CN106166476A - A kind of using method preparing active hargil special activation tower - Google Patents

A kind of using method preparing active hargil special activation tower Download PDF

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Publication number
CN106166476A
CN106166476A CN201610627675.8A CN201610627675A CN106166476A CN 106166476 A CN106166476 A CN 106166476A CN 201610627675 A CN201610627675 A CN 201610627675A CN 106166476 A CN106166476 A CN 106166476A
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assembly
tower
fluidized bed
fly ash
boiler
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CN106166476B (en
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杨松
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Anyang County Intellectual Property Operation Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12Naturally occurring clays or bleaching earth

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)

Abstract

The present invention relates to environmental protection and recycling economy technical field, be specifically related to a kind of using method preparing active hargil special activation tower.It is characterized in that: include activating tower assembly, point acid system, air box impulse bag-type catcher, the using method of bracket assembly.On the one hand using activation tower substantially increase the activation efficiency of hargil and reduce the activation procedure time, turn waste into wealth, high-value-use boiler exhaust gas, the most traditional sour pool process reduces the occupation of land construction area of equipment and reduces investment.

Description

A kind of using method preparing active hargil special activation tower
Technical field
The present invention relates to environmental protection and recycling economy technical field, be specifically related to a kind of active hargil special activation tower prepared Using method.
Background technology
Active hargil is widely used in chemical engineering industry, processes wadding as catalyst, filler, desiccant, adsorbent, waste water Solidifying agent etc..Refining animal and vegetable oil as manufacturing in edible oil;In the oil industry for oil, oils and fats paraffin, wax oil, kerosene etc. The refine of mineral is decoloured and purifies and cracking of oil;In food industry, as wine and the clarifier of fruit juice, medicated beer Stabilizing treatment, saccharifying processes, juice purification etc.;In health care, can be made into chemical defence toxication-absorbing agent, antidote.Along with society and The reach of science, the application of active hargil is more and more extensive.Circulating fluidized bed combustion coal boiler fly ash be during boiler for producing Common garbage, main component SiO2Be pneumoconiosis occupational root, wound to personnel in working space Evil is relatively big, easily causes the occupation disease such as pneumoconiosis, and how the aerial dust of loss, to environment, turns waste into wealth and high Value utilization is such as prepared active hargil always the art engineers and technicians and is wanted the problem solved.Chinese invention is special Profit (Patent No. 201310136573.2, patent name is a kind of system for continuously preparing activated clay) discloses a kind of activity Hargil serialization preparation system, it is characterized in that including pulping system, activation system, point acid system, rinse-system, press filteration system, Drying system, scratch system.Described each system stepped arrangement the most from high to low;Also include spent acid processing system and arrange At the same ladder of press filteration system.Described drying system include air stove and drying kiln, drying kiln two ends be respectively feed end and Exhaust end;Described air stove is placed in the exhaust end of drying kiln, is provided with the aerator that hot blast is sent into drying kiln at exhaust end, or Feed end at drying kiln is provided with air-introduced machine;Make material direction of transfer and hot blast direction of transfer in drying kiln contrary.The present invention Preparation system, utilize serialization mechanization, the reduction environmental pollution of high degree.Dust pollution and the discharge of spent acid boiling water are several Do not have, be the industrial production system of a kind of recycling economy.Chinese invention patent (Patent No. 201510695275.6, patent Entitled a kind of activated clay production device) disclose a kind of activated clay production device, feature is to include: feeding warehouse, mixing Machine, microwave heating equipment, the first stock tank, filter, the second stock tank and pulverizer, wherein, described feeding warehouse by conveyer belt with Described mixer is connected;Described mixer is connected with described microwave heating equipment by conveyer belt;Described mixer passes through Conveyer belt is connected with described first stock tank;Described first stock tank is connected with described second stock tank by described filter;Institute State the second stock tank to be connected with described pulverizer by pressure filter.Present invention also offers a kind of method for producing active clay.This Inventing described activated clay production device and method to utilize microwave activation to process to make bentonite activity more preferably, adsorptivity is strong and steady Fixed performance, and simplify technological process, save production cost, reduced power consumption and pollute, thus improve product matter Amount, improves production efficiency.Prior art is mainly for the device preparing active hargil that ore deposit soil is raw material, to the present invention with circulation Fluidized bed burned-coal boiler fly ash be raw material, heat power source be boiler exhaust gas prepare active hargil needed for device not necessarily fit Close, and need construction fever furnace system and corresponding environment-friendly disposal system.
Summary of the invention
The technical solution used in the present invention is: a kind of using method preparing active hargil special activation tower.Its feature It is: include activating tower assembly, point acid system, air box impulse bag-type catcher, the using method of bracket assembly.
Step one: described activation tower assembly includes tower body, high-temperature blower assembly, circulating fluidized bed combustion coal boiler fly ash spiral Carrier, connection wind pipe component, boiler exhaust gas adapter.Described tower body upper end is designed with spiral casing feeding mouth, and lower end is designed with discharging Mouthful.Described activation tower assembly using method is: high-temperature blower assembly is taken over from boiler heating system by boiler exhaust gas after starting And the pipeline extraction boiler exhaust gas between dry collector, boiler exhaust gas temperature is about 160-190 DEG C, SO2Concentration is about 1000- 2500mg/m3, carry to the spiral casing feeding mouth of tower body at high-temperature blower assembly by connecting wind pipe component, recirculating fluidized bed simultaneously The circulation connected on wind pipe component between the coal-burning boiler flying dust spiral casing feeding mouth through being arranged on high-temperature blower assembly and tower body Fluidized bed burned-coal boiler fly ash auger conveyor delivers into connection wind pipe component and mixes with boiler exhaust gas, by regulation recycle stream The motor speed changing bed coal-burning boiler flying dust auger conveyor can be adjusted flexibly the conveying capacity of circulating fluidized bed combustion coal boiler fly ash.
Step 2: described point of acid system includes storage tank, metering pump assembly, atomizing shower nozzle, connecting conveying pipe assembly.Described Point acid system using method is: storage tank generally is configured with heat-insulation system, and the highest storage temperature of sulphuric acid is less than 70 DEG C, logical during use Cross metering pump assembly and form vaporific sulfuric acid droplets through connecting conveying pipe assembly, atomizing shower nozzle.Sulphuric acid is in absorbing boiler exhaust gas SO2Concentration improves, and is evaporated to rapidly sulfuric acid vapor simultaneously, wraps up and wash away ciculation fluidized after absorbing the waste heat of boiler exhaust gas Bed coal-burning boiler ash surface, circulating fluidized bed combustion coal boiler fly ash granule mass transfer abundant with sulfuric acid vapor in tower body activates also Mutually collision loses kinetic energy and enters air box impulse bag-type catcher by the discharging opening of tower body lower end under the carrying of boiler exhaust gas.
Step 3: described air box impulse bag-type catcher includes differential pressure controller, gas circuit assembly, casing.Described casing It is made up of bag house and exhaust chamber, between bag house and exhaust chamber, is divided into the confined chamber of mutually isolation, described gas by dividing plate Case impulse bag catcher using method is: the circulating fluidized bed combustion coal boiler fly ash after activated enters bag through casing air inlet Filter chamber, granule falls directly into more greatly bag house bottom, and molecule is stopped by filter bay assembly and is attached to filter bay assembly surface, and tail Gas enters exhaust chamber through filter bay assembly and enters environment treating facility process through tail gas row's mouth, is attached to the granule on filter bay assembly surface Thing gets more and more, and bag house air pressure uprises, and when reaching design load, differential pressure controller senses and believes to actuator gas circuit assembly Number, gas circuit component valve is opened compressed air and is purged to filter bay assembly, and the particulate matter being attached to filter bay assembly surface i.e. falls into bag filter Bottom, room, is transported to subsequent processing by Star-like unloader.
Step 4: described activation tower assembly, point acid system, air box impulse bag-type catcher are installed in bracket assembly On.Support frame as described above assembly using method is: bracket assembly is integrated in corresponding operation assembly in one rational space, presses The order of technique circulation completes one by one.
Relative to prior art, the present invention is at least containing having the advantage that first, and the main material preparing active hargil uses Circulating fluidized bed combustion coal boiler fly ash is modal pollutant and garbage during boiler for producing, loss in working space Harm to operator is relatively big, easily causes the occupation disease such as pneumoconiosis, is the occupational of China's keypoint control.Loss Surrounding air and soil are polluted by aerial dust simultaneously, currently mainly use the methods such as landfill to process, both Contaminated soil, again waste resource and manpower.The present invention is then turned waste into wealth, and is used for preparing active hargil, is possible not only to subtract Few environmental pollution, and production cost can be reduced;Second, due to circulating fluidized bed combustion coal boiler fly ash fineness reach 38 μm~ 58 μm, more various prepare that the size-reduced fineness reached of hargil Ore had and too late, its specific surface area and surface in other words Porosity is big compared with the ore deposit of mechanical lapping soil, and the degree of correctability activation is higher, and the quality of treated earth is the highest, energy-conservation while Also preferable base material is obtained;3rd, circulating fluidized bed combustion coal boiler fly ash is gathered materials on the spot, and can directly take from bulk cement storage tank, and Bulk cement storage tank is obturator, and not with air contact, in other words hypoxia dry environment maintains Al2O3、SiO2With uncombusted C particle Activity, and Ore exploitation, pulverize, its water of crystallization is not destroyed in course of conveying, not forming interstitial void is difficult to be activated, Use circulating fluidized bed combustion coal boiler fly ash can be substantially reduced the time of activation as raw material, also subtract while saving cost of transportation The input of few process equipment, activation tower is in Sealing Arrangement, and circulating fluidized bed combustion coal boiler fly ash is difficult to effusion, is substantially reduced ring The risk of environment pollution;4th, activation tower uses boiler exhaust gas to carry as circulating fluidized bed combustion coal boiler fly ash, mix, separate, The medium of activation, and heat energy needed for activating process is provided and reduces the usage amount of sulphuric acid, vaporific sulfuric acid absorption boiler smoke SO in gas2Rear concentration improves, and saves the usage amount of sulphuric acid, absorbs the waste heat in boiler smoke simultaneously and be evaporated to sulphuric acid rapidly Steam, wraps up and washes away circulating fluidized bed combustion coal boiler fly ash surface and realize abundant mass transfer, uses activation tower to substantially increase On the one hand the activation efficiency of hargil and reduce the activation procedure time, turns waste into wealth, high-value-use boiler exhaust gas, the most relatively Traditional sour pool process reduces the occupation of land construction area of equipment and reduces investment;6th, the recycle stream after acid mist tail gas and activation Change bed coal-burning boiler flying dust is directly discharged into environment treating facility process after air box impulse bag-type catcher separates (also can be by right Sulphuric acid is reclaimed in acid mist cooling), just reduce the heavy burdens greatly for lower one rinsing process, it is meant that without taking up an area bigger rinsing Pond, higher water consumption energy consumption, production cost is substantially reduced;7th, the pollutant that active hargil activation production process produces are such as Exhaust emission is possible with boiler original environmental conservation treatment facility and processes, it is not necessary to again build, thus has saved construction money Gold;8th, plant automation degree is high, and the technological process integrated intelligent of each complexity is implemented, and operates with simplicity.
Accompanying drawing explanation
Fig. 1 is the main TV structure schematic diagram of a kind of using method preparing active hargil special activation tower of the present invention.
Fig. 2 is the plan structure schematic diagram of a kind of using method preparing active hargil special activation tower of the present invention.
Fig. 3 is the A partial enlargement structural representation of a kind of using method preparing active hargil special activation tower of the present invention.
Fig. 4 is the B partial enlargement structural representation of a kind of using method preparing active hargil special activation tower of the present invention.
Fig. 5 is the C partial enlargement structural representation of a kind of using method preparing active hargil special activation tower of the present invention.
Fig. 6 is the D partial enlargement structural representation of a kind of using method preparing active hargil special activation tower of the present invention.
Fig. 7 is the E partial enlargement structural representation of a kind of using method preparing active hargil special activation tower of the present invention.
1-activation tower assembly 2-divide acid system 3-air box impulse bag-type catcher
4-bracket assembly 5-tower body 6-connects wind pipe component 7-high-temperature blower assembly
8-boiler exhaust gas adapter 9-spiral casing feeding mouth 10-discharging opening
11-circulating fluidized bed combustion coal boiler fly ash auger conveyor 12-storage tank
13-metering pump assembly 14-atomizing shower nozzle 15-connecting conveying pipe assembly
16-differential pressure controller 17-gas circuit assembly 18-casing
19-exhaust chamber 20-bag house 21-filter bay assembly 22-air inlet
23-Star-like unloader 24-tail gas row's mouth 25-dividing plate.
Detailed description of the invention
With specific embodiment, this device is described further below in conjunction with the accompanying drawings.
The present invention is as shown in accompanying drawing 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5, Fig. 6, Fig. 7, and one prepares active hargil special activation tower Using method, it is characterized in that: include activating tower assembly 1, point acid system 2, air box impulse bag-type catcher 3, bracket assembly 4 Using method.
Step one: described activation tower assembly 1 includes tower body 5, high-temperature blower assembly 7, circulating fluidized bed combustion coal boiler fly ash Auger conveyor 11, connection wind pipe component 6, boiler exhaust gas adapter 8.Described tower body 5 upper end is designed with spiral casing feeding mouth 9, lower end It is designed with discharging opening 10.Described activation tower assembly 1 using method is: high-temperature blower assembly 7 passes through boiler exhaust gas adapter 8 after starting Extracting boiler exhaust gas from the pipeline between boiler heating system and dry collector, boiler exhaust gas temperature is about 160-190 DEG C, SO2Concentration is about 1000-2500mg/m3, by connecting wind pipe component 6 at high-temperature blower assembly 7 to the spiral casing feeding mouth 9 of tower body 5 Conveying, simultaneously between the circulating fluidized bed combustion coal boiler fly ash spiral casing feeding mouth 9 through being arranged on high-temperature blower assembly 7 and tower body 5 The circulating fluidized bed combustion coal boiler fly ash auger conveyor 11 connected on wind pipe component 6 deliver into connection wind pipe component 6 with Boiler exhaust gas mixes, and can be adjusted flexibly by the motor speed of regulation circulating fluidized bed combustion coal boiler fly ash auger conveyor 11 and follow The conveying capacity of ring fluid bed coal-burning boiler flying dust.
Step 2: described point of acid system 2 includes storage tank 12, metering pump assembly 13, atomizing shower nozzle 14, connecting conveying pipe group Part 15.Described point of acid system 2 using method is: storage tank 12 generally is configured with heat-insulation system, and the highest storage temperature of sulphuric acid is less than 70 DEG C, during use, form vaporific sulfuric acid droplets by metering pump assembly 13 through connecting conveying pipe assembly 15, atomizing shower nozzle 14.Sulfur Acid SO in absorbing boiler exhaust gas2Concentration improves, and is evaporated to rapidly sulfuric acid vapor after absorbing the waste heat of boiler exhaust gas simultaneously, Parcel and wash away circulating fluidized bed combustion coal boiler fly ash surface, circulating fluidized bed combustion coal boiler fly ash granule in tower body 5 with sulfur The activation of acid vapor abundant mass transfer mutually collision are lost kinetic energy and are entered by the discharging opening of tower body 5 lower end under the carrying of boiler exhaust gas Enter air box impulse bag-type catcher 3.
Step 3: described air box impulse bag-type catcher 3 includes differential pressure controller 16, gas circuit assembly 17, casing 18.Institute State casing 18 to be made up of bag house 20 and exhaust chamber 19, between bag house 20 and exhaust chamber 19 by dividing plate 25 be divided into mutually every Exhausted confined chamber, described air box impulse bag-type catcher 3 using method is: the circulating fluidized bed combustion coal boiler fly ash after activated Entering bag house 20 through casing 18 air inlet 22, granule falls directly into more greatly bag house 20 bottom, and molecule is by filter bay assembly 21 stop and are attached to filter bay assembly 21 surface, and tail gas enters exhaust chamber 19 through filter bay assembly 21 and enters ring through tail gas row's mouth 24 Guarantor's treatment facility processes, and the particulate matter being attached to filter bay assembly 21 surface gets more and more, and bag house 20 air pressure uprises, and reaches design load Time, differential pressure controller 16 senses and to actuator gas circuit assembly 17 signal, gas circuit assembly 17 valve opening compressed air to Filter bay assembly 21 purges, and the particulate matter being attached to filter bay assembly 21 surface i.e. falls into bag house 20 bottom, defeated by Star-like unloader 23 Deliver to subsequent processing.
Step 4: described activation tower assembly 1, point acid system 2, air box impulse bag-type catcher 3 are installed in bracing frame group On part 4.Support frame as described above assembly 4 using method is: the corresponding operation assembly of bracket assembly 4 is integrated in a rational space In, complete one by one by the order of technique circulation.

Claims (4)

1. prepare a using method for active hargil special activation tower, it is characterized in that: include activating tower assembly, point acid system, Air box impulse bag-type catcher, the using method of bracket assembly, activation tower assembly using method is: high-temperature blower assembly starts Boiler exhaust gas is extracted from the pipeline between boiler heating system and dry collector afterwards, by connecting wind by boiler exhaust gas adapter Pipe assembly carries to the spiral casing feeding mouth of tower body at high-temperature blower assembly, and circulating fluidized bed combustion coal boiler fly ash is through being arranged on simultaneously The circulating fluidized bed combustion coal boiler fly ash spiral shell connected on wind pipe component between the spiral casing feeding mouth of high-temperature blower assembly and tower body Rotation carrier delivers into connection wind pipe component and mixes with boiler exhaust gas, by regulation circulating fluidized bed combustion coal boiler fly ash spiral The motor speed of carrier can be adjusted flexibly the conveying capacity of circulating fluidized bed combustion coal boiler fly ash.
A kind of using method preparing active hargil special activation tower the most according to claim 1, is characterized in that: point acid system System using method is: storage tank generally is configured with heat-insulation system, and the highest storage temperature of sulphuric acid is less than 70 DEG C, by metering during use Pump assembly forms vaporific sulfuric acid droplets through connecting conveying pipe assembly, atomizing shower nozzle, sulphuric acid SO in absorbing boiler exhaust gas2Dense Degree improves, and is evaporated to rapidly sulfuric acid vapor simultaneously, wraps up and wash away circulating fluidized bed combustion coal after absorbing the waste heat of boiler exhaust gas Boiler fly ash surface, circulating fluidized bed combustion coal boiler fly ash granule mass transfer abundant with sulfuric acid vapor in tower body activates and mutually touches Hit and lose kinetic energy under the carrying of boiler exhaust gas by the discharging opening entrance air box impulse bag-type catcher of tower body lower end.
A kind of using method preparing active hargil special activation tower the most according to claim 1, is characterized in that: gas tank arteries and veins Rushing pouched trapper using method is: the circulating fluidized bed combustion coal boiler fly ash after activated enters bag filter through casing air inlet Room, granule falls directly into more greatly bag house bottom, and molecule is stopped by filter bay assembly and is attached to filter bay assembly surface, and tail gas Enter exhaust chamber through filter bay assembly and enter environment treating facility process through tail gas row's mouth, be attached to the particulate matter on filter bay assembly surface More and more, bag house air pressure uprises, and when reaching design load, differential pressure controller senses and believes to actuator gas circuit assembly Number, gas circuit component valve is opened compressed air and is purged to filter bay assembly, and the particulate matter being attached to filter bay assembly surface i.e. falls into bag filter Bottom, room, is transported to subsequent processing by Star-like unloader.
A kind of using method preparing active hargil special activation tower the most according to claim 1, is characterized in that: bracing frame Assembly using method is: bracket assembly is integrated in corresponding operation assembly in one rational space, by technique circulation time Sequence completes one by one.
CN201610627675.8A 2016-08-03 2016-08-03 A kind of application method for preparing the special activation tower of atlapulgite Active CN106166476B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1193601A (en) * 1997-03-14 1998-09-23 新疆石油管理局独山子石油化工总厂 Preparation of activated clay
CN203264723U (en) * 2013-04-18 2013-11-06 黄山市白岳活性白土有限公司 Continuous preparation system for activated clay
CN104096543A (en) * 2014-06-23 2014-10-15 中国科学院广州能源研究所 Preparation method for organic activated clay used for decolorization

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1193601A (en) * 1997-03-14 1998-09-23 新疆石油管理局独山子石油化工总厂 Preparation of activated clay
CN203264723U (en) * 2013-04-18 2013-11-06 黄山市白岳活性白土有限公司 Continuous preparation system for activated clay
CN104096543A (en) * 2014-06-23 2014-10-15 中国科学院广州能源研究所 Preparation method for organic activated clay used for decolorization

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Application publication date: 20161130

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