CN106153522A - Core porosity measurement apparatus and measuring method - Google Patents

Core porosity measurement apparatus and measuring method Download PDF

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Publication number
CN106153522A
CN106153522A CN201610707301.7A CN201610707301A CN106153522A CN 106153522 A CN106153522 A CN 106153522A CN 201610707301 A CN201610707301 A CN 201610707301A CN 106153522 A CN106153522 A CN 106153522A
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valve
pressure
designated
volume
sample room
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CN201610707301.7A
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CN106153522B (en
Inventor
帅宇
童小畅
满向杰
刘朋远
刘伟
刘恭全
刘磊
鲁冲
陆松嵩
杨园园
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Chongqing Pan Jia Sheng Wo Engineering Co Ltd
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Chongqing Pan Jia Sheng Wo Engineering Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • G01N15/08Investigating permeability, pore-volume, or surface area of porous materials
    • G01N15/088Investigating volume, surface area, size or distribution of pores; Porosimetry

Abstract

The invention discloses a kind of core porosity measurement apparatus, including helium tank, pressure-reducing valve, sample room, reference cell, pressure sensor, digital wash, the first valve, the second valve and the 3rd valve, can realize that helium is introduced into sample room and enters back into reference cell by valve.The invention also discloses a kind of core porosity measuring method, comprise the following steps: (1) calibrates: helium is first introduced sample room dividing potential drop again to reference cell, be calculated reference cell volume Vr and sample room volume Vc by simultaneous equations, repeated multiple times complete calibration;(2) measure: be calculated core porosity by simultaneous equations.First the present invention by introducing sample room by high-tension measurement helium, dividing potential drop is to reference cell again, significantly increase pressure change before and after dividing potential drop, and pressure change reduces with rock pore volume and increases, under the conditions of equivalent devices, use the measurement apparatus of the present invention and measuring method can measure the porosity of core sample especially low-porosity sample more accurately.

Description

Core porosity measurement apparatus and measuring method
Technical field
The present invention relates to a kind of core porosity measurement apparatus and measuring method, particularly relate to a kind of measurement gas and be introduced into sample Behind product room, dividing potential drop enters core porosity measurement apparatus and the measuring method of reference cell again.
Background technology
The core porosity measuring method of existing domestic and international main flow, main employing oil and gas industry standard SY/T 5336-2006 " core analysis method " (i.e. API RP 40:1998, Recommended Practices for Core Version introduced in the Chinese of Analysis, IDT) in, 5.3.2.1.1 Boyle law dual chamber method (rock sample cup) measures particle volume Measure the apparent volume of rule rock core with 5.2.3 kind of calliper method, apparent volume deducts the difference of particle volume divided by apparent volume, i.e. For porosity.
In theory, said method can measure the regular core sample of arbitrary dimension, any porosity;But in reality In application, it is necessary to consider that:
During using Robert Boyle dual chamber method to measure particle volume, actual gas pressure is converted to the telecommunications of pressure sensor Number, and finally transmit the registration of the digital wash being converted to, during a series of conversions, there is error;
Manometric figure place showing is limited, i.e. the limited resolution of pressure-measuring system;
As described in SY/T 5336-2006 5.3.2.1.1.8 f, after rock core and filling block are put in sample room, except the hole of rock core Outside gap, in sample room and pipeline, there is also system void volume;
As described in SY/T 5336-2006 5.3.2.1.1.8 g, pore volume should be close with reference cell volume, but works as pore-body When amassing very little, reference cell volume is difficult to and pore volume approximation;
Utilize the essence of Boyle law dual chamber method measurement core porosity, i.e. measure the pressure being caused by rock pore volume and become Changing, pore volume is more big, and the pressure change being caused by it is bigger;Getting over hour at pore volume relative to reference cell, pressure changes then Less, the change of error relative pressure is bigger, bigger on measurement result impact.
To sum up, the Boyle law dual chamber method (rock sample cup) that SY/T 5336-2006 recommends measures particle volume, is measuring During low-porosity sample such as shale (porosity is often 0~2%), measuring result error is relatively big, have impact on follow-up test and research.
Content of the invention
The purpose of the present invention is that provides one measuring low-porosity sample such as shale to solve the problems referred to above When still there is core porosity measurement apparatus and the measuring method of high-acruracy survey result.
The present invention is achieved through the following technical solutions above-mentioned purpose:
A kind of core porosity measurement apparatus, including helium tank, pressure-reducing valve, sample room, reference cell, pressure sensor and numeral show Showing table, also including the first valve, the second valve and the 3rd valve, the outlet of described helium tank is with the entrance of described pressure-reducing valve even Connecing, the outlet of described pressure-reducing valve is connected with the first end of described first valve, the second end of described first valve respectively with described The test side of the first end of the second valve, the entrance of described sample room and described pressure sensor connects, described second valve Second end is connected with described first end of the 3rd valve and the entrance of described reference cell respectively, and the second end of described 3rd valve hangs Sky, the signal output part of described pressure sensor is connected with the signal input part of described digital wash.
The measuring method that a kind of core porosity measurement apparatus as claimed in claim 1 uses, comprises the following steps:
(1) calibrate, specifically include following steps:
(1.1) make helium admission pressure close to the range upper limit of pressure sensor by regulating pressure-reducing valve;
(1.2) open the second valve and the 3rd valve, close after about 30 seconds, the stable registration of record digital wash, it is designated as Pa1;
(1.3) vacant sample room, opens the first valve, closes the first valve after about 30 seconds, and record shows by stablizing of digital wash Number, is designated as P1;
(1.4) open the second valve, the stable registration of record digital wash, be designated as P2, close after opening the 3rd valve emptying Close;
(1.5) sample room loading standard stainless steel filling block as much as possible, filling block cumulative volume is designated as Vf0;
(1.6) open the first valve, close the first valve, the stable registration of record digital wash after about 30 seconds, be designated as P3;
(1.7) open the second valve, the stable registration of record digital wash, be designated as P4, close after opening the 3rd valve emptying Close;
(1.8) simultaneous equation below:
Obtaining reference cell volume Vr and sample room volume Vc, wherein Za1, Z1, Z2, Z3, Z4 are respectively corresponding pressure when temperature is Ta Power Pa1, the Gas Compression Factor of helium under P1, P2, P3, P4;Keeping environment conditions constant during measurement, environment temperature is designated as Ta, and when assuming all pressure readings, in system, gas temperature is Ta
(1.9) in adjustment sample room, after filling block volume, repetition step (1.5) is to (1.8), and repeated multiple times completing is calibrated;
(2) measure, specifically include following steps:
(2.1) rock core that apparent volume is Vs is put into sample room, and load standard stainless steel filling block as much as possible, filling block Cumulative volume is designated as Vf1;
(2.2) open the second valve and the 3rd valve, close after about 30 seconds, the stable registration of record digital wash, it is designated as Pa2;
(2.3) open the first valve, close the first valve, the stable registration of record digital wash after about 30 seconds, be designated as P5;
(2.4) open the second valve, the stable registration of record digital wash, be designated as P6, close after opening the 3rd valve emptying;
(2.5) simultaneous equation below:
%
Obtaining core porosity, wherein Za2, Z5, Z6 are the gas pressure of temperature helium under corresponding pressure Pa2, P5, P6 when being Ta The contracting factor, Vg is the particle volume of sample, and Vp is the pore volume of sample.
Above-mentioned measurement apparatus and measuring method are mutually corresponding, measurement apparatus of the present invention and traditional measurement apparatus Defining difference at helium tank in the attachment structure of reference cell and sample room, this architectural difference is formally seen smaller, But defining substantial variations, this change causes measuring method of the present invention to be implemented smoothly.
The beneficial effects of the present invention is:
First the present invention by introducing sample room by high-tension measurement helium, then dividing potential drop is to reference cell, relative to traditional industry mark Quasi-method significantly increases pressure change before and after dividing potential drop, and pressure change reduces with rock pore volume and increases, and is setting on an equal basis Under the conditions of Bei, use the measurement apparatus of the present invention and measuring method can measure core sample especially low-porosity more accurately The porosity of sample.
Brief description
Fig. 1 is the structural representation of core porosity measurement apparatus of the present invention;
Fig. 2 is structural representation during core porosity measurement apparatus of the present invention application.
Detailed description of the invention
The invention will be further described below in conjunction with the accompanying drawings:
As it is shown in figure 1, core porosity measurement apparatus of the present invention includes helium tank the 1st, pressure-reducing valve the 9th, sample room the 3rd, reference cell 2nd, pressure sensor the 4th, digital wash the 5th, the first valve the 8th, the second valve 7 and the 3rd valve 6, the outlet pressure-reducing valve 9 of helium tank 1 Entrance connect, the outlet of pressure-reducing valve 9 is connected with the first end of the first valve 8, the second end of the first valve 8 respectively with the second valve First end of door 7, the test side of the entrance of sample room 3 and pressure sensor 4 connect, and the second end of the second valve 7 is respectively with the The entrance of the first end of three valves 6 and reference cell 2 connects, and the second end of the 3rd valve 6 is unsettled, as emptying end, pressure sensing The signal output part of device 4 is connected with the signal input part of digital wash 5.In said structure, absolute pressure measured by pressure sensor 4 Power, digital wash 5 at least can show that all significant digits add 1 bit sign position, as measured value should contain 3 reliable digits and 1 Incredible figures, then digital wash 5 should at least show 5;The displacement volume of the first valve the 8th, the second valve 7 and the 3rd valve 6 It is 0.
As in figure 2 it is shown, the measuring method that core porosity measurement apparatus of the present invention uses, comprise the following steps:
(1) calibrate, specifically include following steps:
(1.1) make helium admission pressure close to the range upper limit of pressure sensor 4 by regulating pressure-reducing valve 9;
(1.2) open the second valve 7 and the 3rd valve 6, close after about 30 seconds, the stable registration of record digital wash 5, note For Pa1;
(1.3) vacant sample room 3, opens the first valve 8, closes the first valve 8 after about 30 seconds, records the steady of digital wash 5 Determine registration, be designated as P1;
(1.4) open the second valve 7, the stable registration of record digital wash 5, be designated as P2, after opening the 3rd valve 6 emptying Close;
(1.5) sample room 3 loading standard stainless steel filling block as much as possible, filling block cumulative volume is designated as Vf0;
(1.6) open the first valve 8, close the first valve 8, the stable registration of record digital wash 5 after about 30 seconds, be designated as P3;
(1.7) open the second valve 7, the stable registration of record digital wash 5, be designated as P4, after opening the 3rd valve 6 emptying Close;
(1.8) simultaneous equation below:
Obtaining reference cell volume Vr and sample room volume Vc, wherein Za1, Z1, Z2, Z3, Z4 are respectively corresponding pressure when temperature is Ta Power Pa1, the Gas Compression Factor of helium under P1, P2, P3, P4;Keeping environment conditions constant during measurement, environment temperature is designated as Ta, and when assuming all pressure readings, in system, gas temperature is Ta
(1.9) in adjustment sample room 3, after filling block volume, repetition step (1.5) is to (1.8), and repeated multiple times completing is calibrated;
(2) measure, specifically include following steps:
(2.1) rock core that apparent volume is Vs is put into sample room 3, and load standard stainless steel filling block as much as possible, fill Block cumulative volume is designated as Vf1;
(2.2) open the second valve 7 and the 3rd valve 6, close after about 30 seconds, the stable registration of record digital wash 5, it is designated as Pa2;
(2.3) open the first valve 8, close the first valve 8, the stable registration of record digital wash 5 after about 30 seconds, be designated as P5;
(2.4) open the second valve 7, the stable registration of record digital wash 5, be designated as P6, close after opening the 3rd valve 6 emptying Close;
(2.5) simultaneous equation below:
%
Obtaining core porosity, wherein Za2, Z5, Z6 are the gas pressure of temperature helium under corresponding pressure Pa2, P5, P6 when being Ta The contracting factor, Vg is the particle volume of sample, and Vp is the pore volume of sample.
The marrow of this method is, the volume of air inlet is servo-actuated with pore volume, the pore volume greatly then many dividing potential drops of air inlet The change of rear pressure is relatively small, and after the few dividing potential drop of the little then air inlet of pore volume, pressure change is relatively large;The volume of conventional method air inlet is Reference cell volume, after the big dividing potential drop of pore volume, pressure changes greatly, and after the little dividing potential drop of pore volume, pressure change is little.
Above-described embodiment is presently preferred embodiments of the present invention, is not the restriction to technical solution of the present invention, as long as The technical scheme that can realize on the basis of above-described embodiment without creative work, is regarded as falling into patent of the present invention Rights protection in the range of.

Claims (2)

1. a core porosity measurement apparatus, including helium tank, pressure-reducing valve, sample room, reference cell, pressure sensor and numeral Display table, it is characterised in that: also including the first valve, the second valve and the 3rd valve, the outlet of described helium tank subtracts with described The entrance of pressure valve connects, and the outlet of described pressure-reducing valve is connected with the first end of described first valve, the second of described first valve End is connected with the test side of the first end of described second valve, the entrance of described sample room and described pressure sensor respectively, institute The second end stating the second valve is connected with described first end of the 3rd valve and the entrance of described reference cell respectively, described 3rd valve Second end of door is unsettled, and the signal output part of described pressure sensor is connected with the signal input part of described digital wash.
2. the measuring method that a core porosity measurement apparatus as claimed in claim 1 uses, it is characterised in that: include with Lower step:
Calibration, specifically includes following steps:
Make helium admission pressure close to the range upper limit of pressure sensor by regulating pressure-reducing valve;
Open the second valve and the 3rd valve, close after about 30 seconds, the stable registration of record digital wash, it is designated as Pa1;
Vacant sample room, opens the first valve, closes the first valve, the stable registration of record digital wash, note after about 30 seconds For P1;
Open the second valve, the stable registration of record digital wash, be designated as P2, close after opening the 3rd valve emptying;
Sample room loads standard stainless steel filling block as much as possible, and filling block cumulative volume is designated as Vf0;
Open the first valve, close the first valve, the stable registration of record digital wash after about 30 seconds, be designated as P3;
Open the second valve, the stable registration of record digital wash, be designated as P4, close after opening the 3rd valve emptying;
Simultaneous equation below:
Obtaining reference cell volume Vr and sample room volume Vc, wherein Za1, Z1, Z2, Z3, Z4 are respectively corresponding pressure when temperature is Ta Power Pa1, the Gas Compression Factor of helium under P1, P2, P3, P4;Keeping environment conditions constant during measurement, environment temperature is designated as Ta, and when assuming all pressure readings, in system, gas temperature is Ta
In adjustment sample room, after filling block volume, repetition step (1.5) is to (1.8), and repeated multiple times completing is calibrated;
Measurement, specifically includes following steps:
(2.1) rock core that apparent volume is Vs is put into sample room, and load standard stainless steel filling block as much as possible, filling block Cumulative volume is designated as Vf1;
(2.2) open the second valve and the 3rd valve, close after about 30 seconds, the stable registration of record digital wash, it is designated as Pa2;
(2.3) open the first valve, close the first valve, the stable registration of record digital wash after about 30 seconds, be designated as P5;
(2.4) open the second valve, the stable registration of record digital wash, be designated as P6, close after opening the 3rd valve emptying;
(2.5) simultaneous equation below:
%
Obtaining core porosity, wherein Za2, Z5, Z6 are the gas pressure of temperature helium under corresponding pressure Pa2, P5, P6 when being Ta The contracting factor, Vg is the particle volume of sample, and Vp is the pore volume of sample.
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Cited By (8)

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CN108872045A (en) * 2018-08-06 2018-11-23 四川杰瑞泰克科技有限公司 A kind of measurement method of the broken sample total porosity of shale
CN108956943A (en) * 2018-06-20 2018-12-07 中国石油天然气股份有限公司 Coal rock cleat compressed coefficient measuring method and device
CN109142680A (en) * 2018-08-20 2019-01-04 中国石油天然气股份有限公司 Coal rock cleat compressed coefficient test device determines method and system
CN110095397A (en) * 2019-04-26 2019-08-06 四川杰瑞泰克科技有限公司 The multi-functional full-automatic shale gas gaging hole porosity measurement method of GRT-1 type and device
CN112485175A (en) * 2020-11-12 2021-03-12 武汉古生代检测科技有限公司 Rock porosity measuring method and measuring device
CN112540033A (en) * 2020-11-18 2021-03-23 中国科学院武汉岩土力学研究所 Test device for salt deposit sediment void ratio and gas displacement brine
CN112964598A (en) * 2021-02-22 2021-06-15 科吉思石油技术咨询(北京)有限公司 Method and device for continuously measuring density and organic carbon content of formation cuttings
CN114047105A (en) * 2021-11-15 2022-02-15 东北石油大学 Device and method for testing porosity of high-pressure helium shale

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Publication number Priority date Publication date Assignee Title
CN108956943A (en) * 2018-06-20 2018-12-07 中国石油天然气股份有限公司 Coal rock cleat compressed coefficient measuring method and device
CN108872045A (en) * 2018-08-06 2018-11-23 四川杰瑞泰克科技有限公司 A kind of measurement method of the broken sample total porosity of shale
CN109142680A (en) * 2018-08-20 2019-01-04 中国石油天然气股份有限公司 Coal rock cleat compressed coefficient test device determines method and system
CN109142680B (en) * 2018-08-20 2021-06-01 中国石油天然气股份有限公司 Coal rock cleat compression coefficient testing device, determining method and system
CN110095397A (en) * 2019-04-26 2019-08-06 四川杰瑞泰克科技有限公司 The multi-functional full-automatic shale gas gaging hole porosity measurement method of GRT-1 type and device
CN112485175A (en) * 2020-11-12 2021-03-12 武汉古生代检测科技有限公司 Rock porosity measuring method and measuring device
CN112540033A (en) * 2020-11-18 2021-03-23 中国科学院武汉岩土力学研究所 Test device for salt deposit sediment void ratio and gas displacement brine
CN112964598A (en) * 2021-02-22 2021-06-15 科吉思石油技术咨询(北京)有限公司 Method and device for continuously measuring density and organic carbon content of formation cuttings
CN114047105A (en) * 2021-11-15 2022-02-15 东北石油大学 Device and method for testing porosity of high-pressure helium shale
CN114047105B (en) * 2021-11-15 2022-11-15 东北石油大学 Device and method for testing porosity of high-pressure helium shale

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