CN106189317A - A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material and preparation method thereof - Google Patents
A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material and preparation method thereof Download PDFInfo
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- CN106189317A CN106189317A CN201610574675.6A CN201610574675A CN106189317A CN 106189317 A CN106189317 A CN 106189317A CN 201610574675 A CN201610574675 A CN 201610574675A CN 106189317 A CN106189317 A CN 106189317A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, is made up of the raw material of following weight portion: acetyleugenol 10 20, Plant fiber 5 10, magnesium bromide 10 15, activated carbon 58, wood powder 20 30, caprolactone 10 15, wollastonite 6 10, Caulis Perillae 4, Folium Ginkgo 3, sodium alkyl sulfonate 12.Present invention also offers the manufacture method of a kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, comprise the following steps: mentioned component is carried out carbonization, high pressure batch mixing, through the process heated, mediate, bond, add extrusion molding in comminutor and obtain.Easily manufactured, low cost；Quantity of plastics, consumption of wood are few, environmental friendliness；Rigidity is big, is not susceptible to buckling deformation, do not ftracture, ultraviolet resistance and thermo-oxidative ageing, service life long.Can be widely applied to every field.The wood plastic composite board prepared by the method has Flos Caryophylli type absorption anti-flammability, and preparation method is simple, and raw material is easy to get.
Description
Technical field
The present invention relates to wood producing technical field, in particular to a kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite wood
Flitch material and preparation method thereof.
Background technology
Wood plastic composite, is with resin or recovery waste or used plastics and the natural biological fiber composite such as wood powder, powder of straw
Become, there is the double grading of timber and plastics, fully demonstrated a series of Advanced Idea such as the utilization of resources, environmental protection and saving, be reason
The Green Product thought.Plastic-wood section has waterproof, moistureproof, high-environmental, can substitute timber in a large number and use, and is a kind of great
The exhibition low-carbon (LC) of future, green, the ecomaterial of recyclable regenerative, if develop a kind of to harmful substance tool on the basis of existing
There is the novel plastic wood material of adsorptivity, for interior decoration, the various radioactive substances such as formaldehyde that is difficult to tradition finishing to avoid,
Benzene classes etc. absorb, and provide the living environment of more safety and Health for people, it will have a tremendous social and economic benefits.
Summary of the invention
It is desirable to provide a kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, this wood plastic composite board has
There are absorption and the fire resistance of excellence.
To achieve these goals, the invention provides a kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, by with
The raw material of lower weight portion is made: acetyleugenol 10-20, Plant fiber 5-10, magnesium bromide 10-15, activated carbon 5-8, wood powder
20-30, caprolactone 10-15, wollastonite 6-10, Caulis Perillae 4, Folium Ginkgo 3, sodium alkyl sulfonate 1-2.
Present invention also offers the manufacture method of a kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, comprise following
Step:
(1) acetyleugenol, Caulis Perillae, Folium Ginkgo are placed in hermetic container, by steam, keep 180 DEG C. and high temperature dries
Dry, cool down smashing again and obtain half carbonization material；
(2) being mixed by above-mentioned raw materials, carry out high pressure batch mixing, the temperature of high pressure batch mixing is 120-160 DEG C, and the time is that 6-10 divides
Clock, pressure is 0.3MPa；
(3) step of pelletize, is carried out in comminutor, needs, through the process heated, mediate, bond, to be mixed by high pressure
Material after material adds in comminutor, and prilling temperature is 160-200 DEG C, and the material time in comminutor is 10-20 minute,
Prepare compound material grain eventually；It is subsequently adding extruder and is extruded into sheet material；
By technique scheme, after the present invention is by carrying out mixing granulation process by individual composition, the wood of moulding obtained is combined
Material sheet material has Flos Caryophylli type absorption anti-flammability, and preparation method is simple, and raw material is easy to get.
A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material of the present invention, manufactures convenient, traditional plastics raw
Production. art i.e. can be used for its production and processing and fabricating without improving, and production cost is low；Compare with common plastics sheet material, activated carbon
Physisorption, is dependent on air as medium, and the harmful substance in absorption air, the present invention is added to routine and moulds wood
In material, it is used for adsorbing the toxic gas in air, such as ammonia, formaldehyde, benzene class etc., the abnormal flavour after finishing can be inhaled
Attached, pollution-free, nontoxic, have no side effect, the most relieved.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, is made up of the raw material of following weight portion: acetyl Oleum Caryophylli
Phenol 10-20, Plant fiber 5-10, magnesium bromide 10-15, activated carbon 5-8, wood powder 20-30, caprolactone 10-15, wollastonite 6-10,
Caulis Perillae 4, Folium Ginkgo 3, sodium alkyl sulfonate 1-2.
Present invention also offers the manufacture method of a kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, comprise following step
Rapid:
(1) acetyleugenol, Caulis Perillae, Folium Ginkgo are placed in hermetic container, by steam, keep 180 DEG C. and high temperature dries
Dry, cool down smashing again and obtain half carbonization material；
(2) being mixed by above-mentioned raw materials, carry out high pressure batch mixing, the temperature of high pressure batch mixing is 120-160 DEG C, and the time is that 6-10 divides
Clock, pressure is 0.3MPa；
(3) step of pelletize, is carried out in comminutor, needs, through the process heated, mediate, bond, to be mixed by high pressure
Material after material adds in comminutor, and prilling temperature is 160-200 DEG C, and the material time in comminutor is 10-20 minute,
Prepare compound material grain eventually；It is subsequently adding extruder and is extruded into sheet material；
In the present invention, the time of mixing can select in wide in range scope, but so that prepare moulds wood again
Condensation material sheet material has absorptionization and anti-flammability, it is preferable that incorporation time is 6-10 minute.
In the present invention, temperature can select in wide in range scope, but so that the Wood plastic composite prepared
Sheet material has absorption and anti-flammability, it is preferable that mixing temperature is 120 DEG C-160 DEG C, and pressure is 0.3MPa.
In the present invention, the time of pelletize can select in wide in range scope, but so that prepare moulds wood again
Condensation material sheet material has absorptionization and anti-flammability, it is preferable that granulation time is 10-20 minute.
In the present invention, prilling temperature can select in wide in range scope, but so that the wood of moulding prepared is combined
Material sheet material has absorptionization and anti-flammability, it is preferable that temperature is 160 DEG C-200 DEG C.
Embodiment 1
1) by each for wood plastic composite board composition according to following weight portion: acetyleugenol 10, Plant fiber 5, bromine
Change magnesium 10, activated carbon 5, wood powder 20, caprolactone 10, wollastonite 6, Caulis Perillae 4, Folium Ginkgo 3, sodium alkyl sulfonate 1.
2) through carbonization process after, carbonization material and by above-mentioned material proportion, mixing 6 minutes, mixing temperature is 120 DEG C.
3) gained mixture addition comminutor processes, comminutor temperature 160 DEG C, time 10min, obtains moulding wood compound
Material sheet material A1.
Embodiment 2
1) by each for wood plastic composite board composition according to following weight portion: acetyleugenol 20, Plant fiber 10, bromine
Change magnesium 15, activated carbon 8, wood powder 30, caprolactone 15, wollastonite 10, Caulis Perillae 4, Folium Ginkgo 3, sodium alkyl sulfonate 2.
2) through carbonization process after, carbonization material and by above-mentioned material proportion, mixing 10 minutes, mixing temperature is 160 DEG C.
3) gained mixture addition comminutor processes, comminutor temperature 200 DEG C, time 20min, obtains moulding wood compound
Material sheet material A2.
Embodiment 3
1) by each for wood plastic composite board composition according to following weight portion: acetyleugenol 15, Plant fiber 7, bromine
Change magnesium 12, activated carbon 6, wood powder 25, caprolactone 12, wollastonite 8, Caulis Perillae 4, Folium Ginkgo 3, sodium alkyl sulfonate 1.5.
2) through carbonization process after, carbonization material and by above-mentioned material proportion, mixing 8 minutes, mixing temperature is 150 DEG C.
3) gained mixture addition comminutor processes, comminutor temperature 170 DEG C, time 15min, obtains moulding wood compound
Material sheet material A3.
Comparative example 1
Carry out preparing wood plastic composite board B1 according to the method for embodiment 1, except for the difference that, do not add magnesium bromide.
Comparative example 2
Carry out preparing wood plastic composite board B2 according to the method for embodiment 1, except for the difference that, do not add activated carbon.
Comparative example 3
Carry out preparing wood plastic composite board B3 according to the method for embodiment 1, except for the difference that, do not add caprolactone.
Detection example 1
Detecting Flos Caryophylli taste, adsorptivity and the fire resistance of above-mentioned wood plastic composite board, result is: mould wood multiple
Flos Caryophylli taste, adsorptivity and the anti-flammability of condensation material sheet material A1-A3 is superior to the Flos Caryophylli taste of wood plastic composite board B1-B3, suction
Attached property and anti-flammability.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it should be considered as content disclosed in this invention equally.
Claims (8)
1. a Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material, it is characterised in that be made up of the raw material of following weight portion: second
Acyl eugenol 10-20, Plant fiber 5-10, magnesium bromide 10-15, activated carbon 5-8, wood powder 20-30, caprolactone 10-15, silicon ash
Stone 6-10, Caulis Perillae 4, Folium Ginkgo 3, sodium alkyl sulfonate 1-2.
2. the preparation method of the wood plastic composite board described in kind of claim 1, it is characterised in that described preparation method bag
Include:
(1) acetyleugenol, Caulis Perillae, Folium Ginkgo are placed in hermetic container, by steam, keep 180 DEG C. high temperature drying,
Cool down smashing again and obtain half carbonization material；
(2) being mixed by above-mentioned raw materials, carry out high pressure batch mixing, the temperature of high pressure batch mixing is 120-160 DEG C, and the time is 6-10 minute,
Pressure is 0.3MPa；
(3) step of pelletize, is carried out in comminutor, needs the process through heating, mediating, bond, after high pressure batch mixing
Material add in comminutor, prilling temperature is 160-200 DEG C, and the material time in comminutor is 10-20 minute, finally makes
Material grain must be combined；It is subsequently adding extruder and is extruded into sheet material.
The preparation method of wood plastic composite board the most according to claim 2, it is characterised in that step 2) in temperature
Being 180 DEG C, the type of cooling is air-cooled.
The preparation method of wood plastic composite board the most according to claim 2, it is characterised in that step 2) in mixing
Time is 6-10 minute.
The preparation method of wood plastic composite board the most according to claim 2, it is characterised in that step 2) in temperature
It it is 120 DEG C-160 DEG C.
The preparation method of wood plastic composite board the most according to claim 2, it is characterised in that step 2) in pressure
For 0.3MPa.
The preparation method of wood plastic composite board the most according to claim 2, it is characterised in that step 3) in pelletize
Time is 10-20 minute.
The preparation method of wood plastic composite board the most according to claim 2, it is characterised in that step 3) in temperature
It it is 160 DEG C-200 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610574675.6A CN106189317A (en) | 2016-07-21 | 2016-07-21 | A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610574675.6A CN106189317A (en) | 2016-07-21 | 2016-07-21 | A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material and preparation method thereof |
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| CN106189317A true CN106189317A (en) | 2016-12-07 |
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| CN201610574675.6A Pending CN106189317A (en) | 2016-07-21 | 2016-07-21 | A kind of Flos Caryophylli type absorption flame-resistant plastic-wood composite materials sheet material and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798465A (en) * | 2010-03-16 | 2010-08-11 | 龙海市奈特化工有限责任公司 | Composite material capable of releasing volatile substances persistently and preparation method thereof |
| CN104325668A (en) * | 2014-11-03 | 2015-02-04 | 浙江巨森建材科技有限公司 | Production process of oak-charcoal decorative frame |
| CN105419368A (en) * | 2015-12-18 | 2016-03-23 | 蚌埠市鑫晟新材料科技有限公司 | Production method of delicate fragrance type plastic board material |
| CN105482308A (en) * | 2015-12-31 | 2016-04-13 | 楚雄中信塑木新型材料有限公司 | Novel adsorptive plastic-wood material |
-
2016
- 2016-07-21 CN CN201610574675.6A patent/CN106189317A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798465A (en) * | 2010-03-16 | 2010-08-11 | 龙海市奈特化工有限责任公司 | Composite material capable of releasing volatile substances persistently and preparation method thereof |
| CN104325668A (en) * | 2014-11-03 | 2015-02-04 | 浙江巨森建材科技有限公司 | Production process of oak-charcoal decorative frame |
| CN105419368A (en) * | 2015-12-18 | 2016-03-23 | 蚌埠市鑫晟新材料科技有限公司 | Production method of delicate fragrance type plastic board material |
| CN105482308A (en) * | 2015-12-31 | 2016-04-13 | 楚雄中信塑木新型材料有限公司 | Novel adsorptive plastic-wood material |
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Application publication date: 20161207 |