CN106186605A - A kind of endrin Contaminated Sewage Sludge inorganic agent and preparation method thereof - Google Patents
A kind of endrin Contaminated Sewage Sludge inorganic agent and preparation method thereof Download PDFInfo
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- CN106186605A CN106186605A CN201610619518.2A CN201610619518A CN106186605A CN 106186605 A CN106186605 A CN 106186605A CN 201610619518 A CN201610619518 A CN 201610619518A CN 106186605 A CN106186605 A CN 106186605A
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- Prior art keywords
- endrin
- parts
- inorganic agent
- mud
- sewage sludge
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 52
- DFBKLUNHFCTMDC-GKRDHZSOSA-N endrin Chemical compound C([C@@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@@H]2[C@H]2[C@@H]1O2 DFBKLUNHFCTMDC-GKRDHZSOSA-N 0.000 title claims abstract description 50
- 239000010801 sewage sludge Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 63
- 230000008569 process Effects 0.000 claims abstract description 58
- 230000004048 modification Effects 0.000 claims abstract description 47
- 238000012986 modification Methods 0.000 claims abstract description 47
- 229910052979 sodium sulfide Inorganic materials 0.000 claims abstract description 35
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000003365 glass fiber Substances 0.000 claims abstract description 25
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 25
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 25
- 235000019394 potassium persulphate Nutrition 0.000 claims abstract description 25
- 229920002681 hypalon Polymers 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000010802 sludge Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 72
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 24
- 239000008187 granular material Substances 0.000 claims description 20
- 230000010355 oscillation Effects 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- -1 t-butyl perbenzoate ester Chemical class 0.000 claims description 14
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims description 13
- 238000003828 vacuum filtration Methods 0.000 claims description 12
- 238000000889 atomisation Methods 0.000 claims description 10
- 238000000643 oven drying Methods 0.000 claims description 10
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 17
- 230000008901 benefit Effects 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 238000011109 contamination Methods 0.000 abstract description 3
- 239000003905 agrochemical Substances 0.000 description 9
- 241000272814 Anser sp. Species 0.000 description 8
- 239000000575 pesticide Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 description 2
- 229950006824 dieldrin Drugs 0.000 description 2
- NGPMUTDCEIKKFM-UHFFFAOYSA-N dieldrin Natural products CC1=C(Cl)C2(Cl)C3C4CC(C5OC45)C3C1(Cl)C2(Cl)Cl NGPMUTDCEIKKFM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 208000010513 Stupor Diseases 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 206010047513 Vision blurred Diseases 0.000 description 1
- MVDXHIJBNLVYIZ-UHFFFAOYSA-N [Br].CC(c1ccccc1)c1ccccc1 Chemical compound [Br].CC(c1ccccc1)c1ccccc1 MVDXHIJBNLVYIZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 206010061428 decreased appetite Diseases 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Materials Engineering (AREA)
- Treatment Of Sludge (AREA)
Abstract
The invention discloses a kind of endrin Contaminated Sewage Sludge inorganic agent and preparation method thereof, described endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 24 28 parts of nano modification mud, cobblestone 5 10 parts, chlorosulfonated polyethylene 10 20 parts, polyacrylamide 14 20 parts, TDE 10 15 parts, glass fibre 35 parts, 0.2 0.4 parts of sodium sulfide, potassium peroxydisulfate 0.2 0.4 parts；The present invention can make to be reached GB15618 2008 standard by the physical and chemical index of endrin severe contamination soil；Process technique is simple, and dosage is few, and treatment effect is good, stable performance, and contaminated soil restoration degree is high, can significantly reduce the cost of sludge treating agent, has good economic benefit and social benefit widely.
Description
Technical field
The present invention relates to a kind of sludge technology field, specifically a kind of endrin Contaminated Sewage Sludge inorganic agent and preparation side thereof
Method.
Background technology
Global Agriculture due to illness, worm, the grass three disasters and the grain loss that causes, account for about the half of annual total output of grain.Have
The use of machine pesticide probably can retrieve the loss of wherein 30%.At present, the organic agricultural chemicals of worldwide production and use has reached 1300
Multiple, the most widely used about kind more than 250.China has marched toward world pesticide big producing country, 1994, China's pesticide yield
It is 26.6 ten thousand t, accounts for the 1/10 of world pesticide total output.Within following certain time, organic agricultural chemicals is still guarantor and produces, increase production and tie up
Hold the important means that stable food increases；The environmental pollution that organic agricultural chemicals use simultaneously brings causes to be paid close attention to widely, pesticide
Pollute important topic and the hot issue having become agricultural development research.Currently, the correlational study of organic agricultural chemicals contaminated soil is few
The fewest.Organic agricultural chemicals is diffused with two kinds of forms in soil.A kind of is that the irregular movement of organic agricultural chemicals molecule causes
Lateral transfer；Another kind of then be the organic agricultural chemicals in soil by flowing water or the infitration process of action of gravity, and in soil successively
Distribution.Latter form is the Main Patterns of organic agricultural chemicals diffusion in soil, and organic agricultural chemicals constantly occurs in infitration process
Adsorption and desorption, Transport And Transformation, degrade and the environmental behaviour such as volatilization.Common chemical redemption has that repairing efficiency is short, repairs into
The advantages such as effect is fast, but, due to it costly, easily cause the secondary pollution of soil.Dieldrin, the most organic as one
Chloro pesticide, after human body poisoning, symptom has headache, dizziness, weak, inappetence, blurred vision, has a sleepless night, trembles, and severe one causes
Stupor, the most easily persistency residual in soil；Therefore improvement and the reparation to endrin Contaminated Sewage Sludge, is the most urgent
Task.
Summary of the invention
It is an object of the invention to provide a kind of endrin Contaminated Sewage Sludge inorganic agent and preparation method thereof, above-mentioned to solve
The problem proposed in background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: nano modification mud 24-28
Part, cobblestone 5-10 part, chlorosulfonated polyethylene 10-20 part, polyacrylamide 14-20 part, TDE 10-15 part, glass
Glass fiber 3-5 part, sodium sulfide 0.2-0.4 part, potassium peroxydisulfate 0.2-0.4 part；The preparation method of described nano modification mud: first
T-butyl perbenzoate ester, Hexalin, isoprene are mixed and carries out vacuum filtration and process and obtain mixture, then by second boron
Alkane, mud and mixture carry out reacting i.e. obtaining nano modification mud under microwave.
As the further scheme of the present invention: described endrin Contaminated Sewage Sludge inorganic agent, the most former according to weight portion
Material is: nano modification mud 25-27 part, cobblestone 7-8 part, chlorosulfonated polyethylene 13-17 part, polyacrylamide 15-19 part, ten
Bromine diphenylethane 10-15 part, glass fibre 3-5 part, sodium sulfide 0.2-0.4 part, potassium peroxydisulfate 0.2-0.4 part；Described nanometer changes
The preparation method of property mud: first t-butyl perbenzoate ester, Hexalin, isoprene are mixed and carry out vacuum filtration process
Obtain mixture, then carry out reacting under microwave i.e. obtaining nano modification mud with mixture by diborane, mud.
As the further scheme of the present invention: state endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion
For: 26 parts of nano modification mud, cobblestone 8 parts, chlorosulfonated polyethylene 15 parts, polyacrylamide 17 parts, TDE 13
Part, glass fibre 4 parts, 0.3 part of sodium sulfide, potassium peroxydisulfate 0.3 part；The preparation method of described nano modification mud: first incited somebody to action
T-butyl perbenzoate ester, Hexalin, isoprene mix and carry out vacuum filtration process obtain mixture, then by diborane,
Mud and mixture carry out reacting i.e. obtaining nano modification mud under microwave.
As the further scheme of the present invention: the mesh number of described cobblestone is 800 mesh.
As the further scheme of the present invention: the mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, processes in double-shaft mixers
20min, is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 300-600W, and the time is
50-60 minute, obtain mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
As the further scheme of the present invention: the power that in step (3), sonic oscillation processes is 450W, and the time is 55 points
Clock.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention can make the physical and chemical index by endrin severe contamination soil reach GB15618-2008 standard；Process
Technique is simple, and dosage is few, and treatment effect is good, stable performance, and contaminated soil restoration degree is high, can significantly reduce
The cost of sludge treating agent, has good economic benefit and social benefit widely.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 24 parts of nano modification mud, goose
5 parts of cobble, chlorosulfonated polyethylene 10 parts, polyacrylamide 14 parts, TDE 10 parts, glass fibre 3 parts, sodium sulfide
0.2 part, potassium peroxydisulfate 0.2 part；The preparation method of described nano modification mud: first by t-butyl perbenzoate ester, Hexalin,
Isoprene mix and carry out vacuum filtration process obtain mixture, then diborane, mud are entered under microwave with mixture
Row reaction i.e. obtains nano modification mud；The mesh number of described cobblestone is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, processes in double-shaft mixers
20min, is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 300W, and the time is 50 points
Clock, obtains mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Embodiment 2
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 25 parts of nano modification mud, goose
7 parts of cobble, chlorosulfonated polyethylene 13 parts, polyacrylamide 15 parts, TDE 10 parts, glass fibre 3 parts, sodium sulfide
0.2 part, potassium peroxydisulfate 0.2 part；The preparation method of described nano modification mud: first by t-butyl perbenzoate ester, Hexalin,
Isoprene mix and carry out vacuum filtration process obtain mixture, then diborane, mud are entered under microwave with mixture
Row reaction i.e. obtains nano modification mud；The mesh number of described cobblestone is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, processes in double-shaft mixers
20min, is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 300W, and the time is 50 points
Clock, obtains mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Embodiment 3
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 26 parts of nano modification mud, goose
8 parts of cobble, chlorosulfonated polyethylene 15 parts, polyacrylamide 17 parts, TDE 13 parts, glass fibre 4 parts, sodium sulfide
0.3 part, potassium peroxydisulfate 0.3 part；The preparation method of described nano modification mud: first by t-butyl perbenzoate ester, Hexalin,
Isoprene mix and carry out vacuum filtration process obtain mixture, then diborane, mud are entered under microwave with mixture
Row reaction i.e. obtains nano modification mud；The mesh number of described cobblestone is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, processes in double-shaft mixers
20min, is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 450W, and the time is 55 points
Clock, obtains mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Embodiment 4
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 27 parts of nano modification mud, goose
8 parts of cobble, chlorosulfonated polyethylene 17 parts, polyacrylamide 19 parts, TDE 15 parts, glass fibre 5 parts, sodium sulfide
0.4 part, potassium peroxydisulfate 0.4 part；The preparation method of described nano modification mud: first by t-butyl perbenzoate ester, Hexalin,
Isoprene mix and carry out vacuum filtration process obtain mixture, then diborane, mud are entered under microwave with mixture
Row reaction i.e. obtains nano modification mud；The mesh number of described cobblestone is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, processes in double-shaft mixers
20min, is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 600W, and the time is 60 points
Clock, obtains mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Embodiment 5
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 28 parts of nano modification mud, goose
10 parts of cobble, chlorosulfonated polyethylene 20 parts, polyacrylamide 20 parts, TDE 15 parts, glass fibre 5 parts, sodium sulfide
0.4 part, potassium peroxydisulfate 0.4 part；The preparation method of described nano modification mud: first by t-butyl perbenzoate ester, Hexalin,
Isoprene mix and carry out vacuum filtration process obtain mixture, then diborane, mud are entered under microwave with mixture
Row reaction i.e. obtains nano modification mud；The mesh number of described cobblestone is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, processes in double-shaft mixers
20min, is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 600W, and the time is 60 points
Clock, obtains mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Comparative example 1
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 26 parts of nano modification mud, goose
8 parts of cobble, polyacrylamide 17 parts, TDE 13 parts, glass fibre 4 parts, 0.3 part of sodium sulfide, potassium peroxydisulfate 0.3
Part；The preparation method of described nano modification mud: first t-butyl perbenzoate ester, Hexalin, isoprene mixing are gone forward side by side
Row vacuum filtration processes and obtains mixture, then carries out reacting under microwave i.e. obtaining nanometer with mixture by diborane, mud
Modified sewage sludge；The mesh number of described cobblestone is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone, double-shaft mixers processes 20min, extrudes system subsequently
Become the granule of 10mm diameter；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 450W, and the time is 55 points
Clock, obtains mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Comparative example 2
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 26 parts of mud, cobblestone 8 parts,
Polyacrylamide 17 parts, TDE 13 parts, glass fibre 4 parts, 0.3 part of sodium sulfide, potassium peroxydisulfate 0.3 part；Described goose
The mesh number of cobble is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, mud puts into cobblestone, double-shaft mixers processes 20min, is crushed to 10mm subsequently straight
The granule in footpath；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 450W, and the time is 55 points
Clock, obtains mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Comparative example 3
A kind of endrin Contaminated Sewage Sludge inorganic agent, according to the primary raw material of weight portion be: 26 parts of nano modification mud, goose
8 parts of cobble, chlorosulfonated polyethylene 15 parts, polyacrylamide 17 parts, TDE 13 parts, glass fibre 4 parts, sodium sulfide
0.3 part, potassium peroxydisulfate 0.3 part；The preparation method of described nano modification mud: first by t-butyl perbenzoate ester, Hexalin,
Isoprene mix and carry out vacuum filtration process obtain mixture, then diborane, mud are entered under microwave with mixture
Row reaction i.e. obtains nano modification mud；The mesh number of described cobblestone is 800 mesh；The mesh number of described sodium sulfide is 800 mesh.
The preparation method of described endrin Contaminated Sewage Sludge inorganic agent, concretely comprises the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, processes in double-shaft mixers
20min, is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, obtain after constant speed stirring at 25 DEG C
Mixture I；
(3) then, mixture I is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently
Stirring；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
Test experience
Excavator is utilized to excavate polluting soil to be repaired, different by above-described embodiment 1-5 and comparative example 1-3
After dieldrin Contaminated Sewage Sludge inorganic agent is added on the inorganic agent of surface applying 2cm thickness of contaminated soil, by polluted soil
Soil thick for top layer 20cm is mixed homogeneously by the way of turning over the inorganic agent of applying, after 10 days, carries out sampling monitoring, test
Result chart 1.
As can be seen here, in the embodiment of the present invention, the endrin Contaminated Sewage Sludge inorganic agent of preparation, has more with contrast groups example ratio
Good notable treatment effect, the present invention can make the physical and chemical index by endrin severe contamination soil reach GB15618-2008
Standard；Process technique is simple, and dosage is few, and treatment effect is good, stable performance, and contaminated soil restoration degree is high, can have
Reduce the cost of sludge treating agent to effect, there is good economic benefit and social benefit widely.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of the spirit or essential attributes of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter
From the point of view of which point, all should regard embodiment as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all by fall in the implication of equivalency and scope of claim
Change is included in the present invention.
Although moreover, it will be appreciated that this specification is been described by according to embodiment, but the most each embodiment only wraps
Containing an independent technical scheme, this narrating mode of description is only that for clarity sake those skilled in the art should
Description can also be formed those skilled in the art through appropriately combined as an entirety, the technical scheme in each embodiment
May be appreciated other embodiments.
Claims (7)
1. an endrin Contaminated Sewage Sludge inorganic agent, it is characterised in that be according to the primary raw material of weight portion: nano modification is dirty
Mud 24-28 part, cobblestone 5-10 part, chlorosulfonated polyethylene 10-20 part, polyacrylamide 14-20 part, TDE 10-
15 parts, glass fibre 3-5 part, sodium sulfide 0.2-0.4 part, potassium peroxydisulfate 0.2-0.4 part；The preparation side of described nano modification mud
Method: first t-butyl perbenzoate ester, Hexalin, isoprene mixed and carry out vacuum filtration and process and obtain mixture, connects
And carry out reacting under microwave i.e. obtaining nano modification mud with mixture by diborane, mud.
Endrin Contaminated Sewage Sludge inorganic agent the most according to claim 1, it is characterised in that described endrin pollutes dirt
Mud inorganic agent, according to the primary raw material of weight portion be: nano modification mud 25-27 part, cobblestone 7-8 part, chlorosulfonated polyethylene
13-17 part, polyacrylamide 15-19 part, TDE 10-15 part, glass fibre 3-5 part, sodium sulfide 0.2-0.4 part,
Potassium peroxydisulfate 0.2-0.4 part；The preparation method of described nano modification mud: first by t-butyl perbenzoate ester, Hexalin, different
Pentadiene mix and carry out vacuum filtration process obtain mixture, then diborane, mud are carried out under microwave with mixture
Reaction i.e. obtains nano modification mud.
Endrin Contaminated Sewage Sludge inorganic agent the most according to claim 1 and 2, it is characterised in that described endrin is dirty
Dye sludge treating agent, according to the primary raw material of weight portion be: 26 parts of nano modification mud, cobblestone 8 parts, chlorosulfonated polyethylene 15
Part, polyacrylamide 17 parts, TDE 13 parts, glass fibre 4 parts, 0.3 part of sodium sulfide, potassium peroxydisulfate 0.3 part；Described
The preparation method of nano modification mud: first t-butyl perbenzoate ester, Hexalin, isoprene are mixed and carry out vacuum and take out
Filter processes and obtains mixture, then carries out reacting under microwave i.e. obtaining nano modification mud with mixture by diborane, mud.
Endrin Contaminated Sewage Sludge inorganic agent the most according to claim 3, it is characterised in that the mesh number of described cobblestone is
800 mesh.
Endrin Contaminated Sewage Sludge inorganic agent the most according to claim 3, it is characterised in that the mesh number of described sodium sulfide is
800 mesh.
6. the preparation method of the endrin Contaminated Sewage Sludge inorganic agent as described in claim 1-5 is arbitrary, it is characterised in that
Concretely comprise the following steps:
(1) first, nano modification mud puts into cobblestone and chlorosulfonated polyethylene, double-shaft mixers processes 20min,
It is crushed to the granule of 10mm diameter subsequently；
(2) then, granule is mixed homogeneously with polyacrylamide, TDE, mixed after constant speed stirring at 25 DEG C
Thing I；
(3) secondly, mixture I carries out sonic oscillation process, and the power that sonic oscillation processes is 300-600W, and the time is 50-60
Minute, obtain mixtures II；
(4) then, mixtures II is carried out atomization process, carries out constant temperature with glass fibre, sodium sulfide, potassium peroxydisulfate subsequently and stir
Mix；Oven drying at low temperature pelletize at a temperature of being subsequently placed at 6 DEG C, obtains endrin Contaminated Sewage Sludge inorganic agent.
The preparation method of endrin Contaminated Sewage Sludge inorganic agent the most according to claim 6, it is characterised in that step (3)
The power that middle sonic oscillation processes is 450W, and the time is 55 minutes.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101811764A (en) * | 2010-04-29 | 2010-08-25 | 南京神克隆科技有限公司 | Efficient ecological type sewage and sludge treating agent and preparation method thereof |
| CN102765774A (en) * | 2011-05-04 | 2012-11-07 | 哈尔滨工业大学 | Method for removal of persistent organic pollutants by dispersed siloxane lipid adsorbent |
| CN103118983A (en) * | 2010-04-13 | 2013-05-22 | 莫利康普矿物有限责任公司 | Methods and devices for enhancing contaminant removal by rare earths |
| CN105198181A (en) * | 2015-05-29 | 2015-12-30 | 新疆科力新技术发展有限公司 | Environment-friendly oil field sludge treating agent and preparation method thereof |
-
2016
- 2016-07-29 CN CN201610619518.2A patent/CN106186605A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103118983A (en) * | 2010-04-13 | 2013-05-22 | 莫利康普矿物有限责任公司 | Methods and devices for enhancing contaminant removal by rare earths |
| CN101811764A (en) * | 2010-04-29 | 2010-08-25 | 南京神克隆科技有限公司 | Efficient ecological type sewage and sludge treating agent and preparation method thereof |
| CN102765774A (en) * | 2011-05-04 | 2012-11-07 | 哈尔滨工业大学 | Method for removal of persistent organic pollutants by dispersed siloxane lipid adsorbent |
| CN105198181A (en) * | 2015-05-29 | 2015-12-30 | 新疆科力新技术发展有限公司 | Environment-friendly oil field sludge treating agent and preparation method thereof |
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