CN106186980A - Utilize the concrete that tower mountain mine tailing produces - Google Patents

Utilize the concrete that tower mountain mine tailing produces Download PDF

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Publication number
CN106186980A
CN106186980A CN201610558911.5A CN201610558911A CN106186980A CN 106186980 A CN106186980 A CN 106186980A CN 201610558911 A CN201610558911 A CN 201610558911A CN 106186980 A CN106186980 A CN 106186980A
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CN
China
Prior art keywords
parts
concrete
mine tailing
tower mountain
tower
Prior art date
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Pending
Application number
CN201610558911.5A
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Chinese (zh)
Inventor
张真弟
张彦鹏
赵建强
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Linfen Huaji New Building Materials Co Ltd
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Linfen Huaji New Building Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201610558911.5A priority Critical patent/CN106186980A/en
Publication of CN106186980A publication Critical patent/CN106186980A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2015Sulfate resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to a kind of concrete utilizing tower mountain mine tailing to produce, be to be prepared from by the raw material of following parts by weight: tower mountain CHARACTERISTICS OF TAILINGS SAND 278 328 parts, tower mountain mine tailing building stones 1,124 1354 parts, carbon fiber-containing cement 298 384 parts, 121 186 parts of flyash, alumina cement 214 261 parts, 91 154 parts of graphite, additive 10 12 parts, 124 184 parts of water, ferrite powder 50 95 parts, conduction flocculus 25 61 parts.The concrete of the present invention utilizes ore deposit, tower mountain tail to replace part sand and the interpolation of compound additive, enhance the erosion of the sulfate resistance of concrete, improve the durability of concrete, not only improving the performance of concrete mix, especially concrete cohesiveness improves, and the phenomenon such as bleeding, isolation reduces, water-retaining property strengthens, and fill iron ore mine in large quantities and to the intensity of concrete and do not make significant difference, efficiently utilize iron ore mine, energy-conserving and environment-protective;Preparation is simple for the present invention, be easily achieved.The composition that can shield electromagnetic wave simultaneously contained in the present invention and there is the composition improving electric conductivity.

Description

Utilize the concrete that tower mountain mine tailing produces
Technical field
The invention belongs to technical field of concrete production, be specifically related to a kind of concrete utilizing tower mountain mine tailing to produce.
Background technology
The countries that at present many industry are flourishing have developed the fresh target as mine development, tail using mining waste The comprehensive utilization in ore deposit and the degree of improvement are as weighing a national science and technology level and the mark of economic development level.
Abroad carrying out Tailings utilization research relatively early, state's tailings glass technology such as the U.S., Russia, Canada is the most ripe, Tailings glass rate is higher, and the recycling of iron mine tailings has caused the attention of every country, the iron mine tail of some developed countries Slag recovery utilization rate has reached more than 60%, has even accomplished to stack mine without mine tailing.External practice have shown that, by ore deposit the most for many years Mountain mine tailing carries out whole development utilization as complex mineral raw material, is just becoming economical and practical new mineral resources.It not only can make Originally the mine of resource exhaustion or inadequate resource becomes the recovery of new resources base again and extension produces, and can open up green wood The sciemtifec and technical sphere of material, promotes scientific and technological progress, can also solve environmental pollution simultaneously, improves the ecological environment and renovate territory.At present Domestic iron ore mine output capacity averagely up to more than 70%, according to statistics, within 2000-2009 years, iron mine tailings is discharged in the whole nation altogether 28.32 hundred million tons, account for the 45% of all metal tailings.Iron tailings comprehensive utilization ratio is only 14%, and the utilization rate of iron tailings is the most more Low.
In the tower mountain village of Linfen, Shanxi Province, in the past due to a large amount of exploitated ores, a large amount of discarded mine tailing building stones heaps Amassing in gully, pile up like a mountain, dug dead meal mountain under for it with private due to neighbouring villager later, cause mine tailing stone due to Load-bearing is unbalance, there occurs building stones landslide accident, causes and just works under mountain and movable over one hundred people death, but also makes to work as The governor in the Meng of former Shanxi vice-governor is punished by relevant department, and this accident causes the most serious shadow socially Ring.Owing to tower mountain mine tailing stone containing substantial amounts of mineralogical composition, the performance of concrete there is improvement greatly.The present invention is just More preferable to twice laid and production performance concrete is proposed.
Summary of the invention
It is an object of the invention to provide a kind of concrete utilizing tower mountain mine tailing to produce.The present invention not only increases mixed The erosion of the sulfate resistance of solidifying soil, improves the durability of concrete, and improves the performance of concrete mix, improve The intensity of concrete, energy-conserving and environment-protective.
The technical solution used in the present invention: utilize the concrete that tower mountain mine tailing produces, it is characterised in that by following weight The raw material of number is prepared from: tower mountain CHARACTERISTICS OF TAILINGS SAND 278-328 part, tower mountain mine tailing building stones 1124-1354 part, carbon fiber-containing water Mud 298-384 part, flyash 121-186 part, alumina cement 214-261 part, graphite 91-154 part, additive 10-12 part, water 124-184 part, ferrite powder 50-95 part, conduction flocculus 25-61 part.
Further, described additive be water reducer, air entraining agent, corrosion inhibitor, pumping admixture, aliphatic high-efficiency water reducing agent, One or more in AEA extender.
Further, the described mine tailing stone that tower mountain mine tailing is Linfen, Shanxi area special product, this mine tailing stone chemical composition As follows:: SiO2For 54-76%, Al2O3For 10-15%, Fe2O3For 40-50%, CaO be 4-7%, MgO be 5-7%, silico-calcium acid Salt is 5-7%, K2O is 1-3%, Na2O is 3-6%, tetra calcium aluminoferrite is 7-9%, SO3It is 0.001-for 0.04-0.09%, Cl 0.004%。
The basic active of further, described tower mountain CHARACTERISTICS OF TAILINGS SAND is 0.072%, single-stage maximum crush index is 29%, SO3Content is 0.09%, chloride ion content 0.001%.
The basic active of further, described tower mountain mine tailing building stones is 0.025%, single-stage maximum crush index is 5%, SO3Content is 0.07%, chloride ion content 0.002%.
Compared with prior art it provides the benefit that the present invention: the concrete of the present invention utilizes ore deposit, tower mountain tail replacement part Sand and the interpolation of compound additive, enhance the erosion of the sulfate resistance of concrete, improves the durability of concrete, no Only improving the performance of concrete mix, especially concrete cohesiveness improves, and the phenomenon such as bleeding, isolation reduces, and water-retaining property increases By force, and fill iron ore mine in large quantities and to the intensity of concrete and do not make significant difference, efficiently utilize iron ore mine, energy-conservation Environmental protection;Preparation is simple for the present invention, be easily achieved.The composition that can shield electromagnetic wave simultaneously contained in the present invention With there is the composition improving electric conductivity.
Detailed description of the invention
Embodiment 1
Utilize the concrete that tower mountain mine tailing produces, it is characterised in that be prepared from by the raw material of following parts by weight: Ta Ershan CHARACTERISTICS OF TAILINGS SAND 278 parts, tower mountain mine tailing building stones 1124 parts, carbon fiber-containing cement 298 parts, 121 parts of flyash, alumina cement 214 parts, 91 parts of graphite, additive 10 parts, 124 parts of water, ferrite powder 50 parts, conduction flocculus 25 parts.
Described additive is water reducer, corrosion inhibitor, aliphatic high-efficiency water reducing agent, AEA extender.
The described mine tailing stone that tower mountain mine tailing is Linfen, Shanxi area special product, this mine tailing stone chemical composition is as follows: SiO2 It is 54 parts, Al2O3It is 10 parts, Fe2O3Be 40 parts, CaO be 4 parts, MgO be 5 parts, silico-calcium hydrochlorate be 5 parts, K2O is 1 part, Na2O is 3 Part, tetra calcium aluminoferrite are 7 parts, SO3Be 0.04 part, Cl be 0.001 part.
The basic active of described tower mountain CHARACTERISTICS OF TAILINGS SAND is 0.072%, single-stage maximum crush index is 29%, SO3Content is 0.09%, chloride ion content 0.001%.
Embodiment 2
Utilize the concrete that tower mountain mine tailing produces, it is characterised in that be prepared from by the raw material of following parts by weight: Ta Ershan CHARACTERISTICS OF TAILINGS SAND 3000 parts, tower mountain mine tailing building stones 1202 parts, carbon fiber-containing cement 321 parts, 145 parts of flyash, alumina cement 230 Part, 120 parts of graphite, additive 11 parts, 140 parts of water, ferrite powder 60 parts, conduction flocculus 45 parts.
Described, described additive is water reducer, corrosion inhibitor, pumping admixture, AEA extender.
Described, the described mine tailing stone that tower mountain mine tailing is Linfen, Shanxi area special product, this mine tailing stone chemical composition is such as Under: SiO2It is 60 parts, Al2O3It is 12 parts, Fe2O3Be 45 parts, CaO be 6 parts, MgO be 6 parts, silico-calcium hydrochlorate be 6 parts, K2O is 2 parts, Na2O is 4 parts, tetra calcium aluminoferrite is 8 parts, SO3Be 0.06 part, Cl be 0.003 part.
Described, the basic active of described tower mountain mine tailing building stones is 0.025%, single-stage maximum crush index is 5%, SO3 Content is 0.07%, chloride ion content 0.002%.
Embodiment 3
Utilize the concrete that tower mountain mine tailing produces, it is characterised in that be prepared from by the raw material of following parts by weight: Ta Ershan CHARACTERISTICS OF TAILINGS SAND 328 parts, tower mountain mine tailing building stones 1354 parts, carbon fiber-containing cement 384 parts, 186 parts of flyash, alumina cement 261 parts, 154 parts of graphite, additive 12 parts, 184 parts of water, ferrite powder 95 parts, conduction flocculus 61 parts.
Described, described additive is air entraining agent, pumping admixture, aliphatic high-efficiency water reducing agent.
Described, the described mine tailing stone that tower mountain mine tailing is Linfen, Shanxi area special product, this mine tailing stone chemical composition is such as Under:: SiO2It is 76 parts, Al2O3It is 15 parts, Fe2O3Be 50 parts, CaO be 7%, MgO be 7 parts, silico-calcium hydrochlorate be 7 parts, K2O is 3 Part, Na2O is 6 parts, tetra calcium aluminoferrite is 9 parts, SO3Be 0.09 part, Cl be 0.004 part.
Described, the basic active of described tower mountain CHARACTERISTICS OF TAILINGS SAND is 0.072%, single-stage maximum crush index is 29%, SO3's Content is 0.09%, chloride ion content 0.001%.
Described, the basic active of described tower mountain mine tailing building stones is 0.025%, single-stage maximum crush index is 5%, SO3 Content be 0.07%, chloride ion content 0.002%.

Claims (5)

1. utilize the concrete that tower mountain mine tailing produces, it is characterised in that be prepared from by the raw material of following parts by weight:
Tower mountain CHARACTERISTICS OF TAILINGS SAND 278-328 part, tower mountain mine tailing building stones 1124-1354 part, carbon fiber-containing cement 298-384 part, powder Coal ash 121-186 part, alumina cement 214-261 part, graphite 91-154 part, additive 10-12 part, water 124-184 part, ferrite Powder 50-95 part, conduction flocculus 25-61 part.
The concrete utilizing tower mountain mine tailing to produce the most according to claim 1, it is characterised in that described additive is One or more in water reducer, air entraining agent, corrosion inhibitor, pumping admixture, aliphatic high-efficiency water reducing agent, AEA extender.
The concrete utilizing tower mountain mine tailing to produce the most according to claim 1, it is characterised in that described tower mountain tail Ore deposit is the mine tailing stone of Linfen, Shanxi area special product, and this mine tailing stone chemical composition is as follows:: SiO2For 54-76%, Al2O3For 10- 15%, Fe2O3For 40-50%, CaO be 4-7%, MgO be 5-7%, silico-calcium hydrochlorate be 5-7%, K2O is 1-3%, Na2O is 3- 6%, tetra calcium aluminoferrite is 7-9%, SO3It is 0.001-0.004% for 0.04-0.09%, Cl.
The concrete utilizing tower mountain mine tailing to produce the most according to claim 1, it is characterised in that described tower mountain tail The basic active of ore in sand form is 0.072%, single-stage maximum crush index is 29%, SO3Content is 0.09%, chloride ion content 0.001%.
The concrete utilizing tower mountain mine tailing to produce the most according to claim 1, it is characterised in that described tower mountain tail The basic active of ore charge is 0.025%, single-stage maximum crush index is 5%, SO3Content is 0.07%, chloride ion content 0.002%.
CN201610558911.5A 2016-07-17 2016-07-17 Utilize the concrete that tower mountain mine tailing produces Pending CN106186980A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112521076A (en) * 2020-12-15 2021-03-19 中国十七冶集团有限公司 Iron tailing high-slump high-strength conductive concrete and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1721357A (en) * 2004-07-12 2006-01-18 西南科技大学 Cement based composite materials with electromagnetic screen function
CN101880133A (en) * 2010-06-13 2010-11-10 中国建筑材料科学研究总院 Light thermal insulation mortar with electromagnetic wave absorption function and construction method thereof
CN102850011A (en) * 2011-07-01 2013-01-02 北京建筑材料科学研究总院有限公司 Technological process for preparing active powder concrete by using iron tailing
CN104628326A (en) * 2015-02-16 2015-05-20 福建省盛威建设发展有限公司 Concrete with electromagnetic wave radiation protection function and preparation method thereof
CN105481319A (en) * 2015-12-29 2016-04-13 青岛磊鑫混凝土有限公司 Concrete prepared from aggregate chips, iron tailing sand and polycarboxylic acid water reducing agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1721357A (en) * 2004-07-12 2006-01-18 西南科技大学 Cement based composite materials with electromagnetic screen function
CN101880133A (en) * 2010-06-13 2010-11-10 中国建筑材料科学研究总院 Light thermal insulation mortar with electromagnetic wave absorption function and construction method thereof
CN102850011A (en) * 2011-07-01 2013-01-02 北京建筑材料科学研究总院有限公司 Technological process for preparing active powder concrete by using iron tailing
CN104628326A (en) * 2015-02-16 2015-05-20 福建省盛威建设发展有限公司 Concrete with electromagnetic wave radiation protection function and preparation method thereof
CN105481319A (en) * 2015-12-29 2016-04-13 青岛磊鑫混凝土有限公司 Concrete prepared from aggregate chips, iron tailing sand and polycarboxylic acid water reducing agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112521076A (en) * 2020-12-15 2021-03-19 中国十七冶集团有限公司 Iron tailing high-slump high-strength conductive concrete and preparation method thereof

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Application publication date: 20161207