CN106147257A - A kind of environment-friendly type road-surface heating type sealant material and preparation method thereof and application - Google Patents

A kind of environment-friendly type road-surface heating type sealant material and preparation method thereof and application Download PDF

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Publication number
CN106147257A
CN106147257A CN201610517047.4A CN201610517047A CN106147257A CN 106147257 A CN106147257 A CN 106147257A CN 201610517047 A CN201610517047 A CN 201610517047A CN 106147257 A CN106147257 A CN 106147257A
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China
Prior art keywords
environment
surface heating
road
sealant material
heating type
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Pending
Application number
CN201610517047.4A
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Chinese (zh)
Inventor
崔若宾
孔超
李颖
朱洪志
刘清敬
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Shandong High Speed Material Storage And Transportation Co Ltd
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Shandong High Speed Material Storage And Transportation Co Ltd
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Priority to CN201610517047.4A priority Critical patent/CN106147257A/en
Publication of CN106147257A publication Critical patent/CN106147257A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/18Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
    • E01C7/187Repairing bituminous covers, e.g. regeneration of the covering material in situ, application of a new bituminous topping
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)
  • Road Repair (AREA)

Abstract

The present invention relates to the material of a kind of pavement crack repair, specifically a kind of environment-friendly type road-surface heating type sealant material, it is characterized in that, use and include that the raw material of following weight portion is made: asphalt 50 70, SBS modifier 7 10, SBR modifying agent 58, rubber powder of waste tire 10 30, natural rock asphalt 38, phase solvent 5 20, polyester fiber 14, lignin fibre 25, cross-linking agent 0.1 0.5, inserts 10 30.The present invention is for common road, highway, airfield runway crack and the sealing reparation of seam, it is possible to realizes at high temperature fluid sealant and merges with bituminous paving infiltration, has sufficient elasticity, the most excessive or viscous tire;Produce high cohesive force after cooling, and rely on stronger elasticity, with crack harmomegathus, elastic deformation occurs.

Description

A kind of environment-friendly type road-surface heating type sealant material and preparation method thereof and application
Technical field
The present invention relates to the material of a kind of pavement crack repair, specifically a kind of environment-friendly type road-surface heating type sealant material And preparation method and application.
Background technology
At present, highway in China construction is also continuing expansion construction scale through development for many years, especially highway.So And, perplex Domestic & Overseas Asphalt Pavement problem of Cracking and be well solved the most not yet.The existence in gap can cause road The local failures such as internal frost heave, the corrosion of mineral aggregate and peeling, have a strong impact on stationarity and the safety of driving the most at last, and The service life on road surface can be substantially reduced.The fluid sealant wide material sources of current domestic employing, quality is uneven, and using effect is not Ideal to the greatest extent, because being limited by characteristics such as the low temperature cold fragility of gap-grouting material and hot mastications, the crack after repairing can be with gas The change of temperature is ftractureed again through the surface layer harmomegathus of 1 year.Particularly cryogenic property is the most poor, and a lot of fluid sealant one is to winter I.e. with sides of fracture tear, lose waterproof effect, have become as restriction filling cut of asphaltum road surface technology development one crucial because of Element.The existence of this problem, has increased the weight of workload and material cost that maintenance of surface is safeguarded.
The Chinese patent of Publication No. CN105199666A, discloses a kind of road that can be applicable to various material road surface and splits The Road sealant that seam is repaired produces and construction technology;Main is the matrix pitch of 29% by mass percent, 15% thin Rubber powder, the fossil meal of 45%, the SBS modified pitch of 0.4%, the butadiene-styrene rubber rubber powder of 0.4%, the activating agent of 0.1%, The viscosifier of 0.1% and the diesel oil composition of 10%;For Colophonium, Concrete Highway, highway, high-grade highway, city public affairs The cementation of fissures of the bituminous paving such as road, airfield runway is repaired and the joint seal reparation of cement concrete pavement.
Summary of the invention
It is contemplated that according to different regions and different weather conditions and pavement crack feature, want in particular according to environmental protection Ask, select suitable fluid sealant as the material of pavement crack repair.
Merge with bituminous paving infiltration it addition, the present invention realizes at high temperature fluid sealant, there is sufficient elasticity, the most excessive Or viscous tire;Produce high cohesive force after cooling, and rely on stronger elasticity, with crack harmomegathus, elastic deformation occurs, particularly exist Remain its sealing function winter.
The present invention specifically the technical scheme is that
A kind of environment-friendly type road-surface heating type sealant material, is characterized in that, uses and includes that the raw material of following weight portion is made:
Wherein, described petroleum asphalt penetration is 100-200, and described SBS modifier is s-B-S Block copolymer, described SBR modifying agent is polystyrenebutadienes copolymer, and described phase solvent (compatilizer) is naphthenic rubber Oil, described inserts is sodium bentonite.
In the present invention, the polyester fiber used its be mainly composed of polyethylene terephthalate, described lignin Fiber preferred natural timber organic fiber, the Colophonium that described natural rock asphalt uses marque to be Qing Chuan NES.
Conventional cross-linking agent in state of the art selected by the cross-linking agent of the present invention.
The preparation method of a kind of environment-friendly type road-surface heating type sealant material, is characterized in that, comprise the steps:
1) according to proportioning of the present invention, bi tumenf orr oad is preheated to 180-200 DEG C and adds material-compound tank, continuously stirred state Lower addition SBS modifier, the full and uniform mixing of SBR modifying agent, swelling 10 minutes;
2) shear grinding 2-3 time through colloid mill, make modified grain fineness reach below 5 μm, be delivered to grow tank and add Cross-linking agent, keeps 180-200 DEG C of circulation, stirring to grow 3-5h, forms the high temperature premix material with stabilising system;
3) premix material is delivered to premixing tank, in premixing tank, is sequentially added into waste tire rubber under continuously stirred state Powder, natural rock asphalt, phase solvent, polyester fiber, lignin fibre are warming up to and keep 180-200 DEG C of stirring to grow 1-2h to mixed After closing uniformly, add sodium bentonite under continuously stirred state and be warming up to and keep 180-200 DEG C of stirring to grow 1-2h to mixed Close uniformly;
4) it is delivered to hot mixture in premixing tank in low temperature kneader again be cooled to and keep 150-170 DEG C to mediate 1- 2h to after fully reaction, is cooled to 130-140 DEG C of extruded machine extrusion and weighs vanning molding, make environment-friendly type road-surface heating type close Adhesive material.
The application of a kind of environment-friendly type road-surface heating type sealant material, is characterized in that, described sealant material is for common The sealing reparation of highway, highway, airfield runway crack and seam.
Compared with prior art, the invention have the advantage that
1) due to the naphthenic rubber oil added, it is a kind of material that can meet exported product environmental requirement, substitutes existing Aromatic naphtha in product, environment protection significance is very big;
2), during NES natural rock asphalt in Qing Chuan results from special rock fracture, suffered pressure and temperature conditions are than it His bitumen is high, therefore extent of polymerization is the highest, and molecular weight is very big, and softening point is higher;
3) polyester fiber and the Colophonium being both oil product have extremely strong adsorptivity, have in media as well good adsorptivity and Dispersibility;Lignin fibre has good toughness, dispersibility and chemical stability, has the most outstanding thickening cracking resistance;
4) sodium bentonite Heat stability is good, has stronger plasticity, bloating tendency, caking property, adsorptivity, catalytic, touches Degeneration, suspension and cation commutativity etc..
5) present invention has cohesive, low temperature flexibility, heat stability, anti-embeddability and the resistance to ag(e)ing of excellence, can be extensive It is applied to crack and the sealing reparations of seam such as common road, highway, airfield runway.
Detailed description of the invention
Embodiment: unit: weight portion
1) formula:
2) preparation method:
1) according to the formula any one of embodiment 1-3, bi tumenf orr oad is preheated to 180-200 DEG C and adds dispensing Tank, addition SBS modifier, the full and uniform mixing of SBR modifying agent under continuously stirred state, swelling 10 minutes;
2) shear grinding 2-3 time through colloid mill, make modified grain fineness reach below 5 μm, be delivered to grow tank and add Cross-linking agent, keeps 180-200 DEG C of circulation, stirring to grow 3-5h, forms the high temperature premix material with stabilising system;
3) premix material is delivered to premixing tank, in premixing tank, is sequentially added into waste tire rubber under continuously stirred state Powder, natural rock asphalt, phase solvent, polyester fiber, lignin fibre are warming up to and keep 180-200 DEG C of stirring to grow 1-2h to mixed After closing uniformly, add sodium bentonite under continuously stirred state and be warming up to and keep 180-200 DEG C of stirring to grow 1-2h to mixed Close uniformly;
4) it is delivered to hot mixture in premixing tank in low temperature kneader again be cooled to and keep 150-170 DEG C to mediate 1- 2h to after fully reaction, is cooled to 130-140 DEG C of extruded machine extrusion and weighs vanning molding, make environment-friendly type road-surface heating type close Adhesive material.

Claims (4)

1. an environment-friendly type road-surface heating type sealant material, is characterized in that, uses and includes that the raw material of following weight portion is made:
Environment-friendly type road-surface heating type sealant material the most according to claim 1, is characterized in that, described asphalt pin enters Degree is 100-200, and described SBS modifier is styrene butadiene styrene block copolymer (SBS), and described SBR modifying agent is polyphenyl Ethylene butadiene copolymers, described phase solvent is naphthenic rubber oil, and described inserts is sodium bentonite.
3. a preparation method for environment-friendly type road-surface heating type sealant material, is characterized in that, comprise the steps:
1) according to the proportioning of claim 1, bi tumenf orr oad is preheated to 180-200 DEG C and adds material-compound tank, continuously stirred shape Addition SBS modifier, the full and uniform mixing of SBR modifying agent under state, swelling 10 minutes;
2) shear grinding 2-3 time through colloid mill, make modified grain fineness reach below 5 μm, be delivered to grow tank and add crosslinking Agent, keeps 180-200 DEG C of circulation, stirring to grow 3-5h, forms the high temperature premix material with stabilising system;
3) premix material is delivered to premixing tank, premixing tank is sequentially added under continuously stirred state rubber powder of waste tire, sky So kir, phase solvent, polyester fiber, lignin fibre are warming up to and keep 180-200 DEG C of stirring to grow 1-2h to mixing all After even, add sodium bentonite under continuously stirred state and be warming up to and keep 180-200 DEG C of stirring to grow 1-2h to mixing all Even;
4) it is delivered to hot mixture in premixing tank in low temperature kneader again be cooled to and keep 150-170 DEG C to mediate 1-2h extremely Fully after reaction, it is cooled to 130-140 DEG C of extruded machine and extrudes vanning molding of weighing, make environment-friendly type road-surface heating type fluid sealant Material.
4. the application of the environment-friendly type road-surface heating type sealant material of claim 1, is characterized in that, described sealant material is used for The sealing reparation of common road, highway, airfield runway crack and seam.
CN201610517047.4A 2016-07-01 2016-07-01 A kind of environment-friendly type road-surface heating type sealant material and preparation method thereof and application Pending CN106147257A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883626A (en) * 2017-03-29 2017-06-23 合肥天沃能源科技有限公司 A kind of modified asphalt for road and preparation method
CN106967382A (en) * 2017-03-30 2017-07-21 华北水利水电大学 Environment-friendly type road-surface heating type sealant material and preparation method and application
CN107245321A (en) * 2017-03-30 2017-10-13 北京中天路业科技有限公司 Pavement crack fluid sealant and preparation method thereof
CN108795066A (en) * 2017-04-27 2018-11-13 金华方金雨伞防水科技有限公司 A kind of antifatigue waterproof material and preparation method thereof
CN108948755A (en) * 2017-05-18 2018-12-07 济宁明升新材料有限公司 It is a kind of improve Pavement Performance lignin-base phenolic resin adhesive and its application
CN109135308A (en) * 2018-08-09 2019-01-04 成都道盛路通新材料有限公司 A kind of modified pitch, asphalt modifier and preparation method thereof
CN109251538A (en) * 2017-07-13 2019-01-22 大连韵海贸易有限公司 A kind of modulation formula of bituminous pavement casting glue
CN109439278A (en) * 2018-11-02 2019-03-08 李廷刚 Low cohesive force bituminous pavement hot type sealant and preparation method thereof
CN111171395A (en) * 2020-02-17 2020-05-19 褚乃博 Composite material made of recycled rubber, forming method and application thereof
CN114774079A (en) * 2022-04-14 2022-07-22 鄂尔多斯市路泰公路工程有限责任公司 High-viscosity high-strength pavement heating type sealant and preparation method thereof
CN115286853A (en) * 2022-08-31 2022-11-04 侯马市怡达汽车销售有限公司 Welding fusion strip for highway cracks and welding fusion crack pouring process
WO2023199899A1 (en) * 2022-04-11 2023-10-19 花王株式会社 Asphalt composition

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883626A (en) * 2017-03-29 2017-06-23 合肥天沃能源科技有限公司 A kind of modified asphalt for road and preparation method
CN106967382A (en) * 2017-03-30 2017-07-21 华北水利水电大学 Environment-friendly type road-surface heating type sealant material and preparation method and application
CN107245321A (en) * 2017-03-30 2017-10-13 北京中天路业科技有限公司 Pavement crack fluid sealant and preparation method thereof
CN107245321B (en) * 2017-03-30 2019-06-28 北京中天路业科技有限公司 Pavement crack sealant and preparation method thereof
CN108795066A (en) * 2017-04-27 2018-11-13 金华方金雨伞防水科技有限公司 A kind of antifatigue waterproof material and preparation method thereof
CN108948755A (en) * 2017-05-18 2018-12-07 济宁明升新材料有限公司 It is a kind of improve Pavement Performance lignin-base phenolic resin adhesive and its application
CN109251538A (en) * 2017-07-13 2019-01-22 大连韵海贸易有限公司 A kind of modulation formula of bituminous pavement casting glue
CN109135308A (en) * 2018-08-09 2019-01-04 成都道盛路通新材料有限公司 A kind of modified pitch, asphalt modifier and preparation method thereof
CN109439278A (en) * 2018-11-02 2019-03-08 李廷刚 Low cohesive force bituminous pavement hot type sealant and preparation method thereof
CN111171395A (en) * 2020-02-17 2020-05-19 褚乃博 Composite material made of recycled rubber, forming method and application thereof
WO2023199899A1 (en) * 2022-04-11 2023-10-19 花王株式会社 Asphalt composition
CN114774079A (en) * 2022-04-14 2022-07-22 鄂尔多斯市路泰公路工程有限责任公司 High-viscosity high-strength pavement heating type sealant and preparation method thereof
CN114774079B (en) * 2022-04-14 2023-11-14 鄂尔多斯市路泰公路工程有限责任公司 High-viscosity high-strength pavement heating type sealant and preparation method thereof
CN115286853A (en) * 2022-08-31 2022-11-04 侯马市怡达汽车销售有限公司 Welding fusion strip for highway cracks and welding fusion crack pouring process

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