CN106188773A - A kind of nano packaging material and preparation method thereof - Google Patents

A kind of nano packaging material and preparation method thereof Download PDF

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Publication number
CN106188773A
CN106188773A CN201610651826.3A CN201610651826A CN106188773A CN 106188773 A CN106188773 A CN 106188773A CN 201610651826 A CN201610651826 A CN 201610651826A CN 106188773 A CN106188773 A CN 106188773A
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parts
nano
packaging material
titanium
particle
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叶春会
王泽平
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Anhui Jia Mu Rubber Industry Co Ltd
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Anhui Jia Mu Rubber Industry Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C08J2423/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
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  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

The invention discloses a kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 10 25 parts, polystyrene resin 5 12 parts, 14 25 parts of vinyon particle, nano imvite 7 11 parts, titanate coupling agent 0.8 1.5 parts, nano silicon 2.5 5 parts, de-titanium-type nano titanium oxide 5 10 parts, lubricant 1.5 4.5 parts, plasticizer 25 parts, 0.5 1.2 parts of antioxidant.Nano packaging material in the present invention has that stability is high, wearability is good and the advantage such as length in service life.

Description

A kind of nano packaging material and preparation method thereof
Technical field
The present invention relates to a kind of packaging material, particularly relate to a kind of nano packaging material and preparation method thereof.
Background technology
Along with the fast development of China's economy, improving constantly of resident's cultural quality, people are to the requirement of packaging material also More and more higher.Nano material is the new material just grown up the eighties in 20th century, and nano material causes because of its quantum size The special effectses such as skin effect, quantum size effect, small-size effect, macroscopic quantum orbital effect, are allowed to the light with uniqueness Learn effect, high conductivity and diffusibility, high specific heat and thermal expansion, high susceptibility and coercivity, catalysis, Optical Electro-Chemistry, molten point, The aspects such as superconduction also show that the characteristic different from macroscopic view crystalline material, have the most potential application in each field.At present, receive Rice technology main direction of studying in the food industry has: nano-packaging, and nanometer spray continues thin film, nanoscale composite or nanometer again Close the research of the packaging material for food such as plastics, nanometer antibiotic fresh-keeping plastic film.
Summary of the invention
It is an object of the invention to provide a kind of nano packaging material and preparation method thereof, it has stability height, wearability The advantages such as good and length in service life.
For achieving the above object, the present invention provides following technical scheme:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 10-25 part, polyphenyl second Olefine resin 5-12 part, vinyon particle 14-25 part, nano imvite 7-11 part, titanate coupling agent 0.8-1.5 part, receive Rice silicon dioxide 2.5-5 part, de-titanium-type nano titanium oxide 5-10 part, lubricant 1.5-4.5 part, plasticizer 2-5 part, antioxidant 0.5-1.2 part.
Preferably, described nano packaging material is made up of the raw material of following parts by weight: acrylic resin 14 parts, polyphenyl second Olefine resin 7 parts, 16 parts of vinyon particle, nano imvite 8 parts, titanate coupling agent 1 part, nano silicon 3.6 parts, De-titanium-type nano titanium oxide 6 parts, lubricant 3 parts, plasticizer 3.5 parts, 1 part of antioxidant.
Preferably, described nano packaging material is made up of the raw material of following parts by weight: acrylic resin 21 parts, polyphenyl second Olefine resin 8 parts, 17 parts of vinyon particle, nano imvite 10 parts, titanate coupling agent 1.2 parts, nano silicon 3.8 Part, de-titanium-type nano titanium oxide 8 parts, lubricant 2 parts, plasticizer 3 parts, 0.9 part of antioxidant.
Preferably, described nano packaging material is made up of the raw material of following parts by weight: acrylic resin 12 parts, polyphenyl second Olefine resin 8 parts, 17 parts of vinyon particle, nano imvite 11 parts, titanate coupling agent 1.5 parts, nano silicon 4 Part, de-titanium-type nano titanium oxide 6 parts, lubricant 4 parts, plasticizer 4 parts, 1.2 parts of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Compared with prior art, the invention has the beneficial effects as follows:
Nano packaging material in the present invention there was added lubricant, plasticizer and antioxidant, thus makes it have good Wearability, plasticity, non-oxidizability is strong simultaneously, stability is high, is conducive to extending its service life；Additionally, be additionally added poly-second Alkene plastics particle, de-titanium-type nano titanium oxide so that it is having higher paving property by force, it is comprehensive that nano imvite is conducive to improving it Mechanical property.
Detailed description of the invention
Describe technical scheme in detail below in conjunction with embodiment, but protection domain is not limited thereto.
Embodiment one:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 12 parts, polystyrene tree 8 parts of fat, 16 parts of vinyon particle, nano imvite 9 parts, titanate coupling agent 1 part, nano silicon 3.5 parts, de-titanium Type nano titanium oxide 8 parts, lubricant 3 parts, plasticizer 4 parts, 0.7 part of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment two:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 14 parts, polystyrene tree 6 parts of fat, 21 parts of vinyon particle, nano imvite 11 parts, titanate coupling agent 1.4 parts, nano silicon 3.2 parts, De-titanium-type nano titanium oxide 8 parts, lubricant 4 parts, plasticizer 4 parts, 1.2 parts of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment three:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 14 parts, polystyrene tree 7 parts of fat, 16 parts of vinyon particle, nano imvite 8 parts, titanate coupling agent 1 part, nano silicon 3.6 parts, de-titanium Type nano titanium oxide 6 parts, lubricant 3 parts, plasticizer 3.5 parts, 1 part of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment four:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 21 parts, polystyrene tree 8 parts of fat, 17 parts of vinyon particle, nano imvite 10 parts, titanate coupling agent 1.2 parts, nano silicon 3.8 parts, De-titanium-type nano titanium oxide 8 parts, lubricant 2 parts, plasticizer 3 parts, 0.9 part of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment five:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 12 parts, polystyrene tree 8 parts of fat, 17 parts of vinyon particle, nano imvite 11 parts, titanate coupling agent 1.5 parts, nano silicon 4 parts, de- Titanium-type nano titanium oxide 6 parts, lubricant 4 parts, plasticizer 4 parts, 1.2 parts of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment six:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 25 parts, polystyrene tree 7 parts of fat, 20 parts of vinyon particle, nano imvite 8 parts, titanate coupling agent 0.9 part, nano silicon 2.8 parts, de- Titanium-type nano titanium oxide 9 parts, lubricant 3.6 parts, plasticizer 2.6 parts, 0.9 part of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment seven:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 15 parts, polystyrene tree 10 parts of fat, 18 parts of vinyon particle, nano imvite 10 parts, titanate coupling agent 1.5 parts, nano silicon 2.5 parts, De-titanium-type nano titanium oxide 6 parts, lubricant 2.3 parts, plasticizer 3.4 parts, 1 part of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment eight:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 22 parts, polystyrene tree 9 parts of fat, 17 parts of vinyon particle, nano imvite 9 parts, titanate coupling agent 1.3 parts, nano silicon 4.5 parts, de- Titanium-type nano titanium oxide 10 parts, lubricant 4.5 parts, plasticizer 3 parts, 1 part of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Embodiment nine:
A kind of nano packaging material, it is made up of the raw material of following parts by weight: acrylic resin 12 parts, polystyrene tree 12 parts of fat, 23 parts of vinyon particle, nano imvite 7 parts, titanate coupling agent 1.1 parts, nano silicon 3 parts, de- Titanium-type nano titanium oxide 7.5 parts, lubricant 2.6 parts, plasticizer 2.5 parts, 0.5 part of antioxidant.
The preparation method of described nano packaging material, comprises the following steps:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de- Titanium-type nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-with injection machine pressing after extruding 3min, then it is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing in vinyon particle, step (1) After after 40-50 minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
Finally illustrating, above example is only in order to illustrate technical scheme and unrestricted, although with reference to relatively The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the skill of the present invention Art scheme is modified or equivalent, and without deviating from objective and the scope of the technical program, it all should be contained in the present invention Right in the middle of.

Claims (5)

1. a nano packaging material, it is characterised in that described nano packaging material is made up of the raw material of following parts by weight: poly- Allyl resin 10-25 part, polystyrene resin 5-12 part, vinyon particle 14-25 part, nano imvite 7-11 part, titanium Acid esters coupling agent 0.8-1.5 part, nano silicon 2.5-5 part, de-titanium-type nano titanium oxide 5-10 part, lubricant 1.5- 4.5 parts, plasticizer 2-5 part, antioxidant 0.5-1.2 part.
A kind of nano packaging material the most according to claim 1, it is characterised in that described nano packaging material is by following heavy The raw material of amount number is made: acrylic resin 14 parts, polystyrene resin 7 parts, 16 parts of vinyon particle, nano imvite 8 parts, titanate coupling agent 1 part, nano silicon 3.6 parts, de-titanium-type nano titanium oxide 6 parts, lubricant 3 parts, plasticizer 3.5 parts, 1 part of antioxidant.
A kind of nano packaging material the most according to claim 1, it is characterised in that described nano packaging material is by following heavy The raw material of amount number is made: acrylic resin 21 parts, polystyrene resin 8 parts, 17 parts of vinyon particle, nano imvite 10 parts, titanate coupling agent 1.2 parts, nano silicon 3.8 parts, de-titanium-type nano titanium oxide 8 parts, lubricant 2 parts, plasticising Agent 3 parts, 0.9 part of antioxidant.
A kind of nano packaging material the most according to claim 1, it is characterised in that described nano packaging material is by following heavy The raw material of amount number is made: acrylic resin 12 parts, polystyrene resin 8 parts, 17 parts of vinyon particle, nano imvite 11 parts, titanate coupling agent 1.5 parts, nano silicon 4 parts, de-titanium-type nano titanium oxide 6 parts, lubricant 4 parts, plasticizer 4 parts, 1.2 parts of antioxidant.
5. according to the preparation method of the nano packaging material according to any one of claim 1-4, it is characterised in that include following Step:
(1) by acrylic resin, polystyrene resin, nano imvite, titanate coupling agent, nano silicon and de-titanium-type Nano titanium oxide, after the high speed mixing machine mixing of 90-100 minute, cools down 1-3min with injection machine pressing after extruding, then It is cut to nano-particle；
(2) by the nano-particle of preparation, lubricant, plasticizer, antioxidant mixing 40-50 in vinyon particle, step (1) After after minute, the nano material film becoming thickness to be 45-60um with twin-screw extrusion forming machine blown film.
CN201610651826.3A 2016-08-04 2016-08-04 A kind of nano packaging material and preparation method thereof Pending CN106188773A (en)

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Publication number Priority date Publication date Assignee Title
CN110343318A (en) * 2019-07-23 2019-10-18 李光宽 A kind of high temperature resistant PE film and preparation method thereof that natural-nanometer fiber is modified

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Application publication date: 20161207