CN106188104A - There is the double triazole two dimension copper complex monocrystalline of anthracene nucleus and the application of hydrogen adsorption character - Google Patents
There is the double triazole two dimension copper complex monocrystalline of anthracene nucleus and the application of hydrogen adsorption character Download PDFInfo
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- CN106188104A CN106188104A CN201610602629.2A CN201610602629A CN106188104A CN 106188104 A CN106188104 A CN 106188104A CN 201610602629 A CN201610602629 A CN 201610602629A CN 106188104 A CN106188104 A CN 106188104A
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- Prior art keywords
- triazole
- copper complex
- anthracene nucleus
- anthracene
- monocrystalline
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 32
- 239000001257 hydrogen Substances 0.000 title claims abstract description 32
- 150000001454 anthracenes Chemical class 0.000 title claims abstract description 18
- 150000003852 triazoles Chemical class 0.000 title claims abstract description 18
- 150000004699 copper complex Chemical class 0.000 title claims abstract description 17
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 11
- 239000010949 copper Substances 0.000 claims abstract description 15
- 239000013078 crystal Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000000706 filtrate Substances 0.000 claims abstract description 6
- 230000008569 process Effects 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 239000011232 storage material Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 230000005260 alpha ray Effects 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 abstract description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 abstract 2
- 229910002651 NO3 Inorganic materials 0.000 description 10
- 238000003860 storage Methods 0.000 description 9
- 239000012621 metal-organic framework Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- BRUOAURMAFDGLP-UHFFFAOYSA-N 9,10-dibromoanthracene Chemical compound C1=CC=C2C(Br)=C(C=CC=C3)C3=C(Br)C2=C1 BRUOAURMAFDGLP-UHFFFAOYSA-N 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000005751 Copper oxide Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- -1 metals hydride Chemical class 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- MWVTWFVJZLCBMC-UHFFFAOYSA-N 4,4'-bipyridine Chemical group C1=NC=CC(C=2C=CN=CC=2)=C1 MWVTWFVJZLCBMC-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- 239000013132 MOF-5 Substances 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229920001795 coordination polymer Polymers 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005564 crystal structure determination Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0015—Organic compounds; Solutions thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses the double triazole two dimension copper complex monocrystalline of anthracene nucleus and application, its structure: [Cu (L) with hydrogen adsorption character1.5(NO3)(H2O)2](NO3)·3H2O, wherein, L=1 [9 (1H 1,2,4 triazole 1 base) anthracene 10 base] 1H 1,2,4 triazole.Also disclose the preparation method of monocrystalline simultaneously.It is to use " room temperature volatility process ", i.e. Cu (NO3)2·6H2O and L filters after stirring half an hour in water, and filtrate room temperature obtains being suitable for the blue bulk crystals of X ray single crystal diffraction after volatilizing one week.Wherein Cu (NO3)2·6H2The mol ratio of O and L is 1:1.The present invention further discloses the double triazole two dimension copper complex monocrystalline of anthracene nucleus as hydrogen storage material application in terms of adsorbed hydrogen.
Description
The present invention obtains the subsidy of Tianjin innovation team of Education Commission (TD12-5037).
Technical field
The present invention relates to the preparation method and applications of triazole copper complex hydrogen storage material, be a kind of anthracene nucleus in particular
Double triazole two dimension copper complex monocrystalline and application.
Background technology
The synthesis of metal-organic framework (MOFs) and character research are the nothings that nineteen nineties Later development gets up
One of important field of research in chemical machine and materials chemistry.Owing to open metal-organic coordination polymer density is little, it is only
/ 3rd of conventional metals hydride, use MOFs can be substantially reduced the weight of hydrogen storage device as hydrogen storage media.This feature
Especially meet the hydrogen-feeding system requirement of hydrogen cell automobile.In addition such material also has that specific surface area is big, pore volume is big
Feature, be therefore a kind of novel high-capacity light hydrogen occluding material, the hydrogen storage method the most having become a kind of novel simplicity should
Transport and give birth to.It is, in general, that hydrogen storage mechanism can be divided into chemisorbed and physical absorption, and the hydrogen storage mechanism of coordination compound is mostly physics
Absorption.The Kitagawa etc. of Japan in 1997 reports the metal-organic framework that 4,4 '-bipyridyl constructs, and to have adsorbed gas little
After the character of molecule [S. Kitagawa etc.,Angew. Chem. Int. Ed.1997, 36, 1725], correlational study draws
Play the extensive attention of countries in the world.American scientist Yaghi in 2003 etc. report micropore metal-organic frame MOF-5 tool
After having good hydrogen storage property [O. M. Yaghi etc.,Science2003, 300, 1127], metal-organic framework hydrogen storage skill
Art is increasingly becoming 21st century international emerging research frontier.
Summary of the invention
The present invention is i.e. to select Cu (NO3)2·6H2O and L filters after stirring half an hour in water, and filtrate room temperature volatilizees one week
After obtain be suitable for X-ray single crystal diffraction blue bulk crystals [Cu (L)1.5(NO3)(H2O)2](NO3)·3H2O (1) (L =
1-[9-(1H-1,2,4-triazole-1-base) anthracene-10-base]-1H-1,2,4-triazole).This complex monocrystal is as hydrogen storage material
Hydrogen can be adsorbed by material.
Following technical scheme is current inventor provides for this:
The double triazole two dimension copper complex monocrystalline of a kind of anthracene nucleus, it is characterised in that this mono-crystalline structures uses APEX II CCD monocrystalline to spread out
Penetrating instrument, use through graphite monochromatised Mok alpha ray, λ=0.71073 is incident radiation, withω-2θScan mode is received
Collection point diffraction, obtains cell parameter through least square refinement, utilizes SHELXL-97 straight from difference Fourier electron density map
Connection solves single crystal data:
Its chemical constitution is as follows:
[Cu(L)1.5(NO3)(H2O)2](NO3)·3H2O, wherein
L=1-(2,5-dimethyl-4-(1H-1,2,4-triazol-1-yl) phenyl)-1H-1,2,4-triazole;
DMF=N, N'-dimethylformamide.
The present invention further discloses the preparation method of the double triazole two dimension copper complex monocrystalline of anthracene nucleus, it is characterised in that it is
Use " room temperature volatility process ", i.e. Cu (NO3)2·6H2O and L filters, after filtrate room temperature volatilizees one week after stirring half an hour in water
Obtain being suitable for the blue bulk crystals of X-ray single crystal diffraction;Wherein L and Cu (NO3)2·6H2The mol ratio of O is 1:1;
The structure of the double triazole two dimension copper complex monocrystalline of anthracene nucleus is [Cu (L)1.5(NO3)(H2O)2](NO3)·3H2O;Wherein L=
1-[9-(1H-1,2,4-triazole-1-base) anthracene-10-base]-1H-1,2,4-triazole;DMF=N, N'-dimethylformamide;
L。
The present invention further discloses the double triazole two dimension copper complex monocrystalline of anthracene nucleus and is preparing hydrogen as hydrogen storage material
The application in aspiration subsidiary formula face, experimental result shows: anthracene nucleus double triazole copper nitrate three-dimensional coordination frame complex monocrystalline is about 3.4
Under MPa, when 298 and 77 K, the hydrogen adsorption amount of this hydrogen storage Porous materials has respectively reached 0.87 and 1.38 wt%.
The double triazole two dimension copper complex monocrystalline have the advantage that of a kind of anthracene nucleus disclosed by the invention and feature are:
(1) operation is simple and easy to do.
(2) reaction yield is high, and the purity of products obtained therefrom is high.
(3) the double triazole two dimension copper complex monocrystalline of the anthracene nucleus prepared by the present invention, production cost is low, and method is easy, is suitable for
Large-scale production.The double triazole two dimension copper complex monocrystalline of anthracene nucleus has good application as hydrogen storage material in terms of storing hydrogen
Effect.
Accompanying drawing explanation
The crystal structure figure of Fig. 1: complex monocrystal;
The two-dimensional structure figure of Fig. 2: complex monocrystal;
Fig. 3: inhale hydrogen curve.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, and embodiment is only explanatory, is in no way intended to it
Limit the scope of the present invention by any way.All of raw material is such as: anthracene nucleus etc. are all to enter from chemical reagents corporation both domestic and external
Row is bought, and through continuation purification but does not directly use.Raw materials used 9,10-dibromoanthracene, 1H-1,2,4-triazole, carbon
Acid potassium, copper oxide and copper nitrate etc. are commercially available.
Embodiment 1
9,10-dibromoanthracene: 1H-1,2,4-triazole: potassium carbonate: the mol ratio of copper oxide is 2:10-15:30:1
Be separately added in equipped with 50 mL three neck round bottom flasks of magneton, reflux condenser and thermometer CuO (0.0398 mg,
0.5 mmol), potassium carbonate (2.0731 g, 15 mmol), triazole (0.345 mg, 5 mmol), 9,10-dibromoanthracenes (0.3360
G, 1 mmol), 20 mL DMF.Start stirring 100oC, reacts 24 hours.After reaction terminates, reactant liquor is down to room temperature,
Filtering, filtrate adds 100 mL water, separates out a large amount of precipitation, sucking filtration, collects filter cake, yield 60%.
Embodiment 2
1-[9-(1H-1,2,4-triazole-1-base) anthracene-10-base]-1H-1,2,4-triazole (0.1 mmol) and Cu
(NO3)2·6H2O (0.1 mmo) filters after stirring half an hour in the mixed solvent of 10 mL water and 2 mL DMF, and filtrate is indigo plant
Color.Room temperature has the blue bulk crystals of applicable X-ray single crystal diffraction after volatilizing one week.Productivity: 35%.Elementary analysis
(C54H56Cu2N22O22) theoretical value (%): C, 43.46;H, 3.78;N, 20.65.Measured value: C, 43.49;H, 3.88;N,
20.69。
Embodiment 3
Crystal structure determination uses APEX II CCD single crystal diffractometer, uses through graphite monochromatised Mok alpha ray, and λ=
0.71073 is incident radiation, withω-2θScan mode collects point diffraction, obtains structure cell ginseng through least square refinement
Number, utilizes software to solve crystal structure from difference Fourier electron density map, and through Lorentz lorentz and polarity effect correction.All of
H atom is synthesized by difference Fourier and determines through preferable position calculation.Detailed axonometry data:
Embodiment 4
The suction hydrogen curve of metal-organic framework hydrogen storage Porous materials is as shown in Figure 3.The hydrogen adsorption carried out under 298 and 77 K is real
Testing is an adsorption process quickly, has reached thermodynamical equilibrium, it is believed that this is physical adsorption process within several seconds.
This adsorption process belongs to first kind gas absorption type, and this is also the MOFs most typical one of poromerics adsorption gas molecule.
Hydrogen is located in duct, and the adsorbance that size limit in duct is one layer or which floor hydrogen molecule.This coordination compound has
One key factor of hydrogen adsorption character is that Co (II) the ion coordination number after dehydration is the most saturated, beneficially hydrogen molecule with
Co (II) ion combines with weak interaction.When about 3.4 MPa and 77 K, the adsorbance of hydrogen has reached 1.38 wt%.
After the preferred embodiment described in detail, it is familiar with this skilled worker and is clearly understood that, without departing from above-mentioned
Can carry out various change and amendment under claim and spirit, all technical spirit according to the present invention are to above example institute
Any simple modification, equivalent variations and the modification made, belongs to the scope of technical solution of the present invention.And the present invention is not illustrated
The restriction of example embodiment in book.
Claims (3)
1. the monocrystalline of the double triazole two dimension copper complex of anthracene nucleus, it is characterised in that this mono-crystalline structures uses APEX II CCD mono-
Brilliant diffractometer, uses through graphite monochromatised Mok alpha ray, and λ=0.71073 is incident radiation, withω-2θScanning side
Formula collects point diffraction, obtains cell parameter through least square refinement, utilizes software solution from difference Fourier electron density map
Go out single crystal data:
Its chemical constitution is as follows:
[Cu(L)1.5(NO3)(H2O)2](NO3)·3H2O, wherein
L=1-[9-(1H-1,2,4-triazole-1-base) anthracene-10-base]-1H-1,2,4-triazole.
2. the preparation method of the double triazole two dimension copper complex monocrystalline of anthracene nucleus described in claim 1, it is characterised in that it is " often to use
Temperature volatility process ", i.e. i.e. Cu (NO3)2·6H2O and L filters after stirring half an hour in water, and filtrate room temperature obtains after volatilizing one week
It is suitable for the blue bulk crystals of X-ray single crystal diffraction;Wherein, Cu (NO3)2·6H2The mol ratio of O and L is 1:1;
The structure of the double triazole two dimension copper complex monocrystalline of anthracene nucleus is [Cu (L)1.5(NO3)(H2O)2](NO3)·3H2O;Wherein L=
1-[9-(1H-1,2,4-triazole-1-base) anthracene-10-base]-1H-1,2,4-triazole;DMF=N, N'-dimethylformamide;
L。
3. the double triazole two dimension copper complex monocrystalline of anthracene nucleus described in claim 1 as hydrogen storage material in terms of preparation is to hydrogen adsorption
Application.
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Citations (1)
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CN105418647A (en) * | 2016-01-05 | 2016-03-23 | 天津师范大学 | Anthracene nucleus di-triazole three-dimensional copper nitrate complex single crystal and application |
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CN105418647A (en) * | 2016-01-05 | 2016-03-23 | 天津师范大学 | Anthracene nucleus di-triazole three-dimensional copper nitrate complex single crystal and application |
Non-Patent Citations (2)
Title |
---|
纪穆为等: ""金属有机框架化合物(MOFs)的研究状况"", 《山东化工》 * |
许春慧等: ""金属有机骨架材料上气体吸附存储与分离的研究进展"", 《浙江师范大学学报(自然科学版)》 * |
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