CN106129471A - The lithium battery electrolytes that a kind of compatibility is good - Google Patents

The lithium battery electrolytes that a kind of compatibility is good Download PDF

Info

Publication number
CN106129471A
CN106129471A CN201610746538.6A CN201610746538A CN106129471A CN 106129471 A CN106129471 A CN 106129471A CN 201610746538 A CN201610746538 A CN 201610746538A CN 106129471 A CN106129471 A CN 106129471A
Authority
CN
China
Prior art keywords
parts
compatibility
good
lithium battery
battery electrolytes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610746538.6A
Other languages
Chinese (zh)
Inventor
陈平
陈一平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Baolai Battery Co
Original Assignee
Wuxi Baolai Battery Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Baolai Battery Co filed Critical Wuxi Baolai Battery Co
Priority to CN201610746538.6A priority Critical patent/CN106129471A/en
Publication of CN106129471A publication Critical patent/CN106129471A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0567Liquid materials characterised by the additives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0569Liquid materials characterised by the solvents
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0025Organic electrolyte
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses the lithium battery electrolytes that a kind of compatibility is good, it includes the raw material of following parts by weight: 5 12 parts of stable state lithium powder, cyclic carbonate 38 parts, 4 fluorine 1,3 dioxolanes 2 ketone 40 80 parts, CNT 3 ~ 8 parts, ethylene carbonate 3 ~ 6 parts, SEI film former 48 parts, anti-mistake rush additive 35 parts, fire retardant 0.5 1.5 parts, potassium fluoride 12 parts, 1 ethyl 3 Methylimidazole. 1 ~ 3 part.The good lithium battery electrolytes of a kind of compatibility that the present invention provides, has excellent compatibility, the electrolyte of higher heat stability for obtains through many experiments, makes battery have more excellent high temperature and circulates and storge quality, and battery serviceability is more excellent.

Description

The lithium battery electrolytes that a kind of compatibility is good
Technical field
The present invention relates to cell art, be specifically related to the lithium battery electrolytes that a kind of compatibility is good.
Background technology
Lithium ion battery is high with its specific energy, pollution-free, memory-less effect, life-span length and famous.In recent years, lithium-ion electric Pond attention, is promoted and applies.Little to accutron, mobile phone, arrive greatly electric bicycle, automobile, very popular, even In fields such as military aerospaces, lithium ion battery is also increasingly to obtain favor.The day of lithium ion battery profound influence people Often live and work.Current lithium ion battery causes battery usability owing to compatibility of electrolyte is poor and lithium salts dissolubility is the best Poor.
Summary of the invention
Not enough for prior art, the invention provides the lithium battery electrolytes that a kind of compatibility is good.
The present invention solves the technical scheme of above-mentioned technical problem employing: the lithium battery electrolytes that a kind of compatibility is good, Raw material including following parts by weight: 5 12 parts of stable state lithium powder, cyclic carbonate 3-8 part, 4-fluoro-1,3-dioxolan-2-one 40 80 parts, CNT 3 ~ 8 parts, ethylene carbonate 3 ~ 6 parts, SEI film former 4-8 part, anti-mistake rush additive 3-5 part, fire retardant 0.5 1.5 parts, potassium fluoride 1-2 part, 1-ethyl-3-methylimidazole 1 ~ 3 part.
Preferably, the lithium battery electrolytes that described a kind of compatibility is good, including the raw material of following parts by weight: stable state lithium Powder: 8 parts, cyclic carbonate 5 parts, 4-fluoro-1,3-dioxolan-2-one 60 parts, CNT 5 parts, ethylene carbonate 5 parts, SEI Film former 6 parts, anti-mistake rush additive 4 parts, fire retardant 1 part, potassium fluoride 1.5 parts, 1-ethyl-3-methylimidazole 2 parts.
Compared with prior art, what the present invention possessed has the beneficial effect that
The good lithium battery electrolytes of a kind of compatibility that the present invention provides, the most compatible for having of obtaining through many experiments Property, the electrolyte of higher heat stability, make battery have more excellent high temperature circulation and storge quality, battery serviceability is more Excellent.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: the lithium battery electrolytes that a kind of compatibility is good, including the raw material of following parts by weight: stable state lithium powder: 8 parts, cyclic carbonate 5 parts, 4-fluoro-1,3-dioxolan-2-one 60 parts, CNT 5 parts, ethylene carbonate 5 parts, SEI become Membrane 6 parts, anti-mistake rush additive 4 parts, fire retardant 1 part, potassium fluoride 1.5 parts, 1-ethyl-3-methylimidazole 2 parts.
Embodiment 2: the lithium battery electrolytes that a kind of compatibility is good, including the raw material of following parts by weight: stable state lithium powder 5 Part, cyclic carbonate 3 parts, 4-fluoro-1,3-dioxolan-2-one 40 parts, CNT 3 parts, ethylene carbonate 3 parts, SEI film forming Additive 3 parts, fire retardant 0.5 part, potassium fluoride 1 part, 1-ethyl-3-methylimidazole 1 part are rushed in agent 4 parts, anti-mistake.
Embodiment 3: the lithium battery electrolytes that a kind of compatibility is good, including the raw material of following parts by weight: stable state lithium powder 12 parts, cyclic carbonate 8 parts, 4-fluoro-1,3-dioxolan-2-one 80 parts, CNT 8 parts, ethylene carbonate 6 parts, SEI become Membrane 8 parts, anti-mistake rush additive 5 parts, fire retardant 1.5 parts, potassium fluoride 2 parts, 1-ethyl-3-methylimidazole 3 parts.
Embodiment 4: the lithium battery electrolytes that a kind of compatibility is good, including the raw material of following parts by weight: stable state lithium powder 12 parts, cyclic carbonate 3 parts, 4-fluoro-1,3-dioxolan-2-one 80 parts, CNT 3 parts, ethylene carbonate 6 parts, SEI become Membrane 4 parts, anti-mistake rush additive 5 parts, fire retardant 0.5 part, potassium fluoride 2 parts, 1-ethyl-3-methylimidazole 1 part.
Embodiment 5: the lithium battery electrolytes that a kind of compatibility is good, including the raw material of following parts by weight: stable state lithium powder 10 parts, cyclic carbonate 4 parts, 4-fluoro-1,3-dioxolan-2-one 55 parts, CNT 7 parts, ethylene carbonate 4 parts, SEI become Membrane 7 parts, anti-mistake rush additive 4 parts, fire retardant 0.8 part, potassium fluoride 1.2 parts, 1-ethyl-3-methylimidazole 2 parts.
It should be noted that, foregoing is not limitation of the present invention, present invention is also not necessarily limited to the example above, all The those of ordinary skill of technical field, the change made, retrofits, adds or replaces within the essential scope of the present invention, all answers Belong to protection scope of the present invention.

Claims (4)

1. the lithium battery electrolytes that a compatibility is good, it is characterised in that: include the raw material of following parts by weight: stable state lithium powder 5 12 parts, cyclic carbonate 3-8 part, 4-fluoro-1,3-dioxolan-2-one 40 80 parts, CNT 3 ~ 8 parts, ethylene carbonate 3 ~ 6 parts, SEI film former 4-8 part, anti-mistake rush additive 3-5 part, fire retardant 0.5 1.5 parts, potassium fluoride 1-2 part, 1-ethyl-3- Methylimidazole. 1 ~ 3 part.
The lithium battery electrolytes that a kind of compatibility the most according to claim 1 is good, it is characterised in that include following weight The raw material of number: 8 parts of stable state lithium powder, cyclic carbonate 5 parts, 4-fluoro-1,3-dioxolan-2-one 60 parts, CNT 5 parts, Ethylene carbonate 5 parts, SEI film former 6 parts, anti-mistake rush additive 4 parts, fire retardant 1 part, potassium fluoride 1.5 parts, 1-ethyl-3-first Base imidazoles 2 parts.
The lithium battery electrolytes that a kind of compatibility the most according to claim 1 is good, it is characterised in that include following weight The raw material of number: 5 parts of stable state lithium powder, cyclic carbonate 3 parts, 4-fluoro-1,3-dioxolan-2-one 40 parts, CNT 3 parts, Ethylene carbonate 3 parts, SEI film former 4 parts, anti-mistake rush additive 3 parts, fire retardant 0.5 part, potassium fluoride 1 part, 1-ethyl-3-first Base imidazoles 1 part.
The lithium battery electrolytes that a kind of compatibility the most according to claim 1 is good, it is characterised in that include following weight The raw material of number: 12 parts of stable state lithium powder, cyclic carbonate 8 parts, 4-fluoro-1,3-dioxolan-2-one 80 parts, CNT 8 parts, Ethylene carbonate 6 parts, SEI film former 8 parts, anti-mistake rush additive 5 parts, fire retardant 1.5 parts, potassium fluoride 2 parts, 1-ethyl-3-first Base imidazoles 3 parts.
CN201610746538.6A 2016-08-29 2016-08-29 The lithium battery electrolytes that a kind of compatibility is good Pending CN106129471A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610746538.6A CN106129471A (en) 2016-08-29 2016-08-29 The lithium battery electrolytes that a kind of compatibility is good

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610746538.6A CN106129471A (en) 2016-08-29 2016-08-29 The lithium battery electrolytes that a kind of compatibility is good

Publications (1)

Publication Number Publication Date
CN106129471A true CN106129471A (en) 2016-11-16

Family

ID=57271952

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610746538.6A Pending CN106129471A (en) 2016-08-29 2016-08-29 The lithium battery electrolytes that a kind of compatibility is good

Country Status (1)

Country Link
CN (1) CN106129471A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108288690A (en) * 2017-01-09 2018-07-17 溧阳天目先导电池材料科技有限公司 A kind of lithium solid state battery cathode and its preparation method and application
CN108933047A (en) * 2018-07-17 2018-12-04 中国科学院过程工程研究所 A kind of prelithiation gel electrolyte and preparation method thereof for lithium-ion capacitor
CN109494405A (en) * 2018-09-18 2019-03-19 浙江蓝德能源科技发展有限公司 A kind of lithium-ion battery electrolytes additive and electrolyte

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1770547A (en) * 2004-11-05 2006-05-10 索尼株式会社 Electrolytic solution and battery
CN105514396A (en) * 2016-02-05 2016-04-20 宁波良能新材料有限公司 Cathode material of lithium sulfur battery and preparation method of cathode material
CN105702950A (en) * 2016-02-03 2016-06-22 山东康洋电源有限公司 Special safety lithium-ion battery for new energy vehicle

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1770547A (en) * 2004-11-05 2006-05-10 索尼株式会社 Electrolytic solution and battery
CN105702950A (en) * 2016-02-03 2016-06-22 山东康洋电源有限公司 Special safety lithium-ion battery for new energy vehicle
CN105514396A (en) * 2016-02-05 2016-04-20 宁波良能新材料有限公司 Cathode material of lithium sulfur battery and preparation method of cathode material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108288690A (en) * 2017-01-09 2018-07-17 溧阳天目先导电池材料科技有限公司 A kind of lithium solid state battery cathode and its preparation method and application
CN108933047A (en) * 2018-07-17 2018-12-04 中国科学院过程工程研究所 A kind of prelithiation gel electrolyte and preparation method thereof for lithium-ion capacitor
CN109494405A (en) * 2018-09-18 2019-03-19 浙江蓝德能源科技发展有限公司 A kind of lithium-ion battery electrolytes additive and electrolyte

Similar Documents

Publication Publication Date Title
CN103972588B (en) Non-aqueous electrolyte and lithium ion battery
CN104269576B (en) A kind of electrolyte and the lithium ion battery using the electrolyte
CN105633467B (en) Electrolyte and lithium ion battery adopting same
CN105811010B (en) A kind of lithium battery
CN104362394A (en) Lithium-sulfur rechargeable battery
CN104393290A (en) Aluminum-ion battery using MoS2 as positive electrode material and preparation method of battery
JP2017152375A5 (en)
CN105470563A (en) Lithium ion battery electrolyte suitably used for silicon-carbon negative electrode
CN105720303A (en) Fluoro-carboxylic ester contained electrolyte for high-voltage lithium ion battery
WO2016043823A3 (en) Supercapacitor
CN107910483A (en) A kind of lithium-ion battery system for having high-energy-density and ultralow temperature multiplying power discharging concurrently
JP2017529664A (en) Fluoropropylene carbonate-based electrolyte and lithium ion battery
CN106129471A (en) The lithium battery electrolytes that a kind of compatibility is good
JP2017097955A5 (en)
CN105789685A (en) Lithium ion battery and electrolyte thereof
CN106033824A (en) High-voltage lithium ion battery and electrolyte thereof
CN105428703B (en) A kind of lithium ion battery containing additive
CN106025362A (en) Low-temperature type lithium-ion battery electrolyte
CN106340670A (en) Non-aqueous electrolyte and lithium ion battery
CN105514492A (en) Electrolyte for lithium ion battery
CN107565167A (en) A kind of electrolyte and Dual-ion cell
CN106803571B (en) It is a kind of with high-energy, high magnification and the carbon of long-life anode and its application
CN104157903B (en) High-voltage lithium ion battery carbonate-based electrolyte solution and preparation method and application thereof
CN106328999A (en) High-rate electrolyte of lithium-ion battery
CN104916883A (en) Lithium-air battery and electrolyte thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20161116

WD01 Invention patent application deemed withdrawn after publication