CN106145697A - A kind of high-toughness glass fibre yarn and manufacture method - Google Patents
A kind of high-toughness glass fibre yarn and manufacture method Download PDFInfo
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- CN106145697A CN106145697A CN201610523584.XA CN201610523584A CN106145697A CN 106145697 A CN106145697 A CN 106145697A CN 201610523584 A CN201610523584 A CN 201610523584A CN 106145697 A CN106145697 A CN 106145697A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/48—Coating with two or more coatings having different compositions
- C03C25/50—Coatings containing organic materials only
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/1095—Coating to obtain coated fabrics
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
- D02G3/182—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure
- D02G3/185—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure in the core
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/447—Yarns or threads for specific use in general industrial applications, e.g. as filters or reinforcement
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of high-toughness glass fibre yarn and manufacture method, it is made up of the raw material of following weight portion: glass fibre 50 60 parts, 2,2'[[3 methyl 4 [(4 nitrobenzophenone) azo] phenyl] imino group] diethanol 5 12 parts, 4-aminophenetole 26 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 10 18 parts, N, N dimethyl N 2 acrylic acid chlorine height be polymerized 2 propylene 1 amine 14 parts, hexadecanyl phosphate potassium salt 25 parts.In invention under the synergism of each raw material, improve the hot strength of glass fibre, improve the performances such as the temperature tolerance of glass fibre, wearability and acid resistance simultaneously.
Description
Technical field
The present invention relates to a kind of high-toughness glass fibre yarn, belong to field of inorganic nonmetallic material.
Background technology
Glass fibre is the Inorganic Non-metallic Materials of a kind of excellent performance, of a great variety, and advantage is good insulating, thermostability
By force, corrosion resistance good, mechanical strength is high, but shortcoming is that property is crisp, and wearability is poor.It is with glass bead or discarded glass as raw material
Being manufactured into through high temperature melting, wire drawing, doff, the technique such as weave cotton cloth, a diameter of several microns of its monofilament to twenties meters are micro-
Rice, is equivalent to the 1/20-1/5 of a hairline, and every bundle fiber precursor is all made up of hundreds of the most thousands of monofilament.Glass
The national economy such as fiber is typically used as the reinforcing material in composite, electrically insulating material and heat-insulating material, circuit substrate
Every field.
Summary of the invention
For overcoming above-mentioned deficiency, present invention aim at providing a kind of high-toughness glass fibre yarn and manufacture method, the party
Glass fibre yarn intensity that method processed is high, good toughness and also have wearability.The present invention is mainly suitable for field of cables.
The solution of the present invention is as follows: a kind of high-toughness glass fibre yarn, is made up of the raw material of following weight portion: glass fibre
50-60 part, 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol 5-12 part, p-aminophenyl second
Ether 2-6 part, 1-hydroxy ethylidene-1,1-diphosphonic acid 10-18 part, N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 1-4
Part, hexadecanyl phosphate potassium salt 2-5 part.
Further, it is made up of the raw material of following weight portion: glass fibre 54 parts, 2,2'-[[3-methyl-4-[(4-Nitrobenzol
Base) azo] phenyl] imino group] diethanol 8 parts, 4-aminophenetole 4 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 12 parts, N, N-dimethyl-
N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 2.6 parts, hexadecanyl phosphate potassium salt 3.3 parts.
Further, it is made up of the raw material of following weight portion: glass fibre 52 parts, 2,2'-[[3-methyl-4-[(4-Nitrobenzol
Base) azo] phenyl] imino group] diethanol 10 parts, 4-aminophenetole 3 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 16 parts, N, N-dimethyl-
N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 1.6 parts, hexadecanyl phosphate potassium salt 3.8 parts.
Further, it is made up of the raw material of following weight portion: glass fibre 58 parts, 2,2'-[[3-methyl-4-[(4-Nitrobenzol
Base) azo] phenyl] imino group] diethanol 11 parts, 4-aminophenetole 5 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 15 parts, N, N-dimethyl-
N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 3.6 parts, hexadecanyl phosphate potassium salt 1.8 parts.
The manufacture method of high-toughness glass fibre yarn, comprises the steps of:
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is configured to deionized water
Mass concentration is the solution A of 6-12%, and 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 10-17%；
2) glass fibre is inserted in solution A, be warming up to 72-88 DEG C under nitrogen protection, and heated and stirred 30-at such a temperature
38min, is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 112-120 DEG C, and
Heated and stirred 15-22min at a temperature of Gai；
3) it is cooled to 70-75 DEG C, adds B solution, and heated and stirred 33-45min at such a temperature；It is subsequently adding hydroxy ethylidene two
Phosphonic acids, is warming up to 124-136 DEG C, and heats 30-40min at such a temperature；
4) then drop to 118-125 DEG C, add hexadecanyl phosphate potassium salt heated and stirred 35-38min at such a temperature；
5) 90-100 DEG C then it is down to, and heated and stirred 40-50min at such a temperature, prepare and process glass fibre；
6) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling.
In invention under the synergism of each raw material, improve the hot strength of glass fibre, improve glass simultaneously
The performances such as the temperature tolerance of fiber, wearability and acid resistance.
The present invention not only recipe ingredient is reasonable, stable performance, and technical process is simple to operation, and production efficiency is high, Er Qieke
To improve the toughness of glass fibre, being not easily broken, block-water effect is good, and production cost is low, is suitable to industrialized production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1
High-toughness glass fibre yarn, including following raw material: glass fibre 54 parts, 2,2'-[[3-methyl-4-[(4-nitro
Phenyl) azo] phenyl] imino group] diethanol 8 parts, 4-aminophenetole 4 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 12 parts, N, N-diformazan
Base-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 2.6 parts, hexadecanyl phosphate potassium salt 3.3 parts.
Manufacture method, comprises the steps of:
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is configured to deionized water
Mass concentration is the solution A of 10%, and 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 12%；
2) glass fibre is inserted in solution A, is warming up to 78 DEG C, and heated and stirred 36min at such a temperature under nitrogen protection,
It is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 118 DEG C, and adds at such a temperature
Thermal agitation 20min；
3) it is cooled to 74 DEG C, adds B solution, and heated and stirred 38min at such a temperature；It is subsequently adding 1-hydroxy ethylidene-1,1-diphosphonic acid,
It is warming up to 130 DEG C, and heats 35min at such a temperature；
4) then drop to 119 DEG C, add hexadecanyl phosphate potassium salt heated and stirred 36min at such a temperature；
5) 95 DEG C then it are down to, and heated and stirred 42min at such a temperature, prepare and process glass fibre；
6) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling.
Embodiment 2
High-toughness glass fibre yarn, including following raw material: glass fibre 52 parts, 2,2'-[[3-methyl-4-[(4-nitro
Phenyl) azo] phenyl] imino group] diethanol 10 parts, 4-aminophenetole 3 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 16 parts, N, N-diformazan
Base-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 1.6 parts, hexadecanyl phosphate potassium salt 3.8 parts.
Manufacture method, comprises the steps of:
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is configured to deionized water
Mass concentration is the solution A of 8%, and 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 16%；
2) glass fibre is inserted in solution A, is warming up to 86 DEG C, and heated and stirred 34min at such a temperature under nitrogen protection,
It is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 116 DEG C, and adds at such a temperature
Thermal agitation 21min；
3) it is cooled to 75 DEG C, adds B solution, and heated and stirred 38min at such a temperature；It is subsequently adding 1-hydroxy ethylidene-1,1-diphosphonic acid,
It is warming up to 127 DEG C, and heats 36min at such a temperature；
4) then drop to 120 DEG C, add hexadecanyl phosphate potassium salt heated and stirred 36min at such a temperature；
5) 98 DEG C then it are down to, and heated and stirred 41min at such a temperature, prepare and process glass fibre；
3) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling
Embodiment 3
High-toughness glass fibre yarn, including following raw material: glass fibre 58 parts, 2,2'-[[3-methyl-4-[(4-nitro
Phenyl) azo] phenyl] imino group] diethanol 11 parts, 4-aminophenetole 5 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 15 parts, N, N-diformazan
Base-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 3.6 parts, hexadecanyl phosphate potassium salt 1.8 parts.
Manufacture method, comprises the steps of:
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is configured to deionized water
Mass concentration is the solution A of 12%, and 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 12%；
2) glass fibre is inserted in solution A, is warming up to 77 DEG C, and heated and stirred 34min at such a temperature under nitrogen protection,
It is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 120 DEG C, and adds at such a temperature
Thermal agitation 20min；
3) it is cooled to 75 DEG C, adds B solution, and heated and stirred 35min at such a temperature；It is subsequently adding 1-hydroxy ethylidene-1,1-diphosphonic acid,
It is warming up to 135 DEG C, and heats 40in at such a temperature；
4) then drop to 121 DEG C, add hexadecanyl phosphate potassium salt heated and stirred 36min at such a temperature；
5) 92 DEG C then it are down to, and heated and stirred 50min at such a temperature, prepare and process glass fibre；
6) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling.
Comparative example 1
Compared with Example 1,1-hydroxy ethylidene-1,1-diphosphonic acid is lacked.
Manufacture method is as follows:
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is configured to deionized water
Mass concentration is the solution A of 10%, and 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 12%；
2) glass fibre is inserted in solution A, is warming up to 78 DEG C, and heated and stirred 36min at such a temperature under nitrogen protection,
It is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 118 DEG C, and adds at such a temperature
Thermal agitation 20min；
3) then rise to 119 DEG C, add hexadecanyl phosphate potassium salt heated and stirred 36min at such a temperature；
4) 95 DEG C then it are down to, and heated and stirred 42min at such a temperature, prepare and process glass fibre；
5) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling.
Comparative example 2
Compared with Example 1, hexadecanyl phosphate potassium salt.
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is joined with deionized water
Make the solution A that mass concentration is 10%, 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 12%；
2) glass fibre is inserted in solution A, is warming up to 78 DEG C, and heated and stirred 36min at such a temperature under nitrogen protection,
It is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 118 DEG C, and adds at such a temperature
Thermal agitation 20min；
3) it is cooled to 74 DEG C, adds B solution, and heated and stirred 38min at such a temperature；It is subsequently adding 1-hydroxy ethylidene-1,1-diphosphonic acid,
It is warming up to 130 DEG C, and heats 35min at such a temperature；
4) 95 DEG C then it are down to, and heated and stirred 42min at such a temperature, prepare and process glass fibre；
5) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling.
Comparative example 3
Compared with Example 1,1-hydroxy ethylidene-1,1-diphosphonic acid 12 parts, hexadecanyl phosphate potassium salt are lacked.
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is joined with deionized water
Make the solution A that mass concentration is 10%, 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 12%；
2) glass fibre is inserted in solution A, is warming up to 78 DEG C, and heated and stirred 36min at such a temperature under nitrogen protection,
It is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 118 DEG C, and adds at such a temperature
Thermal agitation 20min；
3) 95 DEG C are then risen to, and heated and stirred 42min at such a temperature, prepare and process glass fibre；
4) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling.
Comparative example 4
Conventional glass fibers yarn.
The winding of above-described embodiment 1-3, comparative example 1-4 glass fiber yarn is covered the cable core surface being rolled in optical cable.
The performance test results is as shown in the table.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | |
| Line density | 600±10 | 600±10 | 600±10 | 390±10 | 220±10 | 220±10 | 210±10 |
| Fracture strength N | ≥382 | ≥368 | ≥361 | ≥190 | ≥120 | ≥112 | ≥92 |
| Elastic modulus G Pa | ≥81 | ≥76 | ≥77 | ≥48 | ≥31 | ≥24 | ≥18 |
| Elongation at break % | ≤2.2 | ≤2.3 | ≤2.3 | ≤3.0 | ≤3.5 | ≤3.8 | ≤2.7 |
| Mouse bite preventing | Substantially | Substantially | Substantially | Inconspicuous | Inconspicuous | Inconspicuous | Inconspicuous |
Although above the detailed description of the invention to the present invention give detailed description and explanation, but it should be noted that we
According to the conception of the present invention, above-mentioned embodiment can be carried out various equivalence to change and amendment, produced by it, function is still
Without departing from description contained spiritual time, all should be within protection scope of the present invention.
Claims (5)
1. a high-toughness glass fibre yarn, it is characterised in that be made up of the raw material of following weight portion: glass fibre 50-60 part,
2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol 5-12 part, 4-aminophenetole 2-6 part,
1-hydroxy ethylidene-1,1-diphosphonic acid 10-18 part, N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 1-4 part, hexadecane
Base phosphate kalium salt 2-5 part.
A kind of high-toughness glass fibre yarn the most according to claim 1, it is characterised in that by the raw material group of following weight portion
Become: glass fibre 54 parts, 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol 8 parts, to ammonia
Base ethyl phenyl ether 4 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 12 parts, N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 2.6
Part, hexadecanyl phosphate potassium salt 3.3 parts.
A kind of high-toughness glass fibre yarn the most according to claim 1, it is characterised in that by the raw material group of following weight portion
Become: glass fibre 52 parts, 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol 10 parts, to ammonia
Base ethyl phenyl ether 3 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 16 parts, N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 1.6
Part, hexadecanyl phosphate potassium salt 3.8 parts.
A kind of high-toughness glass fibre yarn the most according to claim 1, it is characterised in that by the raw material group of following weight portion
Become: glass fibre 58 parts, 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol 11 parts, to ammonia
Base ethyl phenyl ether 5 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 15 parts, N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine 3.6
Part, hexadecanyl phosphate potassium salt 1.8 parts.
5. according to the manufacture method of the arbitrary described high-toughness glass fibre yarn of claim 1-4, it is characterised in that by following step
Rapid composition:
1) 2,2'-[[3-methyl-4-[(4-nitrobenzophenone) azo] phenyl] imino group] diethanol is configured to deionized water
Mass concentration is the solution A of 6-12%, and 4-aminophenetole and dehydrated alcohol are configured to the B solution that mass concentration is 10-17%；
2) glass fibre is inserted in solution A, be warming up to 72-88 DEG C under nitrogen protection, and heated and stirred 30-at such a temperature
38min, is subsequently adding N, N-dimethyl-N-2-acrylic acid-chlorine height polymerization-2-propylene-1-amine, is warming up to 112-120 DEG C, and
Heated and stirred 15-22min at a temperature of Gai；
3) it is cooled to 70-75 DEG C, adds B solution, and heated and stirred 33-45min at such a temperature；It is subsequently adding hydroxy ethylidene two
Phosphonic acids, is warming up to 124-136 DEG C, and heats 30-40min at such a temperature；
4) then drop to 118-125 DEG C, add hexadecanyl phosphate potassium salt heated and stirred 35-38min at such a temperature；
5) 90-100 DEG C then it is down to, and heated and stirred 40-50min at such a temperature, prepare and process glass fibre；
6) process glass fibre is i.e. obtained glass fiber yarn through extruded, traction, rolling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610523584.XA CN106145697A (en) | 2016-07-05 | 2016-07-05 | A kind of high-toughness glass fibre yarn and manufacture method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610523584.XA CN106145697A (en) | 2016-07-05 | 2016-07-05 | A kind of high-toughness glass fibre yarn and manufacture method |
Publications (1)
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| CN106145697A true CN106145697A (en) | 2016-11-23 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531472A (en) * | 2009-03-13 | 2009-09-16 | 珠海富华复合材料有限公司 | Slurry composition of glass fiber yarn and method for preparing same |
| CN102241484A (en) * | 2011-04-12 | 2011-11-16 | 重庆国际复合材料有限公司 | Glass fiber sizing agent for roving cloth and preparation method thereof |
| CN102795792A (en) * | 2011-05-23 | 2012-11-28 | 张建华 | Preparation method for impregnating compound of glass fiber |
-
2016
- 2016-07-05 CN CN201610523584.XA patent/CN106145697A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531472A (en) * | 2009-03-13 | 2009-09-16 | 珠海富华复合材料有限公司 | Slurry composition of glass fiber yarn and method for preparing same |
| CN102241484A (en) * | 2011-04-12 | 2011-11-16 | 重庆国际复合材料有限公司 | Glass fiber sizing agent for roving cloth and preparation method thereof |
| CN102795792A (en) * | 2011-05-23 | 2012-11-28 | 张建华 | Preparation method for impregnating compound of glass fiber |
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Application publication date: 20161123 |