CN106118604A - Ternary refrigerant for 50 DEG C ~ 60 DEG C of cryogenic temperatures - Google Patents
Ternary refrigerant for 50 DEG C ~ 60 DEG C of cryogenic temperatures Download PDFInfo
- Publication number
- CN106118604A CN106118604A CN201610423244.XA CN201610423244A CN106118604A CN 106118604 A CN106118604 A CN 106118604A CN 201610423244 A CN201610423244 A CN 201610423244A CN 106118604 A CN106118604 A CN 106118604A
- Authority
- CN
- China
- Prior art keywords
- parts
- cryogenic temperatures
- refrigerant
- cold
- refrigeration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/122—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/24—Only one single fluoro component present
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Separation By Low-Temperature Treatments (AREA)
Abstract
The open one of the present invention is for the ternary refrigerant of 50 DEG C ~ 60 DEG C of cryogenic temperatures.For the ternary refrigerant of 50 DEG C ~ 60 DEG C of cryogenic temperatures, the most composed of the following components: 45 ~ 75 parts of propane；50 ~ 20 parts of ethane；Tetrafluoroethane 5 parts.Realize the requirement utilizing the ternary refrigerant being used for 50 DEG C ~ 60 DEG C of cryogenic temperatures to meet one-stage steam compressed kind of refrigeration cycle, improve the energy utilization rate of refrigeration system, reduce energy consumption and realize energy-conserving and environment-protective.
Description
Technical field
The present invention relates to refrigeration technology field, be specifically related to a kind of ternary for-50 DEG C ~-60 DEG C of cryogenic temperatures and freeze
Agent.
Background technology
At present, refrigeration plant (such as: refrigerator or refrigerator) is household electrical appliance conventional in people's daily life, and along with people
Living standard improve constantly, people to food and refrigeration plant environmental protection, the aspect such as energy-conservation, fresh-keeping requirement increasingly
Height, the cold-producing medium that general domestic refrigerating appts uses is usually R600a, propane, tetrafluoroethane, R404A etc., and cold-producing medium provides
Lowest refrigerating temperature be-40 DEG C.The existing refrigeration plant many employings Auto-cascade cycle being capable of-50 DEG C ~-60 DEG C of cryogenic temperatures or
Cascade system by realizations such as mix refrigerant R508B, (such as: China Patent No. 201310560534.5, fit by disclosed one
Diversity cold-producing medium for natural gas liquefaction system that precooling temperature is-40 to-60 DEG C), but, auto-cascade refrigeration system
System needs to be separated by high low boiling point refrigerant in system, and the condensation that high boiling point cold-producing medium is low warm spot cold-producing medium provides cold,
And product only provides cold by low boiling point refrigerant；This scheme efficiency is relatively low, and cold-producing medium separates and height refrigerant heat exchanger
Device efficiency is relatively low, also increases the cost of product simultaneously.And cascade system uses multi-stage compression, system cost is higher, and energy
Imitate bigger.How designing a kind of cold-producing medium meeting-50 DEG C ~-60 cryogenic temperatures is the technical problem to be solved.
Summary of the invention
The present invention provides a kind of ternary refrigerant for-50 DEG C ~-60 DEG C of cryogenic temperatures, it is achieved utilize for-50 DEG C ~-
The ternary refrigerant of 60 DEG C of cryogenic temperatures meets the requirement of one-stage steam compressed kind of refrigeration cycle, improves the utilization of energy of refrigeration system
Rate, reduce energy consumption and realize energy-conserving and environment-protective.
In order to realize above-mentioned technical purpose, the present invention adopts the following technical scheme that and is achieved:
A kind of ternary refrigerant for-50 DEG C ~-60 DEG C of cryogenic temperatures, it is characterised in that in parts by weight by following components
Composition:
45 ~ 75 parts of propane；
50 ~ 20 parts of ethane；
Tetrafluoroethane 5 parts.
Compared with prior art, the ternary refrigerant for-50 DEG C ~-60 cryogenic temperatures that the present invention provides, by height
Be combineding with each other of boiling point refrigerant, can realize-50 DEG C ~-60 DEG C with the steam compression type refrigeration circulation that satisfied employing is common
Cryogenic temperature, on the one hand this cold-producing medium comprises a kind of low boiling point refrigerant R170, and its normal boiling point temperature is-88.58 DEG C, permissible
Realize the cryogenic temperature of-60 DEG C ~-80 DEG C, on the other hand this cold-producing medium comprise utilize two kinds of high boiling point cold-producing medium R290 and
R134a, normal boiling point temperature is respectively-42 DEG C and-26 DEG C, can be achieved the system of-50 DEG C ~-60 DEG C by suitable proportioning
The storage temperature of cold scope；It addition, the combination of high low boiling point refrigerant, reduce the pressure reduction of refrigeration system compressor both sides, make
Refrigeration system high pressure end pressure is reduced to 2 ~ 2.5Mpa from 4 ~ 5Mpa, simultaneously maintain compressor two ends pressure ratio 10 ~ 15 model
Enclose inner pressure ratio, make the pressure ratio of compressor be reduced to 9-10, to overcome simple employing R170 to cause too high the asking of kind of refrigeration cycle pressure ratio
Topic,.Use the storage temperature that this mix refrigerant only can realize-50 DEG C ~-60 DEG C by one-stage steam compressed kind of refrigeration cycle,
Instead of the low temperature storage that conventionally employed kind of refrigeration cycle optimization (multi-stage compression or Auto-cascade cycle or multistage overlapping) could realize, reach
One-stage steam compressed kind of refrigeration cycle is used to realize the target of-50 ~-60 DEG C of cryopreservations, it is achieved to utilize for-50 DEG C ~-60 refrigeration
The ternary refrigerant of temperature meets the requirement of one-stage steam compressed kind of refrigeration cycle, improves the energy utilization rate of refrigeration system, reduction
Energy consumption also realizes energy-conserving and environment-protective.
Detailed description of the invention
The one that the present invention provides for the ternary refrigerant of-50 DEG C ~-60 DEG C of cryogenic temperatures, in parts by weight by with
Lower component forms: 45 ~ 75 parts of propane (R290)；50 ~ 20 parts of ethane (R170)；Tetrafluoroethane (R134a) 5 parts.
Specifically, the present invention for-50 DEG C ~-60 DEG C of cryogenic temperatures ternary refrigerant use quasi-boiling temperature be-
The low boiling point refrigerant R170 of 88.58 DEG C, to meet the refrigeration requirement of low temperature-60 DEG C, and in order to meet employing one-stage steam
The use requirement of contraction SAPMAC method, is respectively the R290 of-42 DEG C and the R134a of-26 DEG C by hybrid standard boiling temperature, reduces
The pressure ratio of refrigeration system compressor both sides and pressure reduction, make refrigeration system high pressure in the range of 2 ~ 2.5MPa, it is adaptable to existing business
With piston compressor, instead of what conventionally employed kind of refrigeration cycle optimization (multi-stage compression or Auto-cascade cycle or multistage overlapping) could realize
Low temperature stores.Wherein, the refrigeration requirement of different temperatures can be met by the ternary refrigerant of differently configured weight portion, such as:
Realize the cold-producing medium proportioning of about-50 DEG C storage temperature: propane accounts for 65 ~ 75 parts, 20 ~ 30 parts of ethane, tetrafluoroethane 5 parts；Realize-
The cold-producing medium proportioning of about 55 DEG C storage temperature: 55 ~ 65 parts of propane, 30 ~ 40 parts of ethane, tetrafluoroethane 5 parts；Realize-60 DEG C of left sides
The cold-producing medium proportioning of right storage temperature: 45 ~ 55 parts of propane, 40 ~ 50 parts of ethane, tetrafluoroethane 5 parts.
The ternary refrigerant for-50 DEG C ~-60 DEG C of cryogenic temperatures that the present invention provides, by high low boiling point refrigerant
It is combined with each other, the cryogenic temperature of-50 DEG C ~-60 DEG C, a side can be realized with the steam compression type refrigeration circulation that satisfied employing is common
This cold-producing medium of face comprises a kind of low boiling point refrigerant R170, and its normal boiling point temperature is-88.58 DEG C, it is possible to achieve the system of-60 DEG C
Cold temperature, on the other hand this cold-producing medium utilizes two kinds of high boiling point cold-producing medium R290 and R134a, and normal boiling point temperature is respectively-42
DEG C and-26 DEG C, it is achieved that the storage temperature of-50 DEG C ~-60 DEG C of scopes；It addition, the combination of high low boiling point refrigerant, reduce system
Cooling system high side pressure ensures that pressure ratio, in the range of 10 ~ 15, uses merely R170 to cause kind of refrigeration cycle pressure to overcome simultaneously
The problem that power is too high；Only can be realized the storage temperature of-50 DEG C ~-60 DEG C by one-stage steam compressed kind of refrigeration cycle, instead of biography
System uses the low temperature storage that kind of refrigeration cycle optimization (multi-stage compression or Auto-cascade cycle or multistage overlapping) could realize, and reaches to use single-stage
Vapor Compression Refrigeration Cycle realizes the target of-50 ~-60 DEG C of cryopreservations, it is achieved utilize three for-50 DEG C ~-60 cryogenic temperatures
Unit's cold-producing medium meets the requirement of one-stage steam compressed kind of refrigeration cycle, improves the energy utilization rate of refrigeration system, reduces energy consumption reality
Existing energy-conserving and environment-protective.
Last it is noted that above example is only in order to illustrate technical scheme, it is not intended to limit；Although
With reference to previous embodiment, the present invention is described in detail, it will be understood by those within the art that: it still may be used
So that the technical scheme described in foregoing embodiments to be modified, or wherein portion of techniques feature is carried out equivalent；
And these amendment or replace, do not make appropriate technical solution essence depart from various embodiments of the present invention technical scheme spirit and
Scope.
Claims (4)
1. the ternary refrigerant for-50 DEG C ~-60 DEG C of cryogenic temperatures, it is characterised in that in parts by weight by following group
It is grouped into:
45 ~ 75 parts of propane；
50 ~ 20 parts of ethane；
Tetrafluoroethane 5 parts.
Ternary refrigerant for-50 DEG C ~-60 DEG C of cryogenic temperatures the most according to claim 1, it is characterised in that propane
Account for 65 ~ 75 parts, 20 ~ 30 parts of ethane, tetrafluoroethane 5 parts.
Ternary refrigerant for-50 DEG C ~-60 DEG C of cryogenic temperatures the most according to claim 1, it is characterised in that propane
55 ~ 65 parts, 30 ~ 40 parts of ethane, tetrafluoroethane 5 parts.
Ternary refrigerant for-50 DEG C ~-60 DEG C of cryogenic temperatures the most according to claim 1, it is characterised in that propane
45 ~ 55 parts, 40 ~ 50 parts of ethane, tetrafluoroethane 5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610423244.XA CN106118604A (en) | 2016-06-15 | 2016-06-15 | Ternary refrigerant for 50 DEG C ~ 60 DEG C of cryogenic temperatures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610423244.XA CN106118604A (en) | 2016-06-15 | 2016-06-15 | Ternary refrigerant for 50 DEG C ~ 60 DEG C of cryogenic temperatures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106118604A true CN106118604A (en) | 2016-11-16 |
Family
ID=57270805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610423244.XA Pending CN106118604A (en) | 2016-06-15 | 2016-06-15 | Ternary refrigerant for 50 DEG C ~ 60 DEG C of cryogenic temperatures |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106118604A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112745804A (en) * | 2021-01-29 | 2021-05-04 | 青岛万宝压缩机有限公司 | Low-temperature mixed working medium and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1412267A (en) * | 2002-07-12 | 2003-04-23 | 天津大学 | Green mixed refrigerating agent |
-
2016
- 2016-06-15 CN CN201610423244.XA patent/CN106118604A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1412267A (en) * | 2002-07-12 | 2003-04-23 | 天津大学 | Green mixed refrigerating agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112745804A (en) * | 2021-01-29 | 2021-05-04 | 青岛万宝压缩机有限公司 | Low-temperature mixed working medium and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Gao et al. | A review of application status and replacement progress of refrigerants in the Chinese cold chain industry | |
| CN103512257B (en) | For the non-azeotrope hydrocarbon mixture self-cascade refrigeration system system of two temperature refrigerator | |
| Messineo et al. | Performance evaluation of cascade refrigeration systems using different refrigerants | |
| WO2013049344A3 (en) | High efficiency refrigeration system | |
| CN102003826A (en) | Ultra-low temperature circulation refrigeration method employing injectors | |
| CN108469126A (en) | Outdoor unit and the freezing cycle device for using the outdoor unit | |
| CN103712366B (en) | A kind of cryogen cold energy use system | |
| CN103808068A (en) | Refrigerating system | |
| CN103486754A (en) | Energy-saving middle temperature refrigerant/middle temperature refrigerant cascade refrigeration system | |
| Zhang et al. | Comparative analysis of typical improvement methods in transcritical carbon dioxide refrigeration cycle | |
| CN201852389U (en) | Refrigerator with double refrigeration modes | |
| CN201377954Y (en) | Dual refrigeration cycle system in refrigerated counter | |
| TW200516222A (en) | Refrigeration system using non-azeotropic refrigerants and non-azeotropic refrigerants for ultra low temperature to be used in said refrigeration system | |
| CN104789192A (en) | Novel refrigerating fluid suitable for medium and low temperature freezing and refrigerating system | |
| CN106705308B (en) | Mechanical flash evaporation type air conditioner refrigeration system and working method thereof | |
| CN207922608U (en) | A kind of energy saving double-face show refrigerator | |
| CN106118604A (en) | Ternary refrigerant for 50 DEG C ~ 60 DEG C of cryogenic temperatures | |
| CN202041016U (en) | Centrifugal unit | |
| CN203629121U (en) | Cryogenic fluid cold energy utilization system | |
| CN105969314A (en) | Binary refrigerant for refrigeration temperature of minus 40 DEG C to minus 50 DEG C | |
| CN204165291U (en) | A kind of energy-conserving refrigeration system | |
| CN106568218A (en) | Multi-temperature-zone refrigerating loop system and multi-temperature-zone refrigerating equipment | |
| CN211823239U (en) | Ultra-low temperature transcritical cascade refrigeration system | |
| CN204555403U (en) | Overlapping refrigeration system | |
| CN103994612B (en) | A kind of energy-conserving refrigeration system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161116 |
|
| RJ01 | Rejection of invention patent application after publication |