CN106173170A - A kind of anti-caries lollipop and preparation method thereof - Google Patents
A kind of anti-caries lollipop and preparation method thereof Download PDFInfo
- Publication number
- CN106173170A CN106173170A CN201610533181.3A CN201610533181A CN106173170A CN 106173170 A CN106173170 A CN 106173170A CN 201610533181 A CN201610533181 A CN 201610533181A CN 106173170 A CN106173170 A CN 106173170A
- Authority
- CN
- China
- Prior art keywords
- lollipop
- weight portion
- gum
- essence
- vitamin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000011475 lollipops Nutrition 0.000 title claims abstract description 68
- 230000000675 anti-caries Effects 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 235000009508 confectionery Nutrition 0.000 claims abstract description 37
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 33
- 239000011707 mineral Substances 0.000 claims abstract description 33
- 210000000481 breast Anatomy 0.000 claims abstract description 32
- 150000003839 salts Chemical class 0.000 claims abstract description 32
- 239000000686 essence Substances 0.000 claims abstract description 29
- 150000005846 sugar alcohols Chemical class 0.000 claims abstract description 28
- 229940112822 chewing gum Drugs 0.000 claims abstract description 22
- 235000015218 chewing gum Nutrition 0.000 claims abstract description 22
- 241000894006 Bacteria Species 0.000 claims abstract description 21
- 102000016943 Muramidase Human genes 0.000 claims abstract description 20
- 108010014251 Muramidase Proteins 0.000 claims abstract description 20
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 claims abstract description 20
- 229960000274 lysozyme Drugs 0.000 claims abstract description 20
- 235000010335 lysozyme Nutrition 0.000 claims abstract description 20
- 239000004325 lysozyme Substances 0.000 claims abstract description 20
- 239000006041 probiotic Substances 0.000 claims abstract description 20
- 230000000529 probiotic effect Effects 0.000 claims abstract description 20
- 235000018291 probiotics Nutrition 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 235000000346 sugar Nutrition 0.000 claims abstract description 18
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 16
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 16
- 239000004376 Sucralose Substances 0.000 claims abstract description 14
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 claims abstract description 14
- 235000019408 sucralose Nutrition 0.000 claims abstract description 14
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 239000002585 base Substances 0.000 claims abstract description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 30
- 239000006188 syrup Substances 0.000 claims description 18
- 235000020357 syrup Nutrition 0.000 claims description 18
- -1 hydroxyl isomaltulose Chemical compound 0.000 claims description 17
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 15
- 229930003268 Vitamin C Natural products 0.000 claims description 15
- 239000011691 vitamin B1 Substances 0.000 claims description 15
- 239000011718 vitamin C Substances 0.000 claims description 15
- 235000019154 vitamin C Nutrition 0.000 claims description 15
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 14
- 239000011265 semifinished product Substances 0.000 claims description 14
- 239000008347 soybean phospholipid Substances 0.000 claims description 14
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- 239000000600 sorbitol Substances 0.000 claims description 11
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 238000004513 sizing Methods 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000003904 phospholipids Chemical class 0.000 claims description 3
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- 241000186605 Lactobacillus paracasei Species 0.000 claims description 2
- 244000269722 Thea sinensis Species 0.000 claims 4
- 239000002023 wood Substances 0.000 claims 1
- 208000002925 dental caries Diseases 0.000 abstract description 19
- 241001122767 Theaceae Species 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 12
- 235000013305 food Nutrition 0.000 abstract description 11
- 239000000047 product Substances 0.000 description 36
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 17
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 17
- 239000000811 xylitol Substances 0.000 description 17
- 235000010447 xylitol Nutrition 0.000 description 17
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 17
- 229960002675 xylitol Drugs 0.000 description 17
- 208000002064 Dental Plaque Diseases 0.000 description 12
- 235000013616 tea Nutrition 0.000 description 12
- 239000000463 material Substances 0.000 description 7
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 230000036541 health Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229930006000 Sucrose Natural products 0.000 description 4
- 239000002671 adjuvant Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000007689 inspection Methods 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 229940024545 aluminum hydroxide Drugs 0.000 description 2
- 230000001013 cariogenic effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000013681 dietary sucrose Nutrition 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010006326 Breath odour Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 206010018276 Gingival bleeding Diseases 0.000 description 1
- 208000024283 Gingival haemorrhages Diseases 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 208000032139 Halitosis Diseases 0.000 description 1
- 208000032843 Hemorrhage Diseases 0.000 description 1
- 208000007976 Ketosis Diseases 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 208000008589 Obesity Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 208000008617 Tooth Demineralization Diseases 0.000 description 1
- 206010072665 Tooth demineralisation Diseases 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 229930003270 Vitamin B Natural products 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000170 anti-cariogenic effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 235000020186 condensed milk Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000037123 dental health Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002584 ketoses Chemical class 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 235000020824 obesity Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 208000028169 periodontal disease Diseases 0.000 description 1
- 230000003239 periodontal effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 235000015149 toffees Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/50—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
- A23G3/56—Products with edible or inedible supports, e.g. lollipops
- A23G3/563—Products with edible or inedible supports, e.g. lollipops products with an inedible support, e.g. a stick
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/50—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
- A23G3/54—Composite products, e.g. layered, coated, filled
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/066—Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the fat used
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/12—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
- A23G4/123—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing microorganisms, enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/12—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
- A23G4/126—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing vitamins, antibiotics
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/18—Chewing gum characterised by shape, structure or physical form, e.g. aerated products
- A23G4/184—Chewing gum characterised by shape, structure or physical form, e.g. aerated products products with a supported structure
- A23G4/186—Chewing gum characterised by shape, structure or physical form, e.g. aerated products products with a supported structure products with an inedible support, e.g. a stick
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/18—Chewing gum characterised by shape, structure or physical form, e.g. aerated products
- A23G4/20—Composite products, e.g. centre-filled, multi-layer, laminated
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2400/00—Lactic or propionic acid bacteria
- A23V2400/11—Lactobacillus
- A23V2400/165—Paracasei
Abstract
The present invention relates to field of food, disclose a kind of anti-caries lollipop and preparation method thereof.Lollipop of the present invention includes that gum portion and hard candy portion, described gum portion include lysozyme, probiotic bacteria, tea polyphenols, sugar alcohol, gum base, sucralose and essence；Hard candy portion includes sugar alcohol, breast mineral salt, citric acid, water, pigment and essence.Chewing gum and hard sugar are fused in lollipop by the present invention, by increasing tea polyphenols, probiotic bacteria, lysozyme and using multiple sugar alcohol to substitute sugar, improve oral environment, improve the effect of dental caries, from product novelty or both effectiveness on be all significantly better than similar dental caries sugar products.
Description
Technical field
The present invention relates to field of food, particularly relate to a kind of anti-caries lollipop and preparation method thereof.
Background technology
Dental caries is classified as after cancer and cardiovascular disease and endangers the third-largest chronic of human health by World Health Organization (WHO)
Noninfectious, along with the ratio of sugar and gourmet foods consumption rises, urban children morbidity of dental caries is significantly raised.
Showing according to the investigation of whole nation dental prevention group, China's caries incidence per capita reaches 49.88%, and suffers from periodontal in various degree more than 90%
Sick；Children caries rate reaches 80%, and in rising trend, and whole nation dental caries situation is extremely serious.
The formation of dental caries mainly has a factor of four aspects: antibacterial, food, tooth and time.In simple terms, it is simply that tooth
Inside having a kind of cariogenic antibacterial, allow the sugar in food and carbohydrate fermentation produce acid, acidic materials rest on dental surface warp
Cause tooth demineralization after a period of time, ultimately form decayed tooth.The child being in the period of growing permanent teeth for 5 years old to 7 years old is most susceptible to suffer from dental caries.
Children and teenager is the main consumer group of confectionary products, in daily life and the various climate and other natural phenomena of a season and specific field
Close, define a kind of confection culture, wherein lollipop, can accomplish nice joyful, modern design, especially a kind of favorite.But pass
The confection of system contains substantial amounts of sugar, too takes in, will cause the various problems such as dental caries, obesity, bring much to health
Negative effect.Meanwhile, the dental caries of Children and teenager and oral health, in addition to Candy for food, residual in slot of other foods
Stay, and multiplied by microorganism, ferment and corrode enamel, be also the key factor causing the oral problem such as dental caries.
Chinese patent CN104920774A discloses a kind of enzyme-added chewing gum, with lysozyme, aluminium hydroxide, vitamin C, lemon
Lemon acid, glycerol, gum base, Sorbitol, mannitol, essence, water are composition, and described chewing gum with the addition of lysozyme and Fructus Citri Limoniae
Acid, makes the activity of the pH value maximized holding lysozyme of energy of chewing gum, carries out antibacterial bacteriostatic, anti-tooth knot from biological angle
Stone, anti-caries, alleviate say smelly, suppress dental plaque, to significantly improve tooth tertiary hemorrhage；Aluminium hydroxide and vitamin C can assist bacteriolyze
Enzyme removes bacterial plaque and spot, better significantly, suppress gingival hemorrhage；Chinese patent CN1109711A discloses a kind of anti-caries
Toffee, is prepared from by white sugar, glucose pulp-water, butter, condensed milk, gelatin and tea polyphenols etc..
Although above-mentioned prior art all has certain anti-caries effect, but this effect is the most not fully up to expectations, needs
To improve further；Additionally, above-mentioned patented product is the most single, it is impossible to fully cause the favor of consumer groups.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of anti-caries lollipop and preparation method thereof so that described rod
Lollipop can improve anticariogenic effect, is mainly reflected in dental plaque index and dental plaque pH stability.
To achieve these goals, the present invention provides following technical scheme:
A kind of anti-caries lollipop, including gum portion and hard candy portion, described gum portion includes lysozyme (effect
Valency is preferably >=500000U/g), probiotic bacteria, tea polyphenols, sugar alcohol, gum base, sucralose and essence；Hard candy portion include sugar alcohol,
Breast mineral salt, citric acid, water, pigment and essence.
For the defect that existing anti-caries sugar products dental caries poor effect and product form are single, the present invention merges
Chewing gum and the product of two kinds of forms of hard sugar, and by adjusting product component, reached preferably dental caries effect, simultaneously from
Product functionality and two aspects of novelty are better than like product.
Wherein, in lollipop of the present invention, gum portion each raw material weight number is preferably:
Gum base 15-40 weight portion, sugar alcohol 30-75 weight portion, probiotic bacteria 0.01-0.1 weight portion, lysozyme 0.005-0.01
Weight portion, tea polyphenols 0.1-0.4 weight portion, sucralose 0.015-0.050 weight portion, essence 0.05-0.1 weight portion.Wherein
Sugar alcohol can more preferably 30-35 weight portion.
In certain specific embodiments of the invention, gum portion each raw material weight number is optional as follows:
(1) gum base 30 weight portion, sugar alcohol 30 weight portion, probiotic bacteria 0.05 weight portion, lysozyme 0.005 weight portion, tea is many
Phenol 0.2 weight portion, sucralose 0.02 weight portion, essence 0.05 weight portion.
(2) gum base 35 weight portion, sugar alcohol 35 weight portion, probiotic bacteria 0.1 weight portion, lysozyme 0.005 weight portion, tea polyphenols
0.3 weight portion, sucralose 0.02 weight portion, essence 0.05 weight portion.
As preferably, described hard candy portion each raw material number is as follows:
Sugar alcohol 100 weight portion, water 10-15 weight portion, breast mineral salt 0.5-1 weight portion, citric acid 1-1.5 weight portion,
Essence 0.05-0.1 weight portion, pigment 0.005-0.007 weight portion.
In certain specific embodiments of the invention, gum portion each raw material weight number is optional as follows:
(1) sugar alcohol 100 weight portion, water 10 weight portion, breast mineral salt 0.5 weight portion, citric acid 0.8 weight portion, essence
0.05 weight portion, pigment 0.005 weight portion；
(2) sugar alcohol 100 weight portion, water 15 weight portion, breast mineral salt 1 weight portion, citric acid 1 weight portion, essence 0.05
Weight portion, pigment 0.005 weight portion.
As preferably, described sugar alcohol is the one in hydroxyl isomaltulose, xylitol, sorbitol, D-mannital or two
More than Zhong.In gum portion, described sugar alcohol more preferably hydroxyl isomaltulose, xylitol, sorbitol and D-manna
Sugar alcohol, each weight portion is xylitol 5-40 weight portion, hydroxyl isomaltulose 10-20 weight portion, sorbitol 2.5-10 weight portion, D-
Mannitol 2.5-5 weight portion, in each raw material weight number that above-mentioned gum portion is embodied as, all kinds of sugar alcohol weight portions
Number is as follows:
(1) hydroxyl isomaltulose 15 weight portion, xylitol 5 weight portion, sorbitol 5 weight portion and D-mannital 5 weight
Part.
(2) hydroxyl isomaltulose 20 weight portion, xylitol 10 weight portion, sorbitol 2.5 weight portion and D-mannital 2.5
Weight portion.
In hard candy portion, described sugar alcohol more preferably hydroxyl isomaltulose and xylitol, each weight portion is different wheat
Bud ketose alcohol 25-80 weight portion, xylitol 20-75 weight portion, at each raw material weight number that above-mentioned hard candy portion is embodied as
In, all kinds of sugar alcohol parts by weight are as follows:
(1) hydroxyl isomaltulose 50 weight portion, xylitol 50 weight portion；
(2) hydroxyl isomaltulose 25 weight portion, xylitol 75 weight portion.
As preferably, probiotic bacteria of the present invention is probiotic bacteria ADP-1, i.e. Lactobacillus paracasei GMNL-33.
Gum portion of the present invention and hard candy portion can be combined in any form, the most described hard candy portion bag
Wrapping up in gum portion is interior outer double-layer structure, or described gum portion and hard candy portion are cascaded.Gum portion
Can be any shape with the shape of hard candy portion, such as spherical shape, square, cuboid etc., gum portion and hard candy portion
Weight ratio be 1:1-2.5.
The present invention can also add vitamin C, vitamin B at gum portion1, breast the nutrition such as mineral salt and soybean phospholipid
Composition, reaches the purpose of full diet supplement, coordinates other components to consolidate dental health the most further.Breast mineral therein
Matter salt is with milk surum as raw material, and through going the composition such as isolating protein, lactose to make, breast mineral salt is a kind of " new resource food ", contains
More mineral, mainly calcium and phosphorus, can use as food additive and supplementary.
As preferably, described vitamin C, vitamin B1, breast mineral salt and the content of soybean phospholipid be vitamin C 630-
13000mg/1000g lollipop, vitamin B116-33mg/1000g lollipop, breast mineral salt 2000-20000mg/1000g rod
Lollipop, soybean phospholipid 30-50mg/1000g lollipop.It is further preferred that the content of breast mineral salt and soybean phospholipid is raw for dimension
Element C 1200-1500mg/1000g lollipop, vitamin B125-30mg/1000g lollipop, breast mineral salt 5000-
10000mg/1000g lollipop, soybean phospholipid 35-50mg/1000g lollipop.
In some detailed description of the invention of the present invention, described vitamin C, vitamin B1, breast mineral salt and the content of phospholipid
Can be specifically chosen as follows:
(1) vitamin C 1200mg/1000g lollipop, vitamin B125mg/1000g lollipop, breast mineral salt
5000mg/1000g lollipop, soybean phospholipid 35mg/1000g lollipop.
(2) vitamin C 1500mg/1000g lollipop, vitamin B130mg/1000g lollipop, breast mineral salt
10000mg/1000g lollipop, soybean phospholipid 50mg/1000g lollipop.
Additionally, present invention also offers the preparation method of above-mentioned anti-caries lollipop, including:
Step 1, soften gum base, sugar alcohol and gum base mixed, reduces gum base temperature, be added to lysozyme, probiotic bacteria,
Tea polyphenols, sucralose and essence, extrude after mixing, shear, it is thus achieved that semi-finished product chewing gum, standby；
Step 2, sugar alcohol add water sugar cook, add breast mineral salt, citric acid, water, pigment and essence, stir in gained syrup
Candy syrup is obtained after mixing uniformly, standby；
Step 3, take part candy syrup inject mould, insert the hand-held rod of lollipop, be then placed in semi-finished product chewing gum, continue
Continuous parcel semi-finished product chewing gum that residue candy syrup is injected in mould, cooling sizing, it is thus achieved that described lollipop (inside and outside bilayer
Structure)；Or
By aging for semi-finished product chewing gum, put in mould, insert the hand-held rod of lollipop, in mould, then inject hard sugar sugar
Slurry, is cascaded by hand-held rod with semi-finished product chewing gum, cooling sizing, it is thus achieved that described lollipop (cascaded structure).
As preferably, step 1 is additionally included in interpolation lysozyme, probiotic bacteria, tea polyphenols, sucralose and essence simultaneously, adds
Add vitamin C, vitamin B1, breast mineral salt and phospholipid.
As preferably, described softening gum base concrete operations are:
Gum base toasts 2h～3h at 65 DEG C～72 DEG C, reaches 50-60 DEG C to gum base central temperature.
Evaluate oral health, it is common that use the characteristic presentations such as dental caries, periodontal disease and halitosis, and dental plaque is a weight
Want index, the present invention by with dental plaque indicator dye after directly observe, and according to plaque stain index score standard come right
The lollipop prepared than the present invention and the dental caries effect of existing anti-caries product, the colony bacterium of the product of the result display present invention
Speckle Mean value of index is minimum and has notable difference with existing product.Meanwhile, also by detection dental plaque pH, (this is food to the present invention
Cariogenic power and the Main Means of anti-caries effect assessment) weigh the dental caries effect of product, result show, eats product of the present invention
Dental Plaque pH is stable, without significant change, and edible table sugar series products, pH, within the monitoring phase of one hour, presents decline
The trend of rear rise.
From above technical scheme, chewing gum and hard sugar are fused in lollipop by the present invention, by increase tea polyphenols,
Probiotic bacteria, lysozyme and use multiple sugar alcohol substitute sugar, improve oral environment, no matter improve the effect of dental caries
From product novelty or the most both effectiveness on be all significantly better than similar dental caries sugar products.
Accompanying drawing explanation
Fig. 1 show the structural representation of anti-caries lollipop of the present invention；
Fig. 2 show the structural representation of anti-caries lollipop of the present invention.
Detailed description of the invention
The embodiment of the invention discloses a kind of anti-caries lollipop and preparation method thereof, those skilled in the art can use for reference
Present disclosure, is suitably modified technological parameter and realizes.Special needs to be pointed out is, all similar replacements and change are to this area skill
Being apparent from for art personnel, they are considered as being included in the present invention.Lollipop of the present invention and preparation side thereof
Method is described by preferred embodiment, and related personnel substantially can be right in without departing from present invention, spirit and scope
Method described herein and application are modified or suitably change and combine, and realize and apply the technology of the present invention.
Hereinafter a kind of anti-caries lollipop provided by the present invention and preparation method thereof is described further.
Embodiment 1: prepare anti-caries lollipop of the present invention-inside and outside double-deck chondritic lollipop
1, raw material
Gum portion: gum base 30 weight portion, hydroxyl isomaltulose 15 weight portion, xylitol 5 weight portion, sorbitol 5 weight
Amount part, D-mannital 5 weight portion, probiotic bacteria 0.05 weight portion, lysozyme 0.005 weight portion, tea polyphenols 0.2 weight portion, three
Chlorine sucrose 0.02 weight portion, essence 0.05 weight portion, vitamin C 1200mg/1000g lollipop, vitamin B1 25mg/
1000g lollipop, breast mineral salt 5000mg/1000g lollipop, soybean phospholipid 35mg/1000g lollipop.
Hard candy portion: hydroxyl isomaltulose 50 weight portion, xylitol 50 weight portion, water 10 weight portion, breast mineral salt 0.5
Weight portion, citric acid 0.8 weight portion, essence 0.05 weight portion, pigment 0.005 weight portion；
2, method
Gum base is placed on softened by baking in drying room or electrical heating baking oven, drying room or electrical heating oven temperature should be set to 65 DEG C～72 DEG C
Being advisable, the gum base in terms of chewing gum is the softest, and baking time is 2h～3h, reaches 50-60 with gum base block central temperature
DEG C it is advisable；
Xylitol, hydroxyl isomaltulose, sorbitol and D-mannital mixed material feeding；The softening of about 50-60 DEG C
In gum base, insulated and stirred, and by material uniform feeding.Under shear action, gum base can be made to be uniformly dispersed, accelerate the suction of adjuvant
Receive；
Gradually reduce gum base temperature maintenance stirring, add essence, lysozyme (titer >=500000U/g), dimension life
Element C, vitamin B1, breast mineral salt, soybean phospholipid, tea polyphenols, other supplementary materials such as probiotic bacteria and sucralose；
Extruding, excision forming, it is thus achieved that semi-finished product chewing gum, monolithic control quality is at 4-5g, standby；
Hydroxyl isomaltulose and xylitol mixing and water adding, heat up and stir off, sugar cook temperature 180 DEG C, it is thus achieved that syrup；Breast mineral
Salt, citric acid, essence, pigment adjuvant mix, and add in syrup, are kept stirring for, mixing, and are progressively cooled to 140-150 DEG C, obtain
Obtain candy syrup standby；
The most first inject part candy syrup, put into the hand-held rod of lollipop simultaneously, put into the chewing gum prepared
Semi-finished product, continue to inject candy syrup, and total grammes per square metre controls at about 10g, and product cooling molding, product schematic diagram is by Fig. 1.
Embodiment 2: prepare anti-caries of the present invention lollipop-series connection chondritic lollipop
1, raw material
Gum portion: gum base 35 weight portion, hydroxyl isomaltulose 20 weight portion, xylitol 10 weight portion, sorbitol 2.5
Weight portion, D-mannital 2.5 weight portion, probiotic bacteria 0.1 weight portion, lysozyme 0.005 weight portion, tea polyphenols 0.3 weight portion,
Sucralose 0.02 weight portion, essence 0.05 weight portion, vitamin C 1500mg/1000g lollipop, vitamin B1 30mg/
1000g lollipop, breast mineral salt 10000mg/1000g lollipop, soybean phospholipid 50mg/1000g lollipop.
Hard candy portion: hydroxyl isomaltulose 25 weight portion, xylitol 75 weight portion, water 15 weight portion, breast mineral salt 1 weight
Amount part, citric acid 1 weight portion, essence 0.05 weight portion, pigment 0.005 weight portion；
2, method
Gum base is placed on softened by baking in drying room or electrical heating baking oven, drying room or electrical heating oven temperature should be set to 65 DEG C～72 DEG C
Being advisable, the gum base in terms of chewing gum is the softest, and baking time is 2h～3h, reaches 50-60 with gum base block central temperature
DEG C it is advisable；
Xylitol, hydroxyl isomaltulose, sorbitol and D-mannital mixed material feeding；The softening of about 50-60 DEG C
In gum base, insulated and stirred, and by material uniform feeding.Under shear action, gum base can be made to be uniformly dispersed, accelerate the suction of adjuvant
Receive；
Gradually reduce gum base temperature maintenance stirring, add essence, lysozyme (titer >=500000U/g), dimension life
Element C, vitamin B1, breast mineral salt, soybean phospholipid, tea polyphenols, other supplementary materials such as probiotic bacteria and sucralose；
Extruding, excision forming, it is thus achieved that semi-finished product chewing gum, monolithic control quality is at 4-5g, standby；
Hydroxyl isomaltulose and xylitol mixing and water adding, heat up and stir off, sugar cook temperature 180 DEG C, it is thus achieved that syrup；Breast mineral
Salt, citric acid, essence, pigment adjuvant mix, and add in syrup, are kept stirring for, mixing, and are progressively cooled to 140-150 DEG C, obtain
Obtain candy syrup standby；
By aging for semi-finished product chewing gum, ageing time 12-24h, temperature is maintained at 20-25 DEG C, humidity 40-50%；Aging
After, gum portion is put in mould, put into hand-held rod simultaneously, then complete candy syrup die casting, and with sugared
Hand-held rod fixed by slurry, and hard candy portion and gum portion are cascaded by hand-held rod, and hard sugar grammes per square metre controls at about 5-6g,
Product cooling molding, product schematic diagram is by Fig. 2.
Embodiment 3: dental plaque dye test
Subjects: embodiment of the present invention 1-2 product；Patent CN104920774A embodiment 2 product；Patent
CN1109711A product；
Test method:
The healthy facing of a certain fixed range is established as observation area, each product of comparison and non-table sugar in each product
The volunteer of fruit.4～5 developers are instilled in 8ml (the about amount of water) clear water in order to gargle, spues after 30 seconds and can show
Show dental plaque.After dental plaque dyes, observe and confirm plaque index and colony's plaque index average.Plaque stain index is scored
Standard is shown in Table 1.
Table 1 plaque stain index score standard
Plaque index=person under inspection is by inspection facing score sum
Colony's plaque index average=person under inspection's plaque index sum/by inspection number
Result shows, after edible Example 1 and Example 2 of the present invention product, colony's plaque index average is respectively
0.22 and 0.24, it is near that staining conditions and not Candy for food compare 0.18 split-phase, edible patent CN104920774A embodiment 2 product
Colony's plaque index average is 3.56；Patent CN1109711A product colony plaque index average is 4.28.
Embodiment 4: dental plaque pH tests
Subjects: embodiment of the present invention 1-2 product；Patent CN104920774A embodiment 2 product；Patent
CN1109711A product；
Test method:
The healthy facing of a certain fixed range is established as observation area, each product of comparison and non-table sugar in each product
The volunteer of fruit.Volunteer's (the supposition pH of non-Candy for food is basically unchanged) of each product is detected dental plaque pH change, result
It is shown in Table 2.
Table 2
As shown in Table 2, edible patented product pH is stable, without significant change, and edible comparison patented product, pH is little at one
Time the monitoring phase in, present the trend gone up after decline.
The above method being only intended to understand the present invention and core concept thereof, it is noted that for the art
Those of ordinary skill for, under the premise without departing from the principles of the invention, the present invention can be carried out some improvement and modification,
These improve and modify the protection domain also falling into right of the present invention.
Claims (10)
1. an anti-caries lollipop, it is characterised in that include that gum portion and hard candy portion, described gum portion include
Lysozyme, probiotic bacteria, tea polyphenols, sugar alcohol, gum base, sucralose and essence；Hard candy portion includes sugar alcohol, breast mineral salt, lemon
Lemon acid, water, pigment and essence.
Lollipop the most according to claim 1, it is characterised in that in parts by weight, described gum portion each raw material number
As follows:
Gum base 15-40 weight portion, sugar alcohol 35-75 weight portion, probiotic bacteria 0.01-0.1 weight portion, lysozyme 0.005-0.01 weight
Part, tea polyphenols 0.1-0.4 weight portion, sucralose 0.015-0.050 weight portion, essence 0.05-0.1 weight portion.
The most according to claim 1, lollipop, it is characterised in that in parts by weight, described hard candy portion each raw material number is such as
Under:
Sugar alcohol 100 weight portion, water 10-15 weight portion, breast mineral salt 0.5-1 weight portion, citric acid 1-1.5 weight portion, essence
0.05-0.1 weight portion, pigment 0.005-0.007 weight portion.
4. according to lollipop described in claim 1-3 any one, it is characterised in that described sugar alcohol is hydroxyl isomaltulose, wood
One or more in sugar alcohol, sorbitol, D-mannital.
Lollipop the most according to claim 1 or claim 2, it is characterised in that described probiotic bacteria is Lactobacillus paracasei GMNL-33.
Lollipop the most according to claim 1, it is characterised in that described hard candy portion parcel gum portion is inside and outside bilayer
Structure, or described gum portion and hard candy portion be cascaded.
Lollipop the most according to claim 1, it is characterised in that described gum portion also includes vitamin C, vitamin B1、
Breast mineral salt and soybean phospholipid.
Lollipop the most according to claim 7, it is characterised in that described vitamin C, vitamin B1, breast mineral salt and phospholipid
Content is vitamin C 630-13000mg/1000g lollipop, vitamin B116-33mg/1000g lollipop, breast mineral salt
2000-20000mg/1000g lollipop, soybean phospholipid 30-50mg/1000g lollipop.
9. the preparation method of anti-caries lollipop described in claim 1, it is characterised in that including:
Step 1, soften gum base, sugar alcohol and gum base are mixed, reduces gum base temperature, be added to lysozyme, probiotic bacteria, tea many
Phenol, sucralose and essence, extrude after mixing, shear, it is thus achieved that semi-finished product chewing gum, standby；
Step 2, sugar alcohol add water sugar cook, add breast mineral salt, citric acid, water, pigment and essence in gained syrup, and stirring is all
Candy syrup is obtained after even, standby；
Step 3, taking part candy syrup and inject mould, insert the hand-held rod of lollipop, be then placed in semi-finished product chewing gum, continuing will
Residue candy syrup is injected in mould parcel semi-finished product chewing gum, cooling sizing, it is thus achieved that described lollipop；Or
By aging for semi-finished product chewing gum, put in mould, insert the hand-held rod of lollipop, in mould, then inject candy syrup,
It is cascaded by hand-held rod with semi-finished product chewing gum, cooling sizing, it is thus achieved that described lollipop.
Preparation method the most according to claim 9, it is characterised in that step 1 is additionally included in interpolation lysozyme, probiotic bacteria, tea
Polyphenol, sucralose and essence simultaneously, add vitamin C, vitamin B1, breast mineral salt and soybean phospholipid.
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| CN106942455A (en) * | 2017-04-05 | 2017-07-14 | 大连丹特生物技术有限公司 | A kind of xylitol fruit lollipop and preparation method thereof |
| CN109125880A (en) * | 2018-10-24 | 2019-01-04 | 广东技术师范学院 | Lollipop simulator |
| CN110521843A (en) * | 2019-09-02 | 2019-12-03 | 天津飞享家口腔科技有限公司 | A kind of anti-caries sugar-free lollipop and preparation method thereof rich in dietary fiber |
| CN111887334A (en) * | 2020-08-06 | 2020-11-06 | 江苏史蒂文生物科技有限公司 | Anti-caries lollipop and preparation method thereof |
| CN113693153A (en) * | 2021-08-09 | 2021-11-26 | 雷婷婷 | Sugar-free lollipop capable of preventing decayed teeth and promoting intestinal health and preparation method thereof |
| CN114504045A (en) * | 2022-02-10 | 2022-05-17 | 广州满分牛牛牛电子商务有限公司 | Anti-caries lollipop and preparation method thereof |
| CN114668047A (en) * | 2022-04-18 | 2022-06-28 | 黑龙江飞鹤乳业有限公司 | Milk product and method for producing same |
| CN114698721A (en) * | 2022-03-25 | 2022-07-05 | 南阳市瑞佳食品有限公司 | Tooth-protecting and tooth-strengthening lollipop and preparation method thereof |
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| CN114698721A (en) * | 2022-03-25 | 2022-07-05 | 南阳市瑞佳食品有限公司 | Tooth-protecting and tooth-strengthening lollipop and preparation method thereof |
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Effective date of registration: 20180516 Address after: No. 3758 Binjiang District South Ring Road, Hangzhou, Zhejiang Applicant after: Bei Yinmei Ying Tong food limited-liability company Address before: 311113 Anxi, Ducheng village, Liangzhu street, Yuhang District, Hangzhou, Zhejiang Applicant before: HANGZHOU BEINGMATE BEANS AMUSE CHILD NUTRITION FOOD CO., LTD. Applicant before: Bei Yinmei Ying Tong food limited-liability company |
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Effective date of registration: 20190505 Address after: 310052 19, South Ring Road, Binjiang District, Hangzhou, Zhejiang, 19 Applicant after: Beingmate (Hangzhou) Food Research Institute Co., Ltd. Address before: No. 3758 Binjiang District South Ring Road, Hangzhou, Zhejiang Applicant before: Bei Yinmei Ying Tong food limited-liability company |
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Application publication date: 20161207 |
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