CN106146892A - A kind of rubber defoamer formula and preparation method thereof - Google Patents

A kind of rubber defoamer formula and preparation method thereof Download PDF

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Publication number
CN106146892A
CN106146892A CN201610499388.3A CN201610499388A CN106146892A CN 106146892 A CN106146892 A CN 106146892A CN 201610499388 A CN201610499388 A CN 201610499388A CN 106146892 A CN106146892 A CN 106146892A
Authority
CN
China
Prior art keywords
defoamer
formula
calcium oxide
parts
calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610499388.3A
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Chinese (zh)
Inventor
张训龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Province Han Shanxian Jinhua Zinc Oxide Plant
Original Assignee
Anhui Province Han Shanxian Jinhua Zinc Oxide Plant
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Province Han Shanxian Jinhua Zinc Oxide Plant filed Critical Anhui Province Han Shanxian Jinhua Zinc Oxide Plant
Priority to CN201610499388.3A priority Critical patent/CN106146892A/en
Publication of CN106146892A publication Critical patent/CN106146892A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/10Encapsulated ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of rubber defoamer formula, described defoamer is made up of calcium oxide and PE film, is made up of according to the raw material of weight portion percentage ratio following: calcium carbonate 2 ~ 4 parts, nucleator 1 ~ 3 part, coupling agent 1.2 ~ 1.8 parts, lubricant 0.8 ~ 1.4 part, foaming agent 0.4 ~ 0.8 part and remainder are calcium oxide.This formula can well ensure that defoamer internal oxidation calcium is not hydrolyzed, with low cost, improves storage time, the good stability of calcium oxide greatly, is difficult to the moisture absorption and goes bad, be prone to weigh, and moisture absorption efficiency is high, it is ensured that quality of item is stable.

Description

A kind of rubber defoamer formula and preparation method thereof
Technical field
The present invention relates to field of inorganic materials, particularly relate to a kind of rubber defoamer formula and preparation method thereof.
Background technology
Rubber defoamer, also known as rubber hygroscopic agent, vulcanization of rubber defoamer, can be used for doing in rubber and some product of rubber and plastic Compounding ingredient, absorbs its goods moisture content that filler, vulcanizing agent, accelerator, foaming agent used etc. are brought in process of production, makes The internal pore-free of its goods, section is uniformly, fine and close, smooth surface is attractive in appearance.The most common rubber defoamer mostly is powder Powder so that the shelf-life of defoamer is greatly shortened, the easy moisture absorption goes bad, and is difficult to weigh.
Summary of the invention
In order to overcome the defect of above-mentioned prior art, it is an object of the invention to provide a kind of rubber defoamer formula and system thereof Preparation Method.
The present invention takes techniques below scheme to realize: a kind of rubber defoamer formula, described defoamer is by aoxidizing Calcium and PE film composition, be made up of according to the raw material of weight portion percentage ratio following: calcium carbonate 2 ~ 4 parts, nucleator 1 ~ 3 part, coupling agent 1.2 ~ 1.8 parts, lubricant 0.8 ~ 1.4 part, foaming agent 0.4 ~ 0.8 part and remainder are calcium oxide.
Above-mentioned a kind of rubber defoamer formula, described defoamer is made up of calcium chloride and PE film, by following according to weight The raw material composition of part percentage ratio: calcium carbonate 2 ~ 3 parts, nucleator 1 ~ 2 part, coupling agent 1.2 ~ 1.6 parts, lubricant 0.8 ~ 1.2 part, Infusion 0.4 ~ 0.6 part and remainder are calcium oxide.
Above-mentioned a kind of rubber defoamer formula, described defoamer is made up of calcium chloride and PE film, by following according to weight The raw material composition of part percentage ratio: calcium carbonate 2 parts, nucleator 1.5 parts, coupling agent 1.3 parts, lubricant 0.8 part, foaming agent 0.6 part It is calcium oxide with remainder.
Above-mentioned a kind of rubber defoamer formula, the percentage by weight of described calcium oxide is more than 95%.
The preparation method of above-mentioned a kind of rubber defoamer formula, is prepared from by following steps:
(1) calcium carbonate, nucleator, coupling agent, lubricant and foaming agent are mixed, squeezed by die orifice is linear after spiro rod plasticizing Go out, stretched rear formation PE film;
(2) by combine elastomer make calcium oxide become bulk;
(3) fully sealing parcel calcium oxide with PE film in dry environments, every 18kg uses the PE film packaging of 2kg;
(4) packed in cases, weighs.
The method have the advantages that this formula can well ensure that defoamer internal oxidation calcium exists in sum It is not hydrolyzed before using, with low cost, improve storage time, the good stability of calcium oxide greatly, to be difficult to the moisture absorption rotten, easily In weighing, moisture absorption efficiency is high, it is ensured that quality of item is stable.
Detailed description of the invention
A kind of rubber defoamer formula, described defoamer is made up of calcium oxide and PE film, by following according to weight portion percentage The raw material composition of ratio: calcium carbonate 2 ~ 4 parts, nucleator 1 ~ 3 part, coupling agent 1.2 ~ 1.8 parts, lubricant 0.8 ~ 1.4 part, foaming agent 0.4 ~ 0.8 part is calcium oxide with remainder.
Above-mentioned a kind of rubber defoamer formula, described defoamer is made up of calcium chloride and PE film, by following according to weight The raw material composition of part percentage ratio: calcium carbonate 2 ~ 3 parts, nucleator 1 ~ 2 part, coupling agent 1.2 ~ 1.6 parts, lubricant 0.8 ~ 1.2 part, Infusion 0.4 ~ 0.6 part and remainder are calcium oxide.
Above-mentioned a kind of rubber defoamer formula, described defoamer is made up of calcium chloride and PE film, by following according to weight The raw material composition of part percentage ratio: calcium carbonate 2 parts, nucleator 1.5 parts, coupling agent 1.3 parts, lubricant 0.8 part, foaming agent 0.6 part It is calcium oxide with remainder.
Above-mentioned a kind of rubber defoamer formula, the percentage by weight of described calcium oxide is more than 95%.
The preparation method of above-mentioned a kind of rubber defoamer formula, is prepared from by following steps:
(1) calcium carbonate, nucleator, coupling agent, lubricant and foaming agent are mixed, squeezed by die orifice is linear after spiro rod plasticizing Go out, stretched rear formation PE film;
(2) by combine elastomer make calcium oxide become bulk;
(3) fully sealing parcel calcium oxide with PE film in dry environments, every 18kg uses the PE film packaging of 2kg;
(4) packed in cases, weighs.
This formula can well ensure that defoamer internal oxidation calcium is not hydrolyzed, with low cost, greatly Improving storage time, the good stability of calcium oxide, be difficult to the moisture absorption and go bad, be prone to weigh, moisture absorption efficiency is high, it is ensured that quality of item Stable.
The above is embodiments of the invention, therefore all according to the structure described in the present patent application scope, feature and principle institute The equivalence change done or modification, in the range of being all included in present patent application.

Claims (5)

1. a rubber defoamer formula, it is characterised in that described defoamer is made up of calcium oxide and PE film, by following according to weight Amount part percentage ratio raw material composition: calcium carbonate 2 ~ 4 parts, nucleator 1 ~ 3 part, coupling agent 1.2 ~ 1.8 parts, lubricant 0.8 ~ 1.4 part, Foaming agent 0.4 ~ 0.8 part and remainder are calcium oxide.
A kind of rubber defoamer formula the most according to claim 1, it is characterised in that described defoamer is by calcium chloride and PE Film forms, and is made up of according to the raw material of weight portion percentage ratio following: calcium carbonate 2 ~ 3 parts, nucleator 1 ~ 2 part, coupling agent 1.2 ~ 1.6 Part, lubricant 0.8 ~ 1.2 part, foaming agent 0.4 ~ 0.6 part and remainder are calcium oxide.
A kind of rubber defoamer formula the most according to claim 1, it is characterised in that described defoamer is by calcium chloride and PE Film forms, and is made up of according to the raw material of weight portion percentage ratio following: calcium carbonate 2 parts, nucleator 1.5 parts, coupling agent 1.3 parts, profit Lubrication prescription 0.8 part, foaming agent 0.6 part and remainder are calcium oxide.
A kind of rubber defoamer formula the most according to claim 1, it is characterised in that: the percentage by weight of described calcium oxide More than 95%.
5. according to the preparation method of the arbitrary described a kind of rubber defoamer formula of claim 1-3, it is characterised in that by following Step is prepared from:
(1) calcium carbonate, nucleator, coupling agent, lubricant and foaming agent are mixed, squeezed by die orifice is linear after spiro rod plasticizing Go out, stretched rear formation PE film;
(2) by combine elastomer make calcium oxide become bulk;
(3) fully sealing parcel calcium oxide with PE film in dry environments, every 18kg uses the PE film packaging of 2kg;
(4) packed in cases, weighs.
CN201610499388.3A 2016-06-30 2016-06-30 A kind of rubber defoamer formula and preparation method thereof Pending CN106146892A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610499388.3A CN106146892A (en) 2016-06-30 2016-06-30 A kind of rubber defoamer formula and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610499388.3A CN106146892A (en) 2016-06-30 2016-06-30 A kind of rubber defoamer formula and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106146892A true CN106146892A (en) 2016-11-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610499388.3A Pending CN106146892A (en) 2016-06-30 2016-06-30 A kind of rubber defoamer formula and preparation method thereof

Country Status (1)

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CN (1) CN106146892A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107686667A (en) * 2017-09-08 2018-02-13 宣城市聚源精细化工有限公司 A kind of plastics defoamer

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1398718A (en) * 2001-07-26 2003-02-26 申容焕 Production process of low-density foamed polyethylene
CN104910499A (en) * 2015-07-03 2015-09-16 安徽中杰信息科技有限公司 Environmentally digestible plastic preparation method taking calcium carbonate as filler
CN105037877A (en) * 2015-07-03 2015-11-11 安徽中杰信息科技有限公司 Method for preparing environmentally digestible plastic by using rare earth photosensitizer as coupling agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1398718A (en) * 2001-07-26 2003-02-26 申容焕 Production process of low-density foamed polyethylene
CN104910499A (en) * 2015-07-03 2015-09-16 安徽中杰信息科技有限公司 Environmentally digestible plastic preparation method taking calcium carbonate as filler
CN105037877A (en) * 2015-07-03 2015-11-11 安徽中杰信息科技有限公司 Method for preparing environmentally digestible plastic by using rare earth photosensitizer as coupling agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107686667A (en) * 2017-09-08 2018-02-13 宣城市聚源精细化工有限公司 A kind of plastics defoamer

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SE01 Entry into force of request for substantive examination
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Application publication date: 20161123