CN106128593A - A kind of track traffic rat-and-ant proof trailing cable - Google Patents

A kind of track traffic rat-and-ant proof trailing cable Download PDF

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CN106128593A
CN106128593A CN201610573746.0A CN201610573746A CN106128593A CN 106128593 A CN106128593 A CN 106128593A CN 201610573746 A CN201610573746 A CN 201610573746A CN 106128593 A CN106128593 A CN 106128593A
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rat
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mps
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张翔
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/2806Protection against damage caused by corrosion
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of track traffic rat-and-ant proof trailing cable, outside conductor, set gradually insulating barrier, belting layer, embossing restrictive coating and external sheath layer;Described external sheath layer is made up of the raw material such as polyethylene, polrvinyl chloride, MPS butadiene copolymer 1, pentadiene, isocyanatoethyl, modified amphibole powder, kieselguhr, Ratproof agent 14 parts, anti-termite agent.Cable of the present invention adds special Ratproof agent and anti-termite agent in protective cover material, can destroy by rat-and-ant proof.Protective cover material formula also has fire protecting performance grade excellent, pressure height, length in service life, protection against the tide, anticorrosion, wear-resisting advantage simultaneously.Especially MPS butadiene copolymer and the addition of modified amphibole powder, not only improve the pliability of oversheath;Also further enhance above-mentioned advantage.

Description

A kind of track traffic rat-and-ant proof trailing cable
Technical field
The present invention relates to a kind of track traffic rat-and-ant proof trailing cable, belong to technical field of electric wires and cables.
Background technology
Along with the development of modern social economy, electric wire purposes is more and more extensive, the varying environment property to electric wire Can require widely different.The external sheath layer of general cable, mainly based on functions such as insulation, high temperature resistant, rub resistances, but Mus , even all there is mouse or Coptotermes formosanus Shtrari. animal damage electric wire in general work-at-home place in class or the area of Coptotermes formosanus Shtrari. animal activity wildness The problem of cable, has buried potential safety hazard to people's life.
Summary of the invention
It is an object of the present invention to provide a kind of track traffic rat-and-ant proof trailing cable, it has the same of rat-and-ant proof destruction Time, also there is fire protecting performance grade excellent, pressure height, length in service life, protection against the tide, anticorrosion, wear-resisting advantage.
The solution of the present invention is as follows: a kind of track traffic rat-and-ant proof trailing cable, including conductor, insulating barrier, belting layer, Embossing restrictive coating and external sheath layer, set gradually insulating barrier, belting layer, embossing restrictive coating and external sheath layer outside described conductor; Described external sheath layer is prepared from by following raw material:
Polyethylene 160-180 part, polrvinyl chloride 22-30 part, MPS butadiene copolymer 10-15 part, pentadiene 5-10 part, isocyanatoethyl 5-10 part, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 12-18 part, 2-acrylic acid oxo two-2,1-ethyl 8-15 part, 2-naphthylamines-1,5-disulfonic acid sodium salt 4-11 part, benzothiophene-2-boric acid 0.2-0.8 part, nano calcium oxide 4-10 part, zinc stearate 2-6 part, magnesium hydroxide 4-8 part, trihydroxy polypropylene oxide ether 6-9 Part, white carbon black 1-5 part, tetren 4-8 part, sorbitan tristearate 4-12 part, polyether modified silicon oil 1-3 part, modification Amphibole powder 22-25 part, kieselguhr 12-17 part, Ratproof agent 1-4 part, anti-termite agent 1-4 part;
Described MPS butadiene copolymer is prepared by following methods: by polystyrenebutadienes copolymer 25- 30g, vinyl acetate 10-15g, pyroterebic acid 2-3g stir 2-3 hour at 122-128 DEG C;It is subsequently adding polyamides Polyimide resin 12-15g and attapulgite clay 3-6g stirs 4-5 hour at 136-138 DEG C;It is eventually adding γ-mercapto propyl group three ethoxy Base silane 1.8-3.6g, trihydroxy polypropylene oxide ether 2-4g, TSIM 0.6-1.5g and dimethyl-octa two imidic acid Ester dihydrochloride 2-4g stirs reaction 1-2 hour at 180-185 DEG C, obtains MPS butadiene copolymer;
Described anti-termite agent is that Synthetic Capsaicin, tricyclazole, prallethrin form by the weight ratio of 1:1.6:0.22 is compounding;
Described Ratproof agent be Synthetic Capsaicin, n-nonanoic acid vanillyl amide, prallethrin, rich d-trans cyphenothrin by 1:0.2: The weight ratio of 0.15:0.3 is compounding to be formed.
Further, described external sheath layer is prepared from by following raw material:
Polyethylene 172 parts, polrvinyl chloride 26 parts, MPS butadiene copolymer 12 parts, pentadiene 7 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 8 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 16 parts, 2-acrylic acid oxo two-2,1- Ethyl 12 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 5 parts, benzothiophene-2-boric acid 0.4 part, nano calcium oxide 4-10 part, hard 3 parts of ester acid zinc, 6 parts of magnesium hydroxide, 7 parts of trihydroxy polypropylene oxide ether, white carbon black 4 parts, tetren 5 parts, sorbitol anhydride Stearate 10 parts, polyether modified silicon oil 2 parts, modified 28 parts of amphibole powder, 15 parts of kieselguhr, Ratproof agent 2 parts, anti-termite agent 3 parts;
Further, described external sheath layer is prepared from by following raw material:
Polyethylene 162 parts, polrvinyl chloride 24 parts, MPS butadiene copolymer 13 parts, pentadiene 9 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 6 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 15 parts, 2-acrylic acid oxo two-2,1- Ethyl 12 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 8 parts, benzothiophene-2-boric acid 0.7 part, nano calcium oxide 4 parts, stearic acid 6 parts of zinc, 5 parts of magnesium hydroxide, 8 parts of trihydroxy polypropylene oxide ether, tetren 6 parts, sorbitan tristearate 7 parts, Polyether modified silicon oil 1.6 parts, modified 25 parts of amphibole powder, 14 parts of kieselguhr, Ratproof agent 1 part, anti-termite agent 4 parts;
Further, described external sheath layer is prepared from by following raw material: polyethylene 178 parts, polrvinyl chloride 24 parts, change Property polystyrenebutadienes copolymer 13 parts, pentadiene 6 parts, isocyanatoethyl 8 parts, 3-(2-aminoethyl) Hydroxypropyl methyl dimethoxysilane 14 parts, 2-acrylic acid oxo two-2,1-ethyl 15 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 10 parts, benzothiophene-2-boric acid 0.3 part, nano calcium oxide 7 parts, zinc stearate 5 parts, 7 parts of magnesium hydroxide, trihydroxy polyoxygenated 6 parts of propylene ether, white carbon black 3 parts, tetren 6 parts, sorbitan tristearate 8 parts, polyether modified silicon oil 2.9 parts, modification 5 parts of amphibole powder, 12 parts of kieselguhr, Ratproof agent 3 parts, anti-termite agent 4 parts;
Further, described modified amphibole powder is prepared by following methods: by amphibole 30-40g, calcite 5-10g at 620-630 DEG C Lower calcining 4-5 hour, pulverizes, pulverizes;Soak 5-6 hour with 10-15% hydrogen peroxide solution, deionized water wash, dry; Be subsequently adding 0.2-0.6g dCTP sodium salt, 0.3-0.5g castor oil acid ethyl ester, 0.1-0.6g butyl, 0.12-0.55g Triallyl isocyanurate, 3000-4000 rev/min, stir 1-2h under the conditions of 45-55 DEG C, cold But, dry, to obtain final product.
Cable of the present invention adds special Ratproof agent and anti-termite agent in protective cover material, can destroy by rat-and-ant proof.Protective cover material simultaneously Formula also has fire protecting performance grade excellent, pressure height, length in service life, protection against the tide, anticorrosion, wear-resisting advantage.Especially modified Polystyrenebutadienes copolymer and the addition of modified amphibole powder, not only improve the pliability of oversheath;Strengthen the most further Above-mentioned advantage.
Detailed description of the invention
Prepared by MPS butadiene copolymer
Polystyrenebutadienes copolymer 28g, vinyl acetate 12g, pyroterebic acid 2.6g are stirred at 122-128 DEG C Mix 2-3 hour;It is subsequently adding polyamide 14g and attapulgite clay 5g to stir 4-5 hour at 136-138 DEG C;Finally add Enter gamma-mercaptopropyltriethoxysilane 2.9g, trihydroxy polypropylene oxide ether 2.6g, TSIM 1.1g and dimethyl-octa Two imino-ester dihydrochloride 2.7g stir reaction 1-2 hour at 180-185 DEG C, obtain MPS butadiene altogether Polymers;.
Prepared by modified amphibole powder
Amphibole 33g, calcite 8g are calcined 4-5 hour at 620-630 DEG C, pulverizes, pulverize;Use 10-15% hydrogen peroxide Solution soaking 5-6 hour, deionized water wash, dry;It is subsequently adding 0.47g dCTP sodium salt, 0.46g Oleum Ricini Acetoacetic ester, 0.5g butyl, 0.41g Triallyl isocyanurate, at 3000-4000 rev/min, 45-55 DEG C Under the conditions of stir 1-2h, cool down, dry, to obtain final product.
Anti-termite agent is that Synthetic Capsaicin, tricyclazole, prallethrin form by the weight ratio of 1:1.6:0.22 is compounding.
Ratproof agent be Synthetic Capsaicin, n-nonanoic acid vanillyl amide, prallethrin, rich d-trans cyphenothrin by 1:0.2: The weight ratio of 0.15:0.3 is compounding to be formed.
Embodiment 1
A kind of track traffic rat-and-ant proof trailing cable, including conductor, insulating barrier, belting layer, embossing restrictive coating and external sheath layer, Insulating barrier, belting layer, embossing restrictive coating and external sheath layer is set gradually outside conductor;External sheath layer is prepared by following raw material Form:
Polyethylene 172 parts, polrvinyl chloride 26 parts, MPS butadiene copolymer 12 parts, pentadiene 7 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 8 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 16 parts, 2-acrylic acid oxo two-2,1- Ethyl 12 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 5 parts, benzothiophene-2-boric acid 0.4 part, nano calcium oxide 4-10 part, hard 3 parts of ester acid zinc, 6 parts of magnesium hydroxide, 7 parts of trihydroxy polypropylene oxide ether, white carbon black 4 parts, tetren 5 parts, sorbitol anhydride Stearate 10 parts, polyether modified silicon oil 2 parts, modified 28 parts of amphibole powder, 15 parts of kieselguhr, Ratproof agent 2 parts, anti-termite agent 3 parts;
External sheath layer preparation method for material is as follows: after each raw material mix and blend, sends into extruding pelletization in extruder, air-dries, for often Rule method.
Cable is prepared by conventional method.
Embodiment 2
A kind of track traffic rat-and-ant proof trailing cable, including conductor, insulating barrier, belting layer, embossing restrictive coating and external sheath layer, Insulating barrier, belting layer, embossing restrictive coating and external sheath layer is set gradually outside conductor;External sheath layer is prepared by following raw material Form:
Polyethylene 162 parts, polrvinyl chloride 24 parts, MPS butadiene copolymer 13 parts, pentadiene 9 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 6 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 15 parts, 2-acrylic acid oxo two-2,1- Ethyl 12 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 8 parts, benzothiophene-2-boric acid 0.7 part, nano calcium oxide 4 parts, stearic acid 6 parts of zinc, 5 parts of magnesium hydroxide, 8 parts of trihydroxy polypropylene oxide ether, tetren 6 parts, sorbitan tristearate 7 parts, Polyether modified silicon oil 1.6 parts, modified 25 parts of amphibole powder, 14 parts of kieselguhr, Ratproof agent 1 part, anti-termite agent 4 parts;
External sheath layer preparation method for material is as follows: after each raw material mix and blend, sends into extruding pelletization in extruder, air-dries, for often Rule method.
Cable is prepared by conventional method.
Embodiment 3
A kind of track traffic rat-and-ant proof trailing cable, including conductor, insulating barrier, belting layer, embossing restrictive coating and external sheath layer, Insulating barrier, belting layer, embossing restrictive coating and external sheath layer is set gradually outside conductor;External sheath layer is prepared by following raw material Form:
Polyethylene 178 parts, polrvinyl chloride 24 parts, MPS butadiene copolymer 13 parts, pentadiene 6 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 8 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 14 parts, 2-acrylic acid oxo two-2,1- Ethyl 15 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 10 parts, benzothiophene-2-boric acid 0.3 part, nano calcium oxide 7 parts, hard ester 5 parts of zinc of acid, 7 parts of magnesium hydroxide, 6 parts of trihydroxy polypropylene oxide ether, white carbon black 3 parts, tetren 6 parts, sorbitol anhydride are hard Fat acid ester 8 parts, polyether modified silicon oil 2.9 parts, modified 5 parts of amphibole powder, 12 parts of kieselguhr, Ratproof agent 3 parts, anti-termite agent 4 parts;
External sheath layer preparation method for material is as follows: after each raw material mix and blend, sends into extruding pelletization in extruder, air-dries, for often Rule method.
Cable is prepared by conventional method.
Comparative example 1
It is with at embodiment 1 difference, without MPS butadiene copolymer in restrictive coating.
Comparative example 2
It is with at embodiment 1 difference, restrictive coating does not contains modified amphibole powder.
Comparative example 3
It is with at embodiment 1 difference, restrictive coating does not contains MPS butadiene copolymer and modified amphibole powder.
Sheath layered material performance in above-described embodiment 1-3 is as shown in Table 1.
Table one
Test event Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1 Comparative example 2 Comparative example 3 Common cable sheath layered material
Oxygen index (OI) (%) 41.1 40.2 40.3 36.7 37.6 35.1 32.5
200 DEG C of heat-stable times (min) 251 244 240 210 203 178 133
The cable performance of above-described embodiment 1-3 gained is as shown in Table 2.
Table two
Test event Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1 Comparative example 2 Comparative example 3 Common cable
Hot strength (Mpa) 16.8 16.2 15.8 14.2 14.1 12.9 11
Elongation at break (%) 486 472 479 418 420 366 320
Whether by GB/T19666 fire retardancy test It is It is It is It is It is It is It is
Although above the detailed description of the invention to the present invention give detailed description and explanation, but it should be noted that we According to the conception of the present invention, above-mentioned embodiment can be carried out various equivalence to change and amendment, produced by it, function is still Without departing from description contained spiritual time, all should be within protection scope of the present invention.

Claims (5)

1. a track traffic rat-and-ant proof trailing cable, including conductor, insulating barrier, belting layer, embossing restrictive coating and oversheath Layer, it is characterised in that set gradually insulating barrier, belting layer, embossing restrictive coating and external sheath layer outside described conductor;
Described external sheath layer is prepared from by following raw material:
Polyethylene 160-180 part, polrvinyl chloride 22-30 part, MPS butadiene copolymer 10-15 part, pentadiene 5-10 part, isocyanatoethyl 5-10 part, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 12-18 part, 2-acrylic acid oxo two-2,1-ethyl 8-15 part, 2-naphthylamines-1,5-disulfonic acid sodium salt 4-11 part, benzothiophene-2-boric acid 0.2-0.8 part, nano calcium oxide 4-10 part, zinc stearate 2-6 part, magnesium hydroxide 4-8 part, trihydroxy polypropylene oxide ether 6-9 Part, white carbon black 1-5 part, tetren 4-8 part, sorbitan tristearate 4-12 part, polyether modified silicon oil 1-3 part, modification Amphibole powder 22-25 part, kieselguhr 12-17 part, Ratproof agent 1-4 part, anti-termite agent 1-4 part;
Described MPS butadiene copolymer is prepared by following methods:
By polystyrenebutadienes copolymer 25-30g, vinyl acetate 10-15g, pyroterebic acid 2-3g at 122-128 Stir 2-3 hour at DEG C;It is subsequently adding polyamide 12-15g and attapulgite clay 3-6g at 136-138 DEG C, stirs 4-5 Hour;It is eventually adding gamma-mercaptopropyltriethoxysilane 1.8-3.6g, trihydroxy polypropylene oxide ether 2-4g, trimethyl silicane miaow Azoles 0.6-1.5g and dimethyl-octa two imino-ester dihydrochloride 2-4g stirs reaction 1-2 hour at 180-185 DEG C, obtains MPS butadiene copolymer;
Described anti-termite agent is that Synthetic Capsaicin, tricyclazole, prallethrin form by the weight ratio of 1:1.6:0.22 is compounding;
Described Ratproof agent be Synthetic Capsaicin, n-nonanoic acid vanillyl amide, prallethrin, rich d-trans cyphenothrin by 1:0.2: The weight ratio of 0.15:0.3 is compounding to be formed.
A kind of track traffic rat-and-ant proof trailing cable the most according to claim 1, it is characterised in that described oversheath Layer is prepared from by following raw material:
Polyethylene 172 parts, polrvinyl chloride 26 parts, MPS butadiene copolymer 12 parts, pentadiene 7 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 8 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 16 parts, 2-acrylic acid oxo two-2,1- Ethyl 12 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 5 parts, benzothiophene-2-boric acid 0.4 part, nano calcium oxide 4-10 part, hard 3 parts of ester acid zinc, 6 parts of magnesium hydroxide, 7 parts of trihydroxy polypropylene oxide ether, white carbon black 4 parts, tetren 5 parts, sorbitol anhydride Stearate 10 parts, polyether modified silicon oil 2 parts, modified 28 parts of amphibole powder, 15 parts of kieselguhr, Ratproof agent 2 parts, anti-termite agent 3 parts.
A kind of track traffic rat-and-ant proof trailing cable the most according to claim 1, it is characterised in that described oversheath Layer is prepared from by following raw material:
Polyethylene 162 parts, polrvinyl chloride 24 parts, MPS butadiene copolymer 13 parts, pentadiene 9 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 6 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 15 parts, 2-acrylic acid oxo two-2,1- Ethyl 12 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 8 parts, benzothiophene-2-boric acid 0.7 part, nano calcium oxide 4 parts, stearic acid 6 parts of zinc, 5 parts of magnesium hydroxide, 8 parts of trihydroxy polypropylene oxide ether, tetren 6 parts, sorbitan tristearate 7 parts, Polyether modified silicon oil 1.6 parts, modified 25 parts of amphibole powder, 14 parts of kieselguhr, Ratproof agent 1 part, anti-termite agent 4 parts.
A kind of track traffic rat-and-ant proof trailing cable the most according to claim 1, it is characterised in that described oversheath Layer is prepared from by following raw material:
Polyethylene 178 parts, polrvinyl chloride 24 parts, MPS butadiene copolymer 13 parts, pentadiene 6 parts, methyl-prop Olefin(e) acid isocyano group ethyl ester 8 parts, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 14 parts, 2-acrylic acid oxo two-2,1- Ethyl 15 parts, 2-naphthylamines-1,5-disulfonic acid sodium salt 10 parts, benzothiophene-2-boric acid 0.3 part, nano calcium oxide 7 parts, hard ester 5 parts of zinc of acid, 7 parts of magnesium hydroxide, 6 parts of trihydroxy polypropylene oxide ether, white carbon black 3 parts, tetren 6 parts, sorbitol anhydride are hard Fat acid ester 8 parts, polyether modified silicon oil 2.9 parts, modified 5 parts of amphibole powder, 12 parts of kieselguhr, Ratproof agent 3 parts, anti-termite agent 4 parts.
5. according to the arbitrary described a kind of track traffic rat-and-ant proof trailing cable of claim 1-4, it is characterised in that described Modified amphibole powder is prepared by following methods:
Amphibole 30-40g, calcite 5-10g are calcined 4-5 hour at 620-630 DEG C, pulverizes, pulverize;Use 10-15% Hydrogen peroxide solution soaks 5-6 hour, deionized water wash, dries;
It is subsequently adding 0.2-0.6g dCTP sodium salt, 0.3-0.5g castor oil acid ethyl ester, 0.1-0.6g diethylene glycol Butyl ether, 0.12-0.55g Triallyl isocyanurate, 3000-4000 rev/min, stir 1-under the conditions of 45-55 DEG C 2h, cools down, dries, to obtain final product.
CN201610573746.0A 2016-07-21 2016-07-21 A kind of track traffic rat-and-ant proof trailing cable Pending CN106128593A (en)

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CN105111596A (en) * 2015-08-26 2015-12-02 安徽电缆股份有限公司 Cable insulating material used in harsh environment of third generation nuclear power plant and preparation method of cable insulating material
CN105694313A (en) * 2016-04-26 2016-06-22 隋东阳 Cable sheath basic material preventing mouse and ant biting and making method thereof

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CN102161793A (en) * 2011-03-07 2011-08-24 黑龙江省润特科技有限公司 Ultraviolet deep-crosslinked expansion flame-retardant polyolefine cable material, and preparation method of insulating or jacket layer thereof
CN104861333A (en) * 2014-12-29 2015-08-26 殷培花 High impact resistance and high fluidity polyvinyl chloride cable material
CN105111596A (en) * 2015-08-26 2015-12-02 安徽电缆股份有限公司 Cable insulating material used in harsh environment of third generation nuclear power plant and preparation method of cable insulating material
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107907951A (en) * 2017-12-01 2018-04-13 钱理 A kind of protection against rodents indoor optical-fibre jacket material and preparation method thereof
CN107907951B (en) * 2017-12-01 2019-11-15 国网湖北省电力有限公司荆门供电公司 A kind of protection against rodents indoor optical-fibre jacket material and preparation method thereof

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