CN106167671A - Water-based mono-component plastic coating and its preparation method and application - Google Patents
Water-based mono-component plastic coating and its preparation method and application Download PDFInfo
- Publication number
- CN106167671A CN106167671A CN201510720271.9A CN201510720271A CN106167671A CN 106167671 A CN106167671 A CN 106167671A CN 201510720271 A CN201510720271 A CN 201510720271A CN 106167671 A CN106167671 A CN 106167671A
- Authority
- CN
- China
- Prior art keywords
- water
- coating
- plastic coating
- component plastic
- based mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to the preparation method and application of a kind of water-based mono-component plastic coating and this coating, the water-based mono-component plastic coating of the present invention includes following components: the carboxylic anion aqueous resin of 90～110 weight portions, 15～40 Waterproof pigment, 7～12 auxiliary agent, 2～4 interfacial adhesion promoting agent, 15～25 deionized waters of weight portion of weight portion of weight portion of weight portion；Interfacial adhesion promoting agent is formed by metallorganic, polyisocyanates and the reaction of the oligomer containing hydroxyl.There is between water-based mono-component plastic coating and the noncrystalline plastic rubber substrate of the present invention interfacial adhesion of excellence.
Description
Technical field
The present invention relates to a kind of water-based mono-component coating, the preparation method of this coating, and the purposes of this coating, belong to technical field of coatings.
Background technology
Along with people are to environmental protection and the pay attention to day by day of the energy, countries in the world are the most in succession formulated or are formulating the laws and regulations the most sternly gone through, the strict discharge capacity limiting coating VOC.China, in order to adapt to structural transformation of the economy and the environmental problem being on the rise, clearly proposes high-performance to be accelerated development, energy-conservation and functional coating and the research of supporting raw material, particularly points out water-based automobile paint to be developed and water-borne plastic coatings.Owing to various plastics and more and more many derivative joint products thereof are widely used in people's daily life and manufactured consumer goods industry, the main application fields such as consumer electronics such as including automotive plastic parts, household electrical appliances, toy, mobile phone, large-scale industrial coating brings substantial amounts of VOC emission, therefore, the conversion by organic solvent coating hydrotropism's coating is very urgent.
Polyurethane coating has the advantages such as preferable resistance to water, weatherability, good mechanical performance, Gao Guang, resistance to dampness, and is applied widely.And aqueous polyurethane increasingly comes into one's own, the technology of preparing of aqueous polyurethane was advanced by leaps and bounds especially the most in recent years.The plastics such as ABS, PVC, PS, HIPS, PC belong to noncrystalline plastics, amorphism due to noncrystalline plastics, there are higher surface energy and surface polarity, therefore stronger with coating adhesion, bigger scope is had on water-base resin selects, common acrylic acid ester emulsion, acrylic PU dispersion etc. are used equally to noncrystalline frosting, but these are all the good adhesion that signal layer coating is embodied on above-mentioned plastic rubber substrate, if with UV coating varnish is supporting, the adhesive force of whole coating is lost substantially.
Patent WO2006093916-A2 describes a kind of water-based paint compositions, and it is formed by comprising the organic facies of bottom paint resin, aqueous phase and emulsifying agent, can improve the adhesive force of coating as the additive of coating, may be used for timber or
Frosting.
Michael D. Gerno etc. have studied the interpolation of the aqueous nertralizers such as the alkanolamine impact on aqueous coating for plastic adhesive force, and under identical contrast test, the water paint using different nertralizer is differentiated to the adhesive force of plastic basis material.
United States Patent (USP) US6184281-B2 describes the plastic basis material film of a kind of metal ion crosslinked; it includes many carboxyls aqueous dispersion resin that amine neutralizes and the composite zinc ammonium salt providing crosslinking points; film has the advantages such as good pliability, Gao Guang, resistance to dampness, is mainly used in the outer protection of highly polar plastic basis material.
European patent EP 1159323 describes a kind of aqueous pu dispersions for plastic paint, especially on automobile plastic parts, has excellent adhesive attraction, resistance to water and salt fog resistance to plastic basis material.
Chinese invention patent CN200610026688.6 and Chinese invention patent CN200610026686.7 reports the aqueous polyurethane coating and waterborne polyester-amino resin coating material using water nano composite polyester resin to prepare, and can be used for polar plas face coat.
Producing water-based plastic resin and such as the U.S. PPG company of company of coating, U.S. Rohm and Haas company, Bayer company of Germany, BASF Corp. of Germany, Alberdingk company of Germany, Japan DIC etc., product is mainly used in the frostings such as ABS, PVC, PS, PC and sprays；Chengdu organic chemistry company of the Chinese Academy of Sciences and the aqueous plastic coating of coating company limited of Hengchang exploitation, be mainly used in frosting spraying and the leather finishes such as PVC, ABS, PS, HIPS.The hardness of existing water-borne plastic coatings film, gloss etc. need to improve further.
The water-base resin such as aqueous polyurethane and acrylic acid modified polyurethane has good bonding force for polar plas surface, but how to develop a kind of and UV coating varnish is supporting, supporting with existing production line, it is a problem demanding prompt solution that existing solvent based coating is converted into aqueous one-component plastic coating.
Summary of the invention
The technical problem to be solved in the present invention is to provide between a kind of and noncrystalline plastic rubber substrate the water-based mono-component plastic coating of the interfacial adhesion with excellence, and the preparation method and application of this coating.
The present invention solves that a kind of technical scheme that above-mentioned technical problem proposes is: a kind of water-based mono-component plastic coating, including following components: the carboxylic anion aqueous resin of 90～110 weight portions, 15～40 Waterproof pigment, 7～12 auxiliary agent, 2～4 interfacial adhesion promoting agent, 15～25 deionized waters of weight portion of weight portion of weight portion of weight portion；Described interfacial adhesion promoting agent is formed by metallorganic, polyisocyanates and the reaction of the oligomer containing hydroxyl.
Above-mentioned metallorganic, polyisocyanates and the mass ratio in the reaction of the oligomer containing hydroxyl are 3.5～4.5: 1.5～2.5: 1.
Above-mentioned metallorganic, polyisocyanates and the mass ratio in the reaction of the oligomer containing hydroxyl are 4: 2: 1.
Above-mentioned metallorganic is one or more in isopropyl titanate, aluminum isopropylate., zirconate, aluminium acetylacetonate, ferric acetyl acetonade；Described polyisocyanates is one or more in TDI-TMP addition product, TDI trimer, biuret N75 or N3390HDI trimer；The described oligomer containing hydroxyl is one or more in A81 aldehyde ketone resin, solid Hydroxylated acrylic resin, epoxy resin, alkyd resin, hydroxyl alkyl organosilicon amount of money hydroxyl fluororesin.
Above-mentioned water-based mono-component plastic coating also includes the extender pigment of 5～15 weight portions；Described extender pigment is one or more in calcium carbonate, barium sulfate, aluminium silicate, Kaolin, Pulvis Talci.
Above-mentioned auxiliary agent includes dispersant, wetting agent, levelling agent, defoamer and coalescents；Described dispersant is polycarboxylic acid salt's dispersant；Described wetting agent is one or more in dialkyl sulfosuccinates, Negel, dodecyl sodium sulfate, lauryl sulfate, Fixanol chloride, alkylphenol polyoxyethylene, polyoxyethylene glycol Arrcostab, acetylene ethylene glycol；Described levelling agent is one or more in silicone levelling agent, nonionic polyurethane levelling agent；Described defoamer is one or more in polyethers defoamer, mineral oil antifoam agent, silicone defoamer；Described coalescents is one or more in propylene glycol, butanediol ethere, acid esters compound；
Above-mentioned auxiliary agent also includes one or more in UV absorbers, light stabilizer, antifreezing agent, antifungus agent.
Above-mentioned carboxylic anion aqueous resin is one or more in carboxylic anion aqueous polyurethane resin, carboxylic anion aqueous acrylic acid modified polyurethane resin, carboxylic anion aqueous fluorine richness polyurethane resin, carboxylic anion aqueous silicon modified polyurethane resin；Described carboxylic anion aqueous polyurethane plexiglas transition temperature (tg) is-50～+50 DEG C；Described carboxylic anion aqueous acrylic acid modified polyurethane plexiglas transition temperature (tg) is-25～+80 DEG C；Described carboxylic anion aqueous fluorine richness polyurethane resin glass transition temperature (tg) is-50～+60 DEG C；Described carboxylic anion aqueous silicon modified polyurethane plexiglas transition temperature (tg) is-50～+60 DEG C.
Above-mentioned Waterproof pigment is transparent ferric oxide system, white carbon black, titanium white, azo pigment, phthalocyanine pigment, indigoid type pigment, purple cyclic ketones class pigment, class pigment, quinacridone-type pigments, and isoindoline ketone pigment, metal complex pigment, surface are passivated one or more in aluminium powder, pearl essence.
The present invention solves that the another kind of technical scheme that above-mentioned technical problem proposes is: the preparation method of a kind of above-mentioned water-based mono-component plastic coating, including step in detail below:
Step one, adds the oligomer containing hydroxyl in reaction vessel；
Step 2, adds polyisocyanates, is warming up to 75～85 DEG C of reaction more than 1.5h,
Step 3, adds metallorganic and continues reaction more than 1.5h；
Step 4, is cooled to less than 60 DEG C, obtains interfacial adhesion promoting agent；
Step 5, by Waterproof pigment, carboxylic anion aqueous resin, auxiliary agent, interfacial adhesion promoting agent and deionized water mix and blend 15～50min, obtains water-based mono-component plastic coating after filtration.
The present invention solves that the another kind of technical scheme that above-mentioned technical problem proposes is: the application of a kind of above-mentioned water-based mono-component plastic coating, noncrystalline plastic rubber substrate coats described water-based mono-component plastic coating, after described water-based mono-component plastic coating solidify to form coating, UV coating varnish is coated again in described coating, for improving the interfacial adhesion between the interfacial adhesion between water-based mono-component plastic coating and noncrystalline plastic rubber substrate, and water-based mono-component plastic coating and UV coating varnish.
The present invention has a positive effect:
(1) the water-based mono-component plastic coating of the present invention is emulsion state, can be used for the outer protection such as plastic basis materials such as ABS, PVC, PS, HIPS, PC, it is also possible to support the use with UV coating varnish.Interfacial adhesion promoting agent is by metallorganic, oligomer containing hydroxyl and polyisocyanic acid Lipase absobed, it makes full use of the ammonia ester bond in these raw materials, the urea bond strong adsorption to base material, and also make use of the strong coordination of electron deficiency in the Organic substance Middle molecule such as aluminum, titanium, zirconium to improve the adsorptivity to noncrystalline plastic rubber substrate, say, that resin finally makes the adhesive force of coating and intensity be obtained for raising with base material by the bridging action of the acid esters such as titanium, aluminum, zirconium.So, it directly can be sprayed under conditions of noncrystalline plastic rubber substrate surface does not carry out increasing adhesive force process by the coating of the present invention, obtains good adhesive force, and the adhesive force that remains to keep excellence supporting with UV coating varnish as finish paint.
(2) the water-based mono-component plastic coating of the present invention does not contains the limited heavy metal of European Union rohs and Organic substance, and the coating of formation has the advantages such as preferable resistance to water, weatherability, good mechanical performance, Gao Guang, resistance to dampness.The present invention considers from de-petrochemical, minimizing CO2 emission, the minimizing viewpoint such as VOC emission, practicality, it is possible to alleviate the load to environment significantly.The more important thing is and coating is prepared as one-component, solvent type acrylic resin coating is converted to the one-component plastic coating of Water-borne modification, improves the effective utilization of coating, it is possible to adapt to the requirement of production line.
(3) coating process of the water-based mono-component plastic coating of the present invention is not particularly limited, can brush, roller coating, aerial spraying, high pressure airless spray, dip-coating, electrostatic spraying etc..After coating, by normal temperature drying or heat drying, can obtain solidifying coating.It addition, according to the kind of coating and the coated article of institute's suitable environment, can at random set coating weight, application order, coating layer thickness, drying time etc..
Detailed description of the invention
Embodiment 1
The preparation method of the water-based mono-component plastic coating of the present embodiment, including step in detail below:
Step one, adds A81 urea formaldehyde in the there-necked flask with condenser and stirring.
Step 2, adds TDI trimer, is warming up to 80 DEG C, reacts 2h.Add appropriate catalyst dibutyltin dilaurylate while adding TDI trimer and can effectively shorten the response time.
Step 3, adds isopropyl titanate and continues reaction 2h.
Step 4, be cooled to 60 DEG C with bottom discharge, obtain interfacial adhesion promoting agent.The mass ratio of the isopropyl titanate, TDI trimer and the A81 urea formaldehyde that are added in above-mentioned steps is 4: 2: 1.The interfacial adhesion promoting agent prepared by this mass ratio interpolation metallorganic, polyisocyanates and the oligomer containing hydroxyl is the most stable.
Step 5, the deionized water of the carbon black color paste of 20 weight portions, the carboxylic anion aqueous polyurethane resin of 100 weight portions, the auxiliary agent of 10 weight portions, the interfacial adhesion promoting agent of 3 weight portions and 20 weight portions is put in rustless steel scuffing of cylinder bore and be stirred dispersion, rotating speed is set to 700rad/min, stirs 20min.Carboxylic anion aqueous polyurethane plexiglas transition temperature (tg) is-50～+50 DEG C.Auxiliary agent therein uses existing common dispersants, wetting agent, levelling agent, defoamer and coalescents.If also needing to add other auxiliary agents such as UV absorbers, light stabilizer, antifreezing agent, antifungus agent, can continue to add in scuffing of cylinder bore, being stirred for 30min.Finally with the 120 clean nylon net filters of mesh, packaging, i.e. obtain black water one pack system plastic coating.
The water-based mono-component plastic coating of the present embodiment, after substrate surface solidifies, does controlled trial according to " cross cut test of GB/T9286-1998 paint and varnish paint film " and the water-based mono-component plastic coating being not added with interfacial adhesion promoting agent.The coating that the water-based mono-component plastic coating of the present embodiment is formed, after pulling at hundred lattice with adhesive tape, the edge of otch is completely smooth, and grid edge does not has any peeling.Being not added with the coating that the water-based mono-component plastic coating of interfacial adhesion promoting agent is formed, the gross area that comes off is more than 65%.
Embodiment 2
The preparation method of the water-based mono-component plastic coating of the present embodiment, including step in detail below:
Step one, adds solid Hydroxylated acrylic resin in the there-necked flask with condenser and stirring.
Step 2, adds TDI-TMP addition product, is warming up to 80 DEG C, reacts 2h.
Step 3, adds aluminum isopropylate. and continues reaction 2h.
Step 4, be cooled to 60 DEG C with bottom discharge, obtain interfacial adhesion promoting agent.The mass ratio of the aluminum isopropylate., TDI-TMP addition product and the solid Hydroxylated acrylic resin that are added in above-mentioned steps is 4: 2: 1.
Step 5, the deionized water of the titanium white mill base of 35 weight portions, the barium sulfate of 5 weight portions, the carboxylic anion aqueous acrylic acid modified polyurethane resin of 100 weight portions, the auxiliary agent of 8 weight portions, the interfacial adhesion promoting agent of 3 weight portions and 20 weight portions is put in rustless steel scuffing of cylinder bore and be stirred dispersion, rotating speed is set to 700rad/min, stirs 20min.Carboxylic anion aqueous acrylic acid modified polyurethane plexiglas transition temperature (tg) is-25～+80 DEG C.Auxiliary agent therein uses existing common dispersants, wetting agent, levelling agent, defoamer and coalescents.Finally with the 120 clean nylon net filters of mesh, packaging, i.e. obtain white water-borne one pack system plastic coating.
After the water-based mono-component plastic coating of the present embodiment solidify to form coating on noncrystalline plastic rubber substrate, again at surface spraying UV coating varnish, according to " cross cut test of GB/T9286-1998 paint and varnish paint film " and the water-based mono-component plastic coating being not added with interfacial adhesion promoting agent, spray UV coating varnish after same solidification and do controlled trial.Spraying UV coating varnish coating outside the water-based mono-component plastic coating of the present embodiment, after pulling at hundred lattice with adhesive tape, the edge of otch is completely smooth, and grid edge does not has any peeling.The spraying UV coating varnish coating being not added with outside the water-based mono-component plastic coating of interfacial adhesion promoting agent, the gross area that comes off is more than 65%.
Embodiment 3
The preparation method of the water-based mono-component plastic coating of the present embodiment, including step in detail below:
Step one, adds epoxy resin in the there-necked flask with condenser and stirring.
Step 2, adds biuret N75, is warming up to 80 DEG C, reacts 2h.
Step 3, adds zirconate and continues reaction 2h.
Step 4, be cooled to 60 DEG C with bottom discharge, obtain interfacial adhesion promoting agent.The mass ratio of the zirconate, biuret N75 and the epoxy resin that are added in above-mentioned steps is 4: 2: 1.
Step 5, the deionized water of the phthalocyanine blue mill base of 33 weight portions, the carboxylic anion aqueous fluorine richness polyurethane resin of 100 weight portions, the auxiliary agent of 10 weight portions, the interfacial adhesion promoting agent of 3 weight portions and 20 weight portions is put in rustless steel scuffing of cylinder bore and be stirred dispersion, rotating speed is set to 700rad/min, stirs 20min.Carboxylic anion aqueous fluorine richness polyurethane resin glass transition temperature (tg) is-50～+60 DEG C.Auxiliary agent therein uses existing common dispersants, wetting agent, levelling agent, defoamer and coalescents.Finally with the 120 clean nylon net filters of mesh, packaging, i.e. obtain blue water-based one pack system plastic coating.
Embodiment 4
The preparation method of the water-based mono-component plastic coating of the present embodiment, including step in detail below:
Step one, adds alkyd resin in the there-necked flask with condenser and stirring.
Step 2, adds N3390HDI, is warming up to 80 DEG C, reacts 2h.
Step 3, adds aluminium acetylacetonate and continues reaction 2h.
Step 4, be cooled to 60 DEG C with bottom discharge, obtain interfacial adhesion promoting agent.The mass ratio of the aluminium acetylacetonate, TN3390HDI and the alkyd resin that are added in above-mentioned steps is 4: 2: 1.
Step 5, the deionized water of the titanium white mill base of 35 weight portions, the carboxylic anion aqueous silicon modified polyurethane resin of 100 weight portions, the auxiliary agent of 8 weight portions, the interfacial adhesion promoting agent of 3 weight portions and 20 weight portions is put in rustless steel scuffing of cylinder bore and be stirred dispersion, rotating speed is set to 700rad/min, stirs 20min.Carboxylic anion aqueous silicon modified polyurethane plexiglas transition temperature (tg) is-50～+60 DEG C.Auxiliary agent therein uses existing common dispersants, wetting agent, levelling agent, defoamer and coalescents.Finally with the 120 clean nylon net filters of mesh, packaging, i.e. obtain white water-borne one pack system plastic coating.
Obviously, above-described embodiment is only for clearly demonstrating example of the present invention, and is not the restriction to embodiments of the present invention.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here without also cannot all of embodiment be given exhaustive.And these spirit belonging to the present invention are extended out obvious change or variation still in protection scope of the present invention among.
Claims (10)
1. a water-based mono-component plastic coating, it is characterized in that, including following components: the carboxylic anion aqueous resin of 90～110 weight portions, 15～40 Waterproof pigment, 7～12 auxiliary agent, 2～4 interfacial adhesion promoting agent, 15～25 deionized waters of weight portion of weight portion of weight portion of weight portion；Described interfacial adhesion promoting agent is formed by metallorganic, polyisocyanates and the reaction of the oligomer containing hydroxyl；Described metallorganic, polyisocyanates and the mass ratio in the reaction of the oligomer containing hydroxyl are 3.5～4.5: 1.5～2.5: 1.
Water-based mono-component plastic coating the most according to claim 1, it is characterised in that: described metallorganic, polyisocyanates and the mass ratio in the reaction of the oligomer containing hydroxyl are 4: 2: 1.
Water-based mono-component plastic coating the most according to claim 1, it is characterised in that: described metallorganic is one or more in isopropyl titanate, aluminum isopropylate., zirconate, aluminium acetylacetonate, ferric acetyl acetonade；Described polyisocyanates is one or more in TDI-TMP addition product, TDI trimer, biuret N75 or N3390HDI trimer；The described oligomer containing hydroxyl is one or more in A81 aldehyde ketone resin, solid Hydroxylated acrylic resin, epoxy resin, alkyd resin, hydroxyl alkyl organosilicon amount of money hydroxyl fluororesin.
Water-based mono-component plastic coating the most according to claim 1, it is characterised in that: also include the extender pigment of 5～15 weight portions；Described extender pigment is one or more in calcium carbonate, barium sulfate, aluminium silicate, Kaolin, Pulvis Talci.
5. according to the water-based mono-component plastic coating one of Claims 1-4 Suo Shu, it is characterised in that: described auxiliary agent includes dispersant, wetting agent, levelling agent, defoamer and coalescents；Described dispersant is polycarboxylic acid salt's dispersant；Described wetting agent is one or more in dialkyl sulfosuccinates, Negel, dodecyl sodium sulfate, lauryl sulfate, Fixanol chloride, alkylphenol polyoxyethylene, polyoxyethylene glycol Arrcostab, acetylene ethylene glycol；Described levelling agent is one or more in silicone levelling agent, nonionic polyurethane levelling agent；Described defoamer is one or more in polyethers defoamer, mineral oil antifoam agent, silicone defoamer；Described coalescents is one or more in propylene glycol, butanediol ethere, acid esters compound.
Water-based mono-component plastic coating the most according to claim 5, it is characterised in that: described auxiliary agent also includes one or more in UV absorbers, light stabilizer, antifreezing agent, antifungus agent.
Water-based mono-component plastic coating the most according to claim 1, it is characterised in that: described carboxylic anion aqueous resin is one or more in carboxylic anion aqueous polyurethane resin, carboxylic anion aqueous acrylic acid modified polyurethane resin, carboxylic anion aqueous fluorine richness polyurethane resin, carboxylic anion aqueous silicon modified polyurethane resin；Described carboxylic anion aqueous polyurethane plexiglas transition temperature (tg) is-50～+50 DEG C；Described carboxylic anion aqueous acrylic acid modified polyurethane plexiglas transition temperature (tg) is-25～+80 DEG C；Described carboxylic anion aqueous fluorine richness polyurethane resin glass transition temperature (tg) is-50～+60 DEG C；Described carboxylic anion aqueous silicon modified polyurethane plexiglas transition temperature (tg) is-50～+60 DEG C.
Water-based mono-component plastic coating the most according to claim 1, it is characterized in that: described Waterproof pigment is transparent ferric oxide system, white carbon black, titanium white, azo pigment, phthalocyanine pigment, indigoid type pigment, purple cyclic ketones class pigment, class pigment, quinacridone-type pigments, and isoindoline ketone pigment, metal complex pigment, surface are passivated one or more in aluminium powder, pearl essence.
9. the preparation method of a water-based mono-component plastic coating as claimed in claim 1, it is characterised in that include step in detail below:
Step one, adds the oligomer containing hydroxyl in reaction vessel；
Step 2, adds polyisocyanates, is warming up to 75～85 DEG C of reaction more than 1.5h,
Step 3, adds metallorganic and continues reaction more than 1.5h；
Step 4, is cooled to less than 60 DEG C, obtains interfacial adhesion promoting agent；
Step 5, by Waterproof pigment, carboxylic anion aqueous resin, auxiliary agent, interfacial adhesion promoting agent and deionized water mix and blend 15～50min, obtains water-based mono-component plastic coating after filtration.
10. the application of a water-based mono-component plastic coating as claimed in claim 1, it is characterized in that: on noncrystalline plastic rubber substrate, coat described water-based mono-component plastic coating, after described water-based mono-component plastic coating solidify to form coating, UV coating varnish is coated again in described coating, for improving the interfacial adhesion between the interfacial adhesion between water-based mono-component plastic coating and noncrystalline plastic rubber substrate, and water-based mono-component plastic coating and UV coating varnish.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510720271.9A CN106167671A (en) | 2015-10-30 | 2015-10-30 | Water-based mono-component plastic coating and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510720271.9A CN106167671A (en) | 2015-10-30 | 2015-10-30 | Water-based mono-component plastic coating and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106167671A true CN106167671A (en) | 2016-11-30 |
Family
ID=57359014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510720271.9A Pending CN106167671A (en) | 2015-10-30 | 2015-10-30 | Water-based mono-component plastic coating and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106167671A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041709A (en) * | 2007-03-30 | 2007-09-26 | 东华大学 | Fluorine-containing aqueous polyurethane and preparation method and application thereof |
| CN102002314A (en) * | 2010-09-29 | 2011-04-06 | 中国科学院长春应用化学研究所 | Nano dispersed water-based conductive primer for vehicle bumper and preparation method thereof |
| CN102702956A (en) * | 2012-06-01 | 2012-10-03 | 安徽省金盾涂料有限责任公司 | Water-based paint |
| CN102822220A (en) * | 2010-04-08 | 2012-12-12 | 蓝宝迪有限公司 | Aqueous anionic polyurethane dispersions |
| CN104559901A (en) * | 2014-12-26 | 2015-04-29 | 东莞市腾威电子材料技术有限公司 | Two-component adhesion agent, as well as preparation method and application thereof |
-
2015
- 2015-10-30 CN CN201510720271.9A patent/CN106167671A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041709A (en) * | 2007-03-30 | 2007-09-26 | 东华大学 | Fluorine-containing aqueous polyurethane and preparation method and application thereof |
| CN102822220A (en) * | 2010-04-08 | 2012-12-12 | 蓝宝迪有限公司 | Aqueous anionic polyurethane dispersions |
| CN102002314A (en) * | 2010-09-29 | 2011-04-06 | 中国科学院长春应用化学研究所 | Nano dispersed water-based conductive primer for vehicle bumper and preparation method thereof |
| CN102702956A (en) * | 2012-06-01 | 2012-10-03 | 安徽省金盾涂料有限责任公司 | Water-based paint |
| CN104559901A (en) * | 2014-12-26 | 2015-04-29 | 东莞市腾威电子材料技术有限公司 | Two-component adhesion agent, as well as preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李红强: "《胶粘原理、技术及应用》", 31 January 2014 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103450719B (en) | A kind of long-acting aqueous, environmental protective steel construction protection coating | |
| CN104231901B (en) | A kind of aqueous elastic handfeel paint and preparation method thereof | |
| CN106336754A (en) | Environment-friendly single-component industrial anti-corrosion coating and preparation method thereof | |
| CN103788787A (en) | Single-component water-based natural drying finishing coat for construction crane and preparation method thereof | |
| CN103819988A (en) | Bottom unified aqueous anticorrosive paint and preparation method | |
| CN103351795B (en) | Poly-lucid asparagus car paint and preparation method and application | |
| CN108410301A (en) | A kind of metal surface high salt fog resistance acrylic acid sealing wax and preparation method thereof | |
| CN101831025B (en) | Water-base resin and paint with high corrosion resistance and cohesiveness, environmental protection and low consumption and preparation method thereof | |
| CN103468092A (en) | Water-based coating for surface of mechanical product | |
| CN109206996B (en) | Water-based solvent-free bottom-surface-integrated high-gloss single-component plain-color finish paint and preparation thereof | |
| CN108003748A (en) | A kind of engineering machinery epoxy primer and preparation method thereof | |
| CN103965740A (en) | Sand finish type cathode electrophoretic coating and preparation method thereof | |
| CN103911057B (en) | A kind of aqueous covercoat coating for three painting one bakings and preparation method thereof | |
| CN106189767A (en) | A kind of water paint and its preparation method and application | |
| CN106189766A (en) | Coating and its preparation method and application | |
| CN106189764A (en) | A kind of coating and its preparation method and application | |
| CN102585689B (en) | Voltage-withstand photo-cured anode oxidation coating, as well as preparation method and using method thereof | |
| CN104109428A (en) | 3C1B-enabled wet-on-wet white primer surfacer and preparation method thereof | |
| CN102391753A (en) | Water emulsion polymer camouflage color decorative coating and preparation method and use thereof | |
| CN106189768A (en) | Water paint and its preparation method and application | |
| CN109762439A (en) | A kind of waterborne epoxy coatings and preparation method thereof | |
| CN105647317A (en) | Epoxy modified acrylic aqueous finishing paint for burglarproof doors and preparation method for epoxy modified acrylic aqueous finishing paint | |
| CN104559591A (en) | Environment-friendly water-based paint for aluminum profile production and preparation method thereof | |
| CN106167640A (en) | A kind of interfacial adhesion promoting agent and its preparation method and application | |
| CN103923549A (en) | One-component water-based finish coating made from acrylic amino resin and preparation method of coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161130 |
|
| RJ01 | Rejection of invention patent application after publication |