CN106117762A - A kind of preparation method of aging resistance low-density polyethylene film - Google Patents
A kind of preparation method of aging resistance low-density polyethylene film Download PDFInfo
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Abstract
The present invention relates to the preparation method of a kind of aging resistance low-density polyethylene film, belong to plastic preparing technical field, it is by nano imvite, attapulgite is brilliant, aluminium borate whisker, wollastonite raphioid fiber, after sodium bicarbonate aqueous solution mix and blend, it is dipped in moisture absorption in sulfamic acid solution, heating, dispersion, take float ultrasonic Treatment, the upper strata float obtained is filtered, washing, dry, again by the material obtained and magnesium borate crystal whisker, bulking agent, silane coupler, UV absorbent, light stabilizer, antioxidant mix and blend is dried, add the stirring of LDPE: Low-density polyethylene plastics powder, melt kneading extrusion at parallel dual-screw and obtain aging resistance low-density polyethylene film.Compared with prior art, the present invention is anti-aging materials, UV absorbent, light stabilizer, the antioxidant such as scientific application aluminium borate whisker, wollastonite raphioid fiber in LDPE: Low-density polyethylene plastics, makes high intensity, aging resistance polyethylene film with vinyon blended melting.
Description
Technical field
The present invention relates to the preparation method of a kind of aging resistance low-density polyethylene film, belong to plastic technology of preparing neck
Territory.
Background technology
Low Density Polyethylene is the thermoplastic resin that a kind of degree of crystallinity is relatively low, english abbreviation LDPE, the general 5-50 of molecular weight
Ten thousand, density is 0.910-0.9259/cm3, and softening point is relatively low, and moulding processability is fine, and flexibility is good, toughness,
Lower temperature resistance is fine, can be at-60 DEG C--work at 80 DEG C.The mechanical strength of LDPE is poor, and thermostability is the highest, and chemical stability is excellent
Show, the most stable to acid, alkali, salt, organic solvent.LDPE is mainly used for making film product, as thin in agricultural film, daily packaging
Film, Archtectural Coatings, industrial film etc..Additionally, LDPE is additionally operable to injection-molded item, such as everyday articles, medical apparatus, extruded pipe,
Sheet material, container, electric wire etc.;
Low Density Polyethylene is easy thermo-oxidative ageing and photooxidation resistance under daylight and heat effect, and these ageing results cause low
Density polyethylene generation degradation reaction is main irreversible chemical reaction, and makes its performance depreciation or even completely lose use valency
Value.Low Density Polyethylene is inflammable, can burn away after fire, can melt during burning, has liquid to drip.
Wollastonite raphioid fiber is a kind of anorthic system, thin platelike crystal, and aggregation, in radiation needle-like or threadiness, is to mould
Material, rubber preferable aging resistance packing material, can improve plastics, the impact strength of rubber, strengthen mobility with
And improve tensile strength, impact strength, linear stretch and mould shrinkage factor, nontoxic, resistance to chemical attack, heat stability and dimensionally stable
Well, there are glass and pearly luster, low water absorption and oil factor, mechanical property and electrical property excellent and there is certain reinforcement work
With.
White carbon can uv reflectance consumingly, add to and polyvinyl resin can greatly reduce ultraviolet to polyethylene
Degradation, thus reach to delay the purpose of material aging.Silica particles is less 100 1000 times than SiO2, is added
It is added in polyvinyl resin, is conducive to melted membrane.Due to high fluidity and the small-size effect of white carbon, make material surface more
Add densification the cleanest, in addition the high intensity of nano-particle, make film strength be greatly enhanced.
Montmorillonite is a class by the surface of nano thickness electronegative silicate lamella, relies on the electrostatic interaction of interlayer and heap
The long-pending earthy mineral together constituted, the structure cell in its crystal structure is by one layer of alumina octahedral of folder in the middle of two-layer silicon-oxy tetrahedron
Body is constituted.There is one-dimensional layered nano-structure and the cation commutativity characteristic of uniqueness, thus give the many modifications of montmorillonite
May be with the expansion of application.The montmorillonite being modified has a strongest absorbability, and good dispersive property can be extensive
Application macromolecular material industry, as the additive of nanometer polymer macromolecular material, improves shock resistance, resisting fatigue, dimensionally stable
Property and gas barrier property etc., thus play the effect strengthening polymer comprehensive physical performance, improve materiel machining performance simultaneously.
Application in the polymer can be added when polymer, it is also possible to is blended when melted and adds.
Whisker is the diameter the least (0.1-10um) with single crystal form growth, atomic arrangement high-sequential, intensity
Close to perfect crystal theoretical value, have the fibrous material of certain draw ratio (5-1000), add in thermoplastic macromolecule material
A small amount of whisker, just not only can strengthen but also toughness reinforcing, also can improve other performances such as thermostability.
Magnesium borate crystal whisker has another name called pyroboric acid magnesium whisker, and outward appearance is white fluffy solid, and basis of microscopic observation is threadiness
Crystal, diameter 0.2-10 μm, length 10-100 μm, price is only the 1/20-1/30 of silicon carbide whisker, be current composite
It is hopeful one of wide variety of whisker.It is widely used in military affairs, aviation with the composite of whisker reinforcement in developed country
Space material, building, machinery, bridge, automobile, macromolecular material, sports equipment and aluminum base, magnesium base alloy strengthen, and plastics are multiple
The fields such as condensation material strengthens, and ceramic composite strengthens, macromolecular material enhancing.Magnesium borate crystal whisker have lightweight, high intensity,
High elastic modulus, high rigidity, the excellent properties such as high temperature resistant, corrosion-resistant and good mechanical strength and electrical insulating property, nontoxic nothing
Evil is pollution-free.Magnesium borate crystal whisker reinforced plastics molding good fluidity, close to packless resin, whisker can reach appointing of parts
Meaning corner, has the advantages such as high, strong, the smooth surface of part stability of formed precision.Plastics with magnesium borate crystal whisker as reinforcement
Material has been succeeded application on accurate engineering plastics parts and ultra-thin-wall zero device.The resistance to highly basic of magnesium borate crystal whisker,
Solvent has good dispersibility, is suitable for further surface and processes.
Aluminium borate whisker is a kind of whiskers fiber, belongs to the crystal of structure of right angle intersection, diameter 0.5-1 μm, length 10-
30μm.This whisker has high elastic modelling quantity, good mechanical strength, thermostability, chemical proofing, acid resistance, electricity absolutely
Edge, neutron-absorbing performance and with the features such as metal covalency, can be not only used for thermal insulation, heat-resisting and anticorrosive material, it is possible to
Reinforcing agent as thermoplastic resin, thermosetting resin, cement, pottery and metal.Aluminium borate whisker has the resistance to of excellence and wears away
Mill performance, fire resistant flame retardant etc..The price of Alborex M 12 is relatively low, only the 1/10-1/30 of silicon carbide whisker, is a kind of You Hen great city
The new type whisker material of field potentiality.The matrix resin that research uses at present mainly includes that PP, PE, PVC, PS, PC, PA, polyamides are sub-
Amine, polyphenylene sulfide etc., the composite prepared has the intensity of excellence, rigidity, wearability.
The basic structural unit of attapulgite is bar-shaped, needle-like, threadiness monocrystal, is called for short attapulgite brilliant, attapulgite
The general < of content 50% that middle rod is brilliant, attapulgite crystalline substance is about 0.5-5 μm, and wide about 0.01-0.10 μm, surface is covered with concavo-convex alternate
Groove, Mohs' hardness 2-3 level, it is heated to 700-800 DEG C, hardness > 5 grades, proportion is 2.05-2.32, adds and the most both made
For coloring agent, there is again reinforcement, fire-retardant, anti-aging.
UV absorbent UVP-327, the strong absorbing wavelength of energy is the ultraviolet of 270-380 nanometer, and chemical stability is good,
Volatility is minimum, is particularly well-suited to polyethylene and polypropylene, with antioxidant with for significant cooperative effect, significantly improves system
The thermo-oxidative stability of product.Antioxidant 1010 has remarkable antioxygenic property to polypropylene, polyethylene, can effectively extend goods
Useful life.Light stabilizer HPT, these product can be used as polyethylene and polypropylene light stabilizer, can give the excellent open air of goods and prevent
Ageing properties.
The defect that material scientific worker exists for vinyon for many years, has carried out substantial amounts of study on the modification, with
Phase prepares and has intensity height, aging resistance low-density polyethylene film.
Summary of the invention
It is an object of the invention to the deficiency overcoming prior art to exist, it is provided that a kind of aging resistance low-density polyethylene film
Preparation method.
The preparation method of a kind of aging resistance low-density polyethylene film of the present invention, employing following steps:
A) 0.3-0.5 part nano imvite, 0.6-1.0 part white carbon, 0.4-0.8 part lauryl amine polyoxy are taken by mass fraction
Vinyl Ether, 0.3-0.5 part characterization parameter a length of 0.5-5 μm, a width of 0.01-0.10 μm attapulgite are brilliant, 0.3-0.5 part characterization parameter
A diameter of 0.5-1 μm, the aluminium borate whisker of a length of 10-25 μm, 1.0-1.5 part characterization parameter draw ratio is 14-16:1 silicon ash
Stone raphioid fiber, 3.0-5.0 part mass fraction is the sodium bicarbonate aqueous solution mixing of 20-30%, at 140-160 DEG C of superheated steam
Stirring decatize reaction 45-60min in reactor, under the conditions of 300-400 DEG C, vacuum microwave radiation 3h, is then dipped in 80-120 part
Mass fraction be 30% sulfamic acid solution in vacuum moisture absorption process, inhale post-heating to 60-95 DEG C of ultrasound wave dispersion 0.5-
1.5h, is stirred for disperseing 4.5-5.5h, takes float;
B) by mass fraction by step A) 2.0-4.0 part float 60-100 part of obtaining is containing mass fraction 3-5% tri-
The deionized water of polyphosphate sodium dispersion liquid is ultrasonic Treatment 20-40min at 75-85 DEG C, takes upper strata float through 150-200 mesh
Filtering, distilled water wash is clean, and vacuum drying obtains modified inorganic nano material;
C) step B is taken by mass fraction) modified inorganic nano material that 15-25 part obtains, 5.0-8.0 part characterization parameter is straight
Footpath is 0.2-5 μm, the magnesium borate crystal whisker of length 10-25 μm, 2.0-5.0 part PE-g-MAH bulking agent, 8.0-12 part mass fraction
For the KH-550 silane coupler of 10-20%, 0.4-0.8 part UVP-327 UV absorbent, 0.15-0.2 part HPT light is stable
Agent, 0.1-0.2 part antioxidant, 0.6-1.0 part Rutile type titanium dioxide, with 450-550r/ in mixer under the conditions of 80-90 DEG C
The speed stirring reaction 45-60min of min, vacuum drying under the conditions of 65-75 DEG C, add 250-350 part Low Density Polyethylene
Molding powder, stirs 40-50min with the speed of 250-350r/min, melts the stretching of kneading extruded bidirectional at parallel dual-screw and obtains
Aging resistance low-density polyethylene film.
The preparation method of a kind of aging resistance low-density polyethylene film of the present invention, employing following steps:
A) 0.4 part of nano imvite is taken by mass fraction, 0.8 part of white carbon, 0.6 part of lauryl amine polyoxyethylene ether, 0.4 part
A length of 2.5 μm of characterization parameter, a width of 0.05 μm attapulgite are brilliant, 0.4 part of a diameter of 0.75 μm of characterization parameter, boron of a length of 17 μm
Acid al whisker, 1.2 parts of characterization parameter draw ratios are 15:1 wollastonite raphioid fiber, and 4.0 parts of mass fractions are the bicarbonate of 25%
Sodium water solution mixes, and stirs decatize reaction 50min, vacuum microwave spoke under the conditions of 350 DEG C in 150 DEG C of superheated steam reactors
Penetrate 3h, be then dipped in vacuum moisture absorption in the sulfamic acid solution that 100 parts of mass fractions are 30% and process, inhale post-heating to 75 DEG C
Ultrasound wave dispersion 1h, is stirred for disperseing 5h, takes float;
B) by mass fraction by step A) 3.0 parts of float obtaining divide with 80 parts of sodium tripolyphosphates Han mass fraction 4%
Dissipating deionized water ultrasonic Treatment 30min at 80 DEG C of liquid, take upper strata float and filter through 170 mesh, distilled water wash is clean,
Vacuum drying, obtains modified inorganic nano material;
C) step B is taken by mass fraction) 20 parts of modified inorganic nano materials obtained, 6.5 parts of characterization parameters a diameter of 2.5
μm, the magnesium borate crystal whisker of length 17 μm, 3.5 parts of PE-g-MAH bulking agents, 10 parts of mass fractions be 15% KH-550 silane even
Connection agent, 0.6 part of UVP-327 UV absorbent, 0.17 part of HPT light stabilizer, 0.15 part of antioxidant, 0.8 part of rutile type titanium
White lead, stirs with the speed of 500r/min in mixer under the conditions of 85 DEG C and reacts 50min, vacuum drying under the conditions of 70 DEG C,
Add 300 parts of LDPE: Low-density polyethylene plastics powder, stir 45min with the speed of 300r/min, melt kneading at parallel dual-screw
Extruded bidirectional stretching obtains aging resistance low-density polyethylene film.
Compared with prior art, present invention scientific application aluminium borate whisker, wollastonite pin in LDPE: Low-density polyethylene plastics
Anti-aging materials, UV absorbent, white carbon, light stabilizer, the antioxidant such as shape fiber, with vinyon blended melting system
Become one to be dispersed in inside vinyon with microfibril form, there is the polyethylene film of high intensity, ageing resistace, should
Thin film melting manufactures all kinds of aging resistance polyethylene film products, such as agricultural film, daily packing film, Archtectural Coatings, industry
Thin film etc..
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be described in detail: a kind of aging resistance low-density of the present invention
The preparation method employing following steps of polyethylene film:
A) 0.3-0.5 part nano imvite, 0.6-1.0 part white carbon, 0.4-0.8 part lauryl amine polyoxy are taken by mass fraction
Vinyl Ether, 0.3-0.5 part characterization parameter a length of 0.5-5 μm, a width of 0.01-0.10 μm attapulgite are brilliant, 0.3-0.5 part characterization parameter
A diameter of 0.5-1 μm, the aluminium borate whisker of a length of 10-25 μm, 1.0-1.5 part characterization parameter draw ratio is 14-16:1 silicon ash
Stone raphioid fiber, 3.0-5.0 part mass fraction is the sodium bicarbonate aqueous solution mixing of 20-30%, at 140-160 DEG C of superheated steam
Stirring decatize reaction 45-60min in reactor, under the conditions of 300-400 DEG C, vacuum microwave radiation 3h, is then dipped in 80-120 part
Mass fraction be 30% sulfamic acid solution in vacuum moisture absorption process, inhale post-heating to 60-95 DEG C of ultrasound wave dispersion 0.5-
1.5h, is stirred for disperseing 4.5-5.5h, takes float;
B) by mass fraction by step A) 2.0-4.0 part float 60-100 part of obtaining is containing mass fraction 3-5% tri-
The deionized water of polyphosphate sodium dispersion liquid is ultrasonic Treatment 20-40min at 75-85 DEG C, takes upper strata float through 150-200 mesh
Filtering, distilled water wash is clean, and vacuum drying obtains modified inorganic nano material;
C) step B is taken by mass fraction) modified inorganic nano material that 15-25 part obtains, 5.0-8.0 part characterization parameter is straight
Footpath is 0.2-5 μm, the magnesium borate crystal whisker of length 10-25 μm, 2.0-5.0 part PE-g-MAH bulking agent, 8.0-12 part mass fraction
For the KH-550 silane coupler of 10-20%, 0.4-0.8 part UVP-327 UV absorbent, 0.15-0.2 part HPT light is stable
Agent, 0.1-0.2 part antioxidant, 0.6-1.0 part Rutile type titanium dioxide, with 450-550r/ in mixer under the conditions of 80-90 DEG C
The speed stirring reaction 45-60min of min, vacuum drying under the conditions of 65-75 DEG C, add 250-350 part Low Density Polyethylene
Molding powder, stirs 40-50min with the speed of 250-350r/min, melts the stretching of kneading extruded bidirectional at parallel dual-screw and obtains
Aging resistance low-density polyethylene film.
Embodiment 1: the preparation method of a kind of aging resistance low-density polyethylene film, employing following steps:
A) 0.3 part of nano imvite is taken by mass fraction, 0.6 part of white carbon, 0.4 part of lauryl amine polyoxyethylene ether, 0.3 part
A length of 0.5 μm of characterization parameter, a width of 0.01 μm attapulgite are brilliant, 0.3 part of a diameter of 0.5 μm of characterization parameter, boron of a length of 10 μm
Acid al whisker, 1.0 parts of characterization parameter draw ratios are 14:1 wollastonite raphioid fiber, and 3.0 parts of mass fractions are the bicarbonate of 20%
Sodium water solution mixes, and stirs decatize reaction 45min, vacuum microwave spoke under the conditions of 300 DEG C in 140 DEG C of superheated steam reactors
Penetrate 3h, be then dipped in vacuum moisture absorption in the sulfamic acid solution that 80 parts of mass fractions are 30% and process, inhale post-heating to 60 DEG C
Ultrasound wave dispersion 0.5h, is stirred for disperseing 4.5h, takes float;
B) by mass fraction by step A) 2.0 parts of float obtaining divide with 60 parts of sodium tripolyphosphates Han mass fraction 3%
Dissipating deionized water ultrasonic Treatment 20min at 75 DEG C of liquid, take upper strata float and filter through 150 mesh, distilled water wash is clean,
Vacuum drying, obtains modified inorganic nano material;
C) step B is taken by mass fraction) 15 parts of modified inorganic nano materials obtained, 5.0 parts of characterization parameters a diameter of 0.2
μm, the magnesium borate crystal whisker of length 10 μm, 2.0 parts of PE-g-MAH bulking agents, 8.0 parts of mass fractions be 10% KH-550 silane even
Connection agent, 0.4 part of UVP-327 UV absorbent, 0.15 part of HPT light stabilizer, 0.1 part of antioxidant, 0.6 part of rutile titanium dioxide
Powder, stirs with the speed of 450r/min in mixer under the conditions of 80 DEG C and reacts 45min, vacuum drying under the conditions of 65 DEG C, then
Add 250 parts of LDPE: Low-density polyethylene plastics powder, stir 40min with the speed of 250r/min, melt kneading at parallel dual-screw and squeeze
Go out biaxial tension and obtain aging resistance low-density polyethylene film.
Embodiment 2: the preparation method of a kind of aging resistance low-density polyethylene film, employing following steps:
A) 0.4 part of nano imvite is taken by mass fraction, 0.8 part of white carbon, 0.6 part of lauryl amine polyoxyethylene ether, 0.4 part
A length of 2.5 μm of characterization parameter, a width of 0.05 μm attapulgite are brilliant, 0.4 part of a diameter of 0.75 μm of characterization parameter, boron of a length of 17 μm
Acid al whisker, 1.2 parts of characterization parameter draw ratios are 15:1 wollastonite raphioid fiber, and 4.0 parts of mass fractions are the bicarbonate of 25%
Sodium water solution mixes, and stirs decatize reaction 50min, vacuum microwave spoke under the conditions of 350 DEG C in 150 DEG C of superheated steam reactors
Penetrate 3h, be then dipped in vacuum moisture absorption in the sulfamic acid solution that 100 parts of mass fractions are 30% and process, inhale post-heating to 75 DEG C
Ultrasound wave dispersion 1h, is stirred for disperseing 5h, takes float;
B) by mass fraction by step A) 3.0 parts of float obtaining divide with 80 parts of sodium tripolyphosphates Han mass fraction 4%
Dissipating deionized water ultrasonic Treatment 30min at 80 DEG C of liquid, take upper strata float and filter through 170 mesh, distilled water wash is clean,
Vacuum drying, obtains modified inorganic nano material;
C) step B is taken by mass fraction) 20 parts of modified inorganic nano materials obtained, 6.5 parts of characterization parameters a diameter of 2.5
μm, the magnesium borate crystal whisker of length 17 μm, 3.5 parts of PE-g-MAH bulking agents, 10 parts of mass fractions be 15% KH-550 silane even
Connection agent, 0.6 part of UVP-327 UV absorbent, 0.17 part of HPT light stabilizer, 0.15 part of antioxidant, 0.8 part of rutile type titanium
White lead, stirs with the speed of 500r/min in mixer under the conditions of 85 DEG C and reacts 50min, vacuum drying under the conditions of 70 DEG C,
Add 300 parts of LDPE: Low-density polyethylene plastics powder, stir 45min with the speed of 300r/min, melt kneading at parallel dual-screw
Extruded bidirectional stretching obtains aging resistance low-density polyethylene film.
Embodiment 3: the preparation method of a kind of aging resistance low-density polyethylene film, employing following steps:
A) 0.5 part of nano imvite is taken by mass fraction, 1.0 parts of white carbons, 0.8 part of lauryl amine polyoxyethylene ether, 0.5 part
A length of 5 μm of characterization parameter, a width of 0.10 μm attapulgite are brilliant, 0.5 part of a diameter of 1 μm of characterization parameter, Alborex M 12 of a length of 25 μm
Whisker, 1.5 parts of characterization parameter draw ratios are 16:1 wollastonite raphioid fiber, and 5.0 parts of mass fractions are the sodium bicarbonate water of 30%
Solution mixes, and stirs decatize reaction 60min, vacuum microwave radiation under the conditions of 400 DEG C in 160 DEG C of superheated steam reactors
3h, is then dipped in vacuum moisture absorption in the sulfamic acid solution that 120 parts of mass fractions are 30% and processes, inhale post-heating and surpass to 95 DEG C
Sound wave dispersion 1.5h, is stirred for disperseing 5.5h, takes float;
B) by mass fraction by step A) 4.0 parts of float obtaining divide with 100 parts of sodium tripolyphosphates Han mass fraction 5%
Dissipating deionized water ultrasonic Treatment 40min at 85 DEG C of liquid, take upper strata float and filter through 200 mesh, distilled water wash is clean,
Vacuum drying, obtains modified inorganic nano material;
C) step B is taken by mass fraction) 25 parts of modified inorganic nano materials obtained, 8.0 parts of a diameter of 5 μ of characterization parameter
M, the magnesium borate crystal whisker of length 25 μm, 5.0 parts of PE-g-MAH bulking agents, 12 parts of mass fractions be 20% KH-550 silane coupled
Agent, 0.8 part of UVP-327 UV absorbent, 0.2 part of HPT light stabilizer, 0.2 part of antioxidant, 1.0 parts of Rutile type titanium dioxide,
In mixer, stir reaction 60min, vacuum drying under the conditions of 75 DEG C with the speed of 550r/min under the conditions of 90 DEG C, add
350 parts of LDPE: Low-density polyethylene plastics powder, stir 50min with the speed of 350r/min, melt kneading extrusion at parallel dual-screw double
Aging resistance low-density polyethylene film is obtained to stretching.
Embodiment of the present invention is not limited to embodiment described above, by aforementioned disclosed numerical range, just
Specific embodiment is arbitrarily replaced, such that it is able to obtain numerous embodiment, this is not enumerated.
Claims (2)
1. the preparation method of an aging resistance low-density polyethylene film, it is characterised in that this preparation method employing following steps:
A) 0.3-0.5 part nano imvite, 0.6-1.0 part white carbon, 0.4-0.8 part lauryl amine polyoxyethylene are taken by mass fraction
Ether, 0.3-0.5 part characterization parameter a length of 0.5-5 μm, a width of 0.01-0.10 μm attapulgite are brilliant, 0.3-0.5 part characterization parameter diameter
For 0.5-1 μm, the aluminium borate whisker of a length of 10-25 μm, 1.0-1.5 part characterization parameter draw ratio is 14-16:1 wollastonite pin
Shape fiber, 3.0-5.0 part mass fraction is the sodium bicarbonate aqueous solution mixing of 20-30%, reacts at 140-160 DEG C of superheated steam
Stirring decatize reaction 45-60min in still, under the conditions of 300-400 DEG C, vacuum microwave radiation 3h, is then dipped in 80-120 part quality
Mark be 30% sulfamic acid solution in vacuum moisture absorption process, inhale post-heating to 60-95 DEG C of ultrasound wave dispersion 0.5-1.5h,
It is stirred for disperseing 4.5-5.5h, takes float;
B) by mass fraction by step A) 2.0-4.0 part float 60-100 part 3-5% trimerization phosphorus Han mass fraction of obtaining
Deionized water ultrasonic Treatment 20-40min at 75-85 DEG C of acid sodium dispersion liquid, takes upper strata float through 150-200 mesh mistake
Filter, distilled water wash is clean, and vacuum drying obtains modified inorganic nano material;
C) step B is taken by mass fraction) modified inorganic nano material that 15-25 part obtains, 5.0-8.0 part characterization parameter is a diameter of
0.2-5 μm, the magnesium borate crystal whisker of length 10-25 μm, 2.0-5.0 part PE-g-MAH bulking agent, 8.0-12 part mass fraction is 10-
The KH-550 silane coupler of 20%, 0.4-0.8 part UVP-327 UV absorbent, 0.15-0.2 part HPT light stabilizer,
0.1-0.2 part antioxidant, 0.6-1.0 part Rutile type titanium dioxide, with 450-550r/min in mixer under the conditions of 80-90 DEG C
Speed stirring reaction 45-60min, vacuum drying under the conditions of 65-75 DEG C, add 250-350 part Low Density Polyethylene and mould
Material powder, stirs 40-50min with the speed of 250-350r/min, melts the stretching of kneading extruded bidirectional at parallel dual-screw and is resisted
Aging low-density polyethylene film.
2. the preparation method of an aging resistance low-density polyethylene film, it is characterised in that this preparation method employing following steps:
A) 0.4 part of nano imvite, 0.8 part of white carbon, 0.6 part of lauryl amine polyoxyethylene ether, 0.4 part of sign are taken by mass fraction
A length of 2.5 μm of parameter, a width of 0.05 μm attapulgite are brilliant, 0.4 part of a diameter of 0.75 μm of characterization parameter, Alborex M 12 of a length of 17 μm
Whisker, 1.2 parts of characterization parameter draw ratios are 15:1 wollastonite raphioid fiber, and 4.0 parts of mass fractions are the sodium bicarbonate water of 25%
Solution mixes, and stirs decatize reaction 50min, vacuum microwave radiation under the conditions of 350 DEG C in 150 DEG C of superheated steam reactors
3h, is then dipped in vacuum moisture absorption in the sulfamic acid solution that 100 parts of mass fractions are 30% and processes, inhale post-heating and surpass to 75 DEG C
Sound wave dispersion 1h, is stirred for disperseing 5h, takes float;
B) by mass fraction by step A) 80 parts of sodium tripolyphosphate dispersion liquids Han mass fraction 4% of 3.0 parts of float of obtaining
Deionized water ultrasonic Treatment 30min at 80 DEG C, take upper strata float and filter through 170 mesh, distilled water wash is clean, vacuum
Dry, obtain modified inorganic nano material;
C) step B is taken by mass fraction) 20 parts of modified inorganic nano materials obtained, 6.5 parts of a diameter of 2.5 μm of characterization parameter,
The magnesium borate crystal whisker of length 17 μm, 3.5 parts of PE-g-MAH bulking agents, 10 parts of mass fractions be 15% KH-550 silane coupled
Agent, 0.6 part of UVP-327 UV absorbent, 0.17 part of HPT light stabilizer, 0.15 part of antioxidant, 0.8 part of rutile titanium dioxide
Powder, stirs with the speed of 500r/min in mixer under the conditions of 85 DEG C and reacts 50min, vacuum drying under the conditions of 70 DEG C, then
Add 300 parts of LDPE: Low-density polyethylene plastics powder, stir 45min with the speed of 300r/min, melt kneading at parallel dual-screw and squeeze
Go out biaxial tension and obtain aging resistance low-density polyethylene film.
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Citations (2)
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CN101701079A (en) * | 2009-10-30 | 2010-05-05 | 昆明春叶塑料制成品有限公司 | Preparation method of polyethylene mulching film master batch for magnesium salt whisker reinforced smoke |
CN103435890A (en) * | 2013-08-23 | 2013-12-11 | 吴江市英力达塑料包装有限公司 | Anti-aging plastic film and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101701079A (en) * | 2009-10-30 | 2010-05-05 | 昆明春叶塑料制成品有限公司 | Preparation method of polyethylene mulching film master batch for magnesium salt whisker reinforced smoke |
CN103435890A (en) * | 2013-08-23 | 2013-12-11 | 吴江市英力达塑料包装有限公司 | Anti-aging plastic film and preparation method thereof |
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