CN106148812A - One is corrosion resistant creeps into drilling rod steel - Google Patents

One is corrosion resistant creeps into drilling rod steel Download PDF

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Publication number
CN106148812A
CN106148812A CN201610602025.8A CN201610602025A CN106148812A CN 106148812 A CN106148812 A CN 106148812A CN 201610602025 A CN201610602025 A CN 201610602025A CN 106148812 A CN106148812 A CN 106148812A
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CN
China
Prior art keywords
bismuth
zirconium
drilling rod
ratio
creeps
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610602025.8A
Other languages
Chinese (zh)
Inventor
赵钧羡
赵秀和
刘志强
胡郁乐
段隆臣
胡新丽
李波
崔世明
崔洲
崔一洲
丁跃翔
姚林丽
韩晶晶
周奇
严娟
严一娟
沈笑宇
孙奉存
王所根
纪静
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU HEXIN PETROLEUM MACHINERY CO Ltd
Original Assignee
JIANGSU HEXIN PETROLEUM MACHINERY CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU HEXIN PETROLEUM MACHINERY CO Ltd filed Critical JIANGSU HEXIN PETROLEUM MACHINERY CO Ltd
Priority to CN201610602025.8A priority Critical patent/CN106148812A/en
Publication of CN106148812A publication Critical patent/CN106148812A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings

Abstract

nullThe invention discloses and a kind of corrosion resistant creep into drilling rod steel,Composition including following weight percentage: 0.13~0.15wt% carbon、0.26~0.30wt% silicon、0.03~0.05wt% boron、0.70~0.90wt% manganese、0.02~0.04wt% beryllium、0.015~0.025wt% sulfur、0.08~0.12wt% rubidium、0.10~0.14wt% vanadium、0.40~0.50wt% nickel、0.20~0.30wt% copper、0.06~0.08wt% molybdenum、0.08~0.10wt% titanium、0.02~0.04wt% niobium、0.16~0.20wt% zinc、0.08~0.10wt% thorium,Bismuth and zirconium totally 0.07~0.09wt%,Surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 6~8:1.The drilling rod steel that creeps into of present invention offer has the decay resistance of excellence, the drilling rod that creeps into that can prepare highly corrosion resistant with it, improves the service life creeping into drilling rod.This anticorrosion effect is relevant with the percentage composition ratio of bismuth and zirconium, and when the ratio of bismuth and zirconium is 6~8:1, decay resistance is optimum.

Description

One is corrosion resistant creeps into drilling rod steel
Technical field
The invention belongs to creep into drilling rod field, be specifically related to a kind of corrosion resistant creep into drilling rod steel.
Background technology
Drilling rod is the afterbody steel pipe with a chain for binding criminals stricture of vagina, be used for connecting rig landscape apparatus and be positioned at drilling well bottom bore mill equipment or Bottom outlet device.The purposes of drilling rod is that drilling mud is transported to drill bit, and improves, reduces or rotate bottom outlet dress together with drill bit Put.Drilling rod allows for bearing huge interior external pressure, distorts, bends and vibrate.
Therefore, higher to the requirement creeping into drilling rod steel in engineering, both needed that there is wearability, there is a need to corrosion-resistant Property.
Summary of the invention
It is an object of the invention to provide and a kind of corrosion resistant creep into drilling rod steel.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
One is corrosion resistant creeps into drilling rod steel, including the composition of following weight percentage: 0.13~0.15wt% carbon, 0.26~0.30wt% silicon, 0.03~0.05wt% boron, 0.70~0.90wt% manganese, 0.02~0.04wt% beryllium, 0.015~ 0.025wt% sulfur, 0.08~0.12wt% rubidium, 0.10~0.14wt% vanadium, 0.40~0.50wt% nickel, 0.20~0.30wt% Copper, 0.06~0.08wt% molybdenum, 0.08~0.10wt% titanium, 0.02~0.04wt% niobium, 0.16~0.20wt% zinc, 0.08~ 0.10wt% thorium, bismuth and zirconium totally 0.07~0.09wt%, surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 6~8:1.
Further, the described drilling rod ladle that creeps into includes the composition of following weight percentage: 0.14wt% carbon, 0.28wt% silicon, 0.04wt% boron, 0.80wt% manganese, 0.03wt% beryllium, 0.020wt% sulfur, 0.10wt% rubidium, 0.12wt% Vanadium, 0.45wt% nickel, 0.25wt% copper, 0.07wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.18wt% zinc, 0.09wt% Thorium, bismuth and zirconium 0.08wt% altogether, surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 7:1.
Further, the described drilling rod ladle that creeps into includes the composition of following weight percentage: 0.13wt% carbon, 0.26wt% silicon, 0.03wt% boron, 0.70wt% manganese, 0.02wt% beryllium, 0.015wt% sulfur, 0.08wt% rubidium, 0.10wt% Vanadium, 0.40wt% nickel, 0.20wt% copper, 0.06wt% molybdenum, 0.08wt% titanium, 0.02wt% niobium, 0.16wt% zinc, 0.08wt% Thorium, bismuth and zirconium 0.07wt% altogether, surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 6:1.
Further, the described drilling rod ladle that creeps into includes the composition of following weight percentage: 0.15wt% carbon, 0.30wt% silicon, 0.05wt% boron, 0.90wt% manganese, 0.04wt% beryllium, 0.025wt% sulfur, 0.12wt% rubidium, 0.14wt% Vanadium, 0.50wt% nickel, 0.30wt% copper, 0.08wt% molybdenum, 0.10wt% titanium, 0.04wt% niobium, 0.20wt% zinc, 0.10wt% Thorium, bismuth and zirconium 0.09wt% altogether, surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 8:1.
Advantages of the present invention:
The drilling rod steel that creeps into of present invention offer has the decay resistance of excellence, can prepare highly corrosion resistant with it Creep into drilling rod, improve the service life creeping into drilling rod.This anticorrosion effect is relevant with the percentage composition ratio of bismuth and zirconium, bismuth When being 6~8:1 with the ratio of zirconium, decay resistance is optimum.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit the present invention with this and protect model Enclose.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, can be right Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: creep into drilling rod steel
Composition including following weight percentage: 0.14wt% carbon, 0.28wt% silicon, 0.04wt% boron, 0.80wt% Manganese, 0.03wt% beryllium, 0.020wt% sulfur, 0.10wt% rubidium, 0.12wt% vanadium, 0.45wt% nickel, 0.25wt% copper, 0.07wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.18wt% zinc, 0.09wt% thorium, bismuth and zirconium 0.08wt%, surplus altogether For ferrum;Wherein, the ratio of bismuth and zirconium is 7:1.
Embodiment 2: creep into drilling rod steel
Composition including following weight percentage: 0.13wt% carbon, 0.26wt% silicon, 0.03wt% boron, 0.70wt% Manganese, 0.02wt% beryllium, 0.015wt% sulfur, 0.08wt% rubidium, 0.10wt% vanadium, 0.40wt% nickel, 0.20wt% copper, 0.06wt% molybdenum, 0.08wt% titanium, 0.02wt% niobium, 0.16wt% zinc, 0.08wt% thorium, bismuth and zirconium 0.07wt%, surplus altogether For ferrum;Wherein, the ratio of bismuth and zirconium is 6:1.
Embodiment 3: creep into drilling rod steel
Composition including following weight percentage: 0.15wt% carbon, 0.30wt% silicon, 0.05wt% boron, 0.90wt% Manganese, 0.04wt% beryllium, 0.025wt% sulfur, 0.12wt% rubidium, 0.14wt% vanadium, 0.50wt% nickel, 0.30wt% copper, 0.08wt% molybdenum, 0.10wt% titanium, 0.04wt% niobium, 0.20wt% zinc, 0.10wt% thorium, bismuth and zirconium 0.09wt%, surplus altogether For ferrum;Wherein, the ratio of bismuth and zirconium is 8:1.
Embodiment 4: creep into drilling rod steel
Composition including following weight percentage: 0.14wt% carbon, 0.28wt% silicon, 0.04wt% boron, 0.80wt% Manganese, 0.03wt% beryllium, 0.020wt% sulfur, 0.10wt% rubidium, 0.12wt% vanadium, 0.45wt% nickel, 0.25wt% copper, 0.07wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.18wt% zinc, 0.09wt% thorium, bismuth and zirconium 0.08wt%, surplus altogether For ferrum;Wherein, the ratio of bismuth and zirconium is 6:1.
Embodiment 5: creep into drilling rod steel
Composition including following weight percentage: 0.14wt% carbon, 0.28wt% silicon, 0.04wt% boron, 0.80wt% Manganese, 0.03wt% beryllium, 0.020wt% sulfur, 0.10wt% rubidium, 0.12wt% vanadium, 0.45wt% nickel, 0.25wt% copper, 0.07wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.18wt% zinc, 0.09wt% thorium, bismuth and zirconium 0.08wt%, surplus altogether For ferrum;Wherein, the ratio of bismuth and zirconium is 8:1.
The ratio of embodiment 6: comparative example, bismuth and zirconium is 5:1
Composition including following weight percentage: 0.14wt% carbon, 0.28wt% silicon, 0.04wt% boron, 0.80wt% Manganese, 0.03wt% beryllium, 0.020wt% sulfur, 0.10wt% rubidium, 0.12wt% vanadium, 0.45wt% nickel, 0.25wt% copper, 0.07wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.18wt% zinc, 0.09wt% thorium, bismuth and zirconium 0.08wt%, surplus altogether For ferrum;Wherein, the ratio of bismuth and zirconium is 5:1.
The ratio of embodiment 7: comparative example, bismuth and zirconium is 9:1
Composition including following weight percentage: 0.14wt% carbon, 0.28wt% silicon, 0.04wt% boron, 0.80wt% Manganese, 0.03wt% beryllium, 0.020wt% sulfur, 0.10wt% rubidium, 0.12wt% vanadium, 0.45wt% nickel, 0.25wt% copper, 0.07wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.18wt% zinc, 0.09wt% thorium, bismuth and zirconium 0.08wt%, surplus altogether For ferrum;Wherein, the ratio of bismuth and zirconium is 9:1.
Embodiment 8: effect example
The Steel material of the embodiment 1~7 prepared has been carried out corrosion-resistant test.The Steel material of embodiment~7 is divided Not putting in the potassium hydroxide solution of the NaCl solution of 5wt%, the sulfuric acid solution of 10wt% and 10wt%, minute is 1 year.
Result see table.
The NaCl solution of 5wt% The sulfuric acid solution of 10wt% The potassium hydroxide of 10wt%
Embodiment 1 0.0002mm/ 0.001mm/ 0.001mm/
Embodiment 4 0.0002mm/ 0.001mm/ 0.001mm/
Embodiment 5 0.0002mm/ 0.001mm/ 0.001mm/
Embodiment 6 0.0008mm/ 0.009mm/ 0.008mm/
Embodiment 7 0.0009mm/ 0.009mm/ 0.008mm/
Embodiment 2,3 test result is basically identical with embodiment 4,5.
The above results shows, the drilling rod steel that creeps into of present invention offer has the decay resistance of excellence, can make with it Standby go out highly corrosion resistant creep into drilling rod, improve the service life creeping into drilling rod.This anticorrosion effect and bismuth and the percentage of zirconium Content ratio is relevant, and when the ratio of bismuth and zirconium is 6~8:1, decay resistance is optimum.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent, Essence and protection domain without deviating from technical solution of the present invention.

Claims (4)

1. one kind corrosion resistant is crept into drilling rod steel, it is characterised in that include following weight percentage composition: 0.13~ 0.15wt% carbon, 0.26~0.30wt% silicon, 0.03~0.05wt% boron, 0.70~0.90wt% manganese, 0.02~0.04wt% Beryllium, 0.015~0.025wt% sulfur, 0.08~0.12wt% rubidium, 0.10~0.14wt% vanadium, 0.40~0.50wt% nickel, 0.20 ~0.30wt% copper, 0.06~0.08wt% molybdenum, 0.08~0.10wt% titanium, 0.02~0.04wt% niobium, 0.16~ 0.20wt% zinc, 0.08~0.10wt% thorium, bismuth and zirconium totally 0.07~0.09wt%, surplus is ferrum;Wherein, bismuth and the ratio of zirconium It is 6~8:1.
The most according to claim 1 creep into drilling rod steel, it is characterised in that include the composition of following weight percentage: 0.14wt% carbon, 0.28wt% silicon, 0.04wt% boron, 0.80wt% manganese, 0.03wt% beryllium, 0.020wt% sulfur, 0.10wt% Rubidium, 0.12wt% vanadium, 0.45wt% nickel, 0.25wt% copper, 0.07wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.18wt% Zinc, 0.09wt% thorium, bismuth and zirconium 0.08wt% altogether, surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 7:1.
The most according to claim 1 creep into drilling rod steel, it is characterised in that include the composition of following weight percentage: 0.13wt% carbon, 0.26wt% silicon, 0.03wt% boron, 0.70wt% manganese, 0.02wt% beryllium, 0.015wt% sulfur, 0.08wt% Rubidium, 0.10wt% vanadium, 0.40wt% nickel, 0.20wt% copper, 0.06wt% molybdenum, 0.08wt% titanium, 0.02wt% niobium, 0.16wt% Zinc, 0.08wt% thorium, bismuth and zirconium 0.07wt% altogether, surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 6:1.
The most according to claim 1 creep into drilling rod steel, it is characterised in that include the composition of following weight percentage: 0.15wt% carbon, 0.30wt% silicon, 0.05wt% boron, 0.90wt% manganese, 0.04wt% beryllium, 0.025wt% sulfur, 0.12wt% Rubidium, 0.14wt% vanadium, 0.50wt% nickel, 0.30wt% copper, 0.08wt% molybdenum, 0.10wt% titanium, 0.04wt% niobium, 0.20wt% Zinc, 0.10wt% thorium, bismuth and zirconium 0.09wt% altogether, surplus is ferrum;Wherein, the ratio of bismuth and zirconium is 8:1.
CN201610602025.8A 2016-07-27 2016-07-27 One is corrosion resistant creeps into drilling rod steel Pending CN106148812A (en)

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Publication number Priority date Publication date Assignee Title
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JP2011098437A (en) * 2009-05-22 2011-05-19 Nippon Steel Corp Cutting method for steel for machine structural use having excellent cutting-tool life
US20150030880A1 (en) * 2012-01-26 2015-01-29 Jef Steel Corporation High-strength hot-rolled steel sheet and method for producing same
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Application publication date: 20161123