooled to room temperature.
Embodiment 2:
A kind of high-quality mechanical performance stamping parts material, is made up of following raw material:Aluminum oxide, silica, calcium oxide, oxidation Copper, ferromanganese, chromium steel, molybdenum steel, nickel steel, borax, steel scrap, each element mass percent is after the raw material melting:Aluminium 0.4%, silicon 0.8%th, calcium 0.15%, copper 0.1%, manganese 2%, chromium 0.6%, molybdenum 1.2%, nickel 0.5%, carbon 0.12%, phosphorus 0.01%, sulphur 0.01%th, boron 0.02%, remaining is iron and inevitable impurity.
Preparation process is as follows:
1) by ordinary scrap steel melting, cupric oxide, chromium steel, molybdenum steel, nickel steel, borax is added after molten steel is melting down, 1490 are warming up to DEG C it is changed into liquid molten steel, goes out to add for 10 minutes before molten steel aluminum oxide, silica, calcium oxide, ferromanganese and carry out precipitation desoxydation, adjustment Composition makes each element composition meet the mass fraction requirement of chemical composition in above-mentioned high-quality stamping parts material, skims, moulding by casting, Pouring temperature is 1390 DEG C, is cooled to room temperature, and cleaning burr obtains casting;
2) by step 1) medium casting is warming up to 900 DEG C of insulations makes within 40 minutes microstructure homogenization, then with the fast quickly coolings of 220 DEG C/min But to room temperature, obtain quenching casting.
3) by step 2) in quenching casting be warming up to 600 DEG C again, be incubated 10 minutes, be air-cooled to room temperature.
Embodiment 3:
A kind of high-quality mechanical performance stamping parts material, is made up of following raw material:Aluminum oxide, silica, calcium oxide, oxidation Copper, ferromanganese, chromium steel, molybdenum steel, nickel steel, borax, steel scrap, each element mass percent is after the raw material melting:Aluminium 0.2%, silicon 0.5%th, calcium 0.47%, copper 0.11%, manganese 1.45%, chromium 1.8%, molybdenum 1.5%, nickel 0.85%, carbon 0.2%, phosphorus 0.02%, sulphur 0.01%th, boron 0.04%, remaining is iron and inevitable impurity.
Preparation process is as follows:
1) by ordinary scrap steel melting, cupric oxide, chromium steel, molybdenum steel, nickel steel, borax is added after molten steel is melting down, 1520 are warming up to DEG C it is changed into liquid molten steel, goes out to add for 10 minutes before molten steel aluminum oxide, silica, calcium oxide, ferromanganese and carry out precipitation desoxydation, adjustment Composition makes each element composition meet the mass fraction requirement of chemical composition in above-mentioned high-quality stamping parts material, skims, moulding by casting, Pouring temperature is 1340 DEG C, is cooled to room temperature, and cleaning burr obtains casting;
2) by step 1) medium casting is warming up to 940 DEG C of insulations makes within 30 minutes microstructure homogenization, then with the fast quickly coolings of 250 DEG C/min But to room temperature, obtain quenching casting.
3) by step 2) in quenching casting be warming up to 600 DEG C again, be incubated 10 minutes, be air-cooled to room temperature.
Embodiment 4:
A kind of high-quality mechanical performance stamping parts material, is made up of following raw material:Aluminum oxide, silica, calcium oxide, oxidation Copper, ferromanganese, chromium steel, molybdenum steel, nickel steel, borax, steel scrap, each element mass percent is after the raw material melting:Aluminium 1%, silicon 0.8%th, calcium 0.16%, copper 0.05%, manganese 0.9%, chromium 1.2%, molybdenum 0.9%, nickel 1.1%, carbon 0.13%, phosphorus 0.03%, sulphur 0.01%th, boron 0.01%, remaining is iron and inevitable impurity.
Preparation process is as follows:
1) by ordinary scrap steel melting, cupric oxide, chromium steel, molybdenum steel, nickel steel, borax is added after molten steel is melting down, 1510 are warming up to DEG C it is changed into liquid molten steel, goes out to add for 10 minutes before molten steel aluminum oxide, silica, calcium oxide, ferromanganese and carry out precipitation desoxydation, adjustment Composition makes each element composition meet the mass fraction requirement of chemical composition in above-mentioned high-quality stamping parts material, skims, moulding by casting, Pouring temperature is 1360 DEG C, is cooled to room temperature, and cleaning burr obtains casting;
2) by step 1) medium casting is warming up to 920 DEG C of insulations makes within 60 minutes microstructure homogenization, then with the fast quickly coolings of 270 DEG C/min But to room temperature, obtain quenching casting.
3) by step 2) in quenching casting be warming up to 600 DEG C again, be incubated 10 minutes, be air-cooled to room temperature.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (3)

1. a kind of preparation method of high-quality mechanical performance stamping parts material, it is characterised in that be made up of following raw material:Aluminum oxide, Silica, calcium oxide, cupric oxide, ferromanganese, chromium steel, molybdenum steel, nickel steel, borax, steel scrap, each element quality after the raw material melting Percentage is:Aluminium 0.2-1%, silicon 0.12-0.8%, calcium 0.15-0.47%, copper 0.05-0.18%, manganese 0.9-2%, chromium 0.6- 1.8%th, molybdenum 0.8-1.5%, nickel 0.5-1.2%, carbon 0.1-0.5%, phosphorus 0.01-0.04%, sulphur 0.01-0.05%, boron 0.01- 0.04%, remaining is iron and inevitable impurity;
Its preparation method comprises the following steps:
1) by ordinary scrap steel melting, cupric oxide, chromium steel, molybdenum steel, nickel steel, borax is added after molten steel is melting down, 1490-1520 is warming up to DEG C it is changed into liquid molten steel, goes out to add for 10 minutes before molten steel aluminum oxide, silica, calcium oxide, ferromanganese and carry out precipitation desoxydation, adjustment Composition makes each element composition meet the mass fraction requirement of chemical composition in above-mentioned high-quality stamping parts material, skims, moulding by casting, Pouring temperature is 1340-1390 DEG C, is cooled to room temperature, and cleaning burr obtains casting;
2) by step 1) medium casting is warming up to 935 DEG C of insulations makes within 45 minutes microstructure homogenization, then be quickly cooled to 280 DEG C/min Room temperature, obtains quenching casting;
3) by step 2) in quenching casting be warming up to 600 DEG C again, be incubated 10 minutes, be air-cooled to room temperature.
2. the preparation method of high-quality mechanical performance stamping parts material according to claim 1, it is characterised in that the raw material Each element mass percent is after melting:Aluminium 0.6%, silicon 0.55%, calcium 0.24%, copper 0.09%, manganese 1.6%, chromium 1.1%, Molybdenum 0.9%, nickel 1%, carbon 0.16%, phosphorus 0.02%, sulphur 0.01%, boron 0.03%, remaining is iron and inevitable impurity.
3. the preparation method of high-quality mechanical performance stamping parts material according to claim 1, it is characterised in that:The step 1) ordinary scrap steel melting in, adds cupric oxide, chromium steel, molybdenum steel, nickel steel, borax after molten steel is melting down, is warming up to 1500 DEG C and is changed into liquid State molten steel, the pouring temperature is 1350 DEG C.
CN201610530412.5A 2016-07-06 2016-07-06 A kind of preparation method of high-quality mechanical performance stamping parts material Active CN106191667B (en)

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Denomination of invention: A kind of preparation method of high-quality mechanical properties stamping material

Effective date of registration: 20220825

Granted publication date: 20171020

Pledgee: China Postal Savings Bank Limited by Share Ltd. Ningguo branch

Pledgor: ANHUI HONGQIAO METAL MANUFACTURING Co.,Ltd.

Registration number: Y2022980013601