CN106148951A - A kind of high-temperature wearable laser melting coating alloy powder - Google Patents

A kind of high-temperature wearable laser melting coating alloy powder Download PDF

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Publication number
CN106148951A
CN106148951A CN201610865112.2A CN201610865112A CN106148951A CN 106148951 A CN106148951 A CN 106148951A CN 201610865112 A CN201610865112 A CN 201610865112A CN 106148951 A CN106148951 A CN 106148951A
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China
Prior art keywords
alloy powder
boron
powder
cobalt
chromium
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CN201610865112.2A
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Chinese (zh)
Inventor
赵洪运
舒凤远
刘硕
赵璇
赵一璇
贺文雄
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Harbin Institute of Technology Weihai
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Harbin Institute of Technology Weihai
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Priority to CN201610865112.2A priority Critical patent/CN106148951A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • C23C24/103Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
    • C23C24/106Coating with metal alloys or metal elements only
    • B22F1/0003
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • B22F2009/043Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by ball milling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Powder Metallurgy (AREA)
  • Laser Beam Processing (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

The invention discloses a kind of high-temperature wearable laser melting coating alloy powder, the one-tenth of following atomic molar ratio be grouped into: cobalt 12~20%, ferrum 22~30%, chromium 29%, nickel 8%, silicon 7%, boron 14%;The material of alloy powder is the ferro-boron of 24% selected from the cobalt that precision is more than 99.7%, chromium, ferrum, nickel simple metal and ferrosilicon, Boron contents that silicone content is 77%;The preparation process of alloy powder is as follows: puts in planetary ball mill after the said components weighed being mixed, carries out ball milling under argon shield effect;After ball milling terminates, sieving machine sift out powder body that granularity is 200~300 mesh as finished powder.The present invention can be used for the preparation alloy clad containing amorphous phase, and is capable of the good metallurgical binding of coating and matrix;Use the present invention to prepare alloy clad, be possible not only to be substantially reduced the production cost using rare earth metal to prepare alloy clad, and the alloy clad prepared has stronger microhardness and high temperature abrasion resistance, has great production meaning.

Description

A kind of high-temperature wearable laser melting coating alloy powder
Technical field
The present invention relates to a kind of alloy powder, particularly relate to a kind of high-temperature wearable laser melting coating alloy powder.
Background technology
Laser melting and coating technique is emerging a kind of novel surface engineering seventies in last century, and it is by substrate surface Add cladding material, and utilize the laser beam of high-energy-density to be allowed to consolidation together with substrate surface thin layer, substrate surface can be made Formed and the filling cladding layer that it is metallurgical binding.This cladding layer can significantly improve substrate surface wear-resisting, anti-corrosion, heat-resisting, Non-oxidizability and electrical characteristic, thus reach the purpose of surface modification or reparation, both met material surface particular characteristic Requirement, has saved again substantial amounts of noble element, and therefore, the application prospect of laser melting and coating technique is boundless.
The cladding material of laser melting coating generally adds with the form of powder, silk, plate, the most normal With.Alloy powder of the prior art uses rare earth element to be Main System mostly, such as neodymium, zirconium and tantalum etc., has exploitation application Relatively costly defect, and along with the renewal of modern industrial technology and development, people are resistance to plant equipment and part material Abrasiveness requires more and more higher, and existing alloy powder can not meet people to coating hardness and the needs of abrasion resistance.
Summary of the invention
In order to solve the weak point existing for above-mentioned technology, the invention provides a kind of high-temperature wearable laser melting coating and close Bronze end.
In order to solve above technical problem, the technical solution used in the present invention is: a kind of high-temperature wearable laser melting coating closes Bronze end, is grouped into by the one-tenth of following atomic molar ratio:
Cobalt 12~20%, ferrum 22~30%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%;
The material of alloy powder selected from cobalt, chromium, ferrum, nickel simple metal and the silicone content that precision is more than 99.7% is Ferrosilicon, the Boron contents of 77% are the ferro-boron of 24%;The preparation process of alloy powder is as follows:
Weigh the cobalt of corresponding mass, chromium, nickel, ferrosilicon, ferro-boron successively, further calculate the addition tapped a blast furnace and weigh; By the said components weighed up mix after put in planetary ball mill, under argon shield effect, carry out ball milling, Ball-milling Time be 1~ 2h, rotational speed of ball-mill is 300~400r/min;After ball milling terminates, sieving machine sift out the powder body conduct that granularity is 200~300 mesh Finished powder.
The present invention can be used for the preparation alloy clad containing amorphous phase, and is capable of the good metallurgy of coating and matrix In conjunction with;Use the present invention to prepare alloy clad, be possible not only to be substantially reduced the production using rare earth metal to prepare alloy clad and become This, and the alloy clad prepared has stronger microhardness and high temperature abrasion resistance, has great production meaning.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further detailed explanation.
The present invention is grouped into by the one-tenth of following atomic molar ratio:
Cobalt 12~20%, ferrum 22~30%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%;
The material of alloy powder selected from cobalt, chromium, ferrum, nickel simple metal and the silicone content that precision is more than 99.7% is Ferrosilicon, the Boron contents of 77% are the ferro-boron of 24%;The preparation process of alloy powder is as follows:
Weigh the cobalt of corresponding mass, chromium, nickel, ferrosilicon, ferro-boron successively, further calculate the addition tapped a blast furnace and weigh; By the said components weighed up mix after put in planetary ball mill, under argon shield effect, carry out ball milling, Ball-milling Time be 1~ 2h, rotational speed of ball-mill is 300~400r/min;After ball milling terminates, sieving machine sift out the powder body conduct that granularity is 200~300 mesh Finished powder.
The present invention applying step in laser melting and coating technique field is as follows:
A, base material pretreatment: first with grinding machine, H13 steel substrate surface is machined out, it is ensured that smooth surface is smooth;Make again Clean with acetone and remove surface and oil contaminant and foul, be then placed in drying baker carrying out drying and processing;The alloy powder that will have configured Put in the lump in drying baker;The temperature of regulation drying baker is 100 DEG C, and drying time is 1h;
B, coating: take out the alloy powder and H13 steel substrate dried, alloy powder is preset at H13 steel substrate surface, And the thickness of preset alloy powder is controlled by powder-scraper, the thickness making powder is 200 μm;
C, laser melting coating: be positioned in argon protecting cover by the matrix preseting alloy powder, carry out pre-logical to protective cover Gas, it is 1.5min that argon is passed through the time;Use pulse laser that the preset matrix in argon-filled protection cover is carried out cladding;By pulse The running parameter of laser instrument is set to: electric current 380A, pulsewidth 8ms, frequency 4Hz, and laser scanning speed is 100mm/min, laser Spot diameter is 2.2~2.5mm, and laser defocusing amount is 20mm;After cladding terminates, matrix is cooled to room temperature, i.e. at H13 steel table Face obtains non-crystaline amorphous metal coating, completes preparation.
The material of argon protecting cover is quartz glass, for observing the machining locus within protective cover, and protects laser instrument On optical glass will not be by high temperature powder calcination.The advantage of quartz glass protective cover is less to laser absorption, and laser is saturating Rate of crossing is up to more than 90%.
Pulse laser is Nd:YAG solid state laser.
Below by specific embodiment, the application effect of the present invention is illustrated further.
Embodiment one:
According to following atomic molar than the configuration carrying out alloy powder:
Cobalt 20%, ferrum 22%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%
According to above-mentioned applying step, alloy powder being carried out laser melting coating, test obtains the alloy that content of amorphous is 67% and covers Layer;Alloy clad carries out micro-hardness testing and high temperature abrasion resistance test, and test result is as follows: (1) coating is than matrix Microhardness improves 4.3 times;(2) amorphous coating coefficient of friction from outside to inside maintains 0.11~0.17, and surface abrasion Rate reduces 54% relative to matrix, shows that this alloy clad has fabulous wearability.
Embodiment two:
According to following atomic molar than the configuration carrying out alloy powder:
Cobalt 18%, ferrum 24%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%;
According to above-mentioned applying step, alloy powder being carried out laser melting coating, test obtains the alloy that content of amorphous is 64% and covers Layer;Alloy clad carries out micro-hardness testing and high temperature abrasion resistance test, and test result is as follows: (1) coating is than matrix Microhardness improves 4.1 times;(2) amorphous coating coefficient of friction from outside to inside maintains 0.13~0.18, and surface abrasion Rate reduces 48% relative to matrix, shows that this alloy clad has fabulous wearability.
Embodiment three:
According to following atomic molar than the configuration carrying out alloy powder:
Cobalt 16%, ferrum 28%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%;
According to above-mentioned applying step, alloy powder being carried out laser melting coating, test obtains the alloy that content of amorphous is 63.5% Coating;Alloy clad carries out micro-hardness testing and high temperature abrasion resistance test, and test result is as follows: (1) coating compares matrix Microhardness improve 3.9 times;(2) amorphous coating coefficient of friction from outside to inside maintains 0.13~0.19, and surface mill Loss rate reduces 46% relative to matrix, shows that this alloy clad has fabulous wearability.
Embodiment four:
According to following atomic molar than the configuration carrying out alloy powder:
Cobalt 14%, ferrum 28%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%;
According to above-mentioned applying step, alloy powder being carried out laser melting coating, test obtains the alloy that content of amorphous is 59.5% Coating;Alloy clad carries out micro-hardness testing and high temperature abrasion resistance test, and test result is as follows: (1) coating compares matrix Microhardness improve 3.7 times;(2) amorphous coating coefficient of friction from outside to inside maintains 0.14~0.21, and surface mill Loss rate reduces 42% relative to matrix, shows that this alloy clad has fabulous wearability.
Embodiment five:
According to following atomic molar than the configuration carrying out alloy powder:
Cobalt 12%, ferrum 30%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%;
According to above-mentioned applying step, alloy powder being carried out laser melting coating, test obtains the alloy that content of amorphous is 51% and covers Layer;Alloy clad carries out micro-hardness testing and high temperature abrasion resistance test, and test result is as follows: (1) coating is than matrix Microhardness improves 3.3 times;(2) amorphous coating coefficient of friction from outside to inside maintains 0.15~0.22, and surface abrasion Rate reduces 37% relative to matrix, shows that this alloy clad has fabulous wearability.
Inventive formulation combines laser melting and coating technique, and the alloy clad top prepared is amorphous phase and Crystallization Phases mutually Line and staff control, the ratio shared by amorphous phase reaches as high as 67%;When in mould coating, amorphous content is too high, in amorphous coating Portion can ftracture, so that mould surface coating when forge hot or hot extrusion is easy to fall off, and then affects precision and the use of mould Life-span.Therefore, the rare-earth system in formula is changed into cobalt system by the present invention, although slightly lower amorphous content, but non- Suitably reducing of crystal content is favorably improved the plasticity and toughness of amorphous coating, wearability and impact abrasion performance, and avoids Using rare earth metal or other expensive metal, the production cost of amorphous coating can be made to be greatly lowered, more meet China can Sustainable development strategy requirement, has great production meaning.Additionally, containing the self-fluxing nature element such as silicon, boron, Ke Yi in the present invention Bath is played the effect that deoxidation is the most molten by laser cladding process, thus realizes the good metallurgical binding of coating and matrix, Cladding is in hgher efficiency.
Above-mentioned embodiment is not limitation of the present invention, and the present invention is also not limited to the example above, and this technology is led Change that the technical staff in territory is made in the range of technical scheme, retrofit, add or replace, also belong to this Bright protection domain.

Claims (1)

1. a high-temperature wearable laser melting coating alloy powder, it is characterised in that: described alloy powder is by following atomic molar ratio One-tenth be grouped into:
Cobalt 12~20%, ferrum 22~30%,
Chromium 29%, nickel 8%,
Silicon 7%, boron 14%;
The material of described alloy powder selected from cobalt, chromium, ferrum, nickel simple metal and the silicone content that precision is more than 99.7% is Ferrosilicon, the Boron contents of 77% are the ferro-boron of 24%;The preparation process of described alloy powder is as follows:
Weigh the cobalt of corresponding mass, chromium, nickel, ferrosilicon, ferro-boron successively, further calculate the addition tapped a blast furnace and weigh;To claim Putting in planetary ball mill after good said components mixing, carry out ball milling under argon shield effect, Ball-milling Time is 1~2h, Rotational speed of ball-mill is 300~400r/min;After ball milling terminates, sieving machine sift out powder body that granularity is 200~300 mesh as finished product Powder.
CN201610865112.2A 2016-09-29 2016-09-29 A kind of high-temperature wearable laser melting coating alloy powder Pending CN106148951A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108531904A (en) * 2018-03-30 2018-09-14 昆明理工大学 A kind of wear-resistant coating and preparation method thereof
CN109504965A (en) * 2018-11-26 2019-03-22 海洋化工研究院有限公司 A kind of iron-based anti-corrosion nonskid coating of composite construction high temperature and preparation method thereof
CN111850374A (en) * 2020-08-04 2020-10-30 哈尔滨工业大学(威海) High-entropy alloy powder for laser cladding and coating preparation method
CN111850550A (en) * 2020-08-04 2020-10-30 哈尔滨工业大学(威海) WC reinforced high-entropy alloy powder for laser cladding and coating preparation method
CN113512311A (en) * 2021-04-14 2021-10-19 武汉理工大学 Lubricating wear-resistant coating applied to slewing bearing raceway and preparation method thereof
CN113897607A (en) * 2021-09-18 2022-01-07 安徽昱工激光技术有限公司 Laser cladding process for wear-resisting plate and auxiliary equipment thereof
CN113930652A (en) * 2021-09-26 2022-01-14 西安理工大学 Cobalt-based welding wire for laser cladding and preparation method thereof

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EP1882750A2 (en) * 2006-07-27 2008-01-30 Sanyo Special Steel Co., Ltd. Raw material powder for laser clad valve seat and valve seat using the same
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EP1882750A2 (en) * 2006-07-27 2008-01-30 Sanyo Special Steel Co., Ltd. Raw material powder for laser clad valve seat and valve seat using the same
CN101444981A (en) * 2008-12-30 2009-06-03 东北大学 In-situ preparation of cobalt-base alloy gradient coating on aldary surface through laser induction, and method thereof
CN103290404A (en) * 2013-05-06 2013-09-11 浙江工业大学 Laser-cladding high-entropy alloy powder and preparation method of high-entropy alloy coating

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108531904A (en) * 2018-03-30 2018-09-14 昆明理工大学 A kind of wear-resistant coating and preparation method thereof
CN109504965A (en) * 2018-11-26 2019-03-22 海洋化工研究院有限公司 A kind of iron-based anti-corrosion nonskid coating of composite construction high temperature and preparation method thereof
CN111850374A (en) * 2020-08-04 2020-10-30 哈尔滨工业大学(威海) High-entropy alloy powder for laser cladding and coating preparation method
CN111850550A (en) * 2020-08-04 2020-10-30 哈尔滨工业大学(威海) WC reinforced high-entropy alloy powder for laser cladding and coating preparation method
CN113512311A (en) * 2021-04-14 2021-10-19 武汉理工大学 Lubricating wear-resistant coating applied to slewing bearing raceway and preparation method thereof
CN113512311B (en) * 2021-04-14 2022-04-15 武汉理工大学 Lubricating wear-resistant coating applied to slewing bearing raceway and preparation method thereof
CN113897607A (en) * 2021-09-18 2022-01-07 安徽昱工激光技术有限公司 Laser cladding process for wear-resisting plate and auxiliary equipment thereof
CN113897607B (en) * 2021-09-18 2023-10-31 安徽昱工激光技术有限公司 Laser cladding process for wear-resistant plate and auxiliary equipment thereof
CN113930652A (en) * 2021-09-26 2022-01-14 西安理工大学 Cobalt-based welding wire for laser cladding and preparation method thereof

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