CN106191521A - Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof - Google Patents

Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof Download PDF

Info

Publication number
CN106191521A
CN106191521A CN201610753897.4A CN201610753897A CN106191521A CN 106191521 A CN106191521 A CN 106191521A CN 201610753897 A CN201610753897 A CN 201610753897A CN 106191521 A CN106191521 A CN 106191521A
Authority
CN
China
Prior art keywords
parts
copper
environmental protection
alloy wire
copper alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610753897.4A
Other languages
Chinese (zh)
Inventor
吴明辉
甘昌军
李丽兴
谢道金
狄风雨
孙强
黄景彪
蒋云才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHU CHUANGJIANG ALLOY COPPER CO Ltd
Original Assignee
WUHU CHUANGJIANG ALLOY COPPER CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHU CHUANGJIANG ALLOY COPPER CO Ltd filed Critical WUHU CHUANGJIANG ALLOY COPPER CO Ltd
Priority to CN201610753897.4A priority Critical patent/CN106191521A/en
Publication of CN106191521A publication Critical patent/CN106191521A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B22D11/004Copper alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/005Continuous casting of metals, i.e. casting in indefinite lengths of wire
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/045Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for horizontal casting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/06Alloys based on copper with nickel or cobalt as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon

Abstract

The invention discloses copper alloy wire that a kind of environmental protection easily processes and preparation method thereof, the raw material of following weight portion be prepared from: copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.The preparation method of wire rod of the present invention uses horizontal casting; compared with the most commonly used vacuum melting technology; the method lumber recovery of the present invention is high, and process equipment is simple, invests little; technological process is short; production efficiency is high, and the most excellent wire product preparation process of availability is few, produces equipment simple; it is prone to prepare satisfactory product, and is easily achieved scale and automated production.

Description

Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof
Technical field
The present invention relates to copper alloy wire manufacture field, be specifically related to copper alloy wire and system thereof that a kind of environmental protection is easily processed Preparation Method.
Background technology
In high-elasticity copper alloy, beryllium-bronze is the most frequently used elastic alloy, but in its production process, dust is poisonous, cost High, should not work the most at relatively high temperatures, be restricted in many applications.
Adonic is a kind of Copper-Nickel-Aluminium Alloy without beryllium, compared with beryllium copper, its production process is nontoxic, cost relatively Low and there is higher heat stability and elevated temperature strength, it is easy to hot and cold pressure processing, it is easy to welding, the beryllium copper being well recognized as is good Succedaneum.Such alloy timeliness again after cold working, it is possible to obtain the highest intensity, hardness and excellent elastic performance, There is again good corrosion resisting property and antioxygenic property simultaneously, be widely used in manufacturing corrosion resistance structure part, spring and connector etc..
The production technology of the most commonly used adonic wire rod is: use vacuum melting technology to prepare Alloy cast ingot, through large-sized processing equipment pressure processing to bar, recycling drawing technique produces alloy wire, whole production work Process flow is long, and lumber recovery is the highest, and production cost is the highest.
Summary of the invention
For solving the problems referred to above, the invention provides copper alloy wire that a kind of environmental protection easily processes and preparation method thereof.
For achieving the above object, the technical scheme that the present invention takes is:
Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof, is prepared from by the raw material of following weight portion:
Copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, Niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
Further, the preparation method of the copper alloy wire that a kind of environmental protection is easily processed, comprise the steps:
(1) by copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~ 10 parts, niobium 2~6 parts, cerium 5~9 parts are made into the furnace charge meeting component requirements according to described weight portion, put in smelting furnace in temperature It is smelted into copper molten metal at 1000-1500 DEG C, and does on-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, addition heat conduction material 8~14 parts, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
Further, the copper alloy wire that a kind of environmental protection is easily processed, the raw material of following weight portion be prepared from: copper 50~ 70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, niobium 2~6 parts, cerium 5 ~9 parts, heat conduction material 8~14 parts.
Further, the copper alloy wire that a kind of environmental protection is easily processed, the raw material of following weight portion it is prepared from: copper 60 Part, 15 parts of nickel, 8 parts of stannum, 16 parts of zinc, ferrum 4 parts, yttrium 9 parts, 7 parts of aluminum, niobium 5 parts, cerium 6 parts, 10 parts of heat conduction material.
Further, described in state the temperature of Homogenization Treatments in step (4) and be 800-1000 DEG C, the time is 3-5 hour.
Further, in described step (5), the temperature of annealing is 780-990 DEG C, and the time is 0.5 hour, and water-cooled; After processing, the temperature of Ageing Treatment is 200-400 DEG C, and the time is 0.5 hour.
The preparation method of wire rod of the present invention uses horizontal casting, compared with the most commonly used vacuum melting technology, The method lumber recovery of the present invention is high, and process equipment is simple, invests little, and technological process is short, and production efficiency is high, and availability is same Few etc. excellent wire product preparation process, produce equipment simple, it is easy to prepare satisfactory product, and be easily achieved scale Change and automated production.
Detailed description of the invention
In order to make objects and advantages of the present invention clearer, below in conjunction with embodiment, the present invention is carried out the most in detail Explanation.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The present invention is prepared from by the raw material of following weight portion:
Copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, Niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
The preparation method of the copper alloy wire that a kind of environmental protection is easily processed, comprises the steps:
(1) by copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~ 10 parts, niobium 2~6 parts, cerium 5~9 parts are made into the furnace charge meeting component requirements according to described weight portion, put in smelting furnace in temperature It is smelted into copper molten metal at 1000-1500 DEG C, and does on-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, addition heat conduction material 8~14 parts, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
The copper alloy wire that a kind of environmental protection is easily processed, is prepared from by the raw material of following weight portion: copper 50~70 parts, nickel 14 ~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, niobium 2~6 parts, cerium 5~9 parts, lead 8~14 parts of heat material.
Described stating the temperature of Homogenization Treatments in step (4) and be 800-1000 DEG C, the time is 3-5 hour.
In described step (5), the temperature of annealing is 780-990 DEG C, and the time is 0.5 hour, and water-cooled;Time after processing The temperature that effect processes is 200-400 DEG C, and the time is 0.5 hour.
Embodiment 1:
(1) by copper 60 parts, 15 parts of nickel, 8 parts of stannum, 16 parts of zinc, ferrum 4 parts, yttrium 9 parts, 7 parts of aluminum, niobium 5 parts, cerium 6 parts according to described heavy Amount part is made into the furnace charge meeting component requirements, puts in smelting furnace and is smelted into copper molten metal at temperature 1000-1500 DEG C, and does On-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, add 10 parts of heat conduction material, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
Embodiment 2:
(1) by copper 70 parts, 16 parts of nickel, 9 parts of stannum, 19 parts of zinc, ferrum 9 parts, yttrium 5 parts, 10 parts of aluminum, niobium 6 parts, cerium 9 parts according to described heavy Amount part is made into the furnace charge meeting component requirements, puts in smelting furnace and is smelted into copper molten metal at temperature 1500 DEG C, and does stokehold Analyze;
(2) copper molten metal is guided as in conticaster, add 14 parts of heat conduction material, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
Embodiment 3:
(1) by copper 50 parts, 14 parts of nickel, 7 parts of stannum, 11 parts of zinc, ferrum 3 parts, yttrium 5 parts, 6 parts of aluminum, niobium 2 parts, cerium 5 parts according to described heavy Amount part is made into the furnace charge meeting component requirements, puts in smelting furnace and is smelted into copper molten metal at temperature 1000 DEG C, and does stokehold Analyze;
(2) copper molten metal is guided as in conticaster, add 8 parts of heat conduction material, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
The preparation method of wire rod of the present invention uses horizontal casting, compared with the most commonly used vacuum melting technology, The method lumber recovery of the present invention is high, and process equipment is simple, invests little, and technological process is short, and production efficiency is high, and availability is same Few etc. excellent wire product preparation process, produce equipment simple, it is easy to prepare satisfactory product, and be easily achieved scale Change and automated production.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (6)

1. the copper alloy wire that an environmental protection is easily processed, it is characterised in that be prepared from by the raw material of following weight portion:
Copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, Niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
The preparation method of the copper alloy wire that a kind of environmental protection the most according to claim 1 is easily processed, it is characterised in that include Following steps:
(1) by copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~ 10 parts, niobium 2~6 parts, cerium 5~9 parts are made into the furnace charge meeting component requirements according to described weight portion, put in smelting furnace in temperature It is smelted into copper molten metal at 1000-1500 DEG C, and does on-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, addition heat conduction material 8~14 parts, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
The copper alloy wire that a kind of environmental protection the most according to claim 1 is easily processed, it is characterised in that by following weight portion Raw material is prepared from: copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6 ~10 parts, niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
The copper alloy wire that a kind of environmental protection the most according to claim 1 is easily processed, it is characterised in that by following weight portion Raw material is prepared from: copper 60 parts, 15 parts of nickel, 8 parts of stannum, 16 parts of zinc, ferrum 4 parts, yttrium 9 parts, 7 parts of aluminum, niobium 5 parts, cerium 6 parts, heat conduction material 10 parts.
Copper alloy wire that a kind of environmental protection the most according to claim 2 is easily processed and preparation method thereof, it is characterised in that institute Stating the temperature of Homogenization Treatments in step (4) and be 800-1000 DEG C, the time is 3-5 hour.
Copper alloy wire that a kind of environmental protection the most according to claim 2 is easily processed and preparation method thereof, it is characterised in that institute Stating the temperature of annealing in step (5) and be 780-990 DEG C, the time is 0.5 hour, and water-cooled;The temperature of Ageing Treatment after processing Degree is for 200-400 DEG C, and the time is 0.5 hour.
CN201610753897.4A 2016-08-30 2016-08-30 Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof Pending CN106191521A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610753897.4A CN106191521A (en) 2016-08-30 2016-08-30 Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610753897.4A CN106191521A (en) 2016-08-30 2016-08-30 Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106191521A true CN106191521A (en) 2016-12-07

Family

ID=57526466

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610753897.4A Pending CN106191521A (en) 2016-08-30 2016-08-30 Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106191521A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109079112A (en) * 2017-06-14 2018-12-25 罗奕兵 A kind of forming technology of high-tin bronze silk material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109079112A (en) * 2017-06-14 2018-12-25 罗奕兵 A kind of forming technology of high-tin bronze silk material

Similar Documents

Publication Publication Date Title
CN106636734B (en) High-intensitive, highly conductive, high resistance to stress relaxation copper alloy elastic material and preparation method thereof
CN106029930B (en) Copper-alloy stranded conductor and its manufacture method, electric wire for automobiles
CN109266901B (en) Preparation method of Cu15Ni8Sn high-strength wear-resistant alloy rod/wire
CN103382535B (en) A kind of high-strength, high connductivity, deep drawing quality copper alloy and preparation method thereof
CN104313524A (en) TC4-DT titanium alloy rod processing method
CN102312123A (en) Brass alloy
CN102912178A (en) High-strength and high-conductivity rare-earth copper alloy and preparation method thereof
TW201522671A (en) Copper alloy plate, and electronic component for large current applications and electronic component for heat dissipation applications each provided with same
CN106319280B (en) Cu Ti Cr Zr high-performance Copper-Nickel-Aluminium Alloys and its manufacture method
CN105951009A (en) Heat treatment technology for aluminum alloy
CN106191521A (en) Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof
CN104561638B (en) A kind of Al2O3The preparation method of dispersed and strengthened copper-based composite material
CN102383004A (en) Manganiferous lead-free forgeable easy-cutting brass and preparation method thereof
CN103667823B (en) A kind of high intensity aluminum zinc magnesium alloy material and its preparation method and application
CN106337142A (en) Corrosion-resistant friction-resistant cupronickel wire and machining process thereof
CN105132751A (en) Ni-Cr-Al-Fe type high temperature alloy material and preparation method and application thereof
CN103233147A (en) Al-Er-Zr-Si aluminum alloy and heat treatment process
CN106119596A (en) A kind of high performance copper alloy wire of environmental-friendly lead-free and processing technique thereof
CN113106286A (en) High-conductivity beryllium copper alloy bar for 5G communication and preparation process thereof
CN107739876A (en) A kind of polynary low beryllium content copper alloy and preparation method thereof
CN102888528B (en) Graphite-containing packfong alloy easy for cutting and preparation technology thereof
CN106167863B (en) A kind of low beryllium alumin(i)um alloy and preparation method and application
CN102492869B (en) Copper-zirconium-bismuth alloy and its preparation method
CN106591653A (en) Abrasion-resistant alloy material for machining fixtures and preparation method of alloy material
CN108239709B (en) Elastic copper alloy, strip and strip thereof and composite heat treatment method

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20161207