CN106115836A - A kind of Organic fluoride chemical industry waste water treating agent and preparation method thereof - Google Patents
A kind of Organic fluoride chemical industry waste water treating agent and preparation method thereof Download PDFInfo
- Publication number
- CN106115836A CN106115836A CN201610479673.9A CN201610479673A CN106115836A CN 106115836 A CN106115836 A CN 106115836A CN 201610479673 A CN201610479673 A CN 201610479673A CN 106115836 A CN106115836 A CN 106115836A
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- waste water
- chemical industry
- treating agent
- organic fluoride
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Treatment Of Sludge (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a kind of Organic fluoride chemical industry waste water treating agent and preparation method thereof, formulated by following parts by weight of component: activated sludge 40 60 parts, 10 20 parts of marine mineral mud, tributyl citrate 8 10 parts, polyacrylamide 12 15 parts, myristyl benzyl dimethyl ammonium chloride 58 parts, sodium silicate 57 parts, poly-epoxy succinic acid 24 parts, waterglass 35 parts, silver nitrate 13 parts, cellulose acetate 57 parts, expanded perlite 10 15 parts, bentonite 10 13 parts, glass bead 24 parts, 36 parts of nanometer titanium dioxide carbon, activated alumina 35 parts, adsorption aid 35 parts, 50 60 parts of water.The Organic fluoride chemical industry waste water treating agent of the present invention, adsorption is strong, can be by organic pollution permineralization Cheng Shui and inorganic ions, and non-secondary pollution has good treatment effect, and can purify water waste water from organic fluorine industry.
Description
Technical field
The present invention relates to waste water from organic fluorine industry processing technology field, particularly relate to a kind of Organic fluoride chemical industry waste water treating agent and
Preparation method.
Background technology
Organic fluoride purposes is wide, wide in variety, is the primary raw material of synthesis fluoro-containing macromolecule material.Along with domestic fluorine-containing poly-
The development that compound produces, the pollution of organic fluoride is day by day serious, and wherein the production of fluoroplastics and fluorubber begins to take shape, often
During year produces thousands of tons of fluoroplastics and up to a hundred tons of fluorubber, also produce the generation of the organic fluoride waste water of hundreds of tons.Mesh
The difficulty of front Organic fluoride production wastewater treatment is very big, is not the most specifically designed to the inorganic agent processing Organic fluoride wastewater from chemical industry.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of Organic fluoride chemical industry waste water treating agent, specific surface
Long-pending big, pore structure is reasonable, and adsorption is strong, can be by organic pollution permineralization Cheng Shui and inorganic ions, non-secondary pollution,
Waste water from organic fluorine industry is had good treatment effect, and there is good bactericidal action, can purify water.
To achieve these goals, the present invention adopts the following technical scheme that
A kind of Organic fluoride chemical industry waste water treating agent, formulated by following parts by weight of component: activated sludge 40-60 part, sea
End mineral mud 10-20 part, tributyl citrate 8-10 part, polyacrylamide 12-15 part, myristyl benzyl dimethyl ammonium chloride
5-8 part, sodium silicate 5-7 part, poly-epoxy succinic acid 2-4 part, waterglass 3-5 part, silver nitrate 1-3 part, cellulose acetate 5-7 part,
Expanded perlite 10-15 part, bentonite 10-13 part, glass bead 2-4 part, nanometer titanium dioxide carbon 3-6 part, activated alumina 3-5
Part, adsorption aid 3-5 part, water 50-60 part.
Described adsorption aid is made up of the raw material of following weight portion: volcanic rock 10-15 part, deer natural pond soil 5-8 part, bicarbonate
Sodium 1-3 part, polyacrylamide 2-4 part, ceria 2-3 part, cork 10-13 part, bamboo fibre 10-13 part;Preparation method be by
Volcanic rock, cork, bamboo fibre are dried 1-1.5 hour under the conditions of 100-120 DEG C, are ground into 40-60 mesh powder, are subsequently adding surplus
Remaining raw material and suitable quantity of water stir, and form purees, are then placed in carbonization 2-3 hour in the retort of 400-500 DEG C, take out
It is ground into 80-100 mesh powder after cooling, soaks 1.5-2 hour with the acetum of 50%-60%, filter, take filtering residue and add 1.5-
The pure water of 2 times amount grinds 40-50 minute to obtain slurry.
The preparation method of described Organic fluoride chemical industry waste water treating agent, comprises the following steps:
(1) weigh each component according to above-mentioned weight ratio, add water in blender;
(2) by activated sludge, marine mineral mud, tributyl citrate, polyacrylamide, myristyl benzyl dimethyl chlorine
Change ammonium to add in blender, stir 5-8 minute;
(3) by sodium silicate, cellulose acetate, expanded perlite, bentonite, glass bead, nanometer titanium dioxide carbon, active oxygen
Change aluminum and add in blender, control temperature 50-70 DEG C, stir 10-20 minute;
(4) remaining ingredient is added in blender, control temperature 40-50 DEG C, stir 20-30 minute;
(5), after stirring terminates, inorganic agent is packed.
Compared with the prior art, beneficial effects of the present invention is as follows:
The Organic fluoride chemical industry waste water treating agent of the present invention, specific surface area is big, and pore structure is reasonable, and adsorption is strong, can be by
Organic pollution permineralization Cheng Shui and inorganic ions, non-secondary pollution, waste water from organic fluorine industry is had good treatment effect, and
There is good bactericidal action, can purify water.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated, but the present invention is not limited only to these embodiments, not
On the premise of departing from present inventive concept, within any improvement made all falls within protection scope of the present invention.
Embodiment 1:
A kind of Organic fluoride chemical industry waste water treating agent, formulated by following parts by weight of component: activated sludge 50 parts, submarine mine
15 parts of thing mud, tributyl citrate 10 parts, polyacrylamide 15 parts, myristyl benzyl dimethyl ammonium chloride 6 parts, sodium silicate 6
Part, poly-epoxy succinic acid 3 parts, waterglass 5 parts, silver nitrate 2 parts, cellulose acetate 5 parts, expanded perlite 12 parts, bentonite 12
Part, glass bead 3 parts, 5 parts of nanometer titanium dioxide carbon, activated alumina 5 parts, adsorption aid 4 parts, 60 parts of water.
Described adsorption aid is made up of the raw material of following weight portion: 10 parts of volcanic rock, 5 parts of deer natural pond, sodium bicarbonate 2 parts,
Polyacrylamide 3 parts, ceria 2 parts, cork 10 parts, bamboo fibre 13 parts;Preparation method is by volcanic rock, cork, bamboo fibre
It is dried 15 hours under the conditions of 100 DEG C, is ground into 50 mesh powder, is subsequently adding surplus stock and suitable quantity of water stirs, formed
Purees, is then placed in carbonization 2 hours in the retort of 450 DEG C, is ground into 100 mesh powder, with the vinegar of 55% after taking out cooling
Acid solution soak 2 hours, filter, take filtering residue add 2 times amount pure water grind 50 minutes slurry.
The preparation method of described Organic fluoride chemical industry waste water treating agent, comprises the following steps:
(1) weigh each component according to above-mentioned weight ratio, add water in blender;
(2) by activated sludge, marine mineral mud, tributyl citrate, polyacrylamide, myristyl benzyl dimethyl chlorine
Change ammonium to add in blender, stir 8 minutes;
(3) by sodium silicate, cellulose acetate, expanded perlite, bentonite, glass bead, nanometer titanium dioxide carbon, active oxygen
Change aluminum and add in blender, control temperature 60 C, stir 20 minutes;
(4) remaining ingredient is added in blender, control temperature 45 C, stir 25 minutes;
(5), after stirring terminates, inorganic agent is packed.
Claims (3)
1. an Organic fluoride chemical industry waste water treating agent, it is characterised in that: formulated by following parts by weight of component: activated sludge
40-60 part, marine mineral mud 10-20 part, tributyl citrate 8-10 part, polyacrylamide 12-15 part, dodecyldimethylamine base
Benzyl ammonium chloride 5-8 part, sodium silicate 5-7 part, poly-epoxy succinic acid 2-4 part, waterglass 3-5 part, silver nitrate 1-3 part, acetic acid fibre
Dimension element 5-7 part, expanded perlite 10-15 part, bentonite 10-13 part, glass bead 2-4 part, nanometer titanium dioxide carbon 3-6 part, work
Property aluminium oxide 3-5 part, adsorption aid 3-5 part, water 50-60 part.
Organic fluoride chemical industry waste water treating agent the most according to claim 1, it is characterised in that: described adsorption aid is by following
The raw material of weight portion is made: volcanic rock 10-15 part, deer natural pond soil 5-8 part, sodium bicarbonate 1-3 part, polyacrylamide 2-4 part, dioxy
Change cerium 2-3 part, cork 10-13 part, bamboo fibre 10-13 part;Preparation method is at 100-120 DEG C by volcanic rock, cork, bamboo fibre
Under the conditions of be dried 1-1.5 hour, be ground into 40-60 mesh powder, be subsequently adding surplus stock and suitable quantity of water stirs, formed mud
Shape thing, is then placed in carbonization 2-3 hour in the retort of 400-500 DEG C, is ground into 80-100 mesh powder after taking out cooling, uses
The acetum of 50%-60% soaks 1.5-2 hour, filters, and takes filtering residue and adds the pure water of 1.5-2 times amount and grind 40-50 minute
Slurry.
The preparation method of Organic fluoride chemical industry waste water treating agent the most according to claim 1, it is characterised in that: include following step
Rapid:
(1) weigh each component according to above-mentioned weight ratio, add water in blender;
(2) by activated sludge, marine mineral mud, tributyl citrate, polyacrylamide, myristyl benzyl dimethyl ammonium chloride
Add in blender, stir 5-8 minute;
(3) by sodium silicate, cellulose acetate, expanded perlite, bentonite, glass bead, nanometer titanium dioxide carbon, activated alumina
Add in blender, control temperature 50-70 DEG C, stir 10-20 minute;
(4) remaining ingredient is added in blender, control temperature 40-50 DEG C, stir 20-30 minute;
(5), after stirring terminates, inorganic agent is packed.
Priority Applications (1)
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CN201610479673.9A CN106115836A (en) | 2016-06-27 | 2016-06-27 | A kind of Organic fluoride chemical industry waste water treating agent and preparation method thereof |
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CN201610479673.9A CN106115836A (en) | 2016-06-27 | 2016-06-27 | A kind of Organic fluoride chemical industry waste water treating agent and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106430509A (en) * | 2016-12-22 | 2017-02-22 | 郑州丽福爱生物技术有限公司 | Environment-friendly heavy metal sewage treatment agent and preparation method thereof |
CN106630085A (en) * | 2016-12-22 | 2017-05-10 | 郑州丽福爱生物技术有限公司 | Environment-friendly treating agent for heavy metal-containing wastewater |
CN109095542A (en) * | 2018-09-26 | 2018-12-28 | 深圳市裕农科技股份有限公司 | A kind of clarifying agent and preparation method thereof |
-
2016
- 2016-06-27 CN CN201610479673.9A patent/CN106115836A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106430509A (en) * | 2016-12-22 | 2017-02-22 | 郑州丽福爱生物技术有限公司 | Environment-friendly heavy metal sewage treatment agent and preparation method thereof |
CN106630085A (en) * | 2016-12-22 | 2017-05-10 | 郑州丽福爱生物技术有限公司 | Environment-friendly treating agent for heavy metal-containing wastewater |
CN109095542A (en) * | 2018-09-26 | 2018-12-28 | 深圳市裕农科技股份有限公司 | A kind of clarifying agent and preparation method thereof |
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Application publication date: 20161116 |