CN106129316A - A kind of lithium ion battery separator material of high temperature resistance and high strength - Google Patents

A kind of lithium ion battery separator material of high temperature resistance and high strength Download PDF

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Publication number
CN106129316A
CN106129316A CN201610745453.6A CN201610745453A CN106129316A CN 106129316 A CN106129316 A CN 106129316A CN 201610745453 A CN201610745453 A CN 201610745453A CN 106129316 A CN106129316 A CN 106129316A
Authority
CN
China
Prior art keywords
parts
lithium ion
ion battery
temperature resistance
high temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610745453.6A
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Chinese (zh)
Inventor
陈平
陈一平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Baolai Battery Co
Original Assignee
Wuxi Baolai Battery Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Baolai Battery Co filed Critical Wuxi Baolai Battery Co
Priority to CN201610745453.6A priority Critical patent/CN106129316A/en
Publication of CN106129316A publication Critical patent/CN106129316A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

A kind of lithium ion battery separator material of high temperature resistance and high strength, it includes the raw material of following parts by weight: PPTA 65 85 parts, Tissuemat E 20 parts, polypropylene glycol adipate 5 12 parts, styrene 57 parts, diallyl phthalate 16 parts, gas phase titanium dioxide 5 12 parts, isocyanuric acid three-glycidyl ester 28 parts, 2,5 ditert-butylhydro quinones 0.5 1.5 parts, polyphosphoric acids 13 parts, Triallyl isocyanurate 36 parts.The lithium ion battery separator material of a kind of high temperature resistance and high strength that the present invention provides, the barrier film of the heat-resistant stable, chemical resistance and the mechanical strength that possess excellence for obtaining through many experiments, it is favorably improved the quality of lithium ion battery.

Description

A kind of lithium ion battery separator material of high temperature resistance and high strength
Technical field
The present invention relates to cell art, be specifically related to the lithium ion battery separator material of a kind of high temperature resistance and high strength.
Background technology
In the structure of lithium battery, barrier film is one of crucial interior layer assembly.The performance of barrier film determines the interface knot of battery Structure, internal resistance etc., directly affect the characteristics such as the capacity of battery, circulation and security performance, and the barrier film of excellent performance is to improving battery Combination property there is important effect.The Main Function of barrier film is that the positive and negative electrode making battery is separated, and prevents the two poles of the earth from connecing Touch and short-circuit, additionally there is the function that electrolyte ion can be made to pass through.Existing battery diaphragm material resistance to elevated temperatures and strong Spend poor, have impact on the quality of lithium ion battery to a certain extent.
Summary of the invention
Not enough for prior art, the invention provides the lithium ion battery separator material of a kind of high temperature resistance and high strength.
The present invention solve above-mentioned technical problem use technical scheme be: the lithium ion battery of a kind of high temperature resistance and high strength every Membrane material, including the raw material of following parts by weight: PPTA 65-85 part, Tissuemat E 2-10 part is poly-own Two acid propylene glycol ester 5-12 parts, styrene 5-7 part, diallyl phthalate 1-6 part, gas phase titanium dioxide 5-12 part is different Cyanuric acid three-glycidyl ester 2-8 part, 2,5-ditert-butylhydro quinone 0.5-1.5 parts, polyphosphoric acids 1-3 part, triallyl Isocyanuric acid ester 3-6 part.
As preferably, the lithium ion battery separator material of described a kind of high temperature resistance and high strength, including following parts by weight Raw material: PPTA 75 parts, Tissuemat E 6 parts, polypropylene glycol adipate 8 parts, styrene 6 parts, adjacent benzene Dioctyl phthalate diallyl 4 parts, gas phase titanium dioxide 8 parts, isocyanuric acid three-glycidyl ester 5 parts, 2,5-di-tert-butyls are to benzene two 1 part of phenol, polyphosphoric acids 2 parts, Triallyl isocyanurate 5 parts.
Compared with prior art, what the present invention possessed has the beneficial effect that
The lithium ion battery separator material of a kind of high temperature resistance and high strength that the present invention provides, excellent for possessing of obtaining through many experiments The barrier film of different heat-resistant stable, chemical resistance and mechanical strength, is favorably improved the quality of lithium ion battery.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: the lithium ion battery separator material of a kind of high temperature resistance and high strength, including the raw material of following parts by weight: PPTA 75 parts, Tissuemat E 5 parts, polypropylene glycol adipate 8 parts, styrene 6 parts, phthalic acid Diallyl 4 parts, gas phase titanium dioxide 8 parts, isocyanuric acid three-glycidyl ester 6 parts, 2,5-ditert-butylhydro quinones 1 part, Polyphosphoric acids 2 parts, Triallyl isocyanurate 5 parts.
Embodiment 2: the lithium ion battery separator material of a kind of high temperature resistance and high strength, including the raw material of following parts by weight: PPTA 65 parts, Tissuemat E 3 parts, polypropylene glycol adipate 5 parts, styrene 5 parts, phthalic acid Diallyl 1 part, gas phase titanium dioxide 5 parts, isocyanuric acid three-glycidyl ester 2 parts, 2,5-ditert-butylhydro quinones 0.5 Part, polyphosphoric acids 1 part, Triallyl isocyanurate 3 parts.
Embodiment 3: the lithium ion battery separator material of a kind of high temperature resistance and high strength, including the raw material of following parts by weight: PPTA 85 parts, Tissuemat E 7 parts, polypropylene glycol adipate 12 parts, styrene 7 parts, O-phthalic Diallyl phthalate 6 parts, gas phase titanium dioxide 12 parts, isocyanuric acid three-glycidyl ester 8 parts, 2,5-ditert-butylhydro quinones 1.5 parts, polyphosphoric acids 3 parts, Triallyl isocyanurate 6 parts.
Embodiment 4: the lithium ion battery separator material of a kind of high temperature resistance and high strength, including the raw material of following parts by weight: PPTA 65 parts, Tissuemat E 7 parts, polypropylene glycol adipate 5 parts, styrene 7 parts, phthalic acid Diallyl 1 part, gas phase titanium dioxide 12 parts, isocyanuric acid three-glycidyl ester 2 parts, 2,5-ditert-butylhydro quinones 1.5 Part, polyphosphoric acids 1 part, Triallyl isocyanurate 6 parts.
Embodiment 5: the lithium ion battery separator material of a kind of high temperature resistance and high strength, including the raw material of following parts by weight: PPTA 70 parts, Tissuemat E 6 parts, polypropylene glycol adipate 10 parts, styrene 6 parts, O-phthalic Diallyl phthalate 5 parts, gas phase titanium dioxide 10 parts, isocyanuric acid three-glycidyl ester 5 parts, 2,5-ditert-butylhydro quinones 0.8 part, polyphosphoric acids 2 parts, Triallyl isocyanurate 4 parts.
It should be noted that, foregoing is not limitation of the present invention, present invention is also not necessarily limited to the example above, all The those of ordinary skill of technical field, the change made, retrofits, adds or replaces within the essential scope of the present invention, all answers Belong to protection scope of the present invention.

Claims (4)

1. the lithium ion battery separator material of a high temperature resistance and high strength, it is characterised in that include the raw material of following parts by weight: PPTA 65-85 part, Tissuemat E 2-10 part, polypropylene glycol adipate 5-12 part, styrene 5-7 Part, diallyl phthalate 1-6 part, gas phase titanium dioxide 5-12 part, isocyanuric acid three-glycidyl ester 2-8 part, 2,5- Ditert-butylhydro quinone 0.5-1.5 part, polyphosphoric acids 1-3 part, Triallyl isocyanurate 3-6 part.
The lithium ion battery separator material of a kind of high temperature resistance and high strength the most according to claim 1, it is characterised in that include The raw material of following parts by weight: PPTA 75 parts, Tissuemat E 65 parts, polypropylene glycol adipate 8 parts, Styrene 6 parts, diallyl phthalate 4 parts, gas phase titanium dioxide 8 parts, isocyanuric acid three-glycidyl ester 6 parts, 2,5- Ditert-butylhydro quinone 1 part, polyphosphoric acids 2 parts, Triallyl isocyanurate 5 parts.
The lithium ion battery separator material of a kind of high temperature resistance and high strength the most according to claim 1, it is characterised in that include The raw material of following parts by weight: PPTA 65 parts, Tissuemat E 2 parts, polypropylene glycol adipate 5 parts, Styrene 5 parts, diallyl phthalate 1 part, gas phase titanium dioxide 5 parts, isocyanuric acid three-glycidyl ester 2 parts, 2,5- Ditert-butylhydro quinone 0.5 part, polyphosphoric acids 1 part, Triallyl isocyanurate 3 parts.
The lithium ion battery separator material of a kind of high temperature resistance and high strength the most according to claim 1, it is characterised in that include The raw material of following parts by weight: PPTA 85 parts, Tissuemat E 10 parts, polypropylene glycol adipate 12 Part, styrene 7 parts, diallyl phthalate 6 parts, gas phase titanium dioxide 12 parts, isocyanuric acid three-glycidyl ester 8 parts, 2,5-ditert-butylhydro quinones 1.5 parts, polyphosphoric acids 3 parts, Triallyl isocyanurate 6 parts.
CN201610745453.6A 2016-08-29 2016-08-29 A kind of lithium ion battery separator material of high temperature resistance and high strength Pending CN106129316A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610745453.6A CN106129316A (en) 2016-08-29 2016-08-29 A kind of lithium ion battery separator material of high temperature resistance and high strength

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610745453.6A CN106129316A (en) 2016-08-29 2016-08-29 A kind of lithium ion battery separator material of high temperature resistance and high strength

Publications (1)

Publication Number Publication Date
CN106129316A true CN106129316A (en) 2016-11-16

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Family Applications (1)

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CN201610745453.6A Pending CN106129316A (en) 2016-08-29 2016-08-29 A kind of lithium ion battery separator material of high temperature resistance and high strength

Country Status (1)

Country Link
CN (1) CN106129316A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101987905A (en) * 2010-10-27 2011-03-23 界首市天鸿包装材料有限公司 High-insulation low-static anti-wrinkle heat-seal type functional film
CN103456910A (en) * 2012-06-01 2013-12-18 三星Sdi株式会社 Separator for rechargeable lithium battery and rechargeable lithium battery including the same
CN104167521A (en) * 2014-07-31 2014-11-26 青岛华承天机械制造有限公司 Corrosion-resistant battery diaphragm
CN105175884A (en) * 2015-07-20 2015-12-23 孙晨 Lithium battery diaphragm with stable performance

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101987905A (en) * 2010-10-27 2011-03-23 界首市天鸿包装材料有限公司 High-insulation low-static anti-wrinkle heat-seal type functional film
CN103456910A (en) * 2012-06-01 2013-12-18 三星Sdi株式会社 Separator for rechargeable lithium battery and rechargeable lithium battery including the same
CN104167521A (en) * 2014-07-31 2014-11-26 青岛华承天机械制造有限公司 Corrosion-resistant battery diaphragm
CN105175884A (en) * 2015-07-20 2015-12-23 孙晨 Lithium battery diaphragm with stable performance

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