CN106186793A - A kind of cement expansive material - Google Patents

A kind of cement expansive material Download PDF

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Publication number
CN106186793A
CN106186793A CN201610521223.1A CN201610521223A CN106186793A CN 106186793 A CN106186793 A CN 106186793A CN 201610521223 A CN201610521223 A CN 201610521223A CN 106186793 A CN106186793 A CN 106186793A
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CN
China
Prior art keywords
parts
expansive material
cement expansive
powder
gypsum fibrosum
Prior art date
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Pending
Application number
CN201610521223.1A
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Chinese (zh)
Inventor
曹平
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Individual
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Individual
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Publication date
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Priority to CN201610521223.1A priority Critical patent/CN106186793A/en
Publication of CN106186793A publication Critical patent/CN106186793A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to concrete additives technical field, especially a kind of cement expansive material;The mass parts composition of this cement expansive material is as follows: 12 25 parts of pitchstone ore in sand form powder, meerschaum 46 parts, gangue 6 12 parts, Gypsum Fibrosum powder 20 30 parts, calcium stearate 6 10 parts, nano barium titanate aluminum fiber 38 parts, polyvinyl alcohol 6 10 parts, hydroxypropylcelluloether ether 35 parts, potassium sulfate 18 parts, 24 parts of ammonium sulfate;The cement expansive material of the present invention have raw material be easy to get, the feature such as with low cost and function admirable, reasonably combined, with high admixture usage ratio, low-cementitious material usage ratio as principal character by each component;Ultimately form that workability is good, intensity is high, crack resistance is good, impervious good and life-span long concrete auxiliary agent.

Description

A kind of cement expansive material
Technical field
The present invention relates to concrete additives technical field, especially a kind of cement expansive material.
Background technology
It is known that the construction of seabed tunnel is the project under construction the most complicated in current transport development, standard is the highest;Tunnel Road concrete does not allows hazardness crack occur, and its maximum length of embedment is at about-40m.Seabed tunnel many employings batch production is pre- Tunneling boring processed pours, and one-time-concreting concrete square amount reaches about 3400m3, and design strength is that 56d reaches C50, simultaneously for ensureing early The form removal of age, it is desirable to 3d intensity reaches C30.Owing to tunnel concrete structure needs to bear high pressure sea water effect for a long time, therefore Anti-permeability performance, cracking resistance and the long term life of tunnel concrete is proposed requirements at the higher level.Expand frequently with adding at present Agent improves the cracking resistance of concrete;Mostly be with calcined kaolin, alunite, dickite, aluminium ore slag, calcium aluminate clinker or The entringite class extender of calcium sulphoaluminate grog and Gypsum Fibrosum preparation, exists that expansion energy is low, expansion rate and concrete coagulation core water Change that reaction rate is not mated, volume is big, alkali content is high easily causes the unfavorable factors such as alkali-aggregate reaction;With CaO as main component Calcium oxide expansion agents, exists that speed of expansion is too fast, Bulking Time is short, expands with concrete shrinkage speed is inharmonious, be difficult to protect The shortcoming such as deposit;, there is speed of expansion the slowest in the magnesium oxide class extender with MgO as main component, expansion start time is the most backward In the concrete shrinkage time started, it is impossible to play the drawbacks such as cracking resistance effect.
Summary of the invention
The technical problem to be solved in the present invention is: overcome deficiency of the prior art, it is provided that the coagulation of a kind of stable performance Soil expansion agent.
For solving above-mentioned technical problem, the technical solution used in the present invention is as follows:
A kind of cement expansive material, the mass parts composition of this cement expansive material is as follows: pitchstone ore in sand form powder 12-25 part, Meerschaum 4-6 part, gangue 6-12 part, Gypsum Fibrosum powder 20-30 part, calcium stearate 6-10 part, nano barium titanate aluminum fiber 3-8 part, poly- Vinyl alcohol 6-10 part, hydroxypropylcelluloether ether 3-5 part, potassium sulfate 1-8 part, ammonium sulfate 2-4 part.
As preferably, described a kind of cement expansive material, it is characterised in that: described pitchstone ore in sand form powder is S105 level pine Fat rock ore in sand form powder.
As preferably, described a kind of cement expansive material, it is characterised in that: described Gypsum Fibrosum powder select desulfurization gypsum powder and The mixture of dephosphorization Gypsum Fibrosum powder, its mass ratio is 1:1.5, and fineness is 250 mesh.
As preferably, described a kind of cement expansive material, it is characterised in that: described calcium stearate by calcium chloride with stearic The mixture reaction generation of acid and Palmic acid sodium salt washes removal sodium chloride with water and obtains.
As preferably, described a kind of cement expansive material, it is characterised in that comprise the following steps:
(1) cement expansive material proportion design, its mass parts composition as follows: 12 parts of pitchstone ore in sand form powder, meerschaum 4 parts, Gangue 6 parts, Gypsum Fibrosum powder 20 parts, calcium stearate 6 parts, nano barium titanate aluminum fiber 3 parts, polyvinyl alcohol 6 parts, hydroxypropylcelluloether ether 3 parts, potassium sulfate 1 part, 2 parts of ammonium sulfate;
(2) mixture stirs, and whipping temp is 15-18 DEG C.
Technical scheme is used to provide the benefit that:
The cement expansive material of the present invention have raw material be easy to get, the feature such as with low cost and function admirable, by each group That divides is reasonably combined, with high admixture usage ratio, low-cementitious material usage ratio as principal character;Ultimately form workability good Well, intensity is high, crack resistance is good, impervious good and life-span long concrete auxiliary agent.
The cement expansive material mineralogical composition of the present invention is reasonable, and Bulking Time, speed can be anti-with concrete with swell increment Should shrink and strength development is coordinated mutually, have good swelling properties;Volume is low, and construction usage is convenient, do not affect early strength and Later strength, does not increase slump loss, it is adaptable to anti-crack and anti-seepage requires high water-proof concrete and pumping construction Water-proof concrete.
Detailed description of the invention
A kind of cement expansive material, the mass parts composition of this cement expansive material is as follows: pitchstone ore in sand form powder 12-25 part, Meerschaum 4-6 part, gangue 6-12 part, Gypsum Fibrosum powder 20-30 part, calcium stearate 6-10 part, nano barium titanate aluminum fiber 3-8 part, poly- Vinyl alcohol 6-10 part, hydroxypropylcelluloether ether 3-5 part, potassium sulfate 1-8 part, ammonium sulfate 2-4 part.
As preferably, described a kind of cement expansive material, it is characterised in that: described pitchstone ore in sand form powder is S105 level pine Fat rock ore in sand form powder.
As preferably, described a kind of cement expansive material, it is characterised in that: described Gypsum Fibrosum powder select desulfurization gypsum powder and The mixture of dephosphorization Gypsum Fibrosum powder, its mass ratio is 1:1.5, and fineness is 250 mesh.
As preferably, described a kind of cement expansive material, it is characterised in that: described calcium stearate by calcium chloride with stearic The mixture reaction generation of acid and Palmic acid sodium salt washes removal sodium chloride with water and obtains.
As preferably, described a kind of cement expansive material, it is characterised in that comprise the following steps:
(1) cement expansive material proportion design, its mass parts composition as follows: 12 parts of pitchstone ore in sand form powder, meerschaum 4 parts, Gangue 6 parts, Gypsum Fibrosum powder 20 parts, calcium stearate 6 parts, nano barium titanate aluminum fiber 3 parts, polyvinyl alcohol 6 parts, hydroxypropylcelluloether ether 3 parts, potassium sulfate 1 part, 2 parts of ammonium sulfate.
(2) mixture stirs, and whipping temp is 15-18 DEG C.
With the above-mentioned desirable embodiment according to the present invention for enlightenment, by above-mentioned description, relevant staff is complete Entirely can carry out various change and amendment in the range of without departing from this invention technological thought.The technology of this invention The content that property scope is not limited in description, it is necessary to determine its technical scope according to right.

Claims (5)

1. a cement expansive material, it is characterised in that the mass parts composition of this cement expansive material is as follows: pitchstone ore in sand form powder 12-25 part, meerschaum 4-6 part, gangue 6-12 part, Gypsum Fibrosum powder 20-30 part, calcium stearate 6-10 part, nano barium titanate aluminum fiber 3-8 part, polyvinyl alcohol 6-10 part, hydroxypropylcelluloether ether 3-5 part, potassium sulfate 1-8 part, ammonium sulfate 2-4 part.
2. according to a kind of cement expansive material described in claim 1, it is characterised in that: described pitchstone ore in sand form powder is S105 Level pitchstone ore in sand form powder.
3. according to a kind of cement expansive material described in claim 1-2, it is characterised in that: described Gypsum Fibrosum powder selects desulfurated plaster Powder and the mixture of dephosphorization Gypsum Fibrosum powder, its mass ratio is 1: 1.5, and fineness is 250 mesh.
4. according to a kind of cement expansive material described in claim 1-2, it is characterised in that: described calcium stearate by calcium chloride with The mixture reaction generation of stearic acid and Palmic acid sodium salt washes removal sodium chloride with water and obtains.
5. according to a kind of cement expansive material described in claim 1-4, it is characterised in that comprise the following steps:
(1) cement expansive material proportion design, its mass parts composition is as follows: 12 parts of pitchstone ore in sand form powder, meerschaum 4 parts, bastard coal 6 parts of stone, Gypsum Fibrosum powder 20 parts, calcium stearate 6 parts, nano barium titanate aluminum fiber 3 parts, polyvinyl alcohol 6 parts, hydroxypropylcelluloether ether 3 parts, Potassium sulfate 1 part, 2 parts of ammonium sulfate;
(2) mixture stirs, and whipping temp is 15-18 DEG C.
CN201610521223.1A 2016-07-02 2016-07-02 A kind of cement expansive material Pending CN106186793A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610521223.1A CN106186793A (en) 2016-07-02 2016-07-02 A kind of cement expansive material

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Application Number Priority Date Filing Date Title
CN201610521223.1A CN106186793A (en) 2016-07-02 2016-07-02 A kind of cement expansive material

Publications (1)

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CN106186793A true CN106186793A (en) 2016-12-07

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1607194A (en) * 2003-10-14 2005-04-20 郭金华 Low-alkali low-mixing cement expansive material
CN103011659A (en) * 2012-12-21 2013-04-03 江西迪特科技有限公司 Super retarding high-performance water reducer
CN103601413A (en) * 2013-10-20 2014-02-26 青岛海伴诚远塑业有限公司 Improved concrete anti-cracking modifier
CN103641376A (en) * 2013-11-04 2014-03-19 青岛汇而通商贸有限公司 Concrete crack resistance modifier
CN103937119A (en) * 2014-02-26 2014-07-23 谢彪 Medical-grade wide-waveband high-light avoiding performance polyvinyl chloride granula
CN104262133A (en) * 2014-09-10 2015-01-07 江山市艺天科技有限公司 Production method and equipment of granular calcium stearate
CN204174128U (en) * 2014-09-10 2015-02-25 江山市艺天科技有限公司 Particulate state calcium stearate production unit and tablets press
US20150135997A1 (en) * 2012-05-22 2015-05-21 The Curators Of The University Of Missouri Internal curing composition for concrete mixtures
CN105130252A (en) * 2015-09-02 2015-12-09 王嘉文 Environment-friendly cement expanding agent

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1607194A (en) * 2003-10-14 2005-04-20 郭金华 Low-alkali low-mixing cement expansive material
US20150135997A1 (en) * 2012-05-22 2015-05-21 The Curators Of The University Of Missouri Internal curing composition for concrete mixtures
CN103011659A (en) * 2012-12-21 2013-04-03 江西迪特科技有限公司 Super retarding high-performance water reducer
CN103601413A (en) * 2013-10-20 2014-02-26 青岛海伴诚远塑业有限公司 Improved concrete anti-cracking modifier
CN103641376A (en) * 2013-11-04 2014-03-19 青岛汇而通商贸有限公司 Concrete crack resistance modifier
CN103937119A (en) * 2014-02-26 2014-07-23 谢彪 Medical-grade wide-waveband high-light avoiding performance polyvinyl chloride granula
CN104262133A (en) * 2014-09-10 2015-01-07 江山市艺天科技有限公司 Production method and equipment of granular calcium stearate
CN204174128U (en) * 2014-09-10 2015-02-25 江山市艺天科技有限公司 Particulate state calcium stearate production unit and tablets press
CN105130252A (en) * 2015-09-02 2015-12-09 王嘉文 Environment-friendly cement expanding agent

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