CN106169272A - A kind of surface hydrophobicity label - Google Patents

A kind of surface hydrophobicity label Download PDF

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Publication number
CN106169272A
CN106169272A CN201610479190.9A CN201610479190A CN106169272A CN 106169272 A CN106169272 A CN 106169272A CN 201610479190 A CN201610479190 A CN 201610479190A CN 106169272 A CN106169272 A CN 106169272A
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CN
China
Prior art keywords
label
column
micro
coating
ink layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610479190.9A
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Chinese (zh)
Inventor
龙伟明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangxi Black & Decker Label Printing Co Ltd
Original Assignee
Jiangxi Black & Decker Label Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangxi Black & Decker Label Printing Co Ltd filed Critical Jiangxi Black & Decker Label Printing Co Ltd
Priority to CN201610479190.9A priority Critical patent/CN106169272A/en
Publication of CN106169272A publication Critical patent/CN106169272A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0257Multilayer

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Paints Or Removers (AREA)

Abstract

The open a kind of surface hydrophobicity label of the present invention, including the basic unit in order to provide other compositions of label to adhere to, has ink layer on the top of basic unit, and ink layer forms the content of label display;The upper formation coating of ink layer, coating insulation blocking ink layer;Form hydrophobic surface on the surface of coating, hydrophobic surface is formed by the micro-column that microstructure is column;Having micropore inside micro-column, the microcell length of a portion is big, and the microcell length of another part is little;The bottom of basic unit is formed and is used for sticking labelled glue-line, above-mentioned multiple micropores formed the most existing label of hydrophobic layer can oil rub resistance waterproof.

Description

A kind of surface hydrophobicity label
Technical field
The invention belongs to commercial TAG field, relate to practical adhesive sticker and be pasted onto on commodity or ordinary articles etc. to show it The label of essential information, its role is to show base attribute or the function using method etc. being tagged article to user;Special Not relating to a kind of surface and have the label of hydrophobic structure characteristic, label will not be because of corrosion in actual practical process for hydrophobic label Property material wears or comes off that to lose displaying effect the most superior compared to conventional labels.
Background technology
Label is typically used as identifying commodity classification or content, and effect is to show in article commodity or classification to user The perhaps function commodity that particularly user's dependency degree is high use label to show content straightforward user learning low cost to user, Therefore labelling is the information displaying method of user friendly.
The general mask-making technology method flow of existing label include original copy printing, film technique, rinse, dry, post processing etc..Allusion quotation Type ground label paper longitudinal profile includes basic unit, and layer is puted forth effort as what all material on label depended on by basic unit, is to maintain label simultaneously The key stratum of structural integrity, label substrate may select the such as practical paper of different materials as basic unit according to the difference of application scenarios Form that paper labels intensity is poor easily tears to pieces, or the toughness label using polyethylene polypropylene material to make has stronger Toughness and label are prone to preserve, and the basic unit of certain label is not particularly limited;Glue-line is generally had for marking in the bottom of basic unit Sign the surface sticking to object or commodity;Arrange printing layer i.e. common ink layer on the top of basic unit, ink layer is printed on The important contents such as label information security code, can be attached with its effect of coating in the outside of ink layer be that its protection overall to label is made With, prevent ink layer oxidation or be corroded.
Usually, outermost coating as protection label structure its be prevented from water spilling and to ink layer thus damage oil Ink, prevents ink layer because hard thing scratches loses displaying function, and it is thin that the coating employing material such as polyethylene or polrvinyl chloride is made Film, the good price of its water resistance is low is a kind of ideal clad material.But the shortcoming of polyethylene or polrvinyl chloride be its not There is the hydrophobicity i.e. spilling water to its surface to gather together outflow but the most scattered be attached to its table Face, is specifically similar to the coloured organic solvents such as paint and is easy to stick to its surface, causes defaced being difficult to of label to distinguish Understanding not, also easily leave a trace on label by the lubricating oil on the greasy dirt such as motor vehicles of same part.Therefore for existing Label above shortcomings are necessary that proposing a kind of new label has good hydrophobicity to solve the problems referred to above.
Summary of the invention
It is an object of the invention to the disadvantages mentioned above overcoming existing label to exist, the i.e. coating of label is polyethylene or poly-third second Alkene material, it does not have hydrophobicity water when there being water to splash down on the surface of above-mentioned coating and can not gather together timely and effectively Rapidly clad surface at described label scatters the problem causing label to be blocked by contrast, particularly when splashing down at coating On surface be coloured solvents such as paint time clad surface be easily colored thus block label.
For the shortcoming overcoming above-mentioned existing label to exist, the present invention proposes the label of a kind of surface hydrophobicity relative to prior art The surface of its coating has hydrophobic microcosmic hydrophobic structure, when the liquids such as water or other organic solvents splash down in its surface Time, described microcosmic hydrophobic structure can effectively gather aqueous water or organic solvent makes it will not dissipate rapidly at clad surface Open thus produce the problem blocking label substance.
The technical scheme is that and be done step-by-step according to mode once, basic structure layering and the existing class of hydrophobic label Seemingly, including label substrate, as the integrally-built layer of putting forth effort of label, ink layer, glue-line and coating are included in label, all with basic unit Substrate surface it is superimposed upon layer by layer for depending on basis.The material making described basic unit includes that paper, the feature of papery base material are Cheap for manufacturing cost but with paper as basic unit label is easier to breakage compared to other materials;Replacement material industry as paper wood Also using plastic production basic unit, during its feature, label paper toughness high-strength based on plastic production is big, it is not easy to damaged label is originally Body thickness can largely be reduced.
Including glue-line in the bottom of described basic unit, its effect is described label to stick to the surface of article or product not do As a example by glue, its effect components generally comprises basic unit's epoxy resin etc., reactive diluent, antioxidant etc., glues according to label Attached requirement and practical scene Bu Tong optional coats permanent adhesive material bottom described basic unit or removable property is not done Glue material.
Described basic unit top includes ink layer, in ink layer uses different colours combination or graphics combine to show the essence of label Hold.The main component of ink include pigment its be the solid constituent in ink be the substance that show color of ink, typical ink pigment It is that raw mineral materials is the most water insoluble.Also including in ink that connecting material is usually gluey its important function of fluid is to be filled by powder Ink pigment material Hybrid connections gets up and forms the adherent with certain fluid ability.Described ink is attached to by printing In described basic unit, mode of printing optionally includes letterpress, offset printing, intaglio printing, orifice plate printing, silk screen printing etc..
Being coating on the top of described ink layer, the main material of coating includes that polyethylene or polrvinyl chloride gather, and its thickness is 0.5 Millimeter is once.Two major functions of coating are the first surface isolation ink layer being attached to described ink layer and air contact, Make ink layer with the oxygen generation oxidation reaction in air, aging phenomenon will not occur, cover described in application scenes Layer can also include that uvioresistant coating or uvioresistant material prevent the pigment material in described ink layer because of the purple in sunlight Outside line produces decomposition or color produces aging;Second function of described coating is to prevent water from splashing on described ink layer, or Person is similar to paint and waits to splash down containing the pigment of organic solvent and block the content of label display on described ink layer.
The technical scheme preventing described water or organic solvent pigment from splashing down on coating is achieved in that table in described coating Face directly contacts with described ink layer, and coating outer surface forms hydrophobic layer, the water droplet that described hydrophobic layer can will splash down thereon Gather together and prevent it from four dissipating, or have the stains such as coloured gluey liquid paint and scatter at clad surface, to reach Protect the purpose that described ink layer content is not blocked.
Described hydrophobic layer has the hydrophobic structure of microcosmic;Hydrophobic structure is observed on a microscopic level has following structure in institute State and on the surface of coating, form nano level micro-column, micro-column there is cylindrical structure, but cylindrical structure is not miniature The final structure of post, optionally can also use other column structures easy to implement to replace, such as, will be readily apparent as one Structure can use cross section have polygonized structure cylinder replace described cylindricity structure, for example with hexagon cylinder generation Replace.The approximate range of the height of described micro-column is the scope of 1 times to 2 times of its diameter, described in different application scenarios The height of micro-column fluctuates in above-mentioned scope.Having microcellular structure in the center of cylinder, micropore is at described micro-column Being internally formed air column, the axis coinciding of the axle center of described air column and described micro-column is so that the internal junction of described micro-column Structure uniformity, the diameter of described micropore is more than the 1/2 of described micro-column diameter.An annular is formed between micro-column and micropore Contact surface, it will be apparent that the center of circle of described annular contact surface overlaps with the axle of described micro-column and described micropore.
The length of described micropore is different, and the length of a kind of micropore is relatively big, its length scale substantially with the size substantially phase of micro-column With, the length smaller length of another kind of micropore is roughly equivalent to the half size of elongated hole, and longer micropore has inside it more Air compressible, the compressible space of air is bigger, and the liquid that the little deformation of micro-column tension force of the longest micropore is big has Stronger support;The compressible space of the less air of its inner air of shorter micropore the shortest the most less micropore is applicable to The liquid that tension force large deformation is little.The present invention is in order to concisely only as a example by the micropore of two kinds of length, of course for adapting to more material Material can also use further types of micropore to adapt to different fluent materials, thus reaches best hydrophobic effect.
Two kinds of above-mentioned micro-columns i.e. have the micro-column of longer micropore and have the micro-column of shorter micropore, be distributed in described in cover On layer, multiple described micro-columns are according to the orderly arrangement of a certain straight line at described coating;Typical edge in one direction A linear array.The axis of described micro-column is vertical with described coating and the described straight line that is passed through on clad surface, separately Being arranged in order in the same way in one rectilinear direction, described axis is vertical with described coating and is passed through clad surface Another straight line, two above-mentioned straight lines are mutually perpendicular at clad surface.Distance between axles phase on straight line described in adjacent described micro-column Deng.Described orthogonal straight line arranges some groups, thus forms hydrophobic surface at described clad surface so that coating has thin The characteristic of water is beneficial to prevent each class I liquid I from splashing down when clad surface and scatters rapidly.
When liquid or have the organic liquid volume of pigment or stain and splash down at the novel coating of this use, it is by described miniature Hydrophobic layer and described liquid phase interaction that post is formed prevent it from spreading, during the mechanism of action between micro-column and liquid so : due to the small-sized naked eyes indistinguishable nanometer scale yardstick that reaches of micro-column, from micro-scale, therefore observe institute Because the tension force effect of liquid between liquid and the micro-column stated, do not scatter in liquid is maintained at certain region, liquid Edge presents the trend inwardly gathered.Described micro-column holds liquid by the contact surface of annular, and liquid other not The part held by described ring surface bends in the hole of described micro-column, has longer described micropore inner air relatively Many, the part that liquid bends in introversive described hole is more, and having, shorter described micropore inner air is less, and liquid is to institute The part bent in stating hole is less.
The label clad surface obtained according to technique scheme has hydrophobic structure, and hydrophobic structure constitutes hydrophobic surface, hydrophobic knot The microcosmic point of structure includes micro-column, includes two kinds of length micropores in different micro-columns, these two kinds of micro-columns from different liquid During body material can by the tension effect that liquid itself has make its tend to gathering will not clad surface scatter so that Water or greasy dirt or have coloured organic solvent and can not be attached to label coating, play the effect of protection label display content.
Accompanying drawing explanation
Fig. 1 is the overall structure schematic diagram of label.
Fig. 2 is the overall profile according to label described in A-A boost line in Fig. 1.
Fig. 3 is label surface microstructure schematic diagram.
Fig. 4 shows micro-column internal cross section structure in Fig. 3.
Fig. 5 illustrates the form schematic diagram of contact surface between liquid and micro-column.
Detailed description of the invention
It is an object of the invention to the shortcoming overcoming above-mentioned existing label to exist, the present invention proposes the label of a kind of surface hydrophobicity Relative to the surface of its coating of prior art, there is hydrophobic microcosmic hydrophobic structure, when liquids such as water or other organic solvents When splashing down in its surface, described microcosmic hydrophobic structure can effectively gather aqueous water or organic solvent makes it will not be Clad surface scatters rapidly thus produces the problem blocking label substance.
Below in conjunction with accompanying drawing, technical solution of the present invention is further described in detail, it should be noted that accompanying drawing be only for The technical thought of the short and sweet displaying present invention, simultaneously in order to help skilled in the art to understand technical thought, accompanying drawing The structure of middle displaying is a kind of preferred embodiment as the present invention it is not intended that limit protection scope of the present invention A kind of restriction, the most any change done according to spirit order of the present invention or constitute substantially identical with technical solution of the present invention Or the technical scheme of equivalent is the most within the scope of the present invention.
The technical scheme is that and be done step-by-step in the following way, refer to the base of accompanying drawing 1 and Fig. 2 hydrophobic label 1 This structural stratification is similar with existing, including label substrate 13, as the integrally-built layer of putting forth effort of label 1, the ink layer in label 12, glue-line 14 and coating 11, all with basic unit 13 for depend on basis successively be superimposed upon basic unit 13 surface.Make the material of described basic unit Material include paper, the feature of papery base material be cheap for manufacturing cost but with paper be basic unit 13 label compared to other materials more The most damaged;The material industry also Practical plastic that replaces as paper wood makes the material of basic unit, based on plastic production during its feature Label paper toughness high-strength big, it is not easy to the damaged thickness of label own can largely be reduced.
Include glue-line 14 in the bottom of described basic unit 13, its effect be the surface that described label is sticked to article or product with As a example by adhesive sticker, its effect components generally comprises basic unit's epoxy resin etc., reactive diluent, antioxidant etc., according to mark Sign adhesion requirements and bottom described basic unit 13, coat permanent adhesive material or removable with the Bu Tong optional of practical scene Property adhesive material.
Described basic unit 13 top includes that ink layer 12, the combination of ink layer practicality different colours or graphics combine show the reality of label Matter content.The main component of ink includes pigment, and it is the solid constituent in ink, for the substance that show color of ink, typical ink Pigment is that raw mineral materials is the most water insoluble.Ink also includes connecting material be usually gluey its important function of fluid be by Powder charge of oil ink pigment material Hybrid connections gets up and forms the adherent with certain fluid ability.Described ink is attached by printing In described basic unit 13, mode of printing optionally includes letterpress, offset printing, intaglio printing, orifice plate printing, screen printing Brush etc..
Being coating 11 on the top of described ink layer 12, the main material of coating 11 includes that polyethylene or polrvinyl chloride gather, and it is thick Degree is at 0.5 millimeter once.Two major functions of coating 11 are the first surface isolation ink layeies being attached to described ink layer 12 With air contact so that ink layer aging phenomenon will not occur with the oxygen generation oxidation reaction in air, applies at some Coating 11 described in scene can also include that uvioresistant coating or uvioresistant material prevent the pigment thing in described ink layer 12 Matter is because the ultraviolet in sunlight produces decomposition or color produces aging;Second function of described coating 11 is to prevent water from splashing down On described ink layer 13, or similar paint waits the pigment containing organic solvent to splash down to block label on described ink layer 13 The content shown.
In the technical scheme preventing described water or organic solvent pigment from splashing down on ink is achieved in that described coating 11 Surface directly contacts with described ink layer 12, and coating outer surface forms hydrophobic layer 110 (seeing Fig. 2), and described hydrophobic layer 110 can The water droplet splashed down thereon is gathered together and prevents it from four dissipating, or have the stains such as coloured gluey liquid paint and covering Scatter, to reach the purpose protecting described ink layer 12 content not to be blocked in layer 11 surface.
Refer to the hydrophobic layer 110 described in Fig. 3 and there is the hydrophobic structure of microcosmic;Hydrophobic structure observe on a microscopic level have as Under structure on the surface of described coating, form nano level micro-column 20, micro-column 20 there is cylindrical structure, but circle Columnar structures is not the final structure of micro-column 20, optionally can also replace by other column structures easy to implement practical, example Cylindricity structure as described in the cylinder replacement that cross section can be used to have polygonized structure as a kind of structure that will be readily apparent, example As used hexagon cylinder to replace.The approximate range of the height of described micro-column 20 is the scope of 1 times to 2 times of its diameter, The height of the different micro-columns described in application scenarios fluctuates in above-mentioned scope.There is micropore knot in the center of cylinder Structure 21, micropore is internally formed air column at described micro-column, the axle center X of described air column and the axis coinciding of described micro-column 21 So that the consistent internal structure of described micro-column 20 is consistent, the diameter of described micropore 21 is more than the 1/ of described micro-column 20 diameter 2.The contact surface 24 of an annular is formed, it will be apparent that the center of circle of described annular contact surface 24 and institute between micro-column 20 and micropore 21 The axle X stating micro-column 20 and described micropore overlaps.
The length seeing micropore described in Fig. 4 is different, and the length of a kind of micropore 21L is relatively big, its length scale substantially with micro-column 20 Size roughly the same, the length smaller length of another kind of micropore 21S is roughly equivalent to the half size of elongated hole 21L, longer It is bigger that micropore 21L has the compressible space of the compressible air of more air inside it, and the longest micropore 21L's is miniature The liquid of the little deformation of post 20 tension force big (seeing Fig. 5) has stronger support;The shorter micropore 21S less air of its inner air Compressible space the shortest the most less micropore 21S is applicable to the liquid that tension force large deformation is little.This use is novel for letter Bright only as a example by the micropore of two kinds of length, further types of micropore 21 can also be used with suitable of course for adapting to more material Answer different fluent materials, thus reach best hydrophobic effect.
Seeing Figure 4 and 5, two kinds of above-mentioned micro-columns i.e. have the micro-column 20 of longer micropore 21L and have shorter micropore 21S's Micro-column 21, is distributed on described coating 11, and multiple described micro-columns 20 are orderly according to a certain straight line C1 at described coating Arrangement;It is typical that to arrange the axis of described micro-column 20 along a straight line C1 the most in one direction vertical with described coating and wear Cross the described straight line on coating 11 surface, another straight line C2 direction is arranged in order in the same way, described axle Line X is vertical with described coating 11 and is passed through another straight line C2 on coating 11 surface, and two above-mentioned straight lines are in coating 11 surface phase The most vertical.Distance between axles L on straight line C1 described in adjacent described micro-column 21 is equal.Described orthogonal straight line (C1C2) sets Put some groups, thus form hydrophobic surface 110 on described coating 11 surface so that coating has hydrophobic characteristic and is beneficial to prevent respectively Class I liquid I splashes down and scatters rapidly when coating 11 surface.
Refer to Fig. 4 when liquid or there is the organic liquid volume of pigment or stain splash down at the novel coating 11 of this use, The hydrophobic layer 110 that it is formed by described micro-column 20 interacts with described liquid 30 and prevents it from spreading, micro-column 21 and liquid Between the mechanism of action time such: small-sized due to micro-column 20 reaches the indistinguishable yardstick of naked eyes, therefore from micro- Seeing and observe because the tension force effect of liquid 30 between described liquid 30 and micro-column 20 on yardstick, liquid 30 is maintained at certain Not scattering in region, the edge 31 of liquid presents the trend inwardly gathered.The described micro-column 20 contact surface by annular 24 hold liquid 30, and other sweeps 33 do not held by described ring surface of liquid 30 are in the hole of described micro-column Bending, more at longer micropore 21L inner air, liquid 30 is more to introversive described hole inner curved portion 33, shorter having Described micropore 21S inner air less, the part that liquid bends in described hole is less.
The label clad surface obtained according to technique scheme has hydrophobic structure, and hydrophobic structure constitutes hydrophobic surface, hydrophobic knot The microcosmic point of structure includes micro-column, includes two kinds of length micropores in different micro-columns, these two kinds of micro-columns from different liquid During body material can by the tension effect that liquid itself has make its tend to gathering will not clad surface scatter so that Water or greasy dirt or have coloured organic solvent and can not be attached to label coating, play the effect of protection label display content.

Claims (7)

1. a surface hydrophobicity label, it is characterised in that including:
In order to the basic unit providing other compositions of label to adhere to;
Having ink layer on the top of described basic unit, ink layer forms the content of described label display;
The upper formation coating of ink layer, ink layer described in coating insulation blocking;
Form hydrophobic surface on the surface of described coating, hydrophobic surface is formed by the micro-column that microstructure is column;
Having micropore inside described micro-column, the described microcell length of a portion is big, the described microcell length of another part Little;
The bottom of described basic unit is formed and is used for sticking labelled glue-line.
2. a kind of surface hydrophobicity label as claimed in claim 1, it is characterised in that described micro-column is at described clad surface Linearly arranging, described miniature axis of a cylinder is perpendicular to described straight line.
3. a kind of surface hydrophobicity label as claimed in claim 2, it is characterised in that phase in the hydrophobic surface that described micro-column is formed The adjacent spacing between micro-column is equal.
4. a kind of surface hydrophobicity label as claimed in claim 2, it is characterised in that described micro-column is on described clad surface edge Another linear array, described micro-column is perpendicular to another straight line described.
5. a kind of surface hydrophobicity label as claimed in claim 1, it is characterised in that form ring between described micropore and micro-column Shape face is in order to hold liquid.
6. a kind of surface hydrophobicity label as claimed in claim 1, it is characterised in that described glue-line includes adhesive sticker.
7. a kind of surface hydrophobicity label as claimed in claim 1, it is characterised in that the size of described micro-column is nanometer amount Level.
CN201610479190.9A 2016-06-28 2016-06-28 A kind of surface hydrophobicity label Pending CN106169272A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109345949A (en) * 2018-10-25 2019-02-15 惠州市浩明科技股份有限公司 Antifalsification label

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2821774Y (en) * 2005-07-07 2006-09-27 余张强 Optical disc label and its special mounting tool
CN101998906A (en) * 2008-01-31 2011-03-30 雷蛇(亚太)私人有限公司 Surface coating method
CN204894689U (en) * 2015-06-12 2015-12-23 普立万聚合体(上海)有限公司 Hydrophobous double -deck polypropylene film in surface
CN105197879A (en) * 2015-08-20 2015-12-30 中国科学院深圳先进技术研究院 Super-hydrophobic thin film and preparation method thereof
CN205881306U (en) * 2016-06-27 2017-01-11 江西百得标签印刷有限公司 Anti greasy dirt bar -code label

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2821774Y (en) * 2005-07-07 2006-09-27 余张强 Optical disc label and its special mounting tool
CN101998906A (en) * 2008-01-31 2011-03-30 雷蛇(亚太)私人有限公司 Surface coating method
CN204894689U (en) * 2015-06-12 2015-12-23 普立万聚合体(上海)有限公司 Hydrophobous double -deck polypropylene film in surface
CN105197879A (en) * 2015-08-20 2015-12-30 中国科学院深圳先进技术研究院 Super-hydrophobic thin film and preparation method thereof
CN205881306U (en) * 2016-06-27 2017-01-11 江西百得标签印刷有限公司 Anti greasy dirt bar -code label

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109345949A (en) * 2018-10-25 2019-02-15 惠州市浩明科技股份有限公司 Antifalsification label

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