CN106191521A - Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof - Google Patents
Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof Download PDFInfo
- Publication number
- CN106191521A CN106191521A CN201610753897.4A CN201610753897A CN106191521A CN 106191521 A CN106191521 A CN 106191521A CN 201610753897 A CN201610753897 A CN 201610753897A CN 106191521 A CN106191521 A CN 106191521A
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- CN
- China
- Prior art keywords
- parts
- copper
- environmental protection
- alloy wire
- copper alloy
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
- B22D11/004—Copper alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/005—Continuous casting of metals, i.e. casting in indefinite lengths of wire
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/045—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for horizontal casting
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/04—Alloys based on copper with zinc as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/06—Alloys based on copper with nickel or cobalt as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
Abstract
The invention discloses copper alloy wire that a kind of environmental protection easily processes and preparation method thereof, the raw material of following weight portion be prepared from: copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.The preparation method of wire rod of the present invention uses horizontal casting; compared with the most commonly used vacuum melting technology; the method lumber recovery of the present invention is high, and process equipment is simple, invests little; technological process is short; production efficiency is high, and the most excellent wire product preparation process of availability is few, produces equipment simple; it is prone to prepare satisfactory product, and is easily achieved scale and automated production.
Description
Technical field
The present invention relates to copper alloy wire manufacture field, be specifically related to copper alloy wire and system thereof that a kind of environmental protection is easily processed
Preparation Method.
Background technology
In high-elasticity copper alloy, beryllium-bronze is the most frequently used elastic alloy, but in its production process, dust is poisonous, cost
High, should not work the most at relatively high temperatures, be restricted in many applications.
Adonic is a kind of Copper-Nickel-Aluminium Alloy without beryllium, compared with beryllium copper, its production process is nontoxic, cost relatively
Low and there is higher heat stability and elevated temperature strength, it is easy to hot and cold pressure processing, it is easy to welding, the beryllium copper being well recognized as is good
Succedaneum.Such alloy timeliness again after cold working, it is possible to obtain the highest intensity, hardness and excellent elastic performance,
There is again good corrosion resisting property and antioxygenic property simultaneously, be widely used in manufacturing corrosion resistance structure part, spring and connector etc..
The production technology of the most commonly used adonic wire rod is: use vacuum melting technology to prepare
Alloy cast ingot, through large-sized processing equipment pressure processing to bar, recycling drawing technique produces alloy wire, whole production work
Process flow is long, and lumber recovery is the highest, and production cost is the highest.
Summary of the invention
For solving the problems referred to above, the invention provides copper alloy wire that a kind of environmental protection easily processes and preparation method thereof.
For achieving the above object, the technical scheme that the present invention takes is:
Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof, is prepared from by the raw material of following weight portion:
Copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts,
Niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
Further, the preparation method of the copper alloy wire that a kind of environmental protection is easily processed, comprise the steps:
(1) by copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~
10 parts, niobium 2~6 parts, cerium 5~9 parts are made into the furnace charge meeting component requirements according to described weight portion, put in smelting furnace in temperature
It is smelted into copper molten metal at 1000-1500 DEG C, and does on-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, addition heat conduction material 8~14 parts, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally
It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
Further, the copper alloy wire that a kind of environmental protection is easily processed, the raw material of following weight portion be prepared from: copper 50~
70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, niobium 2~6 parts, cerium 5
~9 parts, heat conduction material 8~14 parts.
Further, the copper alloy wire that a kind of environmental protection is easily processed, the raw material of following weight portion it is prepared from: copper 60
Part, 15 parts of nickel, 8 parts of stannum, 16 parts of zinc, ferrum 4 parts, yttrium 9 parts, 7 parts of aluminum, niobium 5 parts, cerium 6 parts, 10 parts of heat conduction material.
Further, described in state the temperature of Homogenization Treatments in step (4) and be 800-1000 DEG C, the time is 3-5 hour.
Further, in described step (5), the temperature of annealing is 780-990 DEG C, and the time is 0.5 hour, and water-cooled;
After processing, the temperature of Ageing Treatment is 200-400 DEG C, and the time is 0.5 hour.
The preparation method of wire rod of the present invention uses horizontal casting, compared with the most commonly used vacuum melting technology,
The method lumber recovery of the present invention is high, and process equipment is simple, invests little, and technological process is short, and production efficiency is high, and availability is same
Few etc. excellent wire product preparation process, produce equipment simple, it is easy to prepare satisfactory product, and be easily achieved scale
Change and automated production.
Detailed description of the invention
In order to make objects and advantages of the present invention clearer, below in conjunction with embodiment, the present invention is carried out the most in detail
Explanation.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The present invention is prepared from by the raw material of following weight portion:
Copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts,
Niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
The preparation method of the copper alloy wire that a kind of environmental protection is easily processed, comprises the steps:
(1) by copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~
10 parts, niobium 2~6 parts, cerium 5~9 parts are made into the furnace charge meeting component requirements according to described weight portion, put in smelting furnace in temperature
It is smelted into copper molten metal at 1000-1500 DEG C, and does on-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, addition heat conduction material 8~14 parts, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally
It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
The copper alloy wire that a kind of environmental protection is easily processed, is prepared from by the raw material of following weight portion: copper 50~70 parts, nickel 14
~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts, niobium 2~6 parts, cerium 5~9 parts, lead
8~14 parts of heat material.
Described stating the temperature of Homogenization Treatments in step (4) and be 800-1000 DEG C, the time is 3-5 hour.
In described step (5), the temperature of annealing is 780-990 DEG C, and the time is 0.5 hour, and water-cooled;Time after processing
The temperature that effect processes is 200-400 DEG C, and the time is 0.5 hour.
Embodiment 1:
(1) by copper 60 parts, 15 parts of nickel, 8 parts of stannum, 16 parts of zinc, ferrum 4 parts, yttrium 9 parts, 7 parts of aluminum, niobium 5 parts, cerium 6 parts according to described heavy
Amount part is made into the furnace charge meeting component requirements, puts in smelting furnace and is smelted into copper molten metal at temperature 1000-1500 DEG C, and does
On-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, add 10 parts of heat conduction material, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally
It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
Embodiment 2:
(1) by copper 70 parts, 16 parts of nickel, 9 parts of stannum, 19 parts of zinc, ferrum 9 parts, yttrium 5 parts, 10 parts of aluminum, niobium 6 parts, cerium 9 parts according to described heavy
Amount part is made into the furnace charge meeting component requirements, puts in smelting furnace and is smelted into copper molten metal at temperature 1500 DEG C, and does stokehold
Analyze;
(2) copper molten metal is guided as in conticaster, add 14 parts of heat conduction material, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally
It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
Embodiment 3:
(1) by copper 50 parts, 14 parts of nickel, 7 parts of stannum, 11 parts of zinc, ferrum 3 parts, yttrium 5 parts, 6 parts of aluminum, niobium 2 parts, cerium 5 parts according to described heavy
Amount part is made into the furnace charge meeting component requirements, puts in smelting furnace and is smelted into copper molten metal at temperature 1000 DEG C, and does stokehold
Analyze;
(2) copper molten metal is guided as in conticaster, add 8 parts of heat conduction material, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally
It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
The preparation method of wire rod of the present invention uses horizontal casting, compared with the most commonly used vacuum melting technology,
The method lumber recovery of the present invention is high, and process equipment is simple, invests little, and technological process is short, and production efficiency is high, and availability is same
Few etc. excellent wire product preparation process, produce equipment simple, it is easy to prepare satisfactory product, and be easily achieved scale
Change and automated production.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (6)
1. the copper alloy wire that an environmental protection is easily processed, it is characterised in that be prepared from by the raw material of following weight portion:
Copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~10 parts,
Niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
The preparation method of the copper alloy wire that a kind of environmental protection the most according to claim 1 is easily processed, it is characterised in that include
Following steps:
(1) by copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6~
10 parts, niobium 2~6 parts, cerium 5~9 parts are made into the furnace charge meeting component requirements according to described weight portion, put in smelting furnace in temperature
It is smelted into copper molten metal at 1000-1500 DEG C, and does on-the-spot sample analysis;
(2) copper molten metal is guided as in conticaster, addition heat conduction material 8~14 parts, carry out horizontal casting and prepare copper cash base;
(4) the copper cash base prepared in step 2 is carried out Homogenization Treatments and obtain wire rod;
(5) described wire rod is carried out multi pass drawing processing-annealing-drawing cyclic process, it is thus achieved that soft state finished product;Finally
It is polished and Ageing Treatment after cold working, obtains hardness ag(e)ing state finished product.
The copper alloy wire that a kind of environmental protection the most according to claim 1 is easily processed, it is characterised in that by following weight portion
Raw material is prepared from: copper 50~70 parts, nickel 14~16 parts, stannum 7~9 parts, zinc 11~19 parts, ferrum 3~9 parts, yttrium 5~13 parts, aluminum 6
~10 parts, niobium 2~6 parts, cerium 5~9 parts, heat conduction material 8~14 parts.
The copper alloy wire that a kind of environmental protection the most according to claim 1 is easily processed, it is characterised in that by following weight portion
Raw material is prepared from: copper 60 parts, 15 parts of nickel, 8 parts of stannum, 16 parts of zinc, ferrum 4 parts, yttrium 9 parts, 7 parts of aluminum, niobium 5 parts, cerium 6 parts, heat conduction material
10 parts.
Copper alloy wire that a kind of environmental protection the most according to claim 2 is easily processed and preparation method thereof, it is characterised in that institute
Stating the temperature of Homogenization Treatments in step (4) and be 800-1000 DEG C, the time is 3-5 hour.
Copper alloy wire that a kind of environmental protection the most according to claim 2 is easily processed and preparation method thereof, it is characterised in that institute
Stating the temperature of annealing in step (5) and be 780-990 DEG C, the time is 0.5 hour, and water-cooled;The temperature of Ageing Treatment after processing
Degree is for 200-400 DEG C, and the time is 0.5 hour.
Priority Applications (1)
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CN201610753897.4A CN106191521A (en) | 2016-08-30 | 2016-08-30 | Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof |
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CN201610753897.4A CN106191521A (en) | 2016-08-30 | 2016-08-30 | Copper alloy wire that a kind of environmental protection is easily processed and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109079112A (en) * | 2017-06-14 | 2018-12-25 | 罗奕兵 | A kind of forming technology of high-tin bronze silk material |
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2016
- 2016-08-30 CN CN201610753897.4A patent/CN106191521A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109079112A (en) * | 2017-06-14 | 2018-12-25 | 罗奕兵 | A kind of forming technology of high-tin bronze silk material |
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Application publication date: 20161207 |