CN106147560B - A kind of working life adjustable wind-driven power generation blade coating and preparation method thereof - Google Patents

A kind of working life adjustable wind-driven power generation blade coating and preparation method thereof Download PDF

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CN106147560B
CN106147560B CN201610647394.9A CN201610647394A CN106147560B CN 106147560 B CN106147560 B CN 106147560B CN 201610647394 A CN201610647394 A CN 201610647394A CN 106147560 B CN106147560 B CN 106147560B
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parts
agent
working life
power generation
component
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CN106147560A (en
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李陈郭
方大庆
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XIAMEN SHUANGRUI SHIPBUILDING PAINT CO Ltd
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XIAMEN SHUANGRUI SHIPBUILDING PAINT CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/02Polyureas
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to technical field of chemical paint, particularly a kind of working life adjustable wind-driven power generation blade coating and preparation method thereof.The coating is made up of first, the component of second two, and the raw material that wherein first component is matched somebody with somebody by following parts by weight is made:20~40 parts of polyaspartic ester resin, 3~6.5 parts of LNBR, 1.5~4 parts of deicer, 2~12 parts of reactive diluent, 0.4~2 part of anti-wear agent, 34.8~74.9 parts of auxiliary agent;The raw material that second component is matched somebody with somebody by following parts by weight is made:93~99 parts of isocyanate curing agent, 1~7 part of organic solvent.Working life adjustable wind-driven power generation blade coating working life provided by the invention is adjustable between 0.5~2.5 hour, with lower glossiness, solid content is up to more than 80%, unify bottom surface, can single track construction, pliability, impact resistance, rub resistance, have excellent weather resistance, short construction period, meet the long-lasting protection demand of wind electricity blade and prepared paint VOC development trend.

Description

A kind of working life adjustable wind-driven power generation blade coating and preparation method thereof
Technical field
The present embodiments relate to the coating industry in chemical industrial field, more particularly to a kind of working life adjustable wind-powered electricity generation Blade coating and preparation method thereof.
Background technology
Wind energy is a kind of energy of green non-pollution, as traditional fossil resources reserves gradually reduce and its shadow to environment Sound increasingly increases, the utilization Fast Growth of wind energy.Wind electricity blade is one of key core part of wind power generation plant, existing There are most of blades under technology to be made using epoxy glass fiber composite, for the blade of MW class close to 50 meters, bigger can Reach 80 meters, maintenance cost is high, and the area generally geographical position of wind energy enrichment is remote, has inconvenient traffic, therefore blade coating will Overlength protection phase effect is sought, blade can be protected to face the abrasion of dust storm rainwater, ultraviolet, high/low temperature alternation, damp and hot, salt in running The destructive factors such as mist, torsional deformation.Linear velocity is very high when wind electricity blade is run, and vane tip is up to 100Km/h, in wind sand environment In easily wear.
Existing blade coating is most commonly used that the supporting polyurethane finish of solvent borne polyurethane priming paint, and this kind of coating is often consolidated Content is relatively low, and the organic solvent used is more, and not only VOC imposes starting point close to the even more than coating consumption tax, it is also necessary to more Road application can be only achieved required film thickness, dry slow, long construction period.
Polyaspartic Ester-Based Coatings are to plant a new material, not only weather-proof wear-resisting wet-heat resisting salt spray resistance, and making Solid content is high, and the coating of bottom surface unification, single track constructs thickness up to 300 μm, meets application demand and the trend of environmental protection development.
Coating is made there is also some difficult points in presently commercially available polyaspartic ester, and it is inclined with isocyanate curing agent reaction It hurry up, for conventional high-tension airless spraying and paint spraying, working life is short, and this can influence wetting attachment of the coating to ground.
Blade coating requires that surface gloss is as low as possible, prevents from surprisingly occurring caused by light pollution and light pollution.And by Viscosity is easily improved rapidly because of fast reaction in Polyaspartic Ester-Based Coatings, therefore is difficult to add a large amount of flatting silicas low to obtain Gloss coating, unless additional a large amount of solvents reduce viscosity.
CN 105073818A disclose a kind of low-luster high solids content Polyaspartic Ester-Based Coatings, although in formula Delustering agent dosage is up to 12.5 parts, but most of glossiness of coating is still between 30~40, minimum also only to 25.
The characteristics of aspartate resin fast reaction, causes such coating applicable period often very short, and working life is typically small In half an hour, it is unfavorable for actual application.CN 103834282A disclose a kind of Polyaspartic Ester-Based Coatings, and its working life is most Height is no more than 25 minutes.Although carried in a kind of polyaspartic ester wind-driven power generation blade coating that patent CN 102391771A are announced To " more than 0.5 hour working life ", but working life is not made and being illustrated.Polyaspartic ester compared with polyurethane, Molecule chain rigidity is bigger, for a long time from the point of view of its pliability, impact resistance have a certain degree of decline with the raising of curing degree.
The content of the invention
To solve problem above, the present invention provides a kind of working life adjustable wind-driven power generation blade coating and preparation method thereof.
The present invention adopts the following technical scheme that:
A kind of working life adjustable wind-driven power generation blade coating, including first component and second component, wherein first component is mainly by following The raw material of weight is made:
Second component is mainly made by the raw material of following weight:
93~99 parts of isocyanate curing agent
1~7 part of organic solvent.
Further, first component is made up of the raw material below according to parts by weight:23~37 parts of polyaspartic ester resin, 4~6 parts of LNBR, 2~3.5 parts of deicer, 7~11 parts of reactive diluent, 0.5~1.5 part of anti-wear agent, thixotropic agent 0.3~0.5 part, 25~30 parts of color stuffing, 5~10 parts of flatting silica, 8~12 parts of organic solvent, 3~6 parts of auxiliary agent;Second component by with Under according to parts by weight raw material form:94~98 parts of isocyanate curing agent, 2~6 parts of organic solvent.
Further, formed below the auxiliary agent according to the raw material of parts by weight, including 0.5~1.4 part of light stabilizer, it is ultraviolet 0.2~1 part of light absorbers, 0.8~2.4 part of wetting dispersing agent, 0.2~1 part of defoamer, 0.4~1.5 part of levelling agent, coupling agent 0.5~2 part;
Wherein, the ultra-violet absorber is benzotriazole UV absorbers, and light stabilizer is hindered amines light Stabilizer, the two ratio are (0.7~2):(0.5~2), it is preferably in a proportion of (1~1.4):(0.6~1.2);
Described defoamer is organic silicon defoamer;
Described wetting dispersing agent is the polyesters compound with acidic-group, its solids content >=50%, and acid number is 50mgKOH/g~60mgKOH/g;
Described levelling agent is fluorine-carbon macromolecule compounds levelling agent, including and is not limited to what BYK companies provided The EFKA-3600 that BYK306, EFKA company provide;
Described coupling agent is silane coupler;
Described color stuffing is R706 rutile type titanium whites, silica flour, palladium powder, the combination of bright resistance to powder;It is described Color stuffing between mutually act synergistically, contribute to the weatherability of coating, improve wind electricity blade running life, can meet to pass through resistance to Ultraviolet ageing 3000h is tested.
Further, the reactive diluent is higher boiling reactive diluent, selected from vinylene carbonate ester derivative, its Chemical structural formula is expressed as below:
Further, the flatting silica is the aerosil class flatting silica handled by organic matter, and oil absorption is 200g/100g~260g/100g.
Further, described LNBR is terminal hydroxy group or inertia, hydroxy radical content 0~4%, mean molecule quantity 2500~4000, viscosity (30 DEG C) 40~60Pas.
Further, the isocyanate curing agent is selected from and is not limited to hexamethylene diisocyanate trimer, different Fo Er Ketone diisocyanate trimer, at least two mixing in dicyclohexyl methyl hydride diisocyanate tripolymer.
Further, the organic solvent is urethane level organic solvent, selected from ethylene acetate, butyl acetate, and third At least one of glycol methyl ether acetate, dimethylbenzene.
Further, described deicer is non-isocyanate type deicer, and boiling point is less than 60 DEG C;The anti-wear agent is height Molecule wax assistant, compounded selected from least one of ptfe micropowder wax, ultra-high molecular weight polyethylene micro mist is not limited to.
The preparation method of working life adjustable wind-driven power generation blade coating provided by the invention, wherein:
The preparation method of first component is:
Polyaspartic ester resin, auxiliary agent, LNBR, reactive diluent are mixed evenly;
Under the stirring less than 600rpm rotating speeds, thixotropic agent, color stuffing are added, it is dispersed to and grinds 50 points in uniform state Clock~100 minute;
Organic solvent, flatting silica, deicer are added, it is scattered 10 minutes~15 minutes with the rotating speed less than 600rpm, in equal Even state, it is filtrated to get first component.
The preparation method of second component is:
Isocyanate curing agent and organic solvent are mixed evenly, obtain component B.
Working life adjustable wind-driven power generation blade coating provided by the invention employ higher boiling reactive diluent extend it is applicable Phase, reactive diluent can change into the amino of part polyaspartic ester resin hydroxyl, reduce system reaction rate, so as to The problem of overcoming polyaspartic ester and too fast isocyanates reaction rate, pass through polyaspartic ester and higher boiling activity The use ratio of diluent, working life can be controlled at 0.5 hour to 2.5 hours as needed.Higher boiling diluent volatile quantity Seldom, the part of reaction is finally had neither part nor lot in using as the plasticizer of paint film, improves paint film flexibility, impact resistance.
The flatting silica that working life adjustable wind-driven power generation blade coating provided by the invention uses is aerosil class delustring Powder, oil absorption is lower than normal dull powder after being handled by organic matter, alleviates thickening effect, without for obtain low-luster and Additional excessive organic solvent diluting coating.Coating low-luster is reduced, while reducing light pollution, also maintains the Gao Gu of coating Content.Due to having used less organic solvent, VOC discharge is substantially reduced.
The polyaspartic ester resin viscosity that working life adjustable wind-driven power generation blade coating provided by the invention uses is than poly- The resin viscosity of urethane is low, not only weather-proof, wear-resisting, wet-heat resisting, salt spray resistance, and can make solid content height, the painting of bottom surface unification Material, single track constructs thickness up to 300 μm, suitable for preparing the blade coating of large arch dam.Meanwhile employ low-boiling point liquid water removal Agent, higher boiling reactive diluent, the organic assembling of LNBR, further collaboration improves the viscosity of coating, so as to ensure Good application property.
Working life adjustable wind-driven power generation blade coating provided by the invention employs LNBR and poly-aspartic-acid The collaboration of ester resin improves paint film flexibility, tackles the torsional deformation brought in wind electricity blade running.
Working life adjustable wind-driven power generation blade coating provided by the invention adds the macromolecule wax with self-lubricating function and helped Agent, improve the wearability of paint film.
The invention provides working life adjustable wind-driven power generation blade coating, working life is adjustable between 0.5~2.5 hour, tool There is relatively low glossiness, solid content can reach more than 80%, meet spraying application needs, unification single track construction in bottom surface is up to 300 μm. This coating is used for the long-lasting protection of wind electricity blade, greatly reduces the VOC emission of job site, good pliability, shock resistance Property, weatherability and wearability improve wind electricity blade running life, can meet to test by ultraviolet aging resistance 3000h, so as to Reduce maintenance and repair cost.
Embodiment
To make the purpose of the embodiment of the present invention, technical scheme and advantage are clearer, below will be in the embodiment of the present invention Technical scheme carry out clear, be fully described by, it is clear that described embodiment is part of the embodiment of the present invention, rather than Whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creative work premise Lower obtained every other embodiment, belongs to the scope of protection of the invention.
The embodiment of the present invention is shown in Table 1:
Table 1
First and second components of embodiment 1 press first:Second=5.2:1 (mass ratio) is used cooperatively;
The preparation method of first component is:By 23 parts of polyaspartic ester resin, 1.2 parts of light stabilizer, ultraviolet radiation absorption 0.8 part of agent, 2.2 parts of wetting dispersing agent, 0.3 part of defoamer, 1.4 parts of levelling agent, 1.8 parts of coupling agent, 1.8 parts of anti-wear agent, liquid 6.5 parts of nitrile rubber, 7 parts of reactive diluent, is mixed evenly;Under the stirring less than 600rpm rotating speeds, thixotropic agent is added 0.3 part, 30 parts of color stuffing, it is in uniform state to be dispersed to it, is ground 50 minutes~100 minutes;Add 16 parts of organic solvent, delustring 6 parts of powder, 1.7 parts of deicer is scattered 10 minutes~15 minutes with the rotating speed less than 600rpm, in uniform state, is filtrated to get into Product;
The preparation method of second component is:By 94 parts of isocyanate curing agent, 6 parts of organic solvent is mixed evenly, obtained Finished product.
First and second components of embodiment 2 press first:Second=3.6:1 (mass ratio) is used cooperatively;
The preparation method of first component is:By 30 parts of polyaspartic ester resin, 0.9 part of light stabilizer, ultraviolet radiation absorption 0.4 part of agent, 1.5 parts of wetting dispersing agent, 0.2 part of defoamer, 0.5 part of levelling agent, 0.9 part of coupling agent, 0.7 part of anti-wear agent, liquid 3 parts of nitrile rubber, 9 parts of reactive diluent, is mixed evenly;Under the stirring less than 600rpm rotating speeds, thixotropic agent 0.4 is added Part, 33 parts of color stuffing, it is in uniform state to be dispersed to it, is ground 50 minutes~100 minutes;Add 9.6 parts of organic solvent, flatting silica 7 parts, 2.9 parts of deicer is scattered 10 minutes~15 minutes with the rotating speed less than 600rpm, in uniform state, is filtrated to get finished product;
The preparation method of second component is:By 98 parts of isocyanate curing agent, 2 parts of organic solvent is mixed evenly, obtained Finished product.
First and second components of embodiment 3 press first:Second=2.9:1 (mass ratio) is used cooperatively;
The preparation method of first component is:By 37 parts of polyaspartic ester resin, 3 parts of light stabilizer, ultra-violet absorber 0.3 part, 0.9 part of wetting dispersing agent, 0.4 part of defoamer, 0.7 part of levelling agent, 1.3 parts of coupling agent, 0.4 part of anti-wear agent, liquid fourth 3 parts of nitrile rubber, 11 parts of reactive diluent, is mixed evenly;Under the stirring less than 600rpm rotating speeds, thixotropic agent 0.3 is added Part, 21 parts of color stuffing, it is in uniform state to be dispersed to it, is ground 50 minutes~100 minutes;Add 10.6 parts of organic solvent, delustring 11 parts of powder, 1.6 parts of deicer is scattered 10 minutes~15 minutes with the rotating speed less than 600rpm, in uniform state, is filtrated to get into Product;
The preparation method of second component is:By 98 parts of isocyanate curing agent, 2 parts of organic solvent is mixed evenly, obtained Finished product.
Applicant is to the working life adjustable wind-driven power generation blade coating obtained by above-mentioned 3 embodiments and existing wind-powered electricity generation Blade coating contrast sample A and contrast sample B, are tested, test comparison result is as shown in table 2 according to testing standard:
Table 2
Contrast existing product, working life adjustable wind electricity blade provided by the invention are can be seen that from the test result of table 2 The working life of coating is significantly improved;Glossiness (60 °) is lower than the glossiness of existing wind-driven power generation blade coating;Solid content reaches To more than 80%, better than contrast sample;Can be by ultraviolet aging resistance 3000h test, and control sample does not pass through then.
Finally it should be noted that:Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations;To the greatest extent The present invention is described in detail with reference to foregoing embodiments for pipe, it will be understood by those within the art that:Its according to The technical scheme described in foregoing embodiments can so be modified, either which part or all technical characteristic are entered Row equivalent substitution;And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology The scope of scheme.

Claims (9)

1. a kind of working life adjustable wind-driven power generation blade coating, it is characterised in that including first component and second component, wherein first component master To be made by the raw material of following weight:
Second component is mainly made by the raw material of following weight:
93~99 parts of isocyanate curing agent
1~7 part of organic solvent;
The reactive diluent is higher boiling reactive diluent, selected from vinylene carbonate ester derivative;
The auxiliary agent is made according to the raw material of following weight, including 0.5~1.4 part of light stabilizer, ultra-violet absorber 0.2~1 part, 0.8~2.4 part of wetting dispersing agent, 0.2~1 part of defoamer, 0.4~1.5 part of levelling agent, 0.5~2 part of coupling agent.
2. adjustable wind-driven power generation blade coating of a kind of working life according to claim 1, it is characterised in that first component is by following Formed according to the raw material of parts by weight:23~37 parts of polyaspartic ester resin, 4~6 parts of LNBR, deicer 2~ 3.5 parts, 7~11 parts of reactive diluent, 0.5~1.5 part of anti-wear agent, 0.3~0.5 part of thixotropic agent, 25~30 parts of color stuffing, delustring 5~10 parts of powder, 8~12 parts of organic solvent, 3~6 parts of auxiliary agent;Second component is made up of the raw material below according to parts by weight:Isocyanic acid 94~98 parts of ester curing agent, 2~6 parts of organic solvent.
A kind of 3. adjustable wind-driven power generation blade coating of working life according to claim 1 or 2, it is characterised in that:
The ultra-violet absorber is benzotriazole UV absorbers;
The light stabilizer is hindered amine light stabilizer;
Described defoamer is organic silicon defoamer;
Described wetting dispersing agent is the polyesters compound with acidic-group, its solids content >=50%, and acid number is 50mgKOH/g~60mgKOH/g;
Described levelling agent is fluorine-carbon macromolecule compounds levelling agent;
Described coupling agent is silane coupler;
Described color stuffing is R706 rutile type titanium whites, silica flour, the combination of palladium powder and Ming Nai powder.
4. according to the adjustable wind-driven power generation blade coating of a kind of working life described in claim 1 or 2, it is characterised in that:It is described to disappear Light powder is aerosil class flatting silica, and oil absorption is 200g/100g~260g/100g.
5. according to the adjustable wind-driven power generation blade coating of a kind of working life described in claim 1 or 2, it is characterised in that:Described LNBR is the LNBR with terminal hydroxy group, and hydroxy radical content 0~4%, hydroxy radical content is not 0, mean molecule It is 40~60Pas to measure 2500~4000,30 DEG C of viscositys.
6. according to the adjustable wind-driven power generation blade coating of a kind of working life described in claim 1 or 2, it is characterised in that:It is described different Cyanate curing agent is selected from hexamethylene diisocyanate trimer, isophorone diisocyanate trimer and dicyclohexyl first At least two mixing in alkane diisocyanate trimer.
7. according to the adjustable wind-driven power generation blade coating of a kind of working life described in claim 1 or 2, it is characterised in that:It is described to have Solvent is urethane level organic solvent, selected from ethylene acetate, butyl acetate, and propylene glycol methyl ether acetate, in dimethylbenzene At least one.
8. according to the adjustable wind-driven power generation blade coating of a kind of working life described in claim 1 or 2, it is characterised in that:Described Deicer is non-isocyanate type deicer, and boiling point is less than 60 DEG C;The anti-wear agent is macromolecule wax auxiliary agent, selected from polytetrafluoroethyl-ne At least one of alkene micro mist wax and ultra-high molecular weight polyethylene micro mist.
A kind of 9. preparation method of working life as claimed in claim 1 adjustable wind-driven power generation blade coating, it is characterised in that:
The preparation method of first component:Polyaspartic ester resin, auxiliary agent, LNBR, reactive diluent are mixed and stirred Mix uniformly;Under the stirring less than 600rpm rotating speeds, thixotropic agent, color stuffing are added, it is dispersed to and grinds 50 points in uniform state Clock~100 minute;Organic solvent, flatting silica, deicer are added, it is scattered 10 minutes~15 minutes with the rotating speed less than 600rpm, In uniform state, filter and package to obtain first component;
The preparation method of second component:Isocyanate curing agent and organic solvent are mixed evenly, in uniform state, packed Component B.
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