CN106116095B - A kind of sludge dryer and the method using the drying machine drying sludge - Google Patents

A kind of sludge dryer and the method using the drying machine drying sludge Download PDF

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Publication number
CN106116095B
CN106116095B CN201610627332.1A CN201610627332A CN106116095B CN 106116095 B CN106116095 B CN 106116095B CN 201610627332 A CN201610627332 A CN 201610627332A CN 106116095 B CN106116095 B CN 106116095B
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container
octaphenyl
sludge
silsesquioxane
weight
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CN106116095A (en
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郑经耀
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/02—Biological treatment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents

Abstract

The invention discloses a kind of sludge dryers, comprising: rack, supporting mechanism, driving device, agitating device and container；The container is set up on the rack by supporting mechanism；The agitating device is set in the container；The driving device is located on the supporting mechanism, positioned at the container side and connect with agitating device；Heating layer, the upper end setting material feed inlet and observation panel of the container, the entrance of lower end the setting material outlet and heat source of the container, the outlet of the side setting heat source of the container and decompression vacuum pumping mouth is arranged in the outside of the container.The invention also discloses the methods for using the sludge dryer to dry sludge.

Description

A kind of sludge dryer and the method using the drying machine drying sludge
Technical field
The present invention relates to mud drying technology fields, more particularly to one kind is simultaneously using the baking of the sludge of stirring and heat treatment Dry machine and the method for using the drying machine drying sludge.
Background technique
Sludge mainly contains rudimentary organic as remaining residue after sewage collecting processing, standard water discharge discharge Object, polycyclic aromatic hydrocarbon, heterocycle compound, organic sulfur compound, volatility foreign odor object, organic fluoride etc..It is wherein rudimentary organic Object can be amino acid, humic acid, bacterium and its metabolite.In addition, the also heavy metals object containing organic/inorganic substance and mercury, cadmium, lead etc. Matter.
The method that China's processing municipal sludge takes landfill mostly, municipal sludge are sent to suburb and topple over and cover with producing with fortune It buries.The municipal sludge being landfilled easily becomes pollution source, and atmosphere, water body, soil are polluted and endangered, harm Degree and persistence be much larger than waste water, such as without proper treatment and it is rationally effective recycle, will lead to and handling sewage While produce new even more serious pollution, make people survive environment further deteriorate, ecological environment is difficult to repair.
In the prior art, it is generally handled using sludge dryer, but structure is complicated for existing sludge dryer, volume It is big and at high cost, it is also very desirable to which that a kind of simple and high-efficient sludge dryer of structure and a kind of ring are obtained by technological improvement The method for protecting efficient drying sludge.
Summary of the invention
To solve the above-mentioned problems, one aspect of the present invention provides a kind of sludge dryer, comprising: rack, support machine Structure, driving device, agitating device and container；
The container is set up on the rack by the supporting mechanism；
The agitating device is set in the container；
The driving device is located on the supporting mechanism, positioned at the container side and connect with agitating device；
Heating layer is arranged in the outside of the container, and material feed inlet is arranged in the upper end of the container, the container
The entrance of material outlet and heat source is arranged in lower end, and the outlet and decompression of the side setting heat source of the container are taken out
Vacuum port.
In one embodiment, the material of container at least one selected from the group below: stainless steel, cast iron and glass is warded off Glass.
In one embodiment, the agitating device includes agitating shaft and paddle, and the agitating shaft is in the container In extend along the horizontal plane, the stirring blade spirally along the agitating shaft be distributed.
In one embodiment, the agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane-modified The mixture of the poly- pyrrole throat block copolymer of polyetheramine-and polytetrafluoroethylene (PTFE).
Another aspect of the present invention provides the method using the sludge dryer drying sludge, comprising:
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping in container；And
Discharging.
In one embodiment, the stirring rate is 1-1000 revs/min.
In one embodiment, heat source at least one selected from the group below: steam, hot coal oil, high-temperature water and useless Gas.
In one embodiment, before container being added in sludge, further include the steps that mixing sludge with treatment agent, The treatment agent include: the calcium chloride of 10 parts by weight, the cellulase of 1-2 parts by weight, 30-50 parts by weight ethylene glycol and Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl of 2-10 parts by weight.
In one embodiment, the treatment agent include: the calcium chloride of 10 parts by weight, 2 parts by weight cellulase, Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl of the ethylene glycol of 40 parts by weight and 8 parts by weight.
In one embodiment, the preparation side of eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl Method are as follows:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:10-20 is down to room temperature, pours into deionized water, sufficiently wash after reacting 5-10h at 80 DEG C -120 DEG C It washs to neutrality, filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtain partly sulfonated eight silicon sesquialter oxygen of octaphenyl Alkane；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:(1-2): (10-20), after reacting 5-10h at 180 DEG C, be down to room temperature, pour into acetone, sufficiently after washing, filter and in It is 12 hours dry at 120 DEG C in vacuum drying oven, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl.
The above-mentioned of the application and other features, aspects and advantages are more readily understood with reference to following detailed description.
Figure of description
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
Fig. 1: sludge dryer schematic diagram
1: rack；2: supporting mechanism；3: driving device；4: agitating device；5: container；7: material feed inlet；8: material goes out Mouthful；9: decompression vacuum pumping mouth；10: thermal source inlet；11: the outlet of heat source；12: agitating shaft；13: paddle.
Fig. 2: sludge dryer left view
3: driving device；5: container；6: heating layer；7: material feed inlet.
Specific embodiment
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily to understand Bright content.Unless otherwise defined, all technologies used herein and scientific term have common with fields of the present invention The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... preparation " it is synonymous with "comprising".Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this Phrase will make claim closed, so that it is not included the material in addition to the material of those descriptions, but relative normal Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body, It is only limited to element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit When the Range Representation that choosing value limits, this should be understood as specifically disclosing by any range limit or preferred value and any range Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise the range is intended to include its end Value and all integers and score in the range.
Singular includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " any It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component (i.e. frequency of occurrence) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number The element or component of form also include plural form, unless the obvious purport of the quantity refers to singular.
One aspect of the present invention provides a kind of sludge dryer, structure be include: rack 1, supporting mechanism 2, driving dress Set 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by the supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9.
In one embodiment, the material of container at least one selected from the group below: stainless steel, cast iron and glass is warded off Glass；Preferably, the material of the container is stainless steel.
In one embodiment, the agitating device includes agitating shaft 12 and paddle 13, and the agitating shaft is described Extend along the horizontal plane in container, the stirring blade is spirally distributed along the agitating shaft.
In one embodiment, the agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane-modified The mixture of the poly- pyrrole throat block copolymer of polyetheramine-and polytetrafluoroethylene (PTFE)；Preferably, the silane modified polyether amine-poly- pyrrole The weight ratio of throat block copolymer and polytetrafluoroethylene (PTFE) is 1:5~50；It is highly preferred that the silane modified polyether amine-poly- pyrrole The weight ratio of throat block copolymer and polytetrafluoroethylene (PTFE) is 1:8.
In one embodiment, the silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 1~20 hour, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 1~20 hour, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 1~20 hour, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stir It mixes and reacts 1~5 hour, obtain silane modified polyether amine-poly- pyrrole throat block copolymer.
Although polytetrafluoroethylene (PTFE) high comprehensive performance, thermal expansion coefficient is excessively high, and the service life in this system is not It is long, by the way that silane modified polyether amine-poly- pyrrole throat block copolymer is added, it both can use the very strong rigidity of poly- pyrrole throat and inhibited swollen It is swollen, and can use polyetheramine and obtain good compatibility, the attachment with agitating shaft and paddle can also be improved using silane Power to improve the service life of coating to protect agitating shaft and paddle, thus provides advantageous effects of the invention.
Another aspect of the present invention provides the method using the sludge dryer drying sludge, comprising:
Container 5 is added in sludge；
Start driving device 3, stirring；
Heat source is passed through into heating layer 6；Decompression vacuum pumping and
Discharging.
In one embodiment, the stirring rate is 1-1000 revs/min；Preferably, the stirring rate is 50- 500 revs/min；It is highly preferred that the stirring rate is 300 revs/min.
In one embodiment, heat source at least one selected from the group below: steam, hot coal oil and exhaust gas；It is preferred that Ground, the heat source are hot coal oil.
In one embodiment, before container being added in sludge, further include the steps that mixing sludge with treatment agent, The treatment agent include: the calcium chloride of 10 parts by weight, the cellulase of 1-2 parts by weight, 30-50 parts by weight ethylene glycol and Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl of 2-10 parts by weight；Preferably, the treatment agent includes: The calcium chloride of 10 parts by weight, the cellulase of 2 parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight dodecyl sodium sulfonate Eight silsesquioxane of sodium modification sulphonation octaphenyl.
In one embodiment, the weight that the sludge is mixed with treatment agent is 100:(0.1-5)；Preferably, institute Stating the weight that sludge is mixed with treatment agent is 100:1.
In one embodiment, the preparation side of eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl Method are as follows:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:10-20 is down to room temperature, pours into deionized water, sufficiently wash after reacting 5-10h at 80 DEG C -120 DEG C It washs to neutrality, filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtain partly sulfonated eight silicon sesquialter oxygen of octaphenyl Alkane；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:(1-2): (10-20), after reacting 5-10h at 180 DEG C, be down to room temperature, pour into acetone, sufficiently after washing, filter and in It is 12 hours dry at 120 DEG C in vacuum drying oven, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl.
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl has more relative to common surfactant Good heat resistance and dispersion effect, can effectively improve drying effect and improves drying efficiency, and reduce sludge agglomeration, thus Provide advantageous effects of the invention.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field The some nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
Raw material:
Embodiment 1
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 2
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is cast iron；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 3
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is enamel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 4
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:2；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 5
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7,8, the lower end of the container is arranged in the upper end of the container 5 The entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9 are set；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:10；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 6
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is polytetrafluoroethylene (PTFE)；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 7
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 150 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 8
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is steam, and the temperature of the steam is 140 DEG C.
Embodiment 9
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:0.5, and the treatment agent includes: the chlorination of 10 parts by weight Calcium, the cellulase of 2 parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight eight benzene of dodecyl sodium sulfate modification sulphonation Eight silsesquioxane of base；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 10
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:5, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 40 parts by weight and 8 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 11
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 1 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 30 parts by weight and 2 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 12
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Sludge is mixed with treatment agent；
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The weight ratio of the sludge and treatment agent is 100:1, and the treatment agent includes: the calcium chloride of 10 parts by weight, 2 The dodecyl sodium sulfate modification sulphonation octaphenyl eight of the cellulase of parts by weight, the ethylene glycol of 50 parts by weight and 10 parts by weight Silsesquioxane；
Eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl the preparation method comprises the following steps:
(1) by eight silsesquioxane of octaphenyl dissolution in concentrated sulfuric acid, eight silsesquioxane of octaphenyl with it is described dense The weight ratio of sulfuric acid is that 1:15 is down to room temperature, pours into deionized water after reacting 8h at 90 DEG C, sufficiently after washing to neutrality, mistake It filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtains partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in more In polyphosphoric acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids For 1:1.2:15, after reacting 6h at 180 DEG C, it is down to room temperature, is poured into acetone, sufficiently after washing, filtered and in vacuum drying oven It is 12 hours dry at 120 DEG C, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil, and the temperature of the hot coal oil is 250 DEG C.
Embodiment 13
Sludge dryer used, structure be include: rack 1, supporting mechanism 2, driving device 3, agitating device 4 and container 5；
The container 5 is erected in rack 1 by supporting mechanism 2；
The agitating device 4 is located in the container 5；
The driving device 3 is located on the supporting mechanism 2, positioned at the container 5 side and with agitating device 4 connect It connects；Heating layer 6 is arranged in the outside of the container, and material feed inlet 7 is arranged in the upper end of the container 5, and the lower end of the container is set Set the entrance 10 of material outlet 8 and heat source, the outlet 11 of the side setting heat source of the container and decompression vacuum pumping mouth 9；
The material of the container is stainless steel；
The agitating device includes agitating shaft 12 and paddle 13, the agitating shaft 12 in the container 5 along the horizontal plane Extend, the stirring blade 13 is spirally distributed along the agitating shaft 12；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block The mixture of copolymer and polytetrafluoroethylene (PTFE), and the silane modified polyether amine-poly- pyrrole throat block copolymer and polytetrafluoro The weight ratio of ethylene is 1:8；
The protective layer the preparation method comprises the following steps: by silane modified polyether amine-poly- pyrrole throat block copolymer and Du Pont's coating After TE3875 is by weight mixing, coated on agitating shaft and paddle, then dries and obtain at 100 DEG C；
The silane modified polyether amine-poly- pyrrole throat block copolymer the preparation method comprises the following steps:
(1) 0.09mol tetracid and 0.1mol tetramine monomers are dissolved in 100ml dimethyl sulfoxide, at 200 DEG C, stirring And react 5 hours, it obtains tetramine and blocks poly- pyrrole throat pre-polymer solution；
(2) 0.09mol benzylamine and 25g epoxy resin E51 are dissolved in 180ml dimethyl sulfoxide, at 80 DEG C, stirring is simultaneously Reaction 5 hours, obtains epoxy-capped polyetheramine pre-polymer solution；
(3) above-mentioned tetramine poly- pyrrole throat pre-polymer solution is blocked to mix with epoxy-capped polyetheramine pre-polymer solution, and At 80 DEG C, after stirring and reacting 8 hours, 0.02mol amino silicane coupling agent KH-550 is added, and at 80 DEG C, stirring is simultaneously Reaction 3 hours, obtains silane modified polyether amine-poly- pyrrole throat block copolymer；
Use the method for the sludge dryer drying sludge, comprising:
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging；
The water content of the sludge is 85%；
The stirring rate is 300 revs/min, mixing time 60min；
The heat source is hot coal oil.
Test method
Water cut test: the moisture content of material of the test by dryer processing.
Appearance: whether material of the observation by dryer processing is uniformly dispersed, if has obvious agglomeration.
Agitating shaft and paddle coating stability: observation coating cracked time.
Table 1
Example Moisture content Appearance Service life The coating cracking time
Embodiment 1 13% It is uniformly dispersed, no agglomeration At least 5 years 3600 hours
Embodiment 2 15% It is uniformly dispersed, no agglomeration At least 3 years 3600 hours
Embodiment 3 13% It is uniformly dispersed, no agglomeration At least 3 years 3600 hours
Embodiment 4 15% It is uniformly dispersed, no agglomeration At least 5 years 2800 hours
Embodiment 5 14% It is uniformly dispersed, no agglomeration At least 5 years 2300 hours
Embodiment 6 14% It is uniformly dispersed, no agglomeration At least 5 years 800 hours
Embodiment 7 22% It is uniformly dispersed, no agglomeration At least 5 years 3600 hours
Embodiment 8 25% It is uniformly dispersed, no agglomeration At least 5 years 3600 hours
Embodiment 9 34% Dispersion is uneven, a small amount of to agglomerate At least 5 years 3600 hours
Embodiment 10 32% Dispersion is uneven, a small amount of to agglomerate At least 5 years 3600 hours
Embodiment 11 33% Dispersion is uneven, a small amount of to agglomerate At least 5 years 3600 hours
Embodiment 12 30% Dispersion is uneven, a small amount of to agglomerate At least 5 years 3600 hours
Embodiment 13 46% Dispersion is uneven, a large amount of to agglomerate At least 5 years 3600 hours
Above data can be seen that through sludge dryer and dry the technological improvement of sludge method, and the application obtains A kind of method of the drying sludge of a kind of structure simple and high-efficient sludge dryer and environment-friendly high-efficiency, thus provides Advantageous effects of the invention.
Example above-mentioned is merely illustrative, some features of the feature for explaining the disclosure.The attached claims It is intended to the range as wide as possible for requiring to be contemplated that, and embodiments as presented herein is only according to all possible embodiment Combined selection embodiment explanation.Therefore, the purpose of applicant is that the attached claims are not illustrated the present invention Feature exemplary selectional restriction.And the progress in science and technology will be formed language express it is inaccurate due to and not The possible equivalent being presently considered or son replacement, and these variations should also be interpreted in the conceived case by appended Claim covering.

Claims (8)

1. a kind of sludge dryer characterized by comprising rack, supporting mechanism, driving device, agitating device and container；
The container is set up on the rack by the supporting mechanism；
The agitating device is set in the container；
The driving device is located on the supporting mechanism, positioned at the container side and connect with agitating device；
Heating layer is arranged in the outside of the container, and material feed inlet, the side setting of the container is arranged in the upper end of the container Offgas outlet, the entrance of lower end the setting material outlet and heat source of the container, the outlet of the side setting heat source of the container With decompression vacuum pumping mouth；
The agitating device includes agitating shaft and paddle, and the agitating shaft extends along the horizontal plane in the above-described container, described to stir Blade is mixed spirally to be distributed along the agitating shaft；
The agitating shaft and paddle apply matcoveredn outside, and the protective layer is silane modified polyether amine-poly- pyrrole throat block copolymerization The mixture of object and polytetrafluoroethylene (PTFE).
2. sludge dryer as described in claim 1, which is characterized in that the material of the container selected from the group below at least one Kind: stainless steel, cast iron and enamel.
3. using the method for the described in any item sludge dryer drying sludge of claim 1-2 characterized by comprising
Container is added in sludge；
Start driving device, stirring；
Heat source is passed through into heating layer；Decompression vacuum pumping and
Discharging.
4. method as claimed in claim 3, which is characterized in that the stirring rate is 1-1000 revs/min.
5. method as claimed in claim 3, which is characterized in that the heat source at least one selected from the group below: steam, hot coal oil And exhaust gas.
6. method as claimed in claim 3, which is characterized in that further include by sludge and processing before container is added in sludge The step of medicament mixes, the treatment agent include: the calcium chloride of 10 parts by weight, the cellulase of 1-2 parts by weight, 30-50 weight Measure the ethylene glycol of part and eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl of 2-10 parts by weight.
7. method as claimed in claim 6, which is characterized in that the treatment agent includes: the calcium chloride of 10 parts by weight, 2 weights Measure the cellulase, the ethylene glycol of 40 parts by weight and eight silicon of dodecyl sodium sulfate modification sulphonation octaphenyl of 8 parts by weight of part Sesquioxyalkane.
8. the method for claim 7, which is characterized in that eight silicon of dodecyl sodium sulfate modification sulphonation octaphenyl times Half oxygen alkane the preparation method comprises the following steps:
(1) in concentrated sulfuric acid by the dissolution of eight silsesquioxane of octaphenyl, eight silsesquioxane of octaphenyl and the concentrated sulfuric acid Weight ratio be that 1:10-20 is down to room temperature, pours into deionized water after reacting 5-10h at 80 DEG C -120 DEG C, sufficiently washing is extremely After neutrality, filters and 12 hours dry at 120 DEG C in vacuum drying oven, obtain partly sulfonated eight silsesquioxane of octaphenyl；
(2) partly sulfonated eight silsesquioxane of octaphenyl and dodecyl sodium sulfate obtained above are dissolved in poly phosphorus In acid, the weight ratio of partly sulfonated eight silsesquioxane of octaphenyl, dodecyl sodium sulfate and polyphosphoric acids is 1: (1-2): (10-20) is down to room temperature, pours into acetone after reacting 5-10h at 180 DEG C, sufficiently after washing, filters and in vacuum It is 12 hours dry at 120 DEG C in baking oven, obtain eight silsesquioxane of dodecyl sodium sulfate modification sulphonation octaphenyl.
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