CN106190632A - A kind of automobile Colophonium abluent - Google Patents

A kind of automobile Colophonium abluent Download PDF

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Publication number
CN106190632A
CN106190632A CN201610526810.XA CN201610526810A CN106190632A CN 106190632 A CN106190632 A CN 106190632A CN 201610526810 A CN201610526810 A CN 201610526810A CN 106190632 A CN106190632 A CN 106190632A
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abluent
colophonium
automobile
alcohol
parts
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杜燕
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Zhejiang Agricultural Business College
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Zhejiang Agricultural Business College
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Priority to CN201610526810.XA priority Critical patent/CN106190632A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/65Mixtures of anionic with cationic compounds
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/187Hydrocarbons aromatic
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • C11D3/2013Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
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    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
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    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
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    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2082Polycarboxylic acids-salts thereof
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
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    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
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    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
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    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3749Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
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    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
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    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
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    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
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    • C11D1/143Sulfonic acid esters
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    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
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    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
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    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
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    • C11D1/72Ethers of polyoxyalkylene glycols
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Abstract

The invention discloses a kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 28 parts, penetrating agent 25 parts, levelling agent 13 parts, preservative 0.01 0.1 parts, surface active dispersing agent 35 parts, anticoagulant 0.2 0.6 parts, toluene 12 15 parts, alcohol-water mixture 15 30 parts.The present invention is not only to car paint not damaged, and cleaning performance is preferable, and cost is relatively low.

Description

A kind of automobile Colophonium abluent
Technical field
The invention belongs to automobile washing technical field, be specifically related to a kind of automobile Colophonium abluent.
Background technology
Automobile in use can be through construction section or be parked in bower, due to construction section generally with liquid The cement of state state and Colophonium, be easily adhered on automobile chassis, bumper, paint and glass;Bower usual populated with bird Class, the Excreta of birds can be adhered directly on paint and the glass of car surface.
Due to the mixture that Colophonium is complicated Hydrocarbon derivant nonmetal with it composition, after sticking to vehicle body, Organic substance on vehicle body is combined, it is difficult to remove;After liquid cement sticks to vehicle body, it may occur that solidification, in solidification process, water Silicate in mud can tightly be fitted on vehicle body;Containing uric acid in birds Excreta, the pH value of uric acid is 3.89, uric acid energy Enough composition react with the alkyd in paint, epoxyeicosatrienoic acid etc., corrodes and paints, and meanwhile, uric acid also can corrode the metal structure of vehicle body.
Existing Common detergents contains surfactant mostly, it is difficult to remove Colophonium, cement and birds Excreta, generally Use hard objects such as key or scraper plate to scrape removing, Colophonium, cement and birds Excreta, easily damage the paint of vehicle body;And Cleaning performance is preferable, Special cleaning agent prescription undamaged to car paint is usually relatively complex, and price is higher.
Summary of the invention
It is an object of the invention to provide a kind of automobile Colophonium abluent, the present invention is not only to car paint not damaged, cleaning performance Preferably, and cost is relatively low.
A kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 2-8 part, penetrating agent 2-5 part, levelling agent 1-3 Part, preservative 0.01-0.1 part, surface active dispersing agent 3-5 part, anticoagulant 0.2-0.6 part, toluene 12-15 part, the mixing of alcohol water Liquid 15-30 part.
Described alcohol-water mixture refers to the ratio of the mixed liquor of distilled water and low mass molecule alcohol, described distilled water and low mass molecule alcohol For 3:1-3.
Described low mass molecule alcohol uses the one in C1-C4 alcohol.
Described preservative uses sorbic acid and its esters or dehydroactic acid and sodium salt, and potassium sorbate is acid anticorrosion Agent, has higher anti-microbial property, presses down mycostatic growth and breeding, and it is mainly by the dehydrogenase system in suppression microbial body System, thus reach suppress microorganism and play antiseptical effect.Antibacterial, mycete, yeast all there is inhibitory action.Antiseptic effect Apparently higher than benzoic acids, it it is 5-10 times of benzoate.Product toxicity is low, is equivalent to the half of Sal.Its antiseptic effect with The rising of PH and weaken, during PH=3, antiseptic effect is optimal.
Described penetrating agent uses fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, sodium alkyl sulfonate, alkyl benzene sulphonate Sodium, alkyl sulfate sodium one or more.
Described levelling agent uses polydimethylsiloxane or PSI.
Described surface active dispersing agent uses the one in Tissuemat E, Polyethylene Glycol or polyvinylpyrrolidone.
Described anticoagulant uses Disodium oxalate. or ethylenediaminetetraacetic acid.
Described formula also including, essence, described essence proportioning are 1-3 part.
The preparation method of described abluent, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 30- 60min, heating-up temperature is 50-70 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, penetrating agent and surface active dispersing agent, and stirring and dissolving is then added to In the solution of step 2, proceeding stirring, mixing speed is 2000-3000r/min.
Step 4, joins in distilling apparatus by the agitating solution in step 3, decompression distillation 10min, natural cooling, Obtain automobile Colophonium abluent.
Compared with prior art, the method have the advantages that
1, the present invention uses toluene as Colophonium lytic agent, has good solute effect, uses alcohol water as toluene simultaneously Treatment fluid, it is possible to prevent toluene from volatilizing, reduces the pollution of toluene simultaneously.
2, the present invention uses penetrating agent can play good pitch infiltration effect, it is ensured that Colophonium softens with the stripping of lacquer painting, Help clean up Colophonium..
3, the secondary stirring method that the present invention provides can fully discharge the function of each component, and this method has operation letter simultaneously The advantages such as single, waste liquid amount is few, and yield rate is high.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further:
Embodiment 1
A kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 2 parts, penetrating agent 2 parts, levelling agent 1 part, preservative 0.01 part, surface active dispersing agent 3 parts, anticoagulant 0.2 part, toluene 12 parts, alcohol-water mixture 15 parts.
Described alcohol-water mixture refers to the ratio of the mixed liquor of distilled water and low mass molecule alcohol, described distilled water and low mass molecule alcohol For 3:1.
Described low mass molecule alcohol uses methanol.
Described preservative uses sorbic acid.
Described penetrating agent uses fatty alcohol-polyoxyethylene ether.
Described levelling agent uses polydimethylsiloxane.
Described surface active dispersing agent uses Tissuemat E.
Described anticoagulant uses Disodium oxalate..
The preparation method of described abluent, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 30min, heating-up temperature is 50 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, penetrating agent and surface active dispersing agent, and stirring and dissolving is then added to In the solution of step 2, proceeding stirring, mixing speed is 2000r/min.
Step 4, joins in distilling apparatus by the agitating solution in step 3, decompression distillation 10min, natural cooling, Obtain automobile Colophonium abluent.
Embodiment 2
A kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 8 parts, penetrating agent 5 parts, levelling agent 3 parts, preservative 0.1 Part, surface active dispersing agent 5 parts, anticoagulant 0.6 part, toluene 15 parts, alcohol-water mixture 30 parts.
Described alcohol-water mixture refers to the ratio of the mixed liquor of distilled water and low mass molecule alcohol, described distilled water and low mass molecule alcohol For 3:3.
Described low mass molecule alcohol uses ethanol.
Described preservative uses dehydroactic acid.
Described penetrating agent uses fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, sodium alkyl sulfonate, alkyl benzene sulphonate Sodium, alkyl sulfate sodium one or more.
Described levelling agent uses polydimethylsiloxane or PSI.
Described surface active dispersing agent uses Polyethylene Glycol.
Described anticoagulant uses ethylenediaminetetraacetic acid.
The preparation method of described abluent, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 60min, heating-up temperature is 70 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, penetrating agent and surface active dispersing agent, and stirring and dissolving is then added to In the solution of step 2, proceed stirring, mixing speed 3000r/min.
Step 4, joins in distilling apparatus by the agitating solution in step 3, decompression distillation 10min, natural cooling, Obtain automobile Colophonium abluent.
Embodiment 3
A kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 5 parts, penetrating agent 4 parts, levelling agent 2 parts, preservative 0.05 part, surface active dispersing agent 4 parts, anticoagulant 0.4 part, toluene 13 parts, alcohol-water mixture 22 parts.
Described alcohol-water mixture refers to the ratio of the mixed liquor of distilled water and low mass molecule alcohol, described distilled water and low mass molecule alcohol For 3:2.
Described low mass molecule alcohol uses propanol.
Described preservative uses sodium sorbate.
Described penetrating agent uses sodium alkyl sulfonate.
Described levelling agent uses PSI.
Described surface active dispersing agent uses polyvinylpyrrolidone.
Described anticoagulant uses Disodium oxalate..
The preparation method of described abluent, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 45min, heating-up temperature is 60 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, penetrating agent and surface active dispersing agent, and stirring and dissolving is then added to In the solution of step 2, proceeding stirring, mixing speed is 2500r/min.
Step 4, joins in distilling apparatus by the agitating solution in step 3, decompression distillation 10min, natural cooling, Obtain automobile Colophonium abluent.
Embodiment 4
A kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 2 parts, penetrating agent 2 parts, levelling agent 1 part, preservative 0.01 part, surface active dispersing agent 3 parts, anticoagulant 0.2 part, toluene 12 parts, alcohol-water mixture 15 parts, 1 part of essence.
Described alcohol-water mixture refers to the ratio of the mixed liquor of distilled water and low mass molecule alcohol, described distilled water and low mass molecule alcohol For 3:1.
Described low mass molecule alcohol uses methanol.
Described preservative uses sorbic acid.
Described penetrating agent uses fatty alcohol-polyoxyethylene ether.
Described levelling agent uses polydimethylsiloxane.
Described surface active dispersing agent uses Tissuemat E.
Described anticoagulant uses Disodium oxalate..
The preparation method of described abluent, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 30min, heating-up temperature is 50 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, essence, penetrating agent and surface active dispersing agent, stirring and dissolving, then Joining in the solution of step 2, proceed stirring, mixing speed is 2000r/min.
Step 4, joins in distilling apparatus by the agitating solution in step 3, decompression distillation 10min, natural cooling, Obtain automobile Colophonium abluent.
Embodiment 5
A kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 8 parts, penetrating agent 5 parts, levelling agent 3 parts, preservative 0.1 Part, surface active dispersing agent 5 parts, anticoagulant 0.6 part, toluene 15 parts, alcohol-water mixture 30 parts, 3 parts of essence.
Described alcohol-water mixture refers to the ratio of the mixed liquor of distilled water and low mass molecule alcohol, described distilled water and low mass molecule alcohol For 3:3.
Described low mass molecule alcohol uses ethanol.
Described preservative uses dehydroactic acid.
Described penetrating agent uses fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, sodium alkyl sulfonate, alkyl benzene sulphonate Sodium, alkyl sulfate sodium one or more.
Described levelling agent uses polydimethylsiloxane or PSI.
Described surface active dispersing agent uses Polyethylene Glycol.
Described anticoagulant uses ethylenediaminetetraacetic acid.
The preparation method of described abluent, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 60min, heating-up temperature is 50-70 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, essence, penetrating agent and surface active dispersing agent, stirring and dissolving, then Joining in the solution of step 2, proceed stirring, mixing speed is 3000r/min.
Step 4, joins in distilling apparatus by the agitating solution in step 3, decompression distillation 10min, natural cooling, Obtain automobile Colophonium abluent.
Embodiment 6
A kind of automobile Colophonium abluent, its formula is as follows: silicone quaternary ammonium salt 5 parts, penetrating agent 4 parts, levelling agent 2 parts, preservative 0.05 part, surface active dispersing agent 4 parts, anticoagulant 0.4 part, toluene 13 parts, alcohol-water mixture 22 parts, 2 parts of essence.
Described alcohol-water mixture refers to the ratio of the mixed liquor of distilled water and low mass molecule alcohol, described distilled water and low mass molecule alcohol For 3:2.
Described low mass molecule alcohol uses butanol.
Described preservative uses sodium sorbate.
Described penetrating agent uses sodium alkyl sulfonate.
Described levelling agent uses PSI.
Described surface active dispersing agent uses polyvinylpyrrolidone.
Described anticoagulant uses Disodium oxalate..
The preparation method of described abluent, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 45min, heating-up temperature is 60 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, essence, penetrating agent and surface active dispersing agent, stirring and dissolving, then Joining in the solution of step 2, proceed stirring, mixing speed is 2500r/min.
Step 4, joins in distilling apparatus by the agitating solution in step 3, decompression distillation 10min, natural cooling, Obtain automobile Colophonium abluent.
The foregoing is only one embodiment of the invention, be not limiting as the present invention, all employing equivalents or equivalent transformation The technical scheme that obtained of mode, all fall within protection scope of the present invention.

Claims (10)

1. an automobile Colophonium abluent, it is characterised in that: its formula is as follows: silicone quaternary ammonium salt 2-8 part, penetrating agent 2-5 part, stream Flat agent 1-3 part, preservative 0.01-0.1 part, surface active dispersing agent 3-5 part, anticoagulant 0.2-0.6 part, toluene 12-15 part, alcohol Water mixed liquid 15-30 part.
2. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that described alcohol-water mixture refers to steam Distilled water and the mixed liquor of low mass molecule alcohol, described distilled water is 3:1-3 with the ratio of low mass molecule alcohol.
3. according to a kind of automobile Colophonium abluent described in claims 2, it is characterised in that described low mass molecule alcohol uses C1- One in C4 alcohol.
4. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that described preservative uses sorbic acid And its esters or dehydroactic acid and sodium salt.
5. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that described penetrating agent uses fatty alcohol Polyoxyethylene ether, alkylphenol polyoxyethylene, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkyl sulfate sodium one or more.
6. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that described levelling agent uses poly-diformazan Radical siloxane or PSI.
7. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that described surface active dispersing agent is adopted By the one in Tissuemat E, Polyethylene Glycol or polyvinylpyrrolidone.
8. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that described anticoagulant uses Disodium oxalate. Or ethylenediaminetetraacetic acid.
9. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that described formula also includes perfume (or spice) Essence, described essence proportioning is 1-3 part.
10. according to a kind of automobile Colophonium abluent described in claims 1, it is characterised in that the preparation side of described abluent Method, its step is as follows:
Step 1, proportionally requires to weigh raw material,
Step 2, joins in alcohol-water solution by levelling agent, preservative, anticoagulant, carries out low temperature stirring, and mixing time is 30- 60min, heating-up temperature is 50-70 DEG C;
Step 3, joins in toluene by silicone quaternary ammonium salt, penetrating agent and surface active dispersing agent, and stirring and dissolving is then added to In the solution of step 2, proceeding stirring, mixing speed is 2000-3000r/min;Step 4, by the agitating solution in step 3 Join in distilling apparatus, decompression distillation 10min, natural cooling, i.e. can get automobile Colophonium abluent.
CN201610526810.XA 2016-07-06 2016-07-06 A kind of automobile Colophonium abluent Pending CN106190632A (en)

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Publication number Priority date Publication date Assignee Title
CN106929200A (en) * 2017-03-31 2017-07-07 芜湖扬展新材料科技服务有限公司 A kind of antiultraviolet non-water type vehicle cleaning detergent and preparation method thereof
CN106978275A (en) * 2017-03-31 2017-07-25 芜湖扬展新材料科技服务有限公司 A kind of non-water type vehicle cleaning detergent and preparation method thereof
CN107057885A (en) * 2017-03-31 2017-08-18 芜湖扬展新材料科技服务有限公司 A kind of environmental protective car wash without water agent and preparation method thereof
CN112342091A (en) * 2020-11-04 2021-02-09 绍兴市柯桥区欣飞科技有限公司 Automobile cleaning agent and preparation method thereof

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CN105132196A (en) * 2015-09-29 2015-12-09 湖北穆兰同大科技有限公司 Car cleaning nursing agent and preparation method thereof

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CN103540453A (en) * 2013-10-17 2014-01-29 北京新奥混凝土集团有限公司 Cement concrete scale cleaning agent and preparation method thereof
CN105132196A (en) * 2015-09-29 2015-12-09 湖北穆兰同大科技有限公司 Car cleaning nursing agent and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929200A (en) * 2017-03-31 2017-07-07 芜湖扬展新材料科技服务有限公司 A kind of antiultraviolet non-water type vehicle cleaning detergent and preparation method thereof
CN106978275A (en) * 2017-03-31 2017-07-25 芜湖扬展新材料科技服务有限公司 A kind of non-water type vehicle cleaning detergent and preparation method thereof
CN107057885A (en) * 2017-03-31 2017-08-18 芜湖扬展新材料科技服务有限公司 A kind of environmental protective car wash without water agent and preparation method thereof
CN112342091A (en) * 2020-11-04 2021-02-09 绍兴市柯桥区欣飞科技有限公司 Automobile cleaning agent and preparation method thereof
WO2022094996A1 (en) * 2020-11-04 2022-05-12 绍兴市柯桥区欣飞科技有限公司 Automobile cleaning agent and preparation method therefor

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