CN106116268A - Emulsified asphalt, containing its compound and the road surface that formed by this compound - Google Patents

Emulsified asphalt, containing its compound and the road surface that formed by this compound Download PDF

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Publication number
CN106116268A
CN106116268A CN201610478700.0A CN201610478700A CN106116268A CN 106116268 A CN106116268 A CN 106116268A CN 201610478700 A CN201610478700 A CN 201610478700A CN 106116268 A CN106116268 A CN 106116268A
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China
Prior art keywords
emulsified asphalt
asphalt
water
recycled mixture
emulsifying agent
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Pending
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CN201610478700.0A
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Chinese (zh)
Inventor
李胜强
吴剑
吴明刚
张顺松
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Xiamen Ward highway asphalt Technology Co., Ltd.
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SHANGHAI LONGFU MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201610478700.0A priority Critical patent/CN106116268A/en
Publication of CN106116268A publication Critical patent/CN106116268A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/26Bituminous materials, e.g. tar, pitch
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/18Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
    • E01C7/26Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention provides a kind of emulsified asphalt, it contains emulsifying agent, matrix pitch, optional modifying agent and water, and according to the weight meter of emulsified asphalt, it contains: emulsifying agent 2.0~4.0%, matrix pitch 60~65%, modifying agent 0~4% and appropriate water.Emulsifying agent in emulsified asphalt contains aminated lignin, aliphatic amine and water, and according to the weight meter of emulsifying agent, emulsifying agent contains: aminated lignin 23~35%, aliphatic amine 23~35% and appropriate water.Present invention also offers by this emulsified asphalt with meet the Cold Recycled Mixture with Emulsified Asphalt that the mineral aggregate that grating specifies is formed, after the relevant early strength of this compound test specimen and construction, intensity index has surmounted the relevant art index request in relevant regulations.Present invention also offers the road surface formed by this Cold Recycled Mixture with Emulsified Asphalt, it can quickly form intensity, and molding 2~the intensity index of complete core sample taken out after 3 days surmount the relevant art index request of relevant regulations.

Description

Emulsified asphalt, containing its compound and the road surface that formed by this compound
The application is entitled " the emulsifying drip of filing date in December, 2010 Application No. of 31 days 201010621385.5 Blue or green, containing its compound and the road surface that formed by this compound " the divisional application of application for a patent for invention.
[technical field]
The present invention relates to emulsified asphalt, the compound containing emulsified asphalt and the road surface formed by this compound.
[background technology]
Bituminous paving is the main road surface form of highway in China.The design period of high-grade highway is 12~15 years, China The bituminous paving that late 1980s and the beginning of the nineties build comes into the maintenance phase, and some road surface breakage is the tightest Weight.Therefore, the most quickly, these road surfaces are repaired on high-quality ground, it is ensured that the serviceability rate of existing road, reduce the old material pair in road surface as far as possible The pollution of environment, is problem encountered at present and in the future.
Traditional asphalt pavement maintenance mode is old asphalt mixture milling to be discarded, the road surface that making is new again.This Although way ensure that the usability of road, but discarded asphalt great majority are dropped, not only caused significant wastage but also It is unfavorable for environmental conservation.For old asphalt mixture, in addition to asphalt material generation part is aging, the thickness such as sand, stone is gathered materials Do not lost efficacy from performance.Therefore Applied of Asphalt Pavement Recycle Technique is widely adopted as the technology of a kind of environmental protection.
Applied of Asphalt Pavement Recycle Technique has various ways, and wherein emulsified asphalt cold recycling technology is widely used one Kind.Cold Recycled Mixture with Emulsified Asphalt is the most still in a relatively rough design and application stage, is also formed without unified Specification.In China, at present still in highway Large scale construction during, to the concern journey in terms of the maintenance of highway and regeneration Spend the most weak.Although emulsified asphalt cold recycling technology to be done some researchs and application, but due to raw material, design side The controlling factors such as method, construction technology and weather condition are unreasonable, and effect is undesirable.Particularly emulsified asphalt selection is improper usually Compound intensity can be caused not enough, and de-emulsification speed is crossed the road surface after causing molding slowly and the most do not possessed intensity, thus significantly Delay the open to traffic time, have a strong impact on the construction speed in later stage, and easily cause the early damage on road surface, cause cost Increase and the waste of resource.
Accordingly, it is desired to provide a kind of, stability is more preferable, versatility is higher, wrap type more preferably, early strength is bigger, use the longevity Order longer emulsified asphalt.At the same time, it is desirable to provide the Cold Recycled Mixture with Emulsified Asphalt containing this emulsified asphalt and mixed by this Close the road surface that material is formed.
[summary of the invention]
An object of the present invention is to provide a kind of emulsified asphalt, compound containing this emulsified asphalt and by this mixing The road surface that material is formed.The emulsified asphalt of the present invention solves the defect of prior art, have that stability is more preferable, versatility is higher, The advantage that the type that wraps is more preferable, early strength is bigger, service life is longer.The above-mentioned purpose of the present invention obtains by the following technical programs To realize:
Technical solution of the present invention 1 provides a kind of emulsified asphalt, and it contains emulsifying agent, matrix pitch, optional modifying agent And water, according to the weight meter of emulsified asphalt, it contains: emulsifying agent 2.0~4.0%, matrix pitch 60~65%, modifying agent 0~ 4% and appropriate water.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein said emulsifying agent contains aminated lignin, fat Fat race amine and water, according to the weight meter of emulsifying agent, it contains: aminated lignin 23~35%, aliphatic amine 23~35% and Appropriate water.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein said matrix pitch is asphalt, wherein The needle penetration of described asphalt is 50-120.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein said modifying agent is high molecular polymer.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein said modifying agent is selected from butylbenzene block copolymerization One or more in thing, butadiene-styrene rubber and polyethylene.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein said aminated lignin is by amine chemical combination The product that thing, aldehyde compound and lignin obtain through Mannich reaction.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein said aminated lignin selects free divinyl Triamine, formaldehyde, broad-leaved Masson Pine quality obtain product and by triethylene tetramine, formaldehyde, needle Masson Pine quality warp through Mannich reaction One or more in the product that Mannich reaction obtains.
The emulsified asphalt provided according to technique scheme 1 of the present invention, the carbon number of wherein said aliphatic amine is 12- 22, amine groups is primary amine and/or secondary amine.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein the carbon number of aliphatic amine is 16, amido Group is secondary amine.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein emulsified asphalt is possibly together with pH value regulator, its After middle addition pH value regulator, the pH value range of emulsified asphalt is between 1.5~6.5.
The emulsified asphalt provided according to technique scheme 1 of the present invention, wherein pH value regulator is hydrochloric acid.
Technical scheme 2 provides a kind of Cold Recycled Mixture with Emulsified Asphalt, its contain milling material, newly gather materials, Optional breeze, emulsified asphalt, optional cement and water, according to the weight meter of Cold Recycled Mixture with Emulsified Asphalt, it contains: Milling material 60~95%, cement 0~2%, breeze 0~5%, emulsified asphalt 3.0~5.0%, external adding water 1~4% and appropriate Newly gather materials, wherein emulsified asphalt is the described emulsified asphalt provided according to technique scheme 1 of the present invention.
The Cold Recycled Mixture with Emulsified Asphalt provided according to technique scheme 2 of the present invention, wherein said milling material contains The first milling material in the range of 0-9.5mm of granularity and granularity the second milling material in the range of 9.5-31.5mm.
The Cold Recycled Mixture with Emulsified Asphalt provided according to technique scheme 2 of the present invention, newly gathers materials selected from Calx One or more in rock, dolomite, basalt, sandstone, granite.
The Cold Recycled Mixture with Emulsified Asphalt provided according to technique scheme 2 of the present invention, wherein breeze is limestone, its Particle diameter≤the 0.075mm of middle limestone.
The Cold Recycled Mixture with Emulsified Asphalt provided according to technique scheme 2 of the present invention, the morning of wherein said compound Phase intensity is represented by the parameter selected from the loss of brush test mass and/or rut plate coring integrity degree, wherein brush test mass Loss is not more than 2.0%, and rut plate coring integrity degree is not less than 80%.
The Cold Recycled Mixture with Emulsified Asphalt provided according to technique scheme 2 of the present invention, wherein said compound strong Degree index, water stability index and/or high-temperature stability index all surmount " asphalt highway regeneration techniques specification " (JTG F41-2008) the relevant art index request of regulation in.
Technical scheme 3 provides a kind of road surface, and wherein said road surface is by according to technique scheme 2 of the present invention The described Cold Recycled Mixture with Emulsified Asphalt provided is formed, described pavement construction molding 2~can take out complete core sample after 3 days, and The intensity index of complete core sample surmounts the corresponding skill of regulation in " asphalt highway regeneration techniques specification " (JTG F41-2008) Art index request.
The road surface provided according to technique scheme 3 of the present invention, wherein Cold Recycled Mixture with Emulsified Asphalt can be formed following Layer or described cutting optimal any layer below.
The advantage of the emulsified asphalt according to the present invention is: it can meet with formate gradation composition, and " asphalt highway regenerates Technical specification " (JTG F41-2008) mineral aggregate of specifying carries out being mixed to form Cold Recycled Mixture with Emulsified Asphalt, and emulsified asphalt Cold regeneration mix intensity index, water stability index, high-temperature stability index all surmount " asphalt highway regeneration techniques rule Model " (JTG F41-2008) middle relevant art index request specified.Thus it has versatility.
The advantage of the emulsified asphalt according to the present invention also resides in: it just can meet " public by less amount with formate gradation composition Road Applied of Asphalt Pavement Recycle Technique specification " (JTG F41-2008) mineral aggregate of specifying carries out being mixed to form the mixing of emulsified asphalt cold renewal Expect, and Cold Recycled Mixture with Emulsified Asphalt intensity index, water stability index, high-temperature stability index all surmount " highway asphalt Pavement recycling technical specification " (JTG F41-2008) middle relevant art index request specified.Thus it has reduction cost, wraps up in Cover the more preferable advantage of effect.
The advantage of the emulsified asphalt according to the present invention also resides in: its also have stability more preferably, early strength bigger and The advantage that service life is longer.
The early strength index of the Cold Recycled Mixture with Emulsified Asphalt formed by the emulsified asphalt containing the with good grounds present invention, water Stability indicator, high-temperature stability index have all surmounted rule in " asphalt highway regeneration techniques specification " (JTG F41-2008) Fixed relevant art index request, thus repair road surface for quick high-quality ground and provide the foundation, it is effectively utilized Colophonium to be repaired The milling material on road surface, reduces environmental pollution.
It is by the advantage on the road surface formed according to the Cold Recycled Mixture with Emulsified Asphalt of the present invention: can after pavement construction Quickly form intensity, within 2~3 days, i.e. can be taken off complete core sample, and core sample intensity has surmounted, and " asphalt highway regeneration techniques is advised Model " (JTG F41-2008) middle corresponding index requirement specified, thus it is effectively guaranteed the serviceability rate of existing road.
[accompanying drawing explanation]
Referring to the drawings, the disclosure will be easier to understand.Skilled addressee readily understands that: this A little accompanying drawings are used only for illustrating technical scheme, and are not intended to be construed as limiting protection scope of the present invention. In figure:
Fig. 1 shows embodiment 1 Mineral Material final gradation curve.
Fig. 2 shows the curve determining optimal water consumption in embodiment 1 by heavy compaction method.
Fig. 3 shows the cleavage strength of Cold Recycled Mixture with Emulsified Asphalt relevant with Asphalt emulsion content in embodiment 1 Curve.And
Fig. 4 shows embodiment 2, embodiment 3, embodiment 4 Mineral Material final gradation curve.
[detailed description of the invention]
How Fig. 1-4 and the optional embodiment following description describing the present invention are implemented with teaching those skilled in the art With the reproduction present invention.In order to instruct technical solution of the present invention, simplify or eliminated some conventional aspects.Those skilled in the art Should be appreciated that and be derived from the modification of these embodiments or replace and will fall within the scope of the present invention.Those skilled in the art should manage Solve following characteristics and can combine to be formed multiple modification of the present invention in every way.Thus, the invention is not limited in following Optional embodiment, and only limited by claim and their equivalent.
Before the detailed description of the invention of the present invention is described in detail, first to some terms used in the present invention It is defined.Emulsifying agent refers to the material promoting two kinds of immiscible materials to form stable emulsion.The effect of emulsifying agent is Reduce the surface tension of dispersion phase, form thin film or electric double layer on the drop surface of dispersion phase to stop drop mutually to be assembled, to coagulate Knot.Emulsified asphalt is the asphalt emulsion prepared by mechanical dispersion by two kinds of mutual exclusive material Colophoniumes and water, drip Green grass or young crops is scattered in the aqueous solution containing emulsifying agent with tiny graininess.Emulsified asphalt mainly contains Colophonium, emulsifying agent, modification Agent and water.Emulsified asphalt is according to electrically charged anionic, cationic and nonionic three class of can being divided into of microgranule, according to broken Breast speed speed can be divided into again split soon type, in split type and slow breaking three kinds.Emulsified asphalt one in cold regeneration mix As be cation slow breaking.When emulsified asphalt mixes with mineral aggregate, emulsified asphalt medium pitch granule is with electric charge, and it can be with band The mineral aggregate microgranule having opposite charges firmly and equably combines.This improves pavement strength, slow down the premature ageing of Colophonium, prolongs Grow the service life on road surface.In this article mineral aggregate selected from milling material, newly gather materials, one or more in breeze and cement.
In this article, term Cold Recycled Mixture with Emulsified Asphalt refer to emulsified asphalt and milling material, newly gather materials, cement, ore deposit The compound that powder and water are formed according to a certain percentage.Wherein milling material refer to by bituminous paving to be repaired through milling, be dried with And the material obtained after screening.Milling material is generally divided into the first milling material (thin milling material) and the 9.5-31.5mm of 0~9.5mm The second milling material (thick milling material) two grades.Newly gather materials refer to new production out have certain particle diameter composition rubble or ovum Stone, can be one or more in limestone, dolomite, basalt, sandstone, granite.
An aspect of of the present present invention provides a kind of emulsified asphalt, its contain emulsifying agent, matrix pitch, optional modifying agent and Water, according to the weight meter of emulsified asphalt, it contains: emulsifying agent 2.0~4.0%, matrix pitch 60~65%, modifying agent 0~4% And appropriate water.Wherein it is preferred to, emulsifying agent contains aminated lignin, aliphatic amine and water, according to the weight of emulsifying agent Meter, it contains: aminated lignin 23~35%, aliphatic amine 23~35% and appropriate water.Wherein it is preferred to, amination wood Quality selects product that free diethylenetriamine, formaldehyde, broad-leaved Masson Pine quality obtain through Mannich reaction and by triethylene tetramine, first One or more in the product that Mannich reaction obtains of aldehyde, needle Masson Pine quality.Preferably, the carbon atom of aliphatic amine Number is 12-22, and amine groups is usually primary amine and/or secondary amine.It is highly preferred that the carbon number of aliphatic amine is 16, amido base Group is secondary amine.Wherein it is preferred to, matrix pitch be needle penetration be the asphalt of 50-120, such as 70# asphalt.Such as More preferably shell 70# asphalt or Zhenghai 70# asphalt.Wherein it is preferred to, modifying agent be selected from SBS, SBR and One or more in polyethylene, wherein SBS is butadiene-styrene block copolymer, and SBR is butadiene-styrene rubber.In the emulsifying according to the present invention In agent and emulsified asphalt, alternatively, water is common drinking water.
Another aspect provides a kind of Cold Recycled Mixture with Emulsified Asphalt containing above-mentioned emulsified asphalt, it contains Have milling material, newly gather materials, optional breeze, optional cement, emulsified asphalt and external adding water, mix according to emulsified asphalt cold renewal Closing the weight meter of material, it contains: milling material 60~95%, cement 0~2%, breeze 0~5%, emulsified asphalt 3.0~5.0%, External adding water 1~4% and appropriate newly gathering materials.This compound has preferable early strength, water stabilizing and high-temperature behavior, And intensity exceedes the relevant art that " asphalt highway regeneration techniques specification " (JTG F41-2008) specify and refers to after its construction Mark requirement.
It is yet another aspect of the present invention to provide the preparation method of a kind of above-mentioned emulsified asphalt, the preparation side of described emulsified asphalt Method comprises the steps:
A: stir after being mixed according to the ratio of design with the emulsifying agent of the present invention by the water of 55~60 DEG C preparation soap lye, Being added thereto to a certain amount of hydrochloric acid and adjust the pH value of soap lye, according to the needs of engineering, the scope of pH value is typically 1.5~6.5 Between.
B: be positioned in the constant temperature oven of about 55 DEG C after about 2h after the soap lye tinfoil prepared in step a is sealed, Add the Colophonium (if desired add stabilizer or/and modifying agent) fully of 130~140 DEG C again according to design proportion in soap lye Stir.
C: the solution prepared in step b is i.e. prepared emulsified asphalt by after emulsified asphalt colloid mill.
Another aspect of the invention provides the preparation method of a kind of above-mentioned Cold Recycled Mixture with Emulsified Asphalt, described emulsifying The preparation method of cold asphalt rehabilitation compound comprises the steps:
Step 1: analyze milling material;
Step 2: design mineral aggregate gradation;
Step 3: prepare emulsified asphalt;
Step 4: early strength is tested;
Step 5: determine optimal water consumption;
Step 6: determine optimum emulsification asphalt content;And
Step 7: based on a determination that optimal water consumption and optimum emulsification asphalt content formed Cold Recycled Mixture with Emulsified Asphalt.
In above-mentioned steps 1, analyze milling material and refer to, by sieving stepping after milling material sampling drying, be generally divided into 0- The thin milling material of 9.5mm and the thick milling material of 9.5-31.5mm two grades, analyze thick milling material and the grating of thin milling material.The present invention's In one embodiment, milling material sampling refers to use special milling machine that old asphalt pavement is carried out milling sampling.
In step 2 above, design grating be to milling material, newly gather materials, cement, breeze carry out grating according to a certain percentage Synthesis, it is desirable to formate gradation composition meets emulsified asphalt cold renewal in " asphalt highway regeneration techniques specification " (JTG F41-2008) The grading limit requirement of compound.In one particular embodiment of the present invention, give milling material, newly gather materials and cement close Become a preferred embodiment of grating, as shown in Table 2 and Figure 1.As long as it should be noted that milling material, newly gather materials, cement, breeze Formate gradation composition meet Cold Recycled Mixture with Emulsified Asphalt in " asphalt highway regeneration techniques specification " (JTG F41-2008) Grading limit requirement, as long as then according to its component content in above-mentioned Cold Recycled Mixture with Emulsified Asphalt, mineral aggregate just can be with breast Change Colophonium and water just can form the Cold Recycled Mixture with Emulsified Asphalt according to the present invention.
In above-mentioned steps 3, prepare emulsified asphalt and refer to the preparation method of above-mentioned emulsified asphalt.
In above-mentioned steps 4, the early strength test of Cold Recycled Mixture with Emulsified Asphalt is divided into brush test and rut plate Coring test.Brush test refers to: 1) use gyratory compaction method forming diameter 150mm, high 75~the test specimen of 85mm;2) then will Test specimen is placed in the climatic chamber (such as, the climatic chamber of LHS-100CL model) of 25 DEG C (degree Celsius), 70% humidity Place about 4h and carry out health preserving;3) finally this test specimen is rotated under the conditions of such as outside 1.25 ° of angle and 600KPa experimental condition 40 times." asphalt highway regeneration techniques specification " (JTG F41-2008) requires that Cold Recycled Mixture with Emulsified Asphalt brush is tested Mass loss rate≤2.0%.Rut plate coring test refers to: 1) trial-production thickness is the rut plate of 10cm, and wherein this rut plate divides Rolling for twice and form, roll thickness is 5cm every time, and the mode that rolls is according to " Colophonium and Asphalt Mixture Experiment code " operation;2) By the rut plate manufactured experimently 25 DEG C, the climatic chamber of 70% humidity places about 24h;3) finally to rut plate coring Sample." asphalt highway regeneration techniques specification " (JTG F41-2008) requires integrity degree >=80% of rut plate coring sample.
In above-mentioned steps 5, determine that optimal water consumption refers to according to Cold Recycled Mixture with Emulsified Asphalt primary election grading method, Emulsified asphalt content is set to about 4%, and additional water consumption is respectively adopted 1.0%, 1.5%, 2.0%, 2.5%, 3.0%, presses According to the heavy compaction method of regulation in " highway earthwork test rule " (JTG E40-2007) T 0131-2007, most preferably use The water yield is tested, and draws curve, using water consumption corresponding for the maximum dry density of Cold Recycled Mixture with Emulsified Asphalt test specimen as Good water consumption.In one particular embodiment of the present invention, give and determine one example of optimal water consumption, such as table 5 and Fig. 2 institute Show.
In above-mentioned steps 6, determine that optimum emulsification asphalt content refers to the optimal water consumption determined according to heavy compaction method, In the range of 3.0%-5.0%, amplification according to 0.5% adjusts the content of emulsified asphalt, forms 5 kinds of emulsified asphalt cold renewal mixed Close material, and be molded into 5 kinds of corresponding Cold Recycled Mixture with Emulsified Asphalt test specimens.Cold Recycled Mixture with Emulsified Asphalt specimen molding side Method uses gyratory compaction method, and its experimental condition be 1.25 ° of angle, outside, 600kPa, gyratory compaction number of times 40 times.Emulsifying after molding Cold asphalt rehabilitation compound test specimen is according to the health preserving of regulation in " asphalt highway regeneration techniques specification " (JTG F41-2008) Method carries out health preserving, and health preserving carries out 15 DEG C of dry splittings and immersion diametral compression test after terminating, meet in voidage and Ratio of split strength On the premise of " asphalt highway regeneration techniques specification " (JTG F41-2008), right with 15 DEG C of immersion cleavage strength maximum institutes The Asphalt emulsion content answered is optimum emulsification asphalt content.
In above-mentioned steps 7, based on a determination that optimal water consumption and optimum emulsification asphalt content formed emulsified asphalt cold again Raw mix refers to: mineral aggregate step 2 designed after room temperature dry mixing 15~45s, adds step 5 in mineral aggregate and obtains in mixing pot Stir 30~60s after the external adding water consumption corresponding to optimal water consumption arrived, add the optimum amount that step 6 obtains afterwards Emulsified asphalt also stirs 30~60s and i.e. obtains Cold Recycled Mixture with Emulsified Asphalt.
The another further aspect again of the present invention provides emulsified asphalt cold renewal mixing prepared by a kind of method as described above The method for testing performance of material, described detection method comprises the steps:
Step I: Cold Recycled Mixture with Emulsified Asphalt prepared by method as described above is molded into test specimen and to test specimen Carry out health preserving, in terms of intensity, water stability and high-temperature stability three, the performance of test specimen detected subsequently, wherein when On the premise of its intensity and water stability meet " asphalt highway regeneration techniques specification " (JTG F41-2008), perform step Ⅱ;
In above-mentioned steps I: in " asphalt highway regeneration techniques specification " (JTG F41-2008) to ruggedness test and The concrete regulation of water stability inspection is as follows:
1). ruggedness test
15 DEG C of cleavage strength >=0.6MPa (specification regulation basic unit and 15 DEG C of cleavage strength >=0.4MPa of underlayment, cutting optimal ≥0.5MPa)。
Marshall stability >=7KN (specification regulation basic unit and underlayment Marshall stability >=5KN, cutting optimal >=6KN).
2). water stability is checked
Dry and wet Ratio of split strength >=85%, (specification regulation >=75%)
Marshall residual stability MS0 >=85%, (specification regulation >=75%)
Indirect tensile test on frozen-thaw, strength ratio TSR >=80%.(specification regulation >=70%)
3). high-temperature stability is checked
Wheel tracking test dynamic stability test, 60 DEG C of rut dynamic stability >=1000 time/mm;(specification requires)
Step II: Cold Recycled Mixture with Emulsified Asphalt method as described above prepared is raw by special batching plant Puerperal the scene of transporting carry out paving, roller-compaction road surface;Then to the road surface coring sample of roller-compaction and to the core sample obtained Carry out core sample integrity degree and cleavage strength detection.
In above-mentioned steps II, typical case's scheme of rolling is shown in Table 1.
Table 1 Cold Recycled Mixture with Emulsified Asphalt rolls scheme
Roll the stage Road roller type and quantity Roll mode and pass Observation rolling speed
First pressing 10~13 tons of dual-steel wheel road rollers (1~2) Before quiet after shake 1 time About 4.0km/h
Multiple pressure More than 20 tons dual-steel wheel road rollers (1~2) Shake by force 4 times About 4.0km/h
Final pressure More than 26 tons pneumatic-tired rollers (1~2) Static pressure 4 times About 3.5km/h
Under the conditions of fine, the road surface using emulsified asphalt of the present invention to be formed after being rolled by this scheme of rolling has been rolled After get final product open to traffic, within 2~3 days, i.e. can be taken off complete core sample 15 DEG C of the core sample splitting can taken out after outrigger location layer, and 3 days Intensity >=0.5MPa, reaches cutting optimal requirement." asphalt highway regeneration techniques specification " (JTG F41-2008) then requirement It is open to traffic after 1 day, within least 7 days, takes out complete core sample and outrigger location, core sample intensity is not done requirement.
Embodiment 1
The project profile of the present embodiment is: the test paragraph of Cold Recycled Mixture with Emulsified Asphalt is the new woods in Senior Residents in Fengxian District of Shanghai Road, Cold Recycled Mixture with Emulsified Asphalt is located below layer, and design thickness is 8cm, and enforcement paragraph is K2+560-K3+700.New woods Road is the east-west Class III highway in one, Fengxian District, design speed about 40km/h.
(1) milling material design mineral aggregate gradation is analyzed
According to above-mentioned step 1, use the milling machine of the special root W2000 model of such as dimension that bituminous paving to be repaired is carried out milling Dig sample, then the milling material obtained is put into electric oven (such as Binder baking oven) and dry at a temperature of about about 60 DEG C Dry, use 9.5mm mesh screen to be divided into the thick milling material of 9.5~26.5mm and the thin milling material of 0~9.5mm subsequently.Then will take The thickness milling material obtained and the limestone of 10~25mm, No. 32.5 cement of normal silicate are according to ratio synthesis as shown in table 2 Mineral aggregate formate gradation composition, the mineral aggregate formate gradation composition of synthesis is analyzed according to the sieve of 12 kinds of screen sizes as shown in table 2, table 2 He Fig. 1 shows shelves material screening result and formate gradation composition.From table 2 and Fig. 1, mineral aggregate formate gradation composition is positioned at " asphalt highway Regeneration techniques specification " between (JTG F41-2008) the grating upper limit and grating lower limit of requiring, such as through 2.36mm's The mineral aggregate gradation of the granule after sieve aperture screening is 30.19%, fall between the 15-45% of code requirement, similarly to warp Cross the mineral aggregate gradation after the sieve aperture screening of 4.75mm and 9.5mm also to have respectively fallen in the range of code requirement.This shows such as table 2 With the mineral aggregate gradation compliant requirement shown in Fig. 1.Be described below according to an embodiment of the invention emulsified asphalt with upper State the mixed Cold Recycled Mixture with Emulsified Asphalt of mineral aggregate and the performance test thereof of grating.
Table 2 each shelves material screening result and final gradation
(2) design of emulsified asphalt formula and preparation
Table 3 shows different emulsified asphalt formula design, wherein, in formula A: the first splits fast solidifying type emulsifying agent slowly is river The high and steep qi of Yinshih (St 33) sensible chemical plant JQT-2 type splits emulsifying agent slowly;In formula B: it is that Jiangyin City is flourish that the second splits fast solidifying type emulsifying agent slowly Road and bridge material technology development corporation, Ltd. RC-SFRHJ803 is become to split fast solidifying type emulsifying agent slowly;Formula C is the emulsified asphalt of the present invention Formula, wherein the third splits fast solidifying type emulsifying agent slowly is the emulsifying agent according to the present invention.In above-mentioned 3 kinds of formula, matrix pitch For Zhenghai 70# Colophonium, water is common drinking water.According to the formula of the emulsifying agent of the present invention be wherein: 26% by divinyl three Amine, formaldehyde, broad-leaved Masson Pine quality obtain aminated lignin through Mannich reaction, the carbon number of 33% be 16 amidos be secondary amine Aliphatic amine and the water of 41%.
The preparation method of the emulsified asphalt of above-mentioned three kinds of formula is as follows: at a temperature of 58 (± 2 DEG C) DEG C, Jiang Shui and three kinds are joined In side A, B, C, emulsifying agent stirs configuration soap lye after proportionally mixing, and is subsequently added into the concentrated hydrochloric acid of room temperature, by their pH It is adjusted to about 2.0.The such as LHS-100CL model of about 55 DEG C it is positioned over after being sealed by the soap lye tinfoil configured subsequently Calorstat in after about 2h, then in soap lye, add Zhenghai 70# Colophonium fully of 135 (± 2 DEG C) DEG C according to respective ratio Stir.Then the solution configured i.e. is prepared emulsified asphalt by after emulsified asphalt colloid mill.
Table 3 different emulsified asphalt formula design
In three shown in table 3 kind emulsified asphalt formula, the emulsifier of the present invention is minimum.
(3) early strength test
By the emulsified asphalt of above-mentioned three kinds of formula respectively according to 4.0%, the ratio of external adding water 2.0% and the ore deposit of above-mentioned grating Material mixes and stirs in gilson MA-67F mixing device, and the mode of mixing and stirring is under room temperature after mineral aggregate dry mixing about 30s, to mineral aggregate Stir about 45s after the external adding water consumption corresponding to optimal water consumption that middle addition step 5 obtains, add step 6 afterwards and obtain To the emulsified asphalt of optimum amount and stir about 45s and i.e. obtain Cold Recycled Mixture with Emulsified Asphalt, with TROXLER 4141 Type rotary compactor is molded into diameter 150mm, high by 78 (± 2mm) mm under outside 1.25 ° of angle and 600KPa experimental condition respectively Test specimen, number of revolutions is 40 times, by these test specimens 25 DEG C, in the climatic chamber of the LHS-100CL model of 70% humidity Placing about 4h and carry out health preserving, and carry out brush test and rut plate coring test respectively, result of the test is shown in Table 4.
The different emulsified asphalt formula cold regeneration mix early strength result of the test of table 4
Emulsified asphalt formula Brush test mass loss (%) Rut plate coring integrity degree (%)
Formula A 4.8 64.3
Formula B 4.2 73.6
Formula C 1.5 85.7
Result of the test shows, although the corresponding emulsifying than in its Formulations Formula of the emulsifier content in the emulsified asphalt of the present invention The content of agent is the fewest, but the early strength of the Cold Recycled Mixture with Emulsified Asphalt of the present invention is best, and its brush test mass damages Losing and be about 1.5%, its rut plate coring integrity degree is of about 85.7%, and the early stage meeting Cold Recycled Mixture with Emulsified Asphalt is strong The requirement of degree.
(4) determination of optimal water consumption
Determine that method is tested according to water consumption optimal in above-mentioned steps 5, and draw a diagram (as shown in table 5 and Fig. 2). The result of the test of the Cold Recycled Mixture with Emulsified Asphalt test specimen according to the present invention is understood, when emulsified asphalt cold renewal by table 5 and Fig. 2 When mixture moisture content is 3.41%, Cold Recycled Mixture with Emulsified Asphalt test specimen dry density is maximum.Thus, the present invention in this project The optimal water consumption corresponding to Cold Recycled Mixture with Emulsified Asphalt be of about 3.41%.
The Cold Recycled Mixture with Emulsified Asphalt test specimen dry density test result of table 5 present invention
(5) determination of asphalt optimum content
Determine 5 kinds of test specimens of method molding according to above-mentioned steps 6 asphalt optimum content, carry out density test, 15 DEG C of dry splittings Intensity and 15 DEG C of immersion cleavage strengths tests, result of the test is shown in Table 6 respectively, table 7 and Fig. 3.
Table 6 density measurement result
Table 7 cleavage strength result of the test
By table 6, table 7 and Fig. 3 result of the test can preliminary judgement, when Asphalt emulsion content is 4.0%, its with such as table 2 15 DEG C of the emulsified asphalt cold renewal mixture that shown design level compounding is formed after closing are dry splits intensity and 15 DEG C of immersion splittings Maximum intensity.Thus, the optimum emulsification asphalt content for the mineral aggregate formate gradation composition shown in table 2 is of about 4%.Based on above-mentioned really Determining the test of optimum emulsification asphalt content, after conversion, Cold Recycled Mixture with Emulsified Asphalt contains following component by weight: milling The limestone (newly gathering materials) about 9.39% of material about 83.57%, 10~20mm, cement about 0.94%, external adding water are about 2.1% and emulsified asphalt about 4.0%.
6) the performance detection of compound
Employing in embodiment 1 is met regulation and designs grating, optimum emulsification asphalt content and optimal water consumption molding Cold Recycled Mixture with Emulsified Asphalt test specimen carries out indirect tensile test on frozen-thaw and wheel tracking test, the respectively mixing of inspection emulsified asphalt cold renewal The water stabilizing of material and high-temperature behavior.
Table 8 indirect tensile test on frozen-thaw result
Table 9 wheel tracking test result
Note: D in table45And D60Represent deflection when rut test piece is tested 45 minutes and 60 minutes respectively.
The freeze-thaw split strength ratio of the Cold Recycled Mixture with Emulsified Asphalt test specimen of 1 the most according to embodiments of the present invention It is 82.9%, far above " asphalt highway regeneration techniques specification " (JTG F41-2008) requirement not less than 70% (such as Shown in specification sheet 5.4.3).
As shown in Table 9, the average dynamic stability of wheel tracking test of Cold Recycled Mixture with Emulsified Asphalt test specimen is 1382 times/mm, Exceed the high-temperature behavior requirement of cutting optimal in " bituminous pavement design for highway specification ".
7) Pavement Performance detection
The Cold Recycled Mixture with Emulsified Asphalt of 1 uses ARPC400 type full-automatic reworked material mix according to embodiments of the present invention Standing to transport after producing and pave to scene, paver is that Germany produces Fu Gele SUPER-2100 type paver, then uses 12 tons Dual-steel wheel road roller, strong and 26 tons the gluing wheel road roller of single-drum road roller of 22 tons enter according to mode as described in Table 1 Roller-compaction road surface after row first pressing, multiple pressure and final pressure.After pavement construction completes, in 5 day time, carry out on-the-spot coring sample respectively, with The integrity degree of rear detection core sample, testing result is shown in Table 10.
Table 10 has been constructed rear core sample testing result
As shown in Table 10, according to an embodiment of the invention Cold Recycled Mixture with Emulsified Asphalt in fine condition Under, the road surface that the scheme of rolling as shown in Table 1 is formed after rolling gets final product open to traffic after having rolled, and within 2~3 days, i.e. can be taken off Whole core sample the 15 DEG C of cleavage strength >=0.5MPa of core sample that can obtain after outrigger location layer, and 3 days, reach cutting optimal requirement.
Skilled addressee readily understands that: public affairs can be competent at according to the Cold Recycled Mixture with Emulsified Asphalt of the present invention Cutting optimal and following any floor position thereof in the pavement structure of road.
Similarly, embodiment 2, embodiment 3, embodiment 4 are carried out according to the step in embodiment 1 respectively, are individually below Embodiment 2, embodiment 3, the test of embodiment 4 and testing result:
Table 11 embodiment 2, embodiment 3, embodiment 4 each shelves material screening result and final gradation
(2) design of emulsified asphalt formula and preparation
Table 12 embodiment 2, embodiment 3, embodiment 4 emulsified asphalt formula design
In three shown in table 12 embodiment in emulsified asphalt formula, the formula of the emulsifying agent in embodiment 2,3 and 4 For: the aminated lignin obtained through Mannich reaction by diethylenetriamine, formaldehyde, broad-leaved Masson Pine quality of 33%, the carbon of 31% Aliphatic amine and the drinking water of 36% that atomic number is 16, amido is secondary amine.Emulsified asphalt in above three embodiment Preparation method is as follows: stirs after proportionally being mixed with different amounts emulsifying agent by water at a temperature of 58 (± 2 DEG C) DEG C and joins Put soap lye, be subsequently added into the concentrated hydrochloric acid of room temperature, their pH is adjusted to about 6.0.The soap lye tinfoil that will configure subsequently In the calorstat of the such as LHS-100CL model being positioned over about 55 DEG C after sealing after about 2h, then according to respective in soap lye The shell of ratio addition 135 (± 2 DEG C) DEG C or the modifying agent of Zhenghai 70# Colophonium and respective corresponding ratio and type are the most fully Stir.Then the solution configured i.e. is prepared emulsified asphalt by after emulsified asphalt colloid mill.
(3) early strength test
By the emulsified asphalt of emulsified asphalt formula in above three embodiment respectively according to 4.0%, the ratio of external adding water 2.0% The mineral aggregate of example and above-mentioned grating mixes and stirs, shaping test piece (mode according in embodiment 1), and carry out respectively brush test and Rut plate coring test, result of the test is shown in Table 13.
The different emulsified asphalt formula cold regeneration mix early strength result of the test of table 13
Emulsified asphalt formula Brush test mass loss (%) Rut plate coring integrity degree (%)
Embodiment 2 1.85 82.1
Embodiment 3 0.93 94.5
Embodiment 4 1.35 88.7
Result of the test shows, no matter uses Zhenghai 70# Colophonium or uses shell 70# Colophonium, changing with or without employing Property agent or use which kind of modifying agent in SBS and SBR, the early strength of the Cold Recycled Mixture with Emulsified Asphalt of the present invention is the most relatively Good, meet the requirement of the early strength of Cold Recycled Mixture with Emulsified Asphalt.
(4) optimal water consumption and the determination of asphalt optimum content
Determine that in method and steps 6, the method for asphalt optimum content is respectively adopted according to water consumption optimal in above-mentioned steps 5 Emulsified asphalt formula in embodiment 2, embodiment 3, embodiment 4 is tested, and draws the optimum moisture content, of different embodiment Good asphalt content and character index thereof are shown in Table 14:
Character index under the different optimal water consumption of embodiment of table 14 and optimum emulsification asphalt content
By the result of the test of table 14 can preliminary judgement, different emulsified asphalt formula are based on optimal water consumption and optimum emulsification Marshall stability under asphalt content, residual Marshall stability, cleavage strength, dry and wet Ratio of split strength have all surmounted specification Required character index.
Through conversion, in each embodiment, different percentage ratios shared by raw material are shown in Table 15 respectively:
Different percentage ratios shared by raw material in each embodiment of table 15
Have being formed according to the mode described in embodiment 1 corresponding to ratio shown in table 15, embodiment 2,3 and 4 Cold Recycled Mixture with Emulsified Asphalt.
6) the performance detection of compound
Embodiment 2, embodiment 3, embodiment 4 according to respective design grating, optimum emulsification asphalt content and are most preferably used The Cold Recycled Mixture with Emulsified Asphalt test specimen of water yield molding carries out indirect tensile test on frozen-thaw and wheel tracking test, checks emulsified asphalt respectively The water stabilizing of cold regeneration mix and high-temperature behavior.
Table 16 each embodiment indirect tensile test on frozen-thaw result
Table 17 each embodiment wheel tracking test result
Note: D in table45And D60Represent deflection when rut test piece is tested 45 minutes and 60 minutes respectively.
Strong according to the freeze-thaw split of the Cold Recycled Mixture with Emulsified Asphalt test specimen of the present invention in each embodiment as shown in Table 16 Degree ratio is all higher than being 80%, far above " asphalt highway regeneration techniques specification " (JTG F41-2008) wanting not less than 70% Ask (such as shown in specification sheet 5.4.3).
As shown in Table 17, in each embodiment, the wheel tracking test dynamic stability of Cold Recycled Mixture with Emulsified Asphalt test specimen is all higher than 1000 times/mm, exceed the high-temperature behavior requirement of cutting optimal in " bituminous pavement design for highway specification ".
7) indoor rut plate performance detection
After having constructed according to embodiment 2, embodiment 3, the Cold Recycled Mixture with Emulsified Asphalt of embodiment 4 present invention, 5 days Carrying out on-the-spot coring sample in time respectively, detect the integrity degree of core sample subsequently, testing result is shown in Table 18.
The each embodiment of table 18 has been constructed rear core sample testing result
As shown in Table 18, embodiment 2, embodiment 3, embodiment 4 Cold Recycled Mixture with Emulsified Asphalt under different weather, by The road surface that the scheme of rolling shown in table 1 is formed after rolling gets final product open to traffic after having rolled, and within 2~3 days, i.e. can be taken off complete core Sample (integrity degree >=80%) and can complete 15 DEG C of cleavage strength >=0.5MPa of core sample after outrigger location layer, and 3 days, reach cutting optimal Requirement.
Skilled addressee readily understands that: public affairs can be competent at according to the Cold Recycled Mixture with Emulsified Asphalt of the present invention Cutting optimal and following any floor position thereof in the pavement structure of road.
The advantage of the emulsified asphalt according to the present invention is: it can meet with formate gradation composition, and " asphalt highway regenerates Technical specification " (JTG F41-2008) mineral aggregate of specifying carries out being mixed to form Cold Recycled Mixture with Emulsified Asphalt, and emulsified asphalt Cold regeneration mix intensity index, water stability index, high-temperature stability index all surmount " asphalt highway regeneration techniques rule Model " (JTG F41-2008) middle relevant art index request specified.Thus it has versatility.
The advantage of the emulsified asphalt according to the present invention also resides in: it just can meet " public by less amount with formate gradation composition Road Applied of Asphalt Pavement Recycle Technique specification " (JTG F41-2008) mineral aggregate of specifying carries out being mixed to form the mixing of emulsified asphalt cold renewal Expect, and Cold Recycled Mixture with Emulsified Asphalt intensity index, water stability index, high-temperature stability index all surmount " highway asphalt Pavement recycling technical specification " (JTG F41-2008) middle relevant art index request specified.Thus it has reduction cost, wraps up in Cover the more preferable advantage of effect.
The advantage of the emulsified asphalt according to the present invention also resides in: its also have stability more preferably, early strength bigger and The advantage that service life is longer.
The early strength index of the Cold Recycled Mixture with Emulsified Asphalt formed by the emulsified asphalt containing the with good grounds present invention, water Stability indicator, high-temperature stability index all surmount regulation in " asphalt highway regeneration techniques specification " (JTG F41-2008) Relevant art index request, thus for quick high-quality ground repair road surface provide the foundation, be effectively utilized asphalt road to be repaired The milling material in face, reduces environmental pollution.
It is by the advantage on the road surface formed according to the Cold Recycled Mixture with Emulsified Asphalt of the present invention: road surface can quick shape Become intensity, within 2~3 days, i.e. can be taken off complete core sample, and core sample intensity exceedes " asphalt highway regeneration techniques specification " (JTG F41-2008) the relevant art index request of regulation in, thus it is effectively guaranteed the serviceability rate of existing road.

Claims (10)

1. an emulsified asphalt, it is made up of emulsifying agent, matrix pitch, modifying agent, optional pH value regulator and water, Qi Zhongjia Entering after pH value regulator that the pH value range of emulsified asphalt is between 1.5~6.5, according to the weight meter of emulsified asphalt, it contains: breast Agent 2.0~4.0%, matrix pitch 60~65%, modifying agent 0~4% and appropriate water, wherein said modifying agent is selected from fourth One or more in benzene block copolymer, butadiene-styrene rubber and polyethylene.
Emulsified asphalt the most according to claim 1, it is characterised in that described emulsifying agent contains aminated lignin, aliphatic Amine and water, according to the weight meter of emulsifying agent, it contains: aminated lignin 23~35%, aliphatic amine 23~35% and appropriate Water.
Emulsified asphalt the most according to claim 2, it is characterised in that described aminated lignin is by aminated compounds, aldehyde The product that compounds and lignin obtain through Mannich reaction.
Emulsified asphalt the most according to claim 3, it is characterised in that the described aminated lignin free diethylenetriamine of choosing, Formaldehyde, broad-leaved Masson Pine quality obtain product and by triethylene tetramine, formaldehyde, needle Masson Pine quality through Mannich through Mannich reaction One or more in the product that reaction obtains.
Emulsified asphalt the most according to claim 2, it is characterised in that the carbon number of described aliphatic amine is 12-22, amine Base group is primary amine and/or secondary amine.
Emulsified asphalt the most according to claim 2, it is characterised in that the carbon number of aliphatic amine is 16, amine groups For secondary amine.
7. a Cold Recycled Mixture with Emulsified Asphalt, its contain milling material, newly gather materials, optional breeze, emulsified asphalt, optional Cement and water, according to the weight meter of Cold Recycled Mixture with Emulsified Asphalt, it contains: milling material 60~95%, cement 0~2%, Breeze 0~5%, emulsified asphalt 3.5-5%, external adding water 1~4% and appropriate newly gathering materials, it is characterised in that emulsified asphalt is Emulsified asphalt described in any one of claim 1-6.
Compound the most according to claim 7, it is characterised in that the early strength of described compound is tested by selected from brush The parameter of mass loss and/or rut plate coring integrity degree represents, wherein the loss of brush test mass is not more than 2.0%, rut Plate coring integrity degree is not less than 80%.
Compound the most according to claim 7, it is characterised in that the intensity index of described compound, water stability index And/or high-temperature stability index all surmounts the corresponding of " asphalt highway regeneration techniques specification " (JTG F41-2008) middle regulation Technical requirement.
10. a road surface, it is characterised in that described road surface is by Cold Recycled Mixture with Emulsified Asphalt shape as claimed in claim 7 Become, complete core sample within after described pavement construction molding 2~3 days, can be taken out, and the intensity index of complete core sample surmounts " highway asphalt road Face regeneration techniques specification " (JTG F41-2008) middle relevant art index request specified.
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