CN106119646A - A kind of boiler tube and processing technology thereof - Google Patents

A kind of boiler tube and processing technology thereof Download PDF

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Publication number
CN106119646A
CN106119646A CN201610681551.8A CN201610681551A CN106119646A CN 106119646 A CN106119646 A CN 106119646A CN 201610681551 A CN201610681551 A CN 201610681551A CN 106119646 A CN106119646 A CN 106119646A
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China
Prior art keywords
boiler tube
temperature
cooled
vacuum
caesium
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Pending
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CN201610681551.8A
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Chinese (zh)
Inventor
赵凯东
杨国娟
刘杰
王通
叶元华
郑琰
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Zhejiang Tuff Boiler Co Ltd
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Zhejiang Tuff Boiler Co Ltd
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Priority to CN201610681551.8A priority Critical patent/CN106119646A/en
Publication of CN106119646A publication Critical patent/CN106119646A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a kind of boiler tube and processing technology thereof, described boiler tube, by weight percentage, barium 7.2 11.0%, molybdenum 5.9 9.1%, caesium 5.1 8.0%, lithium 2.1 2.6%, lead 1.5 1.9%, aluminum 0.8 1.6%, boron 0.05 0.09%, carbon 0.03 0.08%, ferrum 0.001 0.003%, nickel 0.001 0.003%, magnesium is surplus.The present invention prepares a kind of high-performance boiler tube material with higher-strength, hardness, has light weight, anti abrasive advantage simultaneously, and has excellent anticorrosive, can meet the prescription of boiler tube.

Description

A kind of boiler tube and processing technology thereof
Technical field
The present invention relates to a kind of technical field of alloy, specifically a kind of boiler tube and processing technology thereof.
Background technology
Alloy has that density is little, specific strength and specific stiffness is high, heat-conductivity conducting performance is good, damping vibration attenuation, electromagnetic shielding, be prone to The advantages such as machine-shaping, waste material easily recovery, have important in fields such as automobile, electronic communication, Aero-Space and national defense and military Using value, be referred to as 21 century " green engineering material ".Alloy has that density is little, specific strength and specific stiffness is high, heat conduction is led The advantages such as good electrical property, damping vibration attenuation, electromagnetic shielding, easily processed into type, waste material easily recovery, in automobile, electronic communication, boat The empty field such as space flight and national defense and military has important using value, is referred to as 21 century " green engineering material ".
And boiler is as the important equipment of heating power industry, therefore it is badly in need of a kind of boiler tube of research and development.
Summary of the invention
It is an object of the invention to provide a kind of boiler tube and processing technology thereof, to solve proposition in above-mentioned background technology Problem.
For achieving the above object, the present invention provides following technical scheme:
A kind of boiler tube, by weight percentage, barium 7.2-11.0%, molybdenum 5.9-9.1%, caesium 5.1-8.0%, lithium 2.1- 2.6%, lead 1.5-1.9%, aluminum 0.8-1.6%, boron 0.05-0.09%, carbon 0.03-0.08%, ferrum 0.001-0.003%, nickel 0.001-0.003%, magnesium is surplus.
As the further scheme of the present invention: by weight percentage, barium 8.4-10.0%, molybdenum 7.2-8.5%, caesium 6.3- 7.5%, lithium 2.1-2.6%, lead 1.5-1.9%, aluminum 0.8-1.6%, boron 0.05-0.09%, carbon 0.03-0.08%, ferrum 0.001-0.003%, nickel 0.001-0.003%, magnesium is surplus.
As the further scheme of the present invention: by weight percentage, barium 9.2%, molybdenum 8.1%, caesium 6.9%, lithium 2.5%, lead 1.7%, aluminum 1.1%, boron 0.06%, carbon 0.06%, ferrum 0.002%, nickel 0.002%, magnesium is surplus.
The processing technology of a kind of boiler tube, concretely comprises the following steps:
(1) first, putting in vacuum medium frequency induction furnace by above-mentioned material by weight, smelting temperature is 1045-1100 DEG C, molten The refining time is 25-37min, and then, decompression heats up after being cooled to 10 DEG C, and temperature improves 100 DEG C every 10min, until warm Degree brings up to 1300 DEG C;
(2) then, at 810 DEG C, carry out constant temperature burn casting, keep 10 DEG C of speed per second to lower the temperature when burning casting, be cooled to 240℃;
(3) then, under nitrogen atmosphere, carrying out Quenching Treatment, hardening heat is 600 DEG C, and the process time is 11min, quenches After fire terminates, it is 0.1 × 10 in vacuum-3MPa borehole cooling, is reduced to temperature 600 DEG C, obtains melting solid;
(4) last, casting mould will be burnt at 270 DEG C, preheat 1h, subsequently the melting solid that step (3) obtains will be poured into preheating After burning casting mould in, be 0.1 × 10 in vacuum-3It is cooled to 25 DEG C under MPa, to obtain final product.
As the further scheme of the present invention: smelting temperature is 990 DEG C, smelting time is 32min.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention prepares a kind of high-performance boiler tubing with higher-strength, hardness by selecting specific formula Material, has light weight, anti abrasive advantage simultaneously, and has excellent anticorrosive, can meet the prescription of boiler tube.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the technical scheme of this patent is described in more detail.
Embodiment 1
A kind of boiler tube, by weight percentage, barium 7.2%, molybdenum 5.9%, caesium 5.1%, lithium 2.1%, lead 1.5%, aluminum 0.8%, boron 0.05%, carbon 0.03%, ferrum 0.001%, nickel 0.001%, magnesium is surplus.
The processing technology of a kind of boiler tube, concretely comprises the following steps:
(1) first, putting in vacuum medium frequency induction furnace by above-mentioned material by weight, smelting temperature is 1045 DEG C, during melting Between be 25min, then, decompression be cooled to 10 DEG C after heat up, temperature every 10min improve 100 DEG C, until temperature brings up to 1300℃;
(2) then, at 810 DEG C, carry out constant temperature burn casting, keep 10 DEG C of speed per second to lower the temperature when burning casting, be cooled to 240℃;
(3) then, under nitrogen atmosphere, carrying out Quenching Treatment, hardening heat is 600 DEG C, and the process time is 11min, quenches After fire terminates, it is 0.1 × 10 in vacuum-3MPa borehole cooling, is reduced to temperature 600 DEG C, obtains melting solid;
(4) last, casting mould will be burnt at 270 DEG C, preheat 1h, subsequently the melting solid that step (3) obtains will be poured into preheating After burning casting mould in, be 0.1 × 10 in vacuum-3It is cooled to 25 DEG C under MPa, to obtain final product.
Embodiment 2
A kind of boiler tube, by weight percentage, barium 8.4%, molybdenum 7.2%, caesium 6.3%, lithium 2.1%, lead 1.5%, aluminum 0.8%, boron 0.05%, carbon 0.03%, ferrum 0.001%, nickel 0.001%, magnesium is surplus.
The processing technology of a kind of boiler tube, concretely comprises the following steps:
(1) first, putting in vacuum medium frequency induction furnace by above-mentioned material by weight, smelting temperature is 1045 DEG C, during melting Between be 25min, then, decompression be cooled to 10 DEG C after heat up, temperature every 10min improve 100 DEG C, until temperature brings up to 1300℃;
(2) then, at 810 DEG C, carry out constant temperature burn casting, keep 10 DEG C of speed per second to lower the temperature when burning casting, be cooled to 240℃;
(3) then, under nitrogen atmosphere, carrying out Quenching Treatment, hardening heat is 600 DEG C, and the process time is 11min, quenches After fire terminates, it is 0.1 × 10 in vacuum-3MPa borehole cooling, is reduced to temperature 600 DEG C, obtains melting solid;
(4) last, casting mould will be burnt at 270 DEG C, preheat 1h, subsequently the melting solid that step (3) obtains will be poured into preheating After burning casting mould in, be 0.1 × 10 in vacuum-3It is cooled to 25 DEG C under MPa, to obtain final product.
Embodiment 3
A kind of boiler tube, by weight percentage, barium 9.2%, molybdenum 8.1%, caesium 6.9%, lithium 2.5%, lead 1.7%, aluminum 1.1%, boron 0.06%, carbon 0.06%, ferrum 0.002%, nickel 0.002%, magnesium is surplus.
The processing technology of a kind of boiler tube, concretely comprises the following steps:
(1) first, putting in vacuum medium frequency induction furnace by above-mentioned material by weight, smelting temperature is 990 DEG C, smelting time For 32min, then, decompression heats up after being cooled to 10 DEG C, and temperature improves 100 DEG C every 10min, until temperature brings up to 1300℃;
(2) then, at 810 DEG C, carry out constant temperature burn casting, keep 10 DEG C of speed per second to lower the temperature when burning casting, be cooled to 240℃;
(3) then, under nitrogen atmosphere, carrying out Quenching Treatment, hardening heat is 600 DEG C, and the process time is 11min, quenches After fire terminates, it is 0.1 × 10 in vacuum-3MPa borehole cooling, is reduced to temperature 600 DEG C, obtains melting solid;
(4) last, casting mould will be burnt at 270 DEG C, preheat 1h, subsequently the melting solid that step (3) obtains will be poured into preheating After burning casting mould in, be 0.1 × 10 in vacuum-3It is cooled to 25 DEG C under MPa, to obtain final product.
Embodiment 4
A kind of boiler tube, by weight percentage, barium 10.0%, molybdenum 8.5%, caesium 7.5%, lithium 2.6%, lead 1.9%, aluminum 1.6%, boron 0.09%, carbon 0.08%, ferrum 0.003%, nickel 0.003%, magnesium is surplus.
The processing technology of a kind of boiler tube, concretely comprises the following steps:
(1) first, putting in vacuum medium frequency induction furnace by above-mentioned material by weight, smelting temperature is 1100 DEG C, during melting Between be 37min, then, decompression be cooled to 10 DEG C after heat up, temperature every 10min improve 100 DEG C, until temperature brings up to 1300℃;
(2) then, at 810 DEG C, carry out constant temperature burn casting, keep 10 DEG C of speed per second to lower the temperature when burning casting, be cooled to 240℃;
(3) then, under nitrogen atmosphere, carrying out Quenching Treatment, hardening heat is 600 DEG C, and the process time is 11min, quenches After fire terminates, it is 0.1 × 10 in vacuum-3MPa borehole cooling, is reduced to temperature 600 DEG C, obtains melting solid;
(4) last, casting mould will be burnt at 270 DEG C, preheat 1h, subsequently the melting solid that step (3) obtains will be poured into preheating After burning casting mould in, be 0.1 × 10 in vacuum-3It is cooled to 25 DEG C under MPa, to obtain final product.
Embodiment 5
A kind of boiler tube, by weight percentage, barium 11.0%, molybdenum 9.1%, caesium 8.0%, lithium 2.6%, lead 1.9%, aluminum 1.6%, boron 0.09%, carbon 0.08%, ferrum 0.003%, nickel 0.003%, magnesium is surplus.
The processing technology of a kind of boiler tube, concretely comprises the following steps:
(1) first, putting in vacuum medium frequency induction furnace by above-mentioned material by weight, smelting temperature is 1100 DEG C, during melting Between be 37min, then, decompression be cooled to 10 DEG C after heat up, temperature every 10min improve 100 DEG C, until temperature brings up to 1300℃;
(2) then, at 810 DEG C, carry out constant temperature burn casting, keep 10 DEG C of speed per second to lower the temperature when burning casting, be cooled to 240℃;
(3) then, under nitrogen atmosphere, carrying out Quenching Treatment, hardening heat is 600 DEG C, and the process time is 11min, quenches After fire terminates, it is 0.1 × 10 in vacuum-3MPa borehole cooling, is reduced to temperature 600 DEG C, obtains melting solid;
(4) last, casting mould will be burnt at 270 DEG C, preheat 1h, subsequently the melting solid that step (3) obtains will be poured into preheating After burning casting mould in, be 0.1 × 10 in vacuum-3It is cooled to 25 DEG C under MPa, to obtain final product.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of the spirit or essential attributes of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter From the point of view of which point, all should regard embodiment as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all by fall in the implication of equivalency and scope of claim Change is included in the present invention.
Although moreover, it will be appreciated that this specification is been described by according to embodiment, but the most each embodiment only wraps Containing an independent technical scheme, this narrating mode of description is only that for clarity sake those skilled in the art should Description can also be formed those skilled in the art through appropriately combined as an entirety, the technical scheme in each embodiment May be appreciated other embodiments.

Claims (5)

1. a boiler tube, it is characterised in that by weight percentage, barium 7.2-11.0%, molybdenum 5.9-9.1%, caesium 5.1- 8.0%, lithium 2.1-2.6%, lead 1.5-1.9%, aluminum 0.8-1.6%, boron 0.05-0.09%, carbon 0.03-0.08%, ferrum 0.001-0.003%, nickel 0.001-0.003%, magnesium is surplus.
Boiler tube the most according to claim 1, it is characterised in that by weight percentage, barium 8.4-10.0%, molybdenum 7.2- 8.5%, caesium 6.3-7.5%, lithium 2.1-2.6%, lead 1.5-1.9%, aluminum 0.8-1.6%, boron 0.05-0.09%, carbon 0.03- 0.08%, ferrum 0.001-0.003%, nickel 0.001-0.003%, magnesium is surplus.
Boiler tube the most according to claim 1 and 2, it is characterised in that by weight percentage, barium 9.2%, molybdenum 8.1%, Caesium 6.9%, lithium 2.5%, lead 1.7%, aluminum 1.1%, boron 0.06%, carbon 0.06%, ferrum 0.002%, nickel 0.002%, magnesium is remaining Amount.
4. the processing technology of the boiler tube as described in claim 1-3 is arbitrary, it is characterised in that concretely comprise the following steps:
(1) first, putting in vacuum medium frequency induction furnace by above-mentioned material by weight, smelting temperature is 1045-1100 DEG C, during melting Between be 25-37min, then, decompression be cooled to 10 DEG C after heat up, temperature every 10min improve 100 DEG C, until temperature carries High to 1300 DEG C;
(2) then, at 810 DEG C, carry out constant temperature burn casting, keep 10 DEG C of speed per second to lower the temperature when burning casting, be cooled to 240 ℃;
(3) then, under nitrogen atmosphere, carrying out Quenching Treatment, hardening heat is 600 DEG C, and the process time is 11min, quenching knot Shu Hou, is 0.1 × 10 in vacuum-3MPa borehole cooling, is reduced to temperature 600 DEG C, obtains melting solid;
(4) last, casting mould will be burnt and at 270 DEG C, preheat 1h, after subsequently the melting solid that step (3) obtains being poured into preheating Burn in casting mould, be 0.1 × 10 in vacuum-3It is cooled to 25 DEG C under MPa, to obtain final product.
The processing technology of boiler tube the most according to claim 4, it is characterised in that smelting temperature is 990 DEG C, smelting time For 32min.
CN201610681551.8A 2016-08-17 2016-08-17 A kind of boiler tube and processing technology thereof Pending CN106119646A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101530869A (en) * 2008-03-14 2009-09-16 钱乐中 Process for manufacturing stainless-steel seamless steel pipe used for high-pressure boiler, boiler and heat-exchanger
CN101652489A (en) * 2007-04-03 2010-02-17 株式会社丰田自动织机 Heat-resistant magnesium alloy
CN103334056A (en) * 2013-03-25 2013-10-02 天津理工大学 High-Cr ferritic heat-resistant steel used for thermal power boiler tube and applications thereof
CN104233032A (en) * 2014-08-26 2014-12-24 盐城市鑫洋电热材料有限公司 Mg-Cd intensified magnesium-based alloy and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101652489A (en) * 2007-04-03 2010-02-17 株式会社丰田自动织机 Heat-resistant magnesium alloy
CN101530869A (en) * 2008-03-14 2009-09-16 钱乐中 Process for manufacturing stainless-steel seamless steel pipe used for high-pressure boiler, boiler and heat-exchanger
CN103334056A (en) * 2013-03-25 2013-10-02 天津理工大学 High-Cr ferritic heat-resistant steel used for thermal power boiler tube and applications thereof
CN104233032A (en) * 2014-08-26 2014-12-24 盐城市鑫洋电热材料有限公司 Mg-Cd intensified magnesium-based alloy and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《化工百科全书》编辑委员会: "《化工百科全书》", 31 January 2001, 化学工业出版社 *
В.В.克雷莫夫: "《镁合金的定型铸造》", 31 August 1956, 国防工业出版社 *
白素琴: "《金属学及热处理》", 31 July 2009, 冶金工业出版社 *

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