CN106178937A - Garbage loading embeading foul smell collection and treatment device - Google Patents

Garbage loading embeading foul smell collection and treatment device Download PDF

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Publication number
CN106178937A
CN106178937A CN201610571141.8A CN201610571141A CN106178937A CN 106178937 A CN106178937 A CN 106178937A CN 201610571141 A CN201610571141 A CN 201610571141A CN 106178937 A CN106178937 A CN 106178937A
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CN
China
Prior art keywords
ozone
foul smell
shower
gas
room
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610571141.8A
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Chinese (zh)
Inventor
蔡金傍
苏良湖
孙旭
张龙江
赵志强
陈玉东
陈梅
刘臣伟
何斐
杭小帅
王伟民
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Nanjing Institute of Environmental Sciences MEP
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Nanjing Institute of Environmental Sciences MEP
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Application filed by Nanjing Institute of Environmental Sciences MEP filed Critical Nanjing Institute of Environmental Sciences MEP
Priority to CN201610571141.8A priority Critical patent/CN106178937A/en
Publication of CN106178937A publication Critical patent/CN106178937A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/90Odorous compounds not provided for in groups B01D2257/00 - B01D2257/708

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treating Waste Gases (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The present invention relates to a kind of emission-control equipment, especially garbage loading embeading foul smell collection and treatment device, including ozone generation mechanism, supply tank, ozone solution mixing pit and ozone reaction room;Described ozone generation mechanism and supply tank are connected with gas-liquid mixing pump by pipeline respectively;Gas-liquid mixed delivery side of pump is connected with ozone solution mixing pit, the outlet of described ozone solution mixing pit is connected with catalyst addition room, agitating device is had in catalyst addition room, catalyst addition room is connected with shower by water pump, described shower is arranged on the top that ozone reaction is indoor, spray head being distributed on described shower, has foul smell import bottom ozone reaction room, gas outlet is arranged at top.This device utilizes ozone generation mechanism to produce ozone and is mixed together with water, and adds ozone catalyst, improves ozone treatment effect, this apparatus structure is simple and convenient to operate, and equipment is the most perishable, the waste gas after process does not has foul smell, can be with qualified discharge or comprehensively utilize.

Description

Garbage loading embeading foul smell collection and treatment device
Technical field
The present invention relates to a kind of emission-control equipment, especially garbage loading embeading foul smell collection and treatment device.
Background technology
The rubbish landfill gas of refuse landfill, containing methane and carbon dioxide, these gases are by having in landfill rubbish The degraded of machine refuse produces.Owing to rubbish landfill gas can migrate from top layer, landfill field and underground to neighboring area, the most inflammable easily The high methane gas of quick-fried and fuel value is for all constituting potential hazard near garbage loading embeading, in order to reduce rubbish heap to greatest extent Fill out the potential hazard that this migration of gas brings, it is necessary to collected by rubbish landfill gas and be acted upon.But, due to landfill gas There is the strongest stink, so before landfill gas discharge or comprehensive utilization, needing to carry out deodorization process.
First rubbish material produces volatile fatty acid, including butanoic acid, acetic acid and propanoic acid.It is characterized in Stench threshold value is low, and stench intensity is big.In landfill heap body, the pH of rubbish material is generally higher than 7, odorant by VFAS to low molecule The odorant of quality converts..By to landfill gas sampling analysis find, foul gas be mainly composed of dimethyl sulfide, two Propane mercaptan, two butane thiol etc..The basic reason that odorant produces is that in Organic substance catabolic process, anaerobic state causes point Solve the not exclusively intermediate product formed.
New refuse is more likely formed odorant, and when particularly year landfill is highly more than 2m, change becomes apparent from.Malodorant Matter kind complexity is various, and the most sentient odorant of olfactory sensation with people has kind more than 4000 so far, is divided into 5 classes: 1. sulfur-bearing Compound, 2. nitrogen-containing compound, 3. halogen and derivant, 4. hydro carbons and aromatic hydrocarbon;5. oxygen-bearing organic matter.
At present, existing odor removal measure and technology mainly for concentrating the odorant of discharge, according to material composition with release The difference put.
Absorption method, is divided into physisorphtion, dipping adsorbent method etc..The adsorbent of foul waste gas occupies with activated carbon Many.Often there is due to adsorbent higher adsorptive selectivity, thus there is higher separating effect, trace materials can be removed, But adsorption capacity is the highest.Absorption method is the most usually used in combination with other purification methods (absorb, condense, be catalyzed burning etc.). The shortcoming of this method is that processing equipment volume is big, and flow process is complicated, and when having micelle material or other impurity in waste gas, adsorbent is volatile Effect.
Absorption process, absorption process is the different methods separating gaseous contaminant utilizing Solubility of Substances.Absorption process purifies gas State pollutant, are to utilize suitable absorbent optionally to remove gaseous contaminant from waste gas to eliminate pollution.This method Efficiently, equipment is simple, one-time investment expense is low, is widely used in gaseous contamination control.The major defect of absorption cleaning is Liquid after absorbing need to be processed, equipment corrosion-vulnerable
Combustion method, for poisonous and harmful, the process of the foul gas being not required to recovery, conventional combustion method.Shortcoming is catalyst Price is higher, and requires in waste gas without the composition causing catalysqt deactivation.
Summary of the invention
For solving the problems referred to above, the present invention provides a kind of equipment to mention rubbish little, that technique is simple, equipment is uncorruptible Landfill odor treating device, concrete technical scheme is:
Garbage loading embeading foul smell collection and treatment device, including ozone generation mechanism, supply tank, ozone solution mixing pit and ozone Reative cell;Described ozone generation mechanism and supply tank are connected with gas-liquid mixing pump by pipeline respectively;Going out of gas-liquid mixing pump Mouth is connected with ozone solution mixing pit, and the outlet of described ozone solution mixing pit is connected with catalyst addition room, and catalyst adds Adding indoor and have agitating device, catalyst addition room is connected with shower by water pump, and described shower is arranged on ozone reaction Indoor top, is distributed spray head, has foul smell import bottom ozone reaction room on described shower, top has gas to go out Mouthful.
Described ozone reaction indoor location has corrugated plating, and the trough on corrugated plating has water dropping openings, trough to have air-vent;Ripple Card is arranged on below shower.
Splash board is had below the water dropping openings of described corrugated plating.
Being inclined plane bottom described ozone reaction room, there is outlet pipe relatively low side, and outlet pipe passes through pipeline and water pump Connecting, outlet pipe forms circulation line with shower.
The ozone that ozone generation mechanism produces is input to gas-liquid mixing pump, warp by pipeline again together with the water in supply tank Cross gas-liquid mixing pump and form ozone water solution, ozone solution mixing pit puts into appropriate ozone water solution as required to catalysis In agent addition room, in catalyst addition room, add ozone catalyst, by water pump by water-soluble for the ozone having added ozone catalyst Liquid is driven in shower, and it is indoor that aqueous solution is sprayed ozone reaction by spray head, foul smell is carried out degradation process, by foul smell Stink substance is removed.
The garbage loading embeading foul smell collection and treatment device that the present invention provides, utilizes ozone generation mechanism to produce ozone together with water Mixing, and add ozone catalyst, improving ozone treatment effect, this apparatus structure is simple and convenient to operate, and equipment is the most perishable Erosion, the waste gas after process does not has foul smell, can be with qualified discharge or comprehensively utilize.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention.
Detailed description of the invention
The detailed description of the invention of the present invention is described, as shown in Figure 1 in conjunction with accompanying drawing: garbage loading embeading foul smell collection processes dress Put, including ozone generation mechanism 1, supply tank 2, ozone solution mixing pit 4 and ozone reaction room 11;Described ozone generation mechanism 1 and supply tank 2 be connected with gas-liquid mixing pump 3 by pipeline respectively;The outlet of gas-liquid mixing pump 3 is with ozone solution mixing pit 4 even Connecing, the outlet of described ozone solution mixing pit 4 is connected with catalyst addition room 5, has agitating device in catalyst addition room 5, Catalyst addition room 5 is connected with shower 6 by water pump 12, and described shower 6 is arranged on the top in ozone reaction room 11, Spray head 9 being distributed on described shower 6, has foul smell import 10 bottom ozone reaction room 11, gas outlet 13 is arranged at top.
Being provided with corrugated plating 7 in described ozone reaction room 11, the trough on corrugated plating 7 has water dropping openings, trough to have ventilative Hole;Corrugated plating 7 is arranged on below shower 6.
Splash board 8 is had below the water dropping openings of described corrugated plating 7.
Being inclined plane bottom described ozone reaction room 11, there is outlet pipe relatively low side, and outlet pipe passes through pipeline and water Pump 12 connects, and outlet pipe and shower 6 form circulation line.
The effect of ozone generation mechanism 1 is to produce ozone, and the ozone of generation passes through pipeline again together with the water in supply tank 2 Being input to gas-liquid mixing pump 3, ozone and water are mixed through gas-liquid mixing pump 3, form ozone water solution, ozone water solution is the most defeated Delivering in ozone solution mixing pit 4, ozone solution mixing pit 4 is put into appropriate ozone water solution as required and is added to catalyst In room 5, in catalyst addition room 5, add ozone catalyst, and stir, ozone catalyst will have been added by water pump 12 Ozone water solution is driven in shower 6, and aqueous solution is sprayed in ozone reaction room 11 by spray head 9, in ozone reaction room 11 In, the waste gas that refuse landfill is collected, after foul smell import 10 enters, processes through ozone water solution spray.Wherein in order to extend Aqueous solution and foul smell time of contact with contact fully, devise corrugated plating 7, after shower water is retained by corrugated plating 7, pass through corrugated plating Water dropping openings at trough on 7, then falls into and carries out spattering into little water droplet on the splash board 8 of lower section again, increase aqueous solution by the most lower With foul smell touch opportunity, the air-vent at the trough of corrugated plating 7 of foul smell below rises.
Ozone water solution can be circulated utilization, flows to shower by back of pipeline.According to water quality situation, it is replaced Discharge.

Claims (4)

1. garbage loading embeading foul smell collection and treatment device, it is characterised in that: include ozone generation mechanism (1), supply tank (2), ozone Solution mixing pit (4) and ozone reaction room (11);Described ozone generation mechanism (1) and supply tank (2) respectively by pipeline with Gas-liquid mixing pump (3) connects;The outlet of gas-liquid mixing pump (3) is connected with ozone solution mixing pit (4), and described ozone solution mixes The outlet closing pond (4) is connected with catalyst addition room (5), has agitating device, catalyst addition room in catalyst addition room (5) (5) being connected with shower (6) by water pump (12), described shower (6) is arranged on the top in ozone reaction room (11), institute Spray head (9) is distributed on the shower (6) stated, and foul smell import (10) is arranged at ozone reaction room (11) bottom, and top has gas to go out Mouth (13).
Garbage loading embeading foul smell collection and treatment device the most according to claim 1, it is characterised in that: described ozone reaction room (11) being provided with corrugated plating (7) in, the trough on corrugated plating (7) has water dropping openings, crest to have air-vent;Corrugated plating (7) is arranged on Shower (6) lower section.
Garbage loading embeading foul smell collection and treatment device the most according to claim 2, it is characterised in that: described corrugated plating (7) Water dropping openings below have splash board (8).
4. according to the garbage loading embeading foul smell collection and treatment device described in any one of Claim 1-3, it is characterised in that: described Bottom, ozone reaction room (11) is inclined plane, and there is outlet pipe relatively low side, and outlet pipe is connected by pipeline and water pump (12), goes out Water pipe forms circulation line with shower (6).
CN201610571141.8A 2016-07-19 2016-07-19 Garbage loading embeading foul smell collection and treatment device Pending CN106178937A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106853331A (en) * 2017-02-23 2017-06-16 复旦大学 A kind of device of large-wind-volume low-concentration foul gas purification

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03254890A (en) * 1990-03-02 1991-11-13 Japan Steel Works Ltd:The Ozone water making apparatus
CN2820768Y (en) * 2005-07-21 2006-09-27 张家港圣鑫环保科技有限公司 Deodorizing device for garbage transfer compressing station
CN204093291U (en) * 2014-09-25 2015-01-14 杨新玉 A kind of oxidation spray cleaning device to waste gas in refuse disposal
CN104826462A (en) * 2015-05-06 2015-08-12 胡志勇 Garbage station waste gas processing and deodorizing system
CN204746048U (en) * 2015-06-03 2015-11-11 佛山市新泰隆环保设备制造有限公司 Processing apparatus of catalytic oxidation organic waste gas and foul smell
CN105688631A (en) * 2016-01-19 2016-06-22 青岛欧帝欧环保科技发展有限公司 Hydroxyl oxidation deodorization treatment method and system
KR20160081297A (en) * 2014-12-31 2016-07-08 주식회사 그린이엔지 Environment friendly cleaning apparatus using Ozone photocatalyst

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03254890A (en) * 1990-03-02 1991-11-13 Japan Steel Works Ltd:The Ozone water making apparatus
CN2820768Y (en) * 2005-07-21 2006-09-27 张家港圣鑫环保科技有限公司 Deodorizing device for garbage transfer compressing station
CN204093291U (en) * 2014-09-25 2015-01-14 杨新玉 A kind of oxidation spray cleaning device to waste gas in refuse disposal
KR20160081297A (en) * 2014-12-31 2016-07-08 주식회사 그린이엔지 Environment friendly cleaning apparatus using Ozone photocatalyst
CN104826462A (en) * 2015-05-06 2015-08-12 胡志勇 Garbage station waste gas processing and deodorizing system
CN204746048U (en) * 2015-06-03 2015-11-11 佛山市新泰隆环保设备制造有限公司 Processing apparatus of catalytic oxidation organic waste gas and foul smell
CN105688631A (en) * 2016-01-19 2016-06-22 青岛欧帝欧环保科技发展有限公司 Hydroxyl oxidation deodorization treatment method and system

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Title
湖南大学化工系无机物工学教研室: "《小氮肥生产工艺》", 31 October 1973, 湖南人民出版社 *
王树楹: "《现代填料塔技术指南》", 31 August 1998, 中国石化出版社 *
马晓建等: "《生化工程与设备》", 31 August 1996, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106853331A (en) * 2017-02-23 2017-06-16 复旦大学 A kind of device of large-wind-volume low-concentration foul gas purification
CN106853331B (en) * 2017-02-23 2023-11-24 复旦大学 Device for purifying large-air-quantity low-concentration malodorous gas

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Application publication date: 20161207

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