CN106118486A - The production method of Sucrose Ester of Rosin Acid - Google Patents
The production method of Sucrose Ester of Rosin Acid Download PDFInfo
- Publication number
- CN106118486A CN106118486A CN201610469877.4A CN201610469877A CN106118486A CN 106118486 A CN106118486 A CN 106118486A CN 201610469877 A CN201610469877 A CN 201610469877A CN 106118486 A CN106118486 A CN 106118486A
- Authority
- CN
- China
- Prior art keywords
- production method
- rosin acid
- sucrose ester
- sucrose
- colophonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; DRIERS (SICCATIVES); TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Abstract
The invention discloses the production method of a kind of Sucrose Ester of Rosin Acid, its production method is: alcohols material, Colophonium and sucrose are sequentially added in cavitation machine, is subsequently adding molecular sieve, opens cavitation machine, esterification, is filtered to remove molecular sieve, impurity is distilled off.Colophonium and sucrose single step reaction are prepared Sucrose Ester of Rosin Acid by the present invention, and assist cavitation device, and reaction can complete within a short period of time, and product purity is higher, gained solvent recoverable.
Description
Technical field
The present invention relates to Colophonium deep process technology field, the production method of a kind of Sucrose Ester of Rosin Acid.
Background technology
Colophonium is a kind of reproducible natural resin, is widely used in coating, adhesive, ink, papermaking, soap, metal
The industries such as processing, synthetic rubber, building materials, food, macromolecule, fine chemical product.But due to the unstability of Colophonium itself, as easily
Crystallization, easy oxidized variable color and softening point are low so that it is performance and application are subject to certain restrictions.Colophonium is esterified
Modification is one of the most important mode.
Sucrose Ester of Rosin Acid is a kind of good surfactant of biodegradability, can be used as the emulsifying agent of food, divides
Powder and viscosity modifier etc., being mainly by Colophonium and sucrose is that primary raw material is prepared from.But, current Sucrose Ester of Rosin Acid
Preparation method typically experience for a long time backflow, the time used is longer, accordingly, it would be desirable to seek one quickly prepare rosin acid sugarcane
The method of sugar ester.
Summary of the invention
It is an object of the invention to provide the production method of a kind of Sucrose Ester of Rosin Acid, this production method can solve Colophonium
The problem that the acid sucrose ester production time is longer.
In order to solve the problems referred to above, the technical solution used in the present invention is:
The production method of this Sucrose Ester of Rosin Acid is: be sequentially added into alcohols material, Colophonium and sucrose in cavitation machine, and mixing is all
Even, it is subsequently adding catalysts, opens cavitation machine, control reaction temperature to 130 DEG C～150 DEG C, react 1 hour～1.5 little
Time, filter, collect filtrate, insulation distillation 1 hour～2 hours.
In technique scheme, more specifically technical scheme is it may also is that catalyst is molecular sieve catalyst.
Further, the preparation method of molecular sieve catalyst is: according to 1:1～5:0.3～1:10～the mass ratio of 20, will
Sodium silicate, aluminium oxide and sodium hydroxide and water mixing, proceed in microwave oven, and arranging microwave frequency is 500 hertz～800 hertz,
Microwave 30 minutes～60 minutes.
Further, the one during alcohols material is methanol, ethanol, glycerol and butanol.
Further, the mass ratio of alcohols material, Colophonium, sucrose and catalyst be 1:6～8:8～12:0.05～
0.2。
Further, vapo(u)rizing temperature is 150 DEG C～180 DEG C.
Owing to have employed technique scheme, the present invention compared with prior art has the advantages that
1, Colophonium and sucrose single step reaction are prepared Sucrose Ester of Rosin Acid by the present invention, and assist cavitation device, produce in course of reaction
Raw High Temperature High Pressure makes chemical bond rupture and produces free radical etc., thus promotes that reaction is carried out largely so that reaction
Within a short period of time can complete.
2, feed stock conversion of the present invention is high, side reaction is few, product purity is higher.
3, the present invention distills gained solvent and can recycle.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1
The production method of the present embodiment Sucrose Ester of Rosin Acid is: be sequentially added into ethanol, Colophonium and sucrose in cavitation machine, and mixing is all
Even, it is subsequently adding molecular sieve, opens cavitation machine, the operating pressure of regulation cavitation machine is 0.4 MPa, controls reaction temperature to 150
DEG C, to react 1.2 hours, filter, collect filtrate, regulation vapo(u)rizing temperature is 150 DEG C, insulation distillation 1.2 hours.
In the present embodiment, the mass ratio of ethanol, Colophonium, sucrose and catalyst is 1:6:12:0.05.
The preparation method of the present embodiment molecular sieve catalyst is: according to the mass ratio of 1:1:0.3:10, by sodium silicate, oxidation
Aluminum and sodium hydroxide and water mix, and proceed in microwave oven, and arranging microwave frequency is 800 hertz, and microwave 50 minutes i.e. obtains this reality
Execute example catalyst.
Embodiment 2
The production method of the present embodiment Sucrose Ester of Rosin Acid is: be sequentially added into butanol, Colophonium and sucrose in cavitation machine, and mixing is all
Even, it is subsequently adding molecular sieve, opens cavitation machine, the operating pressure of regulation cavitation machine is 0.6 MPa, controls reaction temperature to 140
DEG C, to react 1 hour, filter, collect filtrate, regulation vapo(u)rizing temperature is 160 DEG C, insulation distillation 1 hour.
In the present embodiment, the mass ratio of butanol, Colophonium, sucrose and catalyst is 1:7:11:0.1.
The preparation method of the present embodiment molecular sieve catalyst is: according to the mass ratio of 1:2:0.5:15, by sodium silicate, oxidation
Aluminum and sodium hydroxide and water mix, and proceed in microwave oven, and arranging microwave frequency is 600 hertz, and microwave 40 minutes i.e. obtains this reality
Execute example catalyst.
Embodiment 3
The production method of the present embodiment Sucrose Ester of Rosin Acid is: be sequentially added into methanol, Colophonium and sucrose in cavitation machine, and mixing is all
Even, it is subsequently adding molecular sieve, opens cavitation machine, the operating pressure of regulation cavitation machine is 0.7 MPa, controls reaction temperature to 135
DEG C, to react 1.1 hours, filter, collect filtrate, regulation vapo(u)rizing temperature is 170 DEG C, insulation distillation 1.6 hours.
In the present embodiment, the mass ratio of methanol, Colophonium, sucrose and catalyst is 1:8:10:0.15.
The preparation method of the present embodiment molecular sieve catalyst is: according to the mass ratio of 1:5:1:16, by sodium silicate, aluminium oxide
Mixing with sodium hydroxide and water, proceed in microwave oven, arranging microwave frequency is 700 hertz, and microwave 60 minutes i.e. obtains this enforcement
Example catalyst.
Embodiment 4
The production method of the present embodiment Sucrose Ester of Rosin Acid is: be sequentially added into glycerol, Colophonium and sucrose in cavitation machine, mixing
Uniformly, being subsequently adding molecular sieve, open cavitation machine, the operating pressure of regulation cavitation machine is 0.8 MPa, controls reaction temperature extremely
130 DEG C, reacting 1.5 hours, filter, collect filtrate, regulation vapo(u)rizing temperature is 180 DEG C, insulation distillation 1 hour.
In the present embodiment, the mass ratio of glycerol, Colophonium, sucrose and catalyst is 1:8:8:0.2.
The preparation method of the present embodiment molecular sieve catalyst is: according to the mass ratio of 1:3:0.8:20, by sodium silicate, oxidation
Aluminum and sodium hydroxide and water mix, and proceed in microwave oven, and arranging microwave frequency is 800 hertz, and microwave 30 minutes i.e. obtains this reality
Execute example catalyst.
Claims (7)
1. the production method of Sucrose Ester of Rosin Acid, it is characterised in that comprise the following steps: be sequentially added into alcohols thing in cavitation machine
Matter, Colophonium and sucrose, mix homogeneously, it is subsequently adding catalysts, opens cavitation machine, control reaction temperature to 130 DEG C～150
DEG C, react 1 hour～1.5 hours, filter, collect filtrate, insulation distillation 1 hour～2 hours.
The production method of Sucrose Ester of Rosin Acid the most according to claim 1, it is characterised in that: described catalyst is molecular sieve
Catalyst.
The production method of Sucrose Ester of Rosin Acid the most according to claim 2, it is characterised in that described molecular sieve catalyst
Preparation method is: according to 1:1～5:0.3～1:10～the mass ratio of 20, sodium silicate, aluminium oxide and sodium hydroxide and water are mixed
Closing, proceed in microwave oven, arranging microwave frequency is 500 hertz～800 hertz, microwave 30 minutes～60 minutes.
4. according to the production method of the Sucrose Ester of Rosin Acid described in claim 1 or 2 or 3, it is characterised in that: described alcohols material
For the one in methanol, ethanol, glycerol and butanol.
5. according to the production method of the Sucrose Ester of Rosin Acid described in claim 1 or 2 or 3, it is characterised in that: described alcohols thing
The mass ratio of matter, Colophonium, sucrose and catalyst is 1:6～8:8～12:0.05～0.2.
6. according to the production method of the Sucrose Ester of Rosin Acid described in claim 1 or 2 or 3, it is characterised in that: described vapo(u)rizing temperature
It it is 150 DEG C～180 DEG C.
7. according to the production method of the Sucrose Ester of Rosin Acid described in claim 1 or 2 or 3, it is characterised in that: described cavitation machine
Operating pressure is 0.4 MPa～0.8 MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610469877.4A CN106118486A (en) | 2016-06-26 | 2016-06-26 | The production method of Sucrose Ester of Rosin Acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610469877.4A CN106118486A (en) | 2016-06-26 | 2016-06-26 | The production method of Sucrose Ester of Rosin Acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106118486A true CN106118486A (en) | 2016-11-16 |
Family
ID=57268840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610469877.4A Pending CN106118486A (en) | 2016-06-26 | 2016-06-26 | The production method of Sucrose Ester of Rosin Acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106118486A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229197A (en) * | 2019-07-06 | 2019-09-13 | 潍坊大耀新材料有限公司 | A kind of preparation method of the one's own physical property sucrose ester of small molecule without solvent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05156209A (en) * | 1991-12-10 | 1993-06-22 | Arakawa Chem Ind Co Ltd | Production of rosin alcohol |
| JP2014070167A (en) * | 2012-09-28 | 2014-04-21 | Seiko Pmc Corp | Rosin polyhydric alcohol ester resin, ink emulsification suitability improver, varnish for offset printing ink, and ink composition for offset printing |
| CN103952082A (en) * | 2014-04-22 | 2014-07-30 | 南京林业大学 | Method for preparing abietinol |
| CN203820747U (en) * | 2014-04-17 | 2014-09-10 | 河南亚太能源科技有限公司 | Efficient cavitation device |
| CN104031100A (en) * | 2014-06-29 | 2014-09-10 | 陈昆 | Method for preparing sucrose abietate |
-
2016
- 2016-06-26 CN CN201610469877.4A patent/CN106118486A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05156209A (en) * | 1991-12-10 | 1993-06-22 | Arakawa Chem Ind Co Ltd | Production of rosin alcohol |
| JP2014070167A (en) * | 2012-09-28 | 2014-04-21 | Seiko Pmc Corp | Rosin polyhydric alcohol ester resin, ink emulsification suitability improver, varnish for offset printing ink, and ink composition for offset printing |
| CN203820747U (en) * | 2014-04-17 | 2014-09-10 | 河南亚太能源科技有限公司 | Efficient cavitation device |
| CN103952082A (en) * | 2014-04-22 | 2014-07-30 | 南京林业大学 | Method for preparing abietinol |
| CN104031100A (en) * | 2014-06-29 | 2014-09-10 | 陈昆 | Method for preparing sucrose abietate |
Non-Patent Citations (2)
| Title |
|---|
| 孟繁智: "《新编精细化工应用配方10000例与生产工艺实用手册 上》", 29 February 2004, 银声音像出版社 * |
| 龙英才: "沸石分子筛催化材料──高科技的硅铝酸盐产品", 《2007全国无机硅化物行业年会论文集》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229197A (en) * | 2019-07-06 | 2019-09-13 | 潍坊大耀新材料有限公司 | A kind of preparation method of the one's own physical property sucrose ester of small molecule without solvent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1277794C (en) | Preparation of levulinate from glucose by molecular screen catalytic hydrolysis | |
| WO2014142289A1 (en) | Method for manufacturing lignin degradation product | |
| CN106118486A (en) | The production method of Sucrose Ester of Rosin Acid | |
| CN102964495A (en) | Synthetic method of terpene resin | |
| CN101712712A (en) | Method for preparing 16-dehydropregnenolone acetate by multistage filtration and recrystallization | |
| CN104140763A (en) | Preparation method of pale rosin pentaerythritol ester | |
| JPS60139701A (en) | Production of cellulose acetate | |
| CN103058849B (en) | Interval reaction rectification process for synthesizing methacrylic anhydride | |
| CN106748767B (en) | Low-hydroxyl-value vegetable oil-based polyol and preparation method thereof | |
| CN106010279A (en) | Preparation method of sucrose ester of rosin acid | |
| CN109053936B (en) | Preparation method of polyvinyl butyral resin | |
| CN104014338B (en) | Solid base carrier thallium catalyst and preparation method | |
| WO2020221435A1 (en) | Method for producing aqueous polymer dispersions in a tube reactor | |
| CN103183970A (en) | Method for reducing sulfur dioxide content in caramel color | |
| CN105950020A (en) | Method for producing rosin ester | |
| CN111378467B (en) | Method for treating cyclohexane oxidation by-product | |
| CN107935845B (en) | Method for preparing cyclohexyl acetate by reactive distillation | |
| CN107151210B (en) | Method for preparing tung oil polyol under ultrasonic condition | |
| CN105524263A (en) | Preparation method for unsaturated polyester resin | |
| CN104211843B (en) | The preparation method of terpene resin | |
| CN105936808A (en) | Preparation method of hydrogenated rosin | |
| CN102775951B (en) | Preparation method and application of polyether-polyester aqueous emulsion/isocyanate adhesive | |
| CN107151217B (en) | Tung oil-based polyol and synthesis method thereof | |
| CN106010269A (en) | Method for preparing hydrogenated rosin glyceride | |
| CN107417533B (en) | Dimethyl isophthalate and process for producing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161116 |
|
| WD01 | Invention patent application deemed withdrawn after publication |