CN106118807A - A kind of environmental protection gear lubricant containing the additives such as Adeps Sus domestica at neopentyl polyol ester - Google Patents

A kind of environmental protection gear lubricant containing the additives such as Adeps Sus domestica at neopentyl polyol ester Download PDF

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Publication number
CN106118807A
CN106118807A CN201610467391.7A CN201610467391A CN106118807A CN 106118807 A CN106118807 A CN 106118807A CN 201610467391 A CN201610467391 A CN 201610467391A CN 106118807 A CN106118807 A CN 106118807A
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polyol ester
neopentyl polyol
sus domestica
adeps sus
npe
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CN201610467391.7A
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Inventor
陈卓君
吴净
周秋忠
邓维维
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Shenyang Ligong University
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Shenyang Ligong University
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Priority to CN201610467391.7A priority Critical patent/CN106118807A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32Esters
    • C10M105/38Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02Natural products
    • C10M159/08Fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)

Abstract

Neopentyl polyol ester (NPE 2) sulfur phosphoric acid nitrogen containing derivative (T305), benzotriazole fatty amine salt (T406E), Keywords dibutyl dithiocarbamate (Rc6340), Adeps Sus domestica cd 1 make by evenly mixing.Its formula is: neopentyl polyol ester (NPE 2) sulfur phosphoric acid nitrogen containing derivative (T305): 0 3%, benzotriazole fatty amine salt (T406E) 0 0.81%, Keywords dibutyl dithiocarbamate (Rc6340): 0 0.189%, Adeps Sus domestica cd 1:0 0.54%, the present invention has the most wear-resistant and load-carrying properties.

Description

A kind of environmental protection gear lubricant containing the additives such as Adeps Sus domestica at neopentyl polyol ester
Technical field
The present invention relates to technical field of lubricating oil, particularly relate to a kind of environmental protection gear lubricant.
Background technology
Sulfur phosphoric acid nitrogen containing derivative (T305), benzotriazole fat is added in artificial oil neopentyl polyol ester (NPE-2) Amine salt (T-406E), Keywords dibutyl dithiocarbamate (RC6340), Adeps Sus domestica cd-1 carry out proportioning, use ANN Network method optimization calculates, and has carried out cumulative evidence.Owing to containing sulfur P elements, therefore carrying up to 1323N, its deficiency is because containing There is more sulfur, have certain corrosivity.
The content adding four kinds of additives in neopentyl polyol ester (NPE-2) base oil joins employing optimization design. In neopentyl polyol ester NPE-2 add sulfur phosphoric acid nitrogen containing derivative (T305), benzotriazole fatty amine salt (T-406E), two Butyl dithiocarbamate (RC6340), Adeps Sus domestica cd-1.T305:0-3%, T406E:0-0.81%, Rc6340: 0- 0.189%, Adeps Sus domestica cd-1:0-0.54%, maximum nonseizure load Pb are 1323N,=0.39mm,=0.35mm.
Selecting oil based on neopentyl polyol ester, lube oil additive chooses benzotriazole fatty amine salt (T-406E), dibutyl two Thiocarbamate (RC6340), sulfur phosphoric acid nitrogen containing derivative (T305), phosphordithiic acid amine salt (T307) research use 4 because of Element 11 horizontal checkouts.Investigation target is Y1=Pb,Y2=,Y3=, use uniform designs table arrangement test, test knot Really, research is applied to additive tribology research in biodegradable base oil in artificial oil, and base oil neopentyl is polynary Alcohol ester (Neopentyl Polyol Ester) NPE-2 is that in molecular structure, ester group ortho position is a class synthetic ester of quaternary carbon atom, Than dibasic acid esters, there is more excellent heat and hydrolytic stability.NPE-2, neopentyl polyol ester has excellent high and low temperature performance, dodges Point is high, and pour point is low, relatively low 40 DEG C of its viscosity, is typically commonly used for II type aviation engine oil, high-temperature chain oil, synthesis of air pressure The base oil of the refrigerator oil that contracting machine oil environmental protection refrigerant therewith is compatible, it is possible to make rubber shrink and to additive with poly-1-olefin The defect that the compatibility is bad.Base oil as internal combustion engine gear oil.
NPE-2 is particularly suitable for II type aviation engine oil.Its physicochemical property is shown in Table 1.
Keywords dibutyl dithiocarbamate (RC6340) RC6340 is Ashless type additive, have both simultaneously extreme pressure with Two kinds of wear-resistant performances, RC6340 is extreme pressure, wear-resistant, antioxygen and ashless multifunction additive, and component is methylene one or two fourth Base dithio ammonia 4.3, main investigate additive compounding after lubricants performance.
Keywords dibutyl dithiocarbamate, its sulfur content accounts for 30%(w) it is mainly used in hydraulic oil and industrial gear oil's work For wear-resistant and antioxygen component.With the performance that inactive additive compound tense can optimize hydraulic oil and industrial gear oil, dibutyl Dithio Methanamide (RC6340) physicochemical property is shown in Table 2.
T406E multifunction additive properties of product benzotriazole fatty amine salt (T-406) tool oil, grease etc., more than 20 plant Lubricating oil, fat are succeeded application.Name as HL-T406E.Rated this new additive agent is flow fluid at normal temperatures Body, oil-soluble is good, not only has the function of T406 additive, its copper corruption supression property, the anti-colloidality of rust-preventing characteristic, antioxygen and carrying Ability is all better than the regeneration product that T406, HL-T406E are T406, and its physics and chemistry is shown in Table 3.
The multiple ester amine salt extreme-pressure anti-friction additive of sulfur phosphorus nitrogen containing derivative T305 sulfur phosphorus is that a kind of sulfur is for the multiple ester amine salt type tooth of phosphorus Wheel lube oil additive, has excellent extreme pressure property, wear resistence and higher chemical stability.For preparing heavy duty automobile tooth Wheel oil, sulfur phosphorus nitrogen containing derivative T305 table 4.
Liquid lard oil cd-1: oiliness additive is to be formed by Corii Sus domestica and Adeps Sus domestica are refined, and yellow oily liquid is soluble in ethers Solvent, in molecule, ester group is prone to metal surface and forms oriented adsorption layer, improves greasy property, reduces the degree of wear, it is adaptable to roll Liquefaction and the allotment of Metal Cutting oil, it is possible to being combined with emulsifying agent, configure oil emulsion, semi-synthetic liquid, Adeps Sus domestica cd-1 is galloped by Shanghai Moral trade Co., Ltd provides.The physicochemical property of liquid lard oil cd-1 sees attached list 5.
Sulfur phosphoric acid nitrogen containing derivative (T305), benzotriazole fatty amine salt (T-is added in neopentyl polyol ester (NPE-2) 406E), Keywords dibutyl dithiocarbamate (RC6340), Adeps Sus domestica cd-1, sulfur phosphoric acid nitrogen containing derivative (T305): 0-3%, benzene Triazole fatty amine salt (T406E) 0-0.81%, Keywords dibutyl dithiocarbamate (Rc6340): 0-0.189%, Adeps Sus domestica cd- 1:0-0.54%, 4 factor 11 levels, make Pb value and long mill value, Pb maximum 1323N, long mill value:=0.39mm,=0.35mm
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of has excellent high/low temperature load-carrying properties, pressure wear resistence Can, meet neopentyl polyol ester (NPE-2) gear lubricant of various automotive gearbox lubrication.
The technical scheme is that
A kind of lubricating oil containing the additives such as Adeps Sus domestica at neopentyl polyol ester, adds in neopentyl polyol ester (NPE-2) Add sulfur phosphoric acid nitrogen containing derivative (T305), benzotriazole fatty amine salt (T-406E), Keywords dibutyl dithiocarbamate (RC6340), Adeps Sus domestica cd-1, sulfur phosphoric acid nitrogen containing derivative (T305): 0-3%, benzotriazole fatty amine salt (T406E) 0-0.81%, Keywords dibutyl dithiocarbamate (Rc6340): 0-0.189%, Adeps Sus domestica cd-1:0-0.54%, through mix homogeneously system after heating Become.
Its formula is:
The following substances accounting for neopentyl polyol ester percentage ratio is added: sulfur phosphoric acid is nitrogenous in neopentyl polyol ester (NPE-2) Derivant (T305): 0-3%;Benzotriazole fatty amine salt (T406E) 0-0.81%;Keywords dibutyl dithiocarbamate (Rc6340 ):0-0.189%;Adeps Sus domestica cd-1:0-0.54%.
Have an advantage in that:
The present invention has neopentyl polyol ester (NPE-2) greasy property, and bearing capacity height is improved, and has the most wear-resistant And load-carrying properties.
Detailed description of the invention
Embodiment one
A kind of lubricating oil containing the additives such as Adeps Sus domestica at neopentyl polyol ester (NPE-2), with neopentyl polyol ester (NPE- 2) oil adds and accounts for neopentyl polyol ester (NPE-2): lube oil additive formula selects sulfur phosphoric acid nitrogen containing derivative (T305): 0.3%, benzotriazole fatty amine salt (T406E) 0.45%, Keywords dibutyl dithiocarbamate (Rc6340): 0.489%, Adeps Sus domestica Cd-1:0.54%, stirs latter 80 DEG C and heats 40 minutes, to obtain final product.
So that neopentyl polyol ester (NPE-2) to add sulfur phosphoric acid nitrogen containing derivative (T305), benzotriazole fatty amine salt (T406E), Keywords dibutyl dithiocarbamate (Rc6340): Adeps Sus domestica cd-1: heated mix homogeneously is made.
Described neopentyl polyol ester (NPE-2) base ortho position is a class synthetic ester of quaternary carbon atom, more excellent than dibasic acid esters has Different heat and hydrolytic stability, mainly include DOPCP, trihydroxymethylpropanyl ester and pentaerythritol ester;
Embodiment two
A kind of lubricating oil containing the additives such as Adeps Sus domestica at neopentyl polyol ester (NPE-2), with neopentyl polyol ester (NPE- 2) it is that mixed base oil adds and accounts for neopentyl polyol ester and decanedioic acid different monooctyl ester percentage by weight: sulfur phosphorus with the different monooctyl ester of decanedioic acid Acid nitrogen containing derivative (T305): 1.8%, benzotriazole fatty amine salt (T406E): 0.81%, Keywords dibutyl dithiocarbamate (Rc6340): 0.021%, Adeps Sus domestica cd-1:0.06%, after mixing and stirring, 80 DEG C are heated 40 minutes, to obtain final product.
Embodiment three
A kind of lubricating oil containing the additives such as Adeps Sus domestica at neopentyl polyol ester, its formula is: at neopentyl polyol ester (NPE-2) the middle following substances accounting for neopentyl polyol ester percentage ratio that adds: sulfur phosphoric acid nitrogen containing derivative (T305): 0.1%;Benzene Triazole fatty amine salt (T406E): 0.1%;Keywords dibutyl dithiocarbamate (Rc6340): 0.1%;Adeps Sus domestica cd-1:0.1%.
Embodiment three
A kind of lubricating oil containing the additives such as Adeps Sus domestica at neopentyl polyol ester, its formula is: at neopentyl polyol ester (NPE-2) the middle following substances accounting for neopentyl polyol ester percentage ratio that adds: sulfur phosphoric acid nitrogen containing derivative (T305): 1.8%;Benzene Triazole fatty amine salt (T406E): 0.81%;Keywords dibutyl dithiocarbamate (Rc6340): 0.021%;Adeps Sus domestica cd-1: 0.06%。
Embodiment three
A kind of lubricating oil containing the additives such as Adeps Sus domestica at neopentyl polyol ester, its formula is: at neopentyl polyol ester (NPE-2) the middle following substances accounting for neopentyl polyol ester percentage ratio that adds: sulfur phosphoric acid nitrogen containing derivative (T305): 3%;Benzene three Azoles fatty amine salt (T406E) 0.81%;Keywords dibutyl dithiocarbamate (Rc6340): 0.189%;Adeps Sus domestica cd-1: 0.54%。
The physicochemical property of table 1 neopentyl polyol ester NPE-3
Table 2 Keywords dibutyl dithiocarbamate (RC6340) physicochemical property
Table 3 benzotriazole fatty amine salt (T406E)
The physicochemical property of table 4 sulfur phosphoric acid nitrogen containing derivative (T305)
Project Outward appearance Phosphorus content wt% Sulfur content wt% Nitrogen content % >= Flash-point DEG C
Quality index Yellow transparent oily liquids 5.5 10 1 150
The physicochemical property of table 5 liquid lard oil cd-1

Claims (1)

1. the lubricating oil containing the additives such as Adeps Sus domestica at neopentyl polyol ester, it is characterised in that: its formula is:
In neopentyl polyol ester (NPE-2), addition accounts for neopentyl polyol ester and accounts for the following substances of percentage ratio: sulfur phosphoric acid is nitrogenous Derivant (T305): 0-3%, benzotriazole fatty amine salt (T406E): 0-0.81%, Keywords dibutyl dithiocarbamate (Rc6340): 0-0.189%, Adeps Sus domestica cd-1:0-0.54%.
CN201610467391.7A 2016-06-24 2016-06-24 A kind of environmental protection gear lubricant containing the additives such as Adeps Sus domestica at neopentyl polyol ester Pending CN106118807A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113667525A (en) * 2021-08-09 2021-11-19 江苏国平油品科技有限公司 High-performance vacuum pump oil composition and preparation method thereof

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CN103409211A (en) * 2013-08-26 2013-11-27 陈卓君 Lubricating oil and preparation method thereof
CN103614195A (en) * 2013-11-26 2014-03-05 沈阳理工大学 Automobile gear lubricant
CN103756757A (en) * 2013-12-27 2014-04-30 沈阳理工大学 Synthetic automobile gear lubricating oil containing pentasulfide and animal oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103409211A (en) * 2013-08-26 2013-11-27 陈卓君 Lubricating oil and preparation method thereof
CN103614195A (en) * 2013-11-26 2014-03-05 沈阳理工大学 Automobile gear lubricant
CN103756757A (en) * 2013-12-27 2014-04-30 沈阳理工大学 Synthetic automobile gear lubricating oil containing pentasulfide and animal oil

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113667525A (en) * 2021-08-09 2021-11-19 江苏国平油品科技有限公司 High-performance vacuum pump oil composition and preparation method thereof

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