CN106118711A - A kind of railway gasoline entrucking oil-gas recovery processing device and technique - Google Patents

A kind of railway gasoline entrucking oil-gas recovery processing device and technique Download PDF

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Publication number
CN106118711A
CN106118711A CN201610741216.2A CN201610741216A CN106118711A CN 106118711 A CN106118711 A CN 106118711A CN 201610741216 A CN201610741216 A CN 201610741216A CN 106118711 A CN106118711 A CN 106118711A
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CN
China
Prior art keywords
oil
gas
processing device
recovery processing
railway
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610741216.2A
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Chinese (zh)
Inventor
丁书兵
卢分配
胡智超
张居超
韩永升
乔智愚
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Shandong Dongming Petrolem & Chemical Group Co Ltd
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Shandong Dongming Petrolem & Chemical Group Co Ltd
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Application filed by Shandong Dongming Petrolem & Chemical Group Co Ltd filed Critical Shandong Dongming Petrolem & Chemical Group Co Ltd
Priority to CN201610741216.2A priority Critical patent/CN106118711A/en
Publication of CN106118711A publication Critical patent/CN106118711A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G5/00Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
    • C10G5/06Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G5/00Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
    • C10G5/02Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas with solid adsorbents

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to Investigation of Petroleum Vapor Recovery Technology field, particularly to a kind of railway gasoline entrucking oil-gas recovery processing device.This railway gasoline entrucking oil-gas recovery processing device includes the gas holder being connected oil tank of train floss hole by collecting pipe, and this gas holder connection oil-gas recovery processing device, oil-gas recovery processing device connects gasoline tank.The invention has the beneficial effects as follows: its simple in construction, utilize existing separate unit petroleum vapor recovery processing equipment can meet railway GASOLINE VAPOR RECOVERY DURING TANK CAR LOADING and process needs, greatly reduce investment and energy consumption.

Description

A kind of railway gasoline entrucking oil-gas recovery processing device and technique
Technical field
The present invention relates to Investigation of Petroleum Vapor Recovery Technology field, particularly to a kind of railway gasoline entrucking oil-gas recovery processing device And technique.
Background technology
According to " storage tank farm atmosphere pollutants emission standards " (GB20960-2007) requirement, the oil gas produced during charge of oil should enter The airtight collection of row and process, efficiency of oil & gas processing >=95% of petroleum vapor recovery facility, concentration of oil and gas discharged≤25mg/m3
According to measuring and calculating, 1m3Concentration is 10%-40%(volume fraction) oil gas be mixed in air and can form 20m3Explosivity Gas, can pollute 6700m3Atmospheric environment, in substantial amounts of oil gas volatilization to air, to the ecological environment of the mankind, security context, strong Health environment causes hidden trouble.
At present, the domestic oil vapor treatment technique mainly taked is: the oil gas produced during charge of oil enters petroleum vapor recovery and processes dress Putting process, the oil gas after oil-gas recovery processing device liquefies returns to gasoline tank.Domestic existing oil-gas recovery processing device Disposal ability is typically at 100m3/h-500m3About/h, maximum 800m3/ h, when oil gas generation amount is 800m3During/more than h, by just Often entrucking situation, needs to arrange multiple stage oil-gas recovery processing device, and uses simultaneously, and it is higher that this results in investment, and energy consumption is bigger.
Summary of the invention
The present invention is in order to make up deficiencies of the prior art, and spy provides a kind of railway gasoline entrucking oil gas and returns Receive processing means and technique.
The present invention is achieved through the following technical solutions:
A kind of railway gasoline entrucking oil-gas recovery processing device, it is characterised in that: include and connect train by collecting pipe The gas holder of oil tank floss hole, this gas holder connection oil-gas recovery processing device, oil-gas recovery processing device connects gasoline tank.
The present invention is provided with gas holder between oil-gas recovery processing device and oil tank of train floss hole so that exceed during entrucking The oil gas of oil-gas recovery processing device disposal ability can be temporarily stored in gas holder, and during twice entrucking, device for recovering oil and gas can be held Continuous process reclaims oil gas.This with prior art (when oil gas generation amount higher than the disposal ability of separate unit oil-gas recovery processing device is, Use mode use simultaneously that multiple stage oil-gas recovery processing device is set) compare, there is small investment, advantage that energy consumption is low.
As more excellent technical scheme:
Above-mentioned gas holder uses double film gas holder, and gas holder external mold uses PVDF material, and gas holder inner membrance uses TPU material.
Caliber imported and exported by above-mentioned gas holder is DN250, between normal production period, operates temperature 20 DEG C, maximum temperature 40 DEG C, operation Pressure≤0.8kPa, the highest come throughput be 2500m3/ h, the highest throughput is 1000m3/h。
For meeting two row train continuous loading needs, the scale of above-mentioned gas holder is 5000m3, cabinet external diameter is 22.5m, cabinet Height is 17m;The outer film thickness of gas holder is 1.3mm, and stretching resistance is 6000N/5cm, and inner film thickness is 1.0mm, stretching resistance 4000N/ 5cm。
Above-mentioned device for recovering oil and gas uses condensation and adsorption combined technology manufacture, and condensation portion is B-grade condensation operating mode, inhales Attached dose uses activated carbon;Condensation method can effectively reduce the gas concentration of residual air after condensed in two stages, can reduce activated carbon dosage, and then Reduce absorbing unit volume.
The technique utilizing above-mentioned railway gasoline entrucking oil-gas recovery processing device to carry out petroleum vapor recovery process is as follows:
When oil article vehicle, first collected oil gas by the floss hole of oil tank of train and the oil gas of collection is introduced gas through collecting pipe Cabinet;
Then, oil-gas recovery processing device is the most balancedly aspirated oil gas and carries out liquefaction recycling from gas holder;
Finally, liquified petroleum is sent back to gasoline tank.
Between normal production period, the operation temperature of gas holder 20 DEG C, maximum temperature 40 DEG C, operate pressure≤0.8kPa, the highest Carrying out throughput is 2500m3/ h, the highest throughput is 1000m3/h。
Above-mentioned technique belongs to first Application at home, can greatly reduce equipment investment, it is ensured that system safety operation.
The invention has the beneficial effects as follows: its simple in construction, utilize existing separate unit petroleum vapor recovery processing equipment can meet ferrum Road GASOLINE VAPOR RECOVERY DURING TANK CAR LOADING processes to be needed, and greatly reduces investment and energy consumption.
Accompanying drawing explanation
The present invention is further illustrated below in conjunction with the accompanying drawings.
Fig. 1 is the structural representation of the present invention.
In figure, 1 oil tank of train, 2 gas holders, 3 oil-gas recovery processing device, 4 gasoline tanks.
Detailed description of the invention
Accompanying drawing 1 is a kind of specific embodiment of the present invention.
This embodiment be oil tank of train 1 floss hole by collecting pipe connect gas holder 2, gas holder connection petroleum vapor recovery at Reason device 3, oil-gas recovery processing device connects gasoline tank 4;Gas holder is double film gas holders, and the external mold of gas holder uses PVDF material, Inner membrance uses TPU material;Gas holder scale is 5000m3, cabinet external diameter 22.5m, cabinet height 17m;The outer film thickness of gas holder is 1.3mm, stretching resistance is 6000N/5cm, and inner film thickness is 1.0mm, stretching resistance 4000N/5cm.
During oil article vehicle, the oil gas collected from oil tank of train floss hole enters gas holder, and oil-gas recovery processing device is from gas holder Quantitatively equilibrium is aspirated oil gas and carries out liquefaction recycling, and liquified petroleum after treatment is transmitted back to gasoline tank again.
About double film gas holders:
Being computed, save train continuous loading needs (being spaced three hours) for meeting two row 60, gas holder construction scale is 5000m3, cabinet Body diameter 22.5m, cabinet height 17m;Gas holder adventitia uses PVDF material, thickness 1.3mm, stretching resistance 6000N/5cm, and inner membrance uses TPU material, thickness 1.0mm, stretching resistance 4000N/5cm.
Caliber imported and exported by gas holder is DN250, between normal production period, operates temperature 20 DEG C, the highest 40 DEG C;Operation pressure≤ 0.8kPa;The highest come throughput 2500m/h;The highest throughput 1000m/h.
About oil-gas recovery processing device:
Oil-gas recovery processing device uses the manufacture of condensation+adsorption combined technology.Condensation method is according to hydrocarbon components various in oil gas The response rate that the saturated vapour pressure of different temperatures, national legislation specify and exhaust emissions concentration limit, determine the temperature of condensing condition Degree, and reduce oil gas temperature according to the method for the packet of component thermo property parameters, zonal cooling cooling, make hydrocarbon vapours component reach To the hypersaturated state from gaseous state to liquid phase-change, thus directly obtain the fluid oil of recovery.Complete oil vapour pollution is administered Recycle with harmful substance resource.
According to oil gas composition and character, condensation portion uses B-grade condensation operating mode, i.e. condensation temperature to reach-60 DEG C, makes oil Gas contains the hydrocarbon component condensation liquefaction of C3 to C5;Adsorbent uses activated carbon.Processed by above, efficiency of oil & gas processing >= 95%, exhaust emissions concentration≤20g/m3
It is concluded that by production technology research
This technique uses existing single set oil-gas recovery processing device, can process 1000m3/ more than h oil and gas content, can meet gasoline ferrum Road entrucking needs;Project investment is less, and more conventional oil-gas recovery processing device reduces investment about 50%;Efficiency of oil & gas processing >= 95%, exhaust emissions concentration≤20g/m3, it is better than country to tank area gas concentration standard criterion requirement.
The present invention successfully utilizes gas holder+petroleum vapor recovery to process technique and achieves the process of gasoline railway entrucking petroleum vapor recovery, item Mesh investment is relatively low, and efficiency of oil & gas processing and exhaust emissions concentration are superior to national standard;In double film gas holders, membrane material belongs to domestic head Secondary application, has filled up domestic blank.
The success of this industrial applications research, fully demonstrates gas holder+petroleum vapor recovery and processes the feasibility of technique industrialization And the maturity of technology, the design for larger-scale commercial plant provides foundation, has established heavily fortified point for promoting this technology at home Real theoretical basis and Applied D emonstration.

Claims (9)

1. a railway gasoline entrucking oil-gas recovery processing device, it is characterised in that: include and connect fire by collecting pipe The gas holder (2) of car oil tank (1) floss hole, described gas holder connection oil-gas recovery processing device (3), described oil-gas recovery processing device Connect gasoline tank (4).
Railway gasoline entrucking oil-gas recovery processing device the most according to claim 1, it is characterised in that: described gas holder is double Film gas holder, gas holder external mold uses PVDF material, and gas holder inner membrance uses TPU material.
Railway gasoline entrucking oil-gas recovery processing device the most according to claim 1 or claim 2, it is characterised in that: described gas holder Scale is 5000m3, cabinet external diameter 22.5m, cabinet height 17m;The outer film thickness of gas holder is 1.3mm, and stretching resistance is 6000N/5cm, interior Film thickness is 1.0mm, stretching resistance 4000N/5cm.
Railway gasoline entrucking oil-gas recovery processing device the most according to claim 1, it is characterised in that: entering of described gas holder Outlet caliber is DN250, the maximum temperature of described gas holder 40 DEG C, operate pressure≤0.8kPa, the highest come throughput be 2500m3/ H, the highest throughput is 1000m3/h。
Railway gasoline entrucking oil-gas recovery processing device the most according to claim 1, it is characterised in that: described petroleum vapor recovery Processing means uses condensation+adsorption combined technology.
Railway gasoline entrucking oil-gas recovery processing device the most according to claim 5, it is characterised in that: described petroleum vapor recovery The condensation portion of processing means is B-grade condensation operating mode.
Railway gasoline entrucking oil-gas recovery processing device the most according to claim 5, it is characterised in that: described petroleum vapor recovery The adsorbent of processing means uses activated carbon.
8. according to any one of exploitation right 1-7, railway gasoline entrucking oil-gas recovery processing device carries out petroleum vapor recovery process Technique, it is characterised in that comprise the steps:
S1. collected oil gas by the floss hole of oil tank of train and the oil gas of collection is introduced gas holder through collecting pipe;
S2. oil-gas recovery processing device is the most balancedly aspirated oil gas and carries out liquefaction recycling from gas holder;
S3. liquified petroleum is sent back to gasoline tank.
Railway gasoline entrucking petroleum vapor recovery the most according to claim 8 processes technique, it is characterised in that: described gas holder exists Operation temperature between normal production period 20 DEG C, maximum temperature 40 DEG C, operate pressure≤0.8kPa, the highest come throughput be 2500m3/ h, the highest throughput is 1000m3/h。
CN201610741216.2A 2016-08-29 2016-08-29 A kind of railway gasoline entrucking oil-gas recovery processing device and technique Pending CN106118711A (en)

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CN201610741216.2A CN106118711A (en) 2016-08-29 2016-08-29 A kind of railway gasoline entrucking oil-gas recovery processing device and technique

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202279687U (en) * 2011-10-17 2012-06-20 中国石油化工股份有限公司 Oil-gas recovery device
CN105214439A (en) * 2015-09-14 2016-01-06 清本环保工程(杭州)有限公司 Oil-gas recovery processing device and method
CN204957454U (en) * 2015-08-17 2016-01-13 中石化洛阳工程有限公司 Storage tank vapor recovery system system
CN204957453U (en) * 2015-08-17 2016-01-13 中石化洛阳工程有限公司 Storage tank vapor recovery system system
CN204957452U (en) * 2015-08-17 2016-01-13 中石化洛阳工程有限公司 Fixed roof tank vapor recovery system system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202279687U (en) * 2011-10-17 2012-06-20 中国石油化工股份有限公司 Oil-gas recovery device
CN204957454U (en) * 2015-08-17 2016-01-13 中石化洛阳工程有限公司 Storage tank vapor recovery system system
CN204957453U (en) * 2015-08-17 2016-01-13 中石化洛阳工程有限公司 Storage tank vapor recovery system system
CN204957452U (en) * 2015-08-17 2016-01-13 中石化洛阳工程有限公司 Fixed roof tank vapor recovery system system
CN105214439A (en) * 2015-09-14 2016-01-06 清本环保工程(杭州)有限公司 Oil-gas recovery processing device and method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
中国石油化工集团人事部: "《油品储运调和操作工》", 30 September 2009, 中国石化出版社 *
樊宝德、杨晓婕: "《油库加油站油气回收与减排技术》", 31 October 2009, 中国石化出版社 *

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