CN106147567A - A kind of anti-graffiti electrophoretic paint and using method thereof - Google Patents
A kind of anti-graffiti electrophoretic paint and using method thereof Download PDFInfo
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- CN106147567A CN106147567A CN201610489771.0A CN201610489771A CN106147567A CN 106147567 A CN106147567 A CN 106147567A CN 201610489771 A CN201610489771 A CN 201610489771A CN 106147567 A CN106147567 A CN 106147567A
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- Prior art keywords
- electrophoretic paint
- graffiti
- methyl
- ethyl
- acid esters
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6295—Polymers of silicium containing compounds having carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/90—Compositions for anticorrosive coatings
Abstract
The invention discloses a kind of anti-graffiti electrophoretic paint, including hydroxyl value water-soluble fluorine silicon cationic resin, close firming agent, coalescents, pigment, cosolvent, remaining component is water.The electrophoretic paint using method of the present invention is: uses electrophoresis process that the metallic substrates with conduction property is carried out top layer coating, then dries coating so that it is crosslinking film forming.It is an advantage of the current invention that: antigraffiti properties is good, tack, wearability, excellent transparency, metallic substrates can be played isolation and protective effect very well.
Description
Technical field
The present invention relates to japanning field, particularly relate to a kind of anti-graffiti paint water dispersible, that be applicable to electrophoresis process and
Its using method.
Background technology
Anti-graffiti coatings is study hotspot in recent years.Have in the world the Massachusetts Institute of Technology Tuteja (Science, 2007,
318,1618), the Aizenberg (NAT COMMUN, 2013,4,2167) of Harvard University, MPG's macromolecule research
Vollmer (Science, 2012,335,67；NAT COMMUN, 2013,4,2512), the Parkin of London university
(Science, 2015,347,1132), the Liu Guojun of Queen's University of Canada, the woods of Deakin University of Australia is virgin, U.S.'s Wei
The Law in Bai Site Xerox research center, the Hozumi of Japanese national advanced person industrial science technical research institute, domestic Chinese Academy of Sciences chemistry
A few group such as Jiang Lei achieve the synthetic work of anti-graffiti coatings at laboratory.
Anti-graffiti coatings can be divided into surface to have micro nano structure and without two kinds of coatings of micro nano structure.Liquid can be had by the former
Higher contact angle, make liquid cannot moistening or sprawl, but the performances such as coating transparent, tack, hardness, wearability are by micro-nano
Rice structure influence, it is more difficult to promote.The latter does not have the highest contact angle, but the combination property of paint film is better than the former.
The present invention uses Industrial raw material, and anti-graffiti coatings system has carried out deep design, transformation and perfect, success
Prepare the water dispersible polymer coating materials with anti-graffiti function, and be applicable to traditional electrophoresis process.This
Bright anti-graffiti electrophoretic paint dispersion Environmental Safety, raw material sources are extensive, and preparation method is simple, and the coating of preparation has
Preferable antigraffiti properties also has the good transparency, tack, wearability；Coating metallic substrates can be played well every
From and protective effect, effectively prevent substrate oxidized or corrosion；Additionally, the style of coating can be by system composition regulation and control.
Summary of the invention
It is an object of the invention to provide that antigraffiti properties is good, tack, wearability, excellent transparency, to metallic substrates
Can play isolation very well and the electrophoretic paint of protective effect, technology is as follows:
A kind of anti-graffiti electrophoretic paint, including following component:
Remaining composition is water.
Remaining composition is water.
Remaining composition is water.
Further, described hydroxyl value water-soluble fluorine silicon cationic resin is to be gathered by Solution Free Radical by vinyl monomer
The polymer that conjunction or emulsion are polymerized, described vinyl monomer includes low-surface-energy monomer A and comonomer B.
Further, described low-surface-energy monomer A includes vinyl fluorochemical monomer and vinyl silicon-containing monomer；
Described vinyl fluorochemical monomer includes perfluoro butyl ethyl propylene acid esters, perfluoro hexyl ethyl propylene acid esters, perfluor
Octyl group ethyl propylene acid esters, perfluoro decyl ethyl propylene acid esters, methyl perfluoro butyl ethyl acrylate, methyl perfluoro hexyl second
Base acrylate, methyl perfluoro octyl group ethyl propylene acid esters, methyl perfluoro decyl ethyl propylene acid esters, methacrylic acid trifluoro
Ethyl ester, hexafluorobutyl acrylate, Hexafluorobutyl mathacrylate, dodecafluorhe-ptylacrylate, dodecafluoroheptyl methacrylate,
One or more in methacrylic acid ten trifluoro monooctyl ester；
Described vinyl silicon-containing monomer includes vinyltrimethoxy silane, VTES, vinyl three
One or more in isopropoxy silane.
Further, described comonomer B include dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate,
Acrylic acid methyl ester., methyl methacrylate, butyl acrylate, butyl methacrylate, octadecyl acrylate, methacrylic acid ten
Octaester, 2-(Acryloyloxy)ethanol, hydroxyethyl methylacrylate, Hydroxypropyl acrylate, Hydroxypropyl methacrylate, isobomyl acrylate
One or more in ester, styrene.
Further, described closing firming agent is reacted by reacted constituent E and isocyanate ester compound and is obtained, and uses electrophoresis
During paint, after reaching to unseal temperature, closing firming agent can unseal, release-NCO group,
Described reacted constituent E includes 2,6-xylenols, trifluoroethanol, ethapon, glycol monoethyl ether, ethylene glycol list
Butyl ether, malonate, ethyl acetoacetate, Ketohexamethylene, methyl iso-butyl ketone (MIBK), methyl ethyl ketoxime, tetramethyl-ring diacetyl, dimethyl
Pyrazoles, 2-ethyl-4-methylimidazole, N-methylacetamide, acetanilide, sodium sulfite, pyrosulfurous acid hydrogen sodium, dibutyl
Amine, diisopropylamine, piperidines；
Isocyanate ester compound includes toluene di-isocyanate(TDI) (TDI), '-diphenylmethane diisocyanate (MDI), naphthalene two
Isocyanates (NDI), PPDI (PPDI), dimethyl diphenyl diisocyanate (TODI), polymethylene polyphenyl
Isocyanates (PAPI), hexamethylene diisocyanate (HDI), trimethyl hexamethylene diisocyanate (m-TMXDI), different fluorine
Your ketone diisocyanate (IPDI), 1,4-cyclohexane diisocyanate (CHDI), dicyclohexyl methyl hydride diisocyanate (HMDI),
Isocyanatomethyl (HTDI), cyclohexanedimethyleterephthalate diisocyanate (HXDI), norboneol alkyl dimethyl isocyanide
One or more in acid esters (NB-DI), HDI trimer, methyl ethyl ketoxime.
Further, described coalescents is the compound that hydroxyl and isocyano have reacted catalytic action, including two
One or more in butyl tin dilaurate, triethylenediamine, double (dimethylaminoethyl) ether.
Further, described cosolvent is to promote electrophoresis solution stability and the solvent of above-mentioned classes of compounds intermiscibility,
Including butanone, acetone, ethyl acetate, butyl acetate, toluene, dimethylformamide, oxolane, dioxane, ethylene glycol
In methyl ether, propylene glycol monomethyl ether, glycol methyl ether acetate, propylene glycol methyl ether acetate, isopropanol, propylene glycol and halogenated hydrocarbons one
Plant or multiple.
The using method of a kind of anti-graffiti electrophoretic paint, comprises the following steps:
(1) electrophoretic paint is prepared according to component ratio；
(2) voltage 10～50V, electrophoresis time 10～1000S are set；
(3), during conductive substrates is placed in electrophoretic paint, electrophoresis is started；
(4) rinse with clear water after electrophoresis terminates and remove unnecessary electrophoretic paint；
(5) adopt and coating carried out temperature 130 DEG C～170 DEG C, time a length of 1min～2h drying, thus cross-link film forming.
Beneficial effects of the present invention has:
1, aqueous dispersion Environmental Safety, raw material sources are extensive, and preparation method is simple；
2, system ionic group can be that system provides water solublity, makes system be applicable to electrophoretic deposition process；
3, fluorine-containing silicon-containing monomer can effectively reduce the surface energy of coating, makes coating have preferable antigraffiti properties；
4, the crosslinking side reaction before the use of closing firming agent effectively avoids drying, the cross-linking reaction in film forming procedure
The hydro-oleophobicity of coating and the tack of coating and wearability can be effectively improved, metallic substrates can be played excellent isolation
And protective effect, effectively prevent substrate oxidized or corrosion；
5, coating style is by changing pigment, thus changes system and form to carry out regulation and control.
Accompanying drawing explanation
Accompanying drawing described herein is used for providing a further understanding of the present invention, constitutes the part of the application, not
Constitute inappropriate limitation of the present invention, in the accompanying drawings:
Fig. 1 is the experiment picture of scribble on aluminium sheet；
Fig. 2 is the experiment picture after wiping of scribbling on aluminium sheet；
Fig. 3 is the experiment picture of scribble on iron plate；
Fig. 4 is the experiment picture after wiping of scribbling on iron plate；
Fig. 5 is iron plate antigraffiti properties and the wearability experiment picture of test wear coating surface；
Fig. 6 is that impact experiment is to sheet metal coating tack, antigraffiti properties experiment and experiment effect picture；
Fig. 7 is to sheet metal coating adhesion test experiments effect picture；
Fig. 8 is to covering cated metallic substrates Corrosion Protection test experiments effect picture；
Fig. 9 is to covering cated U.S. dollar coins antioxygenic property test experiments effect picture.
Detailed description of the invention
The present invention is described in detail, at this with illustrative examples and the explanation of the present invention below in conjunction with specific embodiment
It is used for explaining the present invention, but not as a limitation of the invention.
The anti-graffiti electrophoretic paint of proportions of according to the form below 1, in table, the composition of each embodiment remaining proportion is water；
Table 1:
It is respectively adopted the electrophoretic paint of the various embodiments described above preparation, electrophoretic parameters voltage 50V, electrophoresis time 200s are set, electricity
Remove the conductive substrates of coating after swimming, wash unnecessary electrophoretic paint with clear water, coating is carried out temperature 140 DEG C, time a length of 1h
Dry so that it is crosslinking film forming.
The electrophoretic paint of the various embodiments described above the most such as paint film appearance, viscosity, fineness, surface drying and do solid work time
Between, the testing result of the paint film conventional sense project such as pencil hardness all can reach technical specification, be not repeated herein.The following is for
Each embodiment coating characteristic on metal substrate carries out the project detected:
Test one: coating antigraffiti properties
Writing with permanent pen in the coating of each embodiment, person's handwriting all can completely be put on the skin with common paper towel and remove,
As it is shown in figure 1, the aluminium sheet left side covers colourless coating, the right, without seal coat, uses oil pen to write on aluminium sheet,
After common napkin wiping, result is as in figure 2 it is shown, the person's handwriting in coating can be wiped completely；
As it is shown on figure 3, left side iron plate top half covers colourless coating without seal coat, the latter half；On the iron plate of the right
Half part covers rose-red coating without seal coat, the latter half, and two iron plates are all write with oil pen, with common napkin wiping
After, result as shown in Figure 4, shown in left side iron plate and the right iron plate, can wipe completely by the person's handwriting in coating；
Additionally, after coating surface abrasion, coat inside still has preferable antigraffiti properties, as it is shown in figure 5, coating mill
Still there is after damage preferable antigraffiti properties；
Test two: coating resistance to impact
Using QCJ-50 paint film impactor, the jump bit arranging 1kg rises to 50cm so that it is freely falling body falls, to respectively
The impact resistance of the coating of embodiment is tested, result show each embodiment coating all without abnormality, paint film has
Preferably resistance to impact；As shown in Figure 6, in left figure and middle graph, sheet metal the latter half is coated with coating, picture display impact
Experiment is to coating tack and has no adverse effects；Right figure shows that antigraffiti properties is had no adverse effects by impact experiment；
Test three: coating tack
Using ASTM D3359 standard that each embodiment coating carries out adhesive force test, result display paint film has preferably
Tack；As it is shown in fig. 7, the result of ASTM D3359 tack experiment, paint film is without the phenomenon that drops；
Test four: wearability
On the sand paper of 400 mesh, it is real that the coating mill 10cm of each embodiment of heavy burden 100g carries out being calculated as 500 bout frictions
Testing, result display paint film is respectively provided with preferable wearability；As shown in Figure 5, although coating surface is ground off, the inside of coating is still
So there is preferable antigraffiti properties；
Test five: corrosion resistance
In the coating test to metallic substrates corrosion resistance, half is exposed, half covers cated metallic substrates and puts
Enter in the NaCl solution of 10wt%, after observing 12h-120h, cover the corrosion condition of each embodiment coating metal substrate.
As shown in Figure 8, the metal left side is without seal coat, and right-hand member is coated with coating, after immersing 12h in the solution, without being coated with
Substantially there is corrosion phenomena one end of layer, and one end of seal coat is without exception；
After immersing 120h, uncoated one end is covered with corrosion, covers cated one end without exception；
Result display paint film has preferable etch-proof protective effect to metallic substrates；
Test six: high-temperature oxidation
As it is shown in figure 9, left figure is the U.S. dollar coins under room temperature without seal coat；
As shown in middle graph, top half is without seal coat, and the latter half covers cated U.S. dollar coins, through 160 DEG C
After high-temperature baking 1h, compared with left figure, at non-coating, (top) color is substantially deepened, and illustrates to occur oxidation reaction；Coating portion
Divide (bottom) to change without obvious color, illustrate that coating has good high temperature oxidation resisting effect to metal；
As shown at right, the top half toasted is covered cated coin be placed in without seal coat, the latter half
12h in the NaCl solution of 10wt%, is not coated with layer segment and has obvious rust staining, and it is as excellent as before to be coated with layer segment, illustrates that coating has
There is good salt water resistance corrosiveness, can prevent metal from being corroded by chemicals or high temperature, play preferable protective effect.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included in protection scope of the present invention.
Claims (10)
1. an anti-graffiti electrophoretic paint, it is characterised in that include following component:
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 1, it is characterised in that include following component:
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 1, it is characterised in that include following component:
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 1, it is characterised in that described hydroxyl value water-soluble fluorine silicon cation tree
Fat is the polymer being polymerized by solution free radical polymerization or emulsion by vinyl monomer, and described vinyl monomer includes low
Surface energy monomers A and comonomer B.
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 2, it is characterised in that described low-surface-energy monomer A includes vinyl
Fluorochemical monomer and vinyl silicon-containing monomer；
Described vinyl fluorochemical monomer includes perfluoro butyl ethyl propylene acid esters, perfluoro hexyl ethyl propylene acid esters, perfluoro capryl
Ethyl propylene acid esters, perfluoro decyl ethyl propylene acid esters, methyl perfluoro butyl ethyl acrylate, methyl perfluoro hexyl ethyl third
Olefin(e) acid ester, methyl perfluoro octyl group ethyl propylene acid esters, methyl perfluoro decyl ethyl propylene acid esters, trifluoroethyl methacrylate,
Hexafluorobutyl acrylate, Hexafluorobutyl mathacrylate, dodecafluorhe-ptylacrylate, dodecafluoroheptyl methacrylate, methyl
One or more in acrylic acid ten trifluoro monooctyl ester；
Described vinyl silicon-containing monomer includes vinyltrimethoxy silane, VTES, vinyl three isopropyl
One or more in TMOS.
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 3, it is characterised in that described comonomer B includes acrylic acid diformazan
Amino ethyl ester, dimethylaminoethyl methacrylate, acrylic acid methyl ester., methyl methacrylate, butyl acrylate, metering system
Acid butyl ester, octadecyl acrylate, octadecyl methacrylate, 2-(Acryloyloxy)ethanol, hydroxyethyl methylacrylate, acrylic acid hydroxypropyl
One or more in ester, Hydroxypropyl methacrylate, isobornyl acrylate, styrene.
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 1, it is characterised in that described closing firming agent by reacted constituent E and
Isocyanate ester compound reacts and obtains, and when using electrophoretic paint, after reaching to unseal temperature, closing firming agent can unseal, and release-
NCO group,
Described reacted constituent E includes 2,6-xylenols, trifluoroethanol, ethapon, glycol monoethyl ether, ethylene glycol only son
Ether, malonate, ethyl acetoacetate, Ketohexamethylene, methyl iso-butyl ketone (MIBK), methyl ethyl ketoxime, tetramethyl-ring diacetyl, dimethyl pyrazole
Azoles, 2-ethyl-4-methylimidazole, N-methylacetamide, acetanilide, sodium sulfite, pyrosulfurous acid hydrogen sodium, dibutylamine,
Diisopropylamine, piperidines；
Isocyanate ester compound includes toluene di-isocyanate(TDI) (TDI), '-diphenylmethane diisocyanate (MDI), naphthalene two isocyanide
Acid esters (NDI), PPDI (PPDI), dimethyl diphenyl diisocyanate (TODI), polymethylene polyphenyl isocyanide
Acid esters (PAPI), hexamethylene diisocyanate (HDI), trimethyl hexamethylene diisocyanate (m-TMXDI), isophorone
Diisocyanate (IPDI), 1,4-cyclohexane diisocyanate (CHDI), dicyclohexyl methyl hydride diisocyanate (HMDI), methyl
Cyclohexyl isocyanate (HTDI), cyclohexanedimethyleterephthalate diisocyanate (HXDI), norboneol alkyl dimethyl isocyanates
(NB-DI), one or more in HDI trimer, methyl ethyl ketoxime.
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 1, it is characterised in that described coalescents is to hydroxyl and Carbimide.
Root has reacted the compound of catalytic action, including dibutyltin dilaurate, triethylenediamine, double (dimethylaminoethyls)
One or more in ether.
A kind of anti-graffiti electrophoretic paint the most as claimed in claim 1, it is characterised in that described cosolvent is stable for promoting electrophoresis solution
Property and the solvent of above-mentioned classes of compounds intermiscibility, including butanone, acetone, ethyl acetate, butyl acetate, toluene, dimethyl
Methanamide, oxolane, dioxane, ethylene glycol monomethyl ether, propylene glycol monomethyl ether, glycol methyl ether acetate, propylene glycol monomethyl ether vinegar
One or more in acid esters, isopropanol, propylene glycol and halogenated hydrocarbons.
10. the using method of an anti-graffiti electrophoretic paint, it is characterised in that comprise the following steps:
(1) electrophoretic paint is prepared according to component ratio；
(2) voltage 10～50V, electrophoresis time 10～1000S are set；
(3), during conductive substrates is placed in electrophoretic paint, electrophoresis is started；
(4) rinse with clear water after electrophoresis terminates and remove unnecessary electrophoretic paint；
(5) adopt and coating carried out temperature 130 DEG C～170 DEG C, time a length of 1min～2h drying, thus cross-link film forming.
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| CN201610489771.0A CN106147567B (en) | 2016-06-24 | 2016-06-24 | A kind of anti-graffiti electrophoretic paint and its application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610489771.0A CN106147567B (en) | 2016-06-24 | 2016-06-24 | A kind of anti-graffiti electrophoretic paint and its application method |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN101993576A (en) * | 2010-11-04 | 2011-03-30 | 安吉万国涂料有限公司 | Resin emulsion for hydrophobic cathode electrophoretic coating as well as preparation method and application thereof |
| CN103333596A (en) * | 2013-06-24 | 2013-10-02 | 浩力森涂料（上海）有限公司 | Self-cleaning fluorosilicone-modified acrylic acid cathode electrophoresis paint and preparation method thereof |
| CN103601838A (en) * | 2013-11-13 | 2014-02-26 | 深圳市志邦科技有限公司 | Method for preparing special fluorocarbon resin for fluorinated electrophoretic paint |
| CN105482604A (en) * | 2015-12-26 | 2016-04-13 | 杭州吉华高分子材料股份有限公司 | Water-based anti-doodling paint and preparation method thereof |
-
2016
- 2016-06-24 CN CN201610489771.0A patent/CN106147567B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN101993576A (en) * | 2010-11-04 | 2011-03-30 | 安吉万国涂料有限公司 | Resin emulsion for hydrophobic cathode electrophoretic coating as well as preparation method and application thereof |
| CN103333596A (en) * | 2013-06-24 | 2013-10-02 | 浩力森涂料（上海）有限公司 | Self-cleaning fluorosilicone-modified acrylic acid cathode electrophoresis paint and preparation method thereof |
| CN103601838A (en) * | 2013-11-13 | 2014-02-26 | 深圳市志邦科技有限公司 | Method for preparing special fluorocarbon resin for fluorinated electrophoretic paint |
| CN105482604A (en) * | 2015-12-26 | 2016-04-13 | 杭州吉华高分子材料股份有限公司 | Water-based anti-doodling paint and preparation method thereof |
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